CN107400740A - A kind of environment-friendly high-efficiency multifunctional leather care agent and preparation method thereof - Google Patents

A kind of environment-friendly high-efficiency multifunctional leather care agent and preparation method thereof Download PDF

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Publication number
CN107400740A
CN107400740A CN201710622410.3A CN201710622410A CN107400740A CN 107400740 A CN107400740 A CN 107400740A CN 201710622410 A CN201710622410 A CN 201710622410A CN 107400740 A CN107400740 A CN 107400740A
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China
Prior art keywords
parts
environment
friendly high
care agent
efficiency multifunctional
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CN201710622410.3A
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张力
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Hefei Far Garment Design Co Ltd
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Hefei Far Garment Design Co Ltd
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Priority to CN201710622410.3A priority Critical patent/CN107400740A/en
Publication of CN107400740A publication Critical patent/CN107400740A/en
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    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C9/00Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
    • C14C9/02Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes using fatty or oily materials, e.g. fat liquoring

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention discloses a kind of environment-friendly high-efficiency multifunctional leather care agent, include the raw material of following parts by weight:55 65 parts of solvent, 7 15 parts of palm oil, 57 parts of coconut fatty acid sodium, 12 parts of surfactant, 13 parts of stabilizer, 0.2 0.4 parts of preservative, 35 parts of NMF, 26 parts of APES, 12 parts of antioxidant, 12 parts of antimildew disinfectant, 8 10 parts of deionized water.The present invention can effectively remove leather surface spot, and and can protects the elasticity of leather, keeps leather effect that is soft, moist, vivid, playing mould proof anti-soil;Preparation method provided by the invention simultaneously, its material cost is relatively low, raw material is easy to get and technique is concise, has higher practical value and good application prospect.

Description

A kind of environment-friendly high-efficiency multifunctional leather care agent and preparation method thereof
Technical field
The present invention relates to leather nursing technical field, and in particular to a kind of environment-friendly high-efficiency multifunctional leather care agent and its system Preparation Method.
Background technology
With people's living standard more and more higher, leather and fur products is gradually entered into daily life, leather shoes, fur clothing, The leathercrafts such as suitcase turn into popular consumer goods.With the increase of usage time, leather and fur products can be hardened, and feel is deteriorated, and loses Gloss, influence attractive in appearance.
Why soft leather is, and when its basic reason is that process hides, grease is introduced to the inside of Animal Skin, is formed comprehensive The oil film of intracutaneous fiber surface is covered, i.e., is separated between intracutaneous fiber surface with the oil film of one layer of suitable depth, so, leather The frictional force moved between internal fiber is equivalent to the frictional force of oil molecule, thus leather will be very soft.But due to drawing Enter grease inside leather in its natural state, can over time remote and slowly volatilize and wander away, or because other reasons make Oil film is destroyed, and under water generation hydrolysis or hot environment, oil film is destroyed, and grease volatilization is wandered away, thus inside leather Will mutually it be bonded together between fiber, so that leather is hardened, become fragile.
Leather care products are to be used to nurse the leather and fur products such as fur clothing, leather sofa, suitcase, skin chair, leather shoes, and make the extensive light of leather It is bright multiple soft such as new product.Although existing leather care products have good effect in terms of softening cortex, feel on the market Fruit, but the injury to leather is too big, also easily skin is faded.
On the other hand it is particularly significant to show cleaning and the nursing of leather and fur products, if leather can not only be damaged by dealing with improperly, can also The feel of leather and fur products is deteriorated, or even destroy the outward appearance of product.Though existing leather decontamination agent can effectively remove leather surface Dirt, but its antifouling property is poor, it is impossible to effectively prevents fur clothing by dirt immune.And there are some researches show, leather is dry and cracked, Mostly it is because leather natural moisture preserving structure disequilibrium.Cause the unbalanced internal and external condition of leather natural moisture preserving structure main Have:With the growth of usage time, leather aging, its moisture-keeping function and barrier function gradually weaken, NMF content Reduce;Cold weather is dried, humidity is relatively low, such as autumn and winter;Environment and chemical factor, such as washing powder, soap, liquid detergent etc. are washed Wash the organic solvents such as agent and alcohol, and prolonged adverse circumstances etc..Therefore, it is necessary to be entered using the leather of suitable care agent Row protection.
