CN106120320B - A kind of glossy scrooping finiss agent - Google Patents
A kind of glossy scrooping finiss agent Download PDFInfo
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- CN106120320B CN106120320B CN201610578834.XA CN201610578834A CN106120320B CN 106120320 B CN106120320 B CN 106120320B CN 201610578834 A CN201610578834 A CN 201610578834A CN 106120320 B CN106120320 B CN 106120320B
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- scrooping
- finiss
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
Abstract
The invention discloses a kind of glossy scrooping finiss agent, include following components by mass parts：30 60 parts of epoxidised long chain fatty acids or alcohol ether analog derivative, 10 30 parts of natural oil, 10 30 parts of machinery oil, 20 40 parts of water.The glossy scrooping finiss agent appearance of the present invention is milky fluid, solidification point at 10 DEG C hereinafter, pH value is between 67, solid content >=45%, in aqueous solution stable and uniform disperse.The glossy scrooping finiss agent of the present invention is nontoxic, nuisanceless, sufficient biological degradability, with significant greasy feeling, scroop effect, shelf-stable can be applied to the big tmaterial finishing technique of pure cotton, and it is good in other finishing agent compatibility, this product is cost-effective, improves fabric class and added value, has the preferable market advantage.
Description
One, technical field
The present invention relates to a kind of textile touch finishing agent, specifically a kind of glossy scrooping finiss agent is applied to spin
Knitting pure cotton fabric has glossy gloss and scroop effect.
Two, background technology
In recent years, the big tmaterial of glossy pure cotton with scroop effect has reality in great demand in Africa, Middle East
Demand.What is meant by scroopThe snowy day like at the beginning of winter, visitor's slow step snowfield, " cluck creak " sound that foot steps on that new snow sent out.In addition, hand is pinched
Edible tulip dry powder can similarly send out this sound.When it is because of friction is mutually generated between object under external force, because shaking
Dynamic sent out sound.
Scroop is exactly fiber by outer force effect, and fiber surface generates phase mutual friction, makes fiber vibration and the sound that sends out.Cause
This, scroop effect (power of scroop sound) is mainly derived from the friction between Fiber-Fiber, between the power and fiber of effect
Static friction coefficient-dynamic friction coefficient difference (△) it is related, then there is scroop effect in value >=0.02 △, and △ values (+) are more
Greatly, then scroop effect is more apparent.
The excessively related scroop agent patent of external Mosher et al. invention, they think by certain class it is special contain 10 carbon atoms
After on above organic compound or their specific derivatives processing to fabric, it can assign fiber apparent scroop effect,
And there is certain persistence.Stephens and Allen et al. use polyhydroxy or the water-insoluble ester of monohydroxy compound
Class compound handles silk or artificial silk, to assigning fabric with scroop effect.
The first printing and dyeing mill of Shanghai dissects import scrooping finiss agent, and oneself has developed scrooping finiss agent SH (A types
And Type B), A types are Paraffinic, and Type B is non-Paraffinic.Two kinds have problem when in use, and A types also need to add when in use
Other to help ring agent, scroop effect is poor and generates oil mark, and though poor storage stability does not generate oil mark after Type B stability,
Due to its be applied to fiber surface △ values it is relatively low, scroop is not sufficiently effective, and persistence is poor.
Three, invention content
The present invention is intended to provide a kind of glossy scrooping finiss agent, is applied to weaving pure cotton fabric, superior performance improves economical
Benefit.
The glossy scrooping finiss agent of the present invention, includes following components by mass parts：
30-60 parts of epoxidised long chain fatty acids or alcohol ether analog derivative, 10-30 parts of natural oil, machinery oil 10-30
Part, 20-40 parts of water.
The general structure of the epoxidised long chain fatty acids or alcohol ether analog derivative is：CnH2n(EO)mOH、CnH2n(EO)mCOOH or CnH2n+1(EO)mO；
The sum of carbon atom is 10-18, preferably 16-18 in epoxidised long chain fatty acids or alcohol ether analog derivative；Ring
The value of oxygen number m is 1-9, preferably 2-5.
The natural oil is the mixing of a variety of terpene hydro carbons to be linked in various ways by isoprene or isopentane
Attar of rose can be selected in object, eucalyptus oil, one or more in rosin mix.
The machinery oil is that dimethicone and polyethylene wax mixing are constituted, and the two mass ratio is 1-1.5：1.
It measures according to the ratio and is mixed and stirred for being uniformly dispersed by above-mentioned each component, you can glossy scrooping finiss agent is made, is milky white
Color fluid.The glossy scrooping finiss agent solidification point of the present invention at -10 DEG C hereinafter, pH value is between 6-7, solid content >=45%, in water
Stable and uniform is disperseed in solution.
Glossy scrooping finiss agent provided by the invention is nontoxic, nuisanceless, and solidification point is low, and sufficient biological degradability has
Significant greasy feeling and scroop effect, shelf-stable, this product are applied to the big tmaterial finishing technique of pure cotton, and simultaneous in other finishing agents
Capacitive is good.
Four, specific implementation mode
Specific technical solution of the present invention is described further below by way of specific embodiment.Illustrate below only with example
The mode of act, protection scope of the present invention should not be limited to thoses mentioned above.
Embodiment 1：
Glossy scrooping finiss agent includes following components by mass parts in the present embodiment：
20 parts of cetostearyl alcohol, 20 parts of oleic acid, 20 parts of rosin, 10 parts of dimethicone, 10 parts of polyethylene wax, 20 parts of water.