The content of the invention
The defects of for prior art, should it is an object of the invention to provide a kind of environment-friendly high-efficiency multifunctional leather care agent Leather care products can effectively remove leather surface spot, and and can protects the elasticity of leather, keep leather it is soft, it is moist, vivid, Play the effect of mould proof anti-soil;Preparation method provided by the invention simultaneously, its material cost is relatively low, raw material is easy to get and technique letter It is bright, there is higher practical value and good application prospect.
The present invention solves technical problem and adopted the following technical scheme that:
The invention provides a kind of environment-friendly high-efficiency multifunctional leather care agent, include the raw material of following parts by weight:
It is solvent 55-65 parts, palm oil 7-15 parts, coconut fatty acid sodium 5-7 parts, surfactant 1-2 parts, stabilizer 1-3 parts, anti- Rotten agent 0.2-0.4 parts, NMF 3-5 parts, APES 2-6 parts, antioxidant 1-2 parts, antimildew disinfectant 1-2 parts, Deionized water 8-10 parts.
Preferably, the environment-friendly high-efficiency multifunctional leather care agent includes the raw material of following parts by weight:
60 parts of solvent, 11 parts of palm oil, 6 parts of coconut fatty acid sodium, 1.5 parts of surfactant, 2 parts of stabilizer, preservative 0.3 Part, 4 parts of NMF, 4 parts of APES, 1.5 parts of antioxidant, 1.5 parts of antimildew disinfectant, 9 parts of deionized water.
Preferably, the solvent be i-octadecanol, alcohol, acetone according to weight than 2:4:The mixture of 1 composition.
Preferably, the surfactant is polyoxyethylene fatty acid ester, fatty acid glycerine fat, neopelex And APES, according to weight than 3:2:1:The mixture of 1 composition.
Preferably, the stabilizer is acrylate copolymer and triphenyl phosphite according to weight ratio 3:The mixing of 2 compositions Thing.
Preferably, the preservative be methyl hydroxybenzoate, ethyl hydroxy benzoate according to weight than 2:The mixture of 1 composition;The guarantor Humectant be polyalcohol, hyaluronic acid according to weight than 1:The mixture of 3 compositions.
Preferably, the antioxidant is tert-butyl group cresols.
Preferably, the antimildew disinfectant be tea tree extract solution, extract solution from aloe, Folium Artemisiae Argyi extractive liquid according to weight than 2:1: The mixture of 2 compositions.
The present invention also provides a kind of preparation method of environment-friendly high-efficiency multifunctional leather care agent, comprises the following steps:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 2-4 DEG C/ Min, 78-84 DEG C is warming up to, stirs 20-30 minutes, speed of agitator 200-300r/min, obtain mixture A;
Step 3, deionized water is heated to 50-60 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, guarantor Humectant, antioxidant are sent into mixer, are stirred 15-25 minutes, speed of agitator 650-750r/min, add step 2 preparation Mixture A, continue to stir 20-30 minutes, add in homogenizer, be 5000-7000r/min in homogeneous speed, homogenizing temperature Control homogeneous 7-9 minutes, cools down the environment-friendly high-efficiency multifunctional leather care agent invented at 80-90 DEG C.
Preferably, the preparation process of the environment-friendly high-efficiency multifunctional leather care agent is:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 3 DEG C/ Min, 81 DEG C are warming up to, stir 25 minutes, speed of agitator 250r/min, obtain mixture A;
Step 3, deionized water is heated to 55 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, moisturizing Agent, antioxidant are sent into mixer, are stirred 20 minutes, speed of agitator 700r/min, add the mixture A of step 2 preparation, Continue stirring 25 minutes, add in homogenizer, be 6000r/min in homogeneous speed, homogenizing temperature is controlled at 85 DEG C, homogeneous 8 Minute, cool down the environment-friendly high-efficiency multifunctional leather care agent invented.
Compared with prior art, the present invention has following beneficial effect:
(1)A kind of environment-friendly high-efficiency multifunctional leather care agent of the present invention, is shared by multi-solvents, is repeatedly stirred in preparation process Mix, homogeneous so that product is easily absorbed by leather, is moist leather agent well, also has good reparation to the leather of rupture Effect.
(2)A kind of antimildew disinfectant of environment-friendly high-efficiency multifunctional leather care agent addition of the present invention, predominantly plant carry Liquid is taken, on the one hand can effectively kill mould, prevents the mildew phenomena of leather surface, the bactericide of another aspect plant source is nontoxic It is harmless, it is useful and harmless to human body.
(3)A kind of environment-friendly high-efficiency multifunctional leather care agent of the present invention with the addition of surfactant, predominantly polyoxy second Alkene fatty acid ester, fatty acid glycerine fat, neopelex and APES, it can effectively remove leather The spot on surface so that it is smooth as new using the leather surface of the care agent of the present invention, effectively remove leather texture dirt and Not damage leathers fabric.
(4)Preservative, the antioxidant added in a kind of environment-friendly high-efficiency multifunctional leather care agent raw material of the present invention can Effectively extend the service life of leather, the NMF of addition can be good at moistening leather agent, control the loss of moisture.
(5)A kind of environment-friendly high-efficiency multifunctional leather care agent of the present invention can effectively remove leather surface spot, and can The elasticity of leather is protected, keeps leather effect that is soft, moist, vivid, playing mould proof anti-soil;Preparation provided by the invention simultaneously Method, its material cost is relatively low, raw material is easy to get and technique is concise, has higher practical value and good application prospect.
Embodiment
With reference to specific embodiment, the technical scheme in the embodiment of the present invention is clearly and completely described, shown So, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based on the reality in the present invention Example is applied, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, is all belonged to In the scope of protection of the invention.
Embodiment 1.
A kind of environment-friendly high-efficiency multifunctional leather care agent of the present embodiment, include the raw material of following parts by weight:
55 parts of solvent, palm oil 7,5 parts of coconut fatty acid sodium, 1 part of surfactant, 1 part of stabilizer, 0.2 part of preservative, moisturizing 3 parts of agent, 2 parts of APES, 1 part of antioxidant, 1 part of antimildew disinfectant, 8 parts of deionized water.
Solvent in the present embodiment is i-octadecanol, alcohol, acetone according to weight than 2:4:The mixture of 1 composition.
Surfactant in the present embodiment is polyoxyethylene fatty acid ester, fatty acid glycerine fat, DBSA Sodium and APES, according to weight than 3:2:1:The mixture of 1 composition.
Stabilizer in the present embodiment is acrylate copolymer and triphenyl phosphite according to weight ratio 3:The mixing of 2 compositions Thing.
Preservative in the present embodiment is methyl hydroxybenzoate, ethyl hydroxy benzoate according to weight than 2:The mixture of 1 composition;The guarantor Humectant be polyalcohol, hyaluronic acid according to weight than 1:The mixture of 3 compositions.
Antioxidant in the present embodiment is tert-butyl group cresols.
Antimildew disinfectant in the present embodiment is tea tree extract solution, extract solution from aloe, Folium Artemisiae Argyi extractive liquid according to weight than 2: 1:The mixture of 2 compositions.
A kind of preparation method of environment-friendly high-efficiency multifunctional leather care agent of the present embodiment, comprises the following steps:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 2 DEG C/ Min, 78 DEG C are warming up to, stir 20 minutes, speed of agitator 200r/min, obtain mixture A;
Step 3, deionized water is heated to 50 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, moisturizing Agent, antioxidant are sent into mixer, are stirred 15 minutes, speed of agitator 650r/min, add the mixture A of step 2 preparation, Continue stirring 20 minutes, add in homogenizer, be 5000r/min in homogeneous speed, homogenizing temperature is controlled at 80 DEG C, homogeneous 7 Minute, cool down the environment-friendly high-efficiency multifunctional leather care agent invented.
Embodiment 2.
A kind of environment-friendly high-efficiency multifunctional leather care agent of the present embodiment, include the raw material of following parts by weight:
65 parts of solvent, 15 parts of palm oil, 7 parts of coconut fatty acid sodium, 2 parts of surfactant, 3 parts of stabilizer, 0.4 part of preservative, 5 parts of NMF, 6 parts of APES, 2 parts of antioxidant, 2 parts of antimildew disinfectant, 10 parts of deionized water.
Solvent in the present embodiment is i-octadecanol, alcohol, acetone according to weight than 2:4:The mixture of 1 composition.
Surfactant in the present embodiment is polyoxyethylene fatty acid ester, fatty acid glycerine fat, DBSA Sodium and APES, according to weight than 3:2:1:The mixture of 1 composition.
Stabilizer in the present embodiment is acrylate copolymer and triphenyl phosphite according to weight ratio 3:The mixing of 2 compositions Thing.
Preservative in the present embodiment is methyl hydroxybenzoate, ethyl hydroxy benzoate according to weight than 2:The mixture of 1 composition;The guarantor Humectant be polyalcohol, hyaluronic acid according to weight than 1:The mixture of 3 compositions.
Antioxidant in the present embodiment is tert-butyl group cresols.
Antimildew disinfectant in the present embodiment is tea tree extract solution, extract solution from aloe, Folium Artemisiae Argyi extractive liquid according to weight than 2: 1:The mixture of 2 compositions.
A kind of preparation method of environment-friendly high-efficiency multifunctional leather care agent of the present embodiment, comprises the following steps:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 4 DEG C/ Min, 84 DEG C are warming up to, stir 30 minutes, speed of agitator 300r/min, obtain mixture A;
Step 3, deionized water is heated to 60 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, moisturizing Agent, antioxidant are sent into mixer, are stirred 25 minutes, speed of agitator 750r/min, add the mixture A of step 2 preparation, Continue stirring 30 minutes, add in homogenizer, be 7000r/min in homogeneous speed, homogenizing temperature is controlled at 90 DEG C, homogeneous 9 Minute, cool down the environment-friendly high-efficiency multifunctional leather care agent invented.
Embodiment 3.
A kind of environment-friendly high-efficiency multifunctional leather care agent of the present embodiment, include the raw material of following parts by weight:
60 parts of solvent, 11 parts of palm oil, 6 parts of coconut fatty acid sodium, 1.5 parts of surfactant, 2 parts of stabilizer, preservative 0.3 Part, 4 parts of NMF, 4 parts of APES, 1.5 parts of antioxidant, 1.5 parts of antimildew disinfectant, 9 parts of deionized water.
Solvent in the present embodiment is i-octadecanol, alcohol, acetone according to weight than 2:4:The mixture of 1 composition.
Surfactant in the present embodiment is polyoxyethylene fatty acid ester, fatty acid glycerine fat, DBSA Sodium and APES, according to weight than 3:2:1:The mixture of 1 composition.
Stabilizer in the present embodiment is acrylate copolymer and triphenyl phosphite according to weight ratio 3:The mixing of 2 compositions Thing.
Preservative in the present embodiment is methyl hydroxybenzoate, ethyl hydroxy benzoate according to weight than 2:The mixture of 1 composition;The guarantor Humectant be polyalcohol, hyaluronic acid according to weight than 1:The mixture of 3 compositions.
Antioxidant in the present embodiment is tert-butyl group cresols.
Antimildew disinfectant in the present embodiment is tea tree extract solution, extract solution from aloe, Folium Artemisiae Argyi extractive liquid according to weight than 2: 1:The mixture of 2 compositions.
A kind of preparation method of environment-friendly high-efficiency multifunctional leather care agent of the present embodiment, comprises the following steps:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 3 DEG C/ Min, 81 DEG C are warming up to, stir 25 minutes, speed of agitator 250r/min, obtain mixture A;
Step 3, deionized water is heated to 55 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, moisturizing Agent, antioxidant are sent into mixer, are stirred 20 minutes, speed of agitator 700r/min, add the mixture A of step 2 preparation, Continue stirring 25 minutes, add in homogenizer, be 6000r/min in homogeneous speed, homogenizing temperature is controlled at 85 DEG C, homogeneous 8 Minute, cool down the environment-friendly high-efficiency multifunctional leather care agent invented.
A kind of environment-friendly high-efficiency multifunctional leather care agent of the present invention can effectively remove leather surface spot, and can protection The elasticity of leather, keep leather effect that is soft, moist, vivid, playing mould proof anti-soil;Preparation side provided by the invention simultaneously Method, its material cost is relatively low, raw material is easy to get and technique is concise, has higher practical value and good application prospect.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (10)

1. a kind of environment-friendly high-efficiency multifunctional leather care agent, it is characterised in that include the raw material of following parts by weight:
It is solvent 55-65 parts, palm oil 7-15 parts, coconut fatty acid sodium 5-7 parts, surfactant 1-2 parts, stabilizer 1-3 parts, anti- Rotten agent 0.2-0.4 parts, NMF 3-5 parts, APES 2-6 parts, antioxidant 1-2 parts, antimildew disinfectant 1-2 parts, Deionized water 8-10 parts.
A kind of 2. environment-friendly high-efficiency multifunctional leather care agent according to claim 1, it is characterised in that the environment-friendly high-efficiency Multifunctional leather care agent includes the raw material of following parts by weight:
60 parts of solvent, 11 parts of palm oil, 6 parts of coconut fatty acid sodium, 1.5 parts of surfactant, 2 parts of stabilizer, preservative 0.3 Part, 4 parts of NMF, 4 parts of APES, 1.5 parts of antioxidant, 1.5 parts of antimildew disinfectant, 9 parts of deionized water.
A kind of 3. environment-friendly high-efficiency multifunctional leather care agent according to claim 1 or 2, it is characterised in that the solvent For i-octadecanol, alcohol, acetone according to weight than 2:4:The mixture of 1 composition.
A kind of 4. environment-friendly high-efficiency multifunctional leather care agent according to claim 1 or 2, it is characterised in that the surface Activating agent is polyoxyethylene fatty acid ester, fatty acid glycerine fat, neopelex and APES, according to Weight is than 3:2:1:The mixture of 1 composition.
A kind of 5. environment-friendly high-efficiency multifunctional leather care agent according to claim 1 or 2, it is characterised in that the stabilization Agent is acrylate copolymer and triphenyl phosphite according to weight ratio 3:The mixture of 2 compositions.
A kind of 6. environment-friendly high-efficiency multifunctional leather care agent according to claim 1 or 2, it is characterised in that the anti-corrosion Agent be methyl hydroxybenzoate, ethyl hydroxy benzoate according to weight than 2:The mixture of 1 composition;The NMF is polyalcohol, hyaluronic acid is pressed According to weight than 1:The mixture of 3 compositions.
A kind of 7. environment-friendly high-efficiency multifunctional leather care agent according to claim 1 or 2, it is characterised in that the antioxygen Agent is tert-butyl group cresols.
8. a kind of environment-friendly high-efficiency multifunctional leather care agent according to claim 1 or 2, it is characterised in that described mould proof Bactericide be tea tree extract solution, extract solution from aloe, Folium Artemisiae Argyi extractive liquid according to weight than 2:1:The mixture of 2 compositions.
A kind of 9. method for preparing environment-friendly high-efficiency multifunctional leather care agent as claimed in claim 1 or 2, it is characterised in that Comprise the following steps:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 2-4 DEG C/ Min, 78-84 DEG C is warming up to, stirs 20-30 minutes, speed of agitator 200-300r/min, obtain mixture A;
Step 3, deionized water is heated to 50-60 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, guarantor Humectant, antioxidant are sent into mixer, are stirred 15-25 minutes, speed of agitator 650-750r/min, add step 2 preparation Mixture A, continue to stir 20-30 minutes, add in homogenizer, be 5000-7000r/min in homogeneous speed, homogenizing temperature Control homogeneous 7-9 minutes, cools down the environment-friendly high-efficiency multifunctional leather care agent invented at 80-90 DEG C.
A kind of 10. preparation method of environment-friendly high-efficiency multifunctional leather care agent according to claim 9, it is characterised in that The preparation process is:
Step 1, each component raw material is weighed on request;
Step 2, by palm oil, coconut fatty acid sodium, APES, solvent mix add container in, with 3 DEG C/ Min, 81 DEG C are warming up to, stir 25 minutes, speed of agitator 250r/min, obtain mixture A;
Step 3, deionized water is heated to 55 DEG C, mixing antimildew disinfectant, surfactant, stabilizer, preservative, moisturizing Agent, antioxidant are sent into mixer, are stirred 20 minutes, speed of agitator 700r/min, add the mixture A of step 2 preparation, Continue stirring 25 minutes, add in homogenizer, be 6000r/min in homogeneous speed, homogenizing temperature is controlled at 85 DEG C, homogeneous 8 Minute, cool down the environment-friendly high-efficiency multifunctional leather care agent invented.
CN201710622410.3A 2017-07-27 2017-07-27 A kind of environment-friendly high-efficiency multifunctional leather care agent and preparation method thereof Withdrawn CN107400740A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085194A (en) * 2017-12-11 2018-05-29 定远县杰仕达体育用品有限公司 A kind of surface cleaning agent used after basketball production
CN111234941A (en) * 2020-01-19 2020-06-05 上海贝能环保科技有限公司 Environment-friendly cleaning agent and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914414A (en) * 2010-07-28 2010-12-15 深圳市洁王精细化工科技有限公司 Cleaning and nursing agent for sports shoes and preparation method thereof
CN104419786A (en) * 2013-08-28 2015-03-18 青岛医防消毒专业技术中心 Improved leather nursing agent
CN105274267A (en) * 2014-07-11 2016-01-27 青岛蓝农谷农产品研究开发有限公司 Mould-proof brightening leather care agent

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914414A (en) * 2010-07-28 2010-12-15 深圳市洁王精细化工科技有限公司 Cleaning and nursing agent for sports shoes and preparation method thereof
CN