It measures according to the ratio and is mixed and stirred for being uniformly dispersed by above-mentioned each component, you can glossy scrooping finiss agent is made, is milky fluid.It is real
Apply example 2：
Glossy scrooping finiss agent includes following components by mass parts in the present embodiment：
20 parts of cetostearyl alcohol, 20 parts of linoleic acid, 15 parts of rosin, 15 parts of dimethicone, 10 parts of polyethylene wax, water 20
Part.It measures according to the ratio and is mixed and stirred for being uniformly dispersed by above-mentioned each component, you can glossy scrooping finiss agent is made, is milky stream
Body.
Embodiment 3：
Glossy scrooping finiss agent includes following components by mass parts in the present embodiment：
20 parts of cetostearyl alcohol, 20 parts of linoleic acid, 5 parts of eucalyptus oil, 10 parts of rosin rosin, 15 parts of dimethicone, poly- second
10 parts of alkene wax, 20 parts of water.It measures according to the ratio and is mixed and stirred for being uniformly dispersed by above-mentioned each component, you can glossy scrooping finiss is made
Agent is milky fluid.
Embodiment 4：
Glossy scrooping finiss agent includes following components by mass parts in the present embodiment：
20 parts of cetostearyl alcohol, 20 parts of linoleic acid, 10 parts of eucalyptus oil, 5 parts of rosin rosin, 10 parts of dimethicone, poly- second
15 parts of alkene wax, 20 parts of water.It measures according to the ratio and is mixed and stirred for being uniformly dispersed by above-mentioned each component, you can glossy scrooping finiss is made
Agent is milky fluid.
Product prepared by above-described embodiment is each configured to 20g/L, 40g/L solution, cotton tmaterial is impregnated two respectively
The glossy scroop agent solution of group, impregnates 5-8 minute, control band liquid measure 100% ± 5%, 60 DEG C of preliminary dryings 3-5 minutes, then 105 DEG C are dried
It is dry, static and dynamic friction coefficient is tested, is shown in Table 1.It is listened using feel ear, the fabric after arrangement is overlapped 4 layers, its hand is felt with hand rubbing
Sense, the uniformity, sound listen its scroop sound with ear.
1 glossy scroop agent of table handles cotton tmaterial performance
Through embodiment test result it is found that four groups of embodiment products, are using the glossy scroop agent of 20g/L, 40g/L molten respectively
After liquid pads furnace drying method processing cotton tmaterial, the △ differences of cotton tmaterial static friction coefficient-dynamic friction coefficient are all higher than
0.02, and by after arrangement cotton fabric be overlapped 4 layers, with hand rubbing feel its feel, the uniformity, sound, have scroop step on snow sound and
Greasy feeling.Paired observation △ values and handle effect, △ values (+) are bigger, then scroop effect is more apparent.By test result, 15 are placed
Its observation, product are stablized, the scroop effect that processing cotton fabric has still been kept.
The above is only the preferred embodiment of the present invention, it is noted that those skilled in the art, not
Under the premise of being detached from the invention design, several similar modification and improvement can also be made, these also should be regarded as the present invention
Protection domain in.
Claims (5)
1. a kind of glossy scrooping finiss agent, it is characterised in that by mass parts include following components：
30-60 parts of epoxidised long chain fatty acids or alcohol derivatives, 10-30 parts of natural oil, 10-30 parts of machinery oil, water 20-
40 parts；
The general structure of the epoxidised long chain fatty acids or alcohol derivatives is：CnH2n(EO)mOH or CnH2n(EO)m
COOH；
The sum of carbon atom is 10-18 in epoxidised long chain fatty acids or alcohol derivatives, and the value of epoxy number m is 1-9.
2. glossy scrooping finiss agent according to claim 1, it is characterised in that：
The sum of carbon atom is 16-18 in epoxidised long chain fatty acids or alcohol derivatives；The value of epoxy number m is 2-5.
3. glossy scrooping finiss agent according to claim 1, it is characterised in that：
The natural oil is the mixture of a variety of terpene hydro carbons to be linked in various ways by isoprene or isopentane.
4. glossy scrooping finiss agent according to claim 3, it is characterised in that：
The natural oil is that one or more in attar of rose, eucalyptus oil, rosin mix.
5. glossy scrooping finiss agent according to claim 1, it is characterised in that：
The machinery oil is that dimethicone and polyethylene wax mixing are constituted, and the two mass ratio is 1-1.5：1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610578834.XA CN106120320B (en) | 2016-07-21 | 2016-07-21 | A kind of glossy scrooping finiss agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610578834.XA CN106120320B (en) | 2016-07-21 | 2016-07-21 | A kind of glossy scrooping finiss agent |
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| Publication Number | Publication Date |
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| CN106120320A CN106120320A (en) | 2016-11-16 |
| CN106120320B true CN106120320B (en) | 2018-07-27 |
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| CN201610578834.XA Active CN106120320B (en) | 2016-07-21 | 2016-07-21 | A kind of glossy scrooping finiss agent |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107869049A (en) * | 2017-11-30 | 2018-04-03 | 山东黄河三角洲纺织科技研究院有限公司 | A kind of glossy finishing agent of real wax print cloth cover and its preparation method and application technique |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB455782A (en) * | 1935-04-27 | 1936-10-27 | British Celanese | Improvements in the treatment of textile materials |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2995442B2 (en) * | 1992-11-06 | 1999-12-27 | 鐘紡株式会社 | Method for producing silk fibroin-graft polymer processed fabric |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB455782A (en) * | 1935-04-27 | 1936-10-27 | British Celanese | Improvements in the treatment of textile materials |
Non-Patent Citations (1)
| Title |
|---|
| 纤维素纤维织物用丝鸣整理剂的研究和应用;乔向召;《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》;20140115;第B024-63页 * |
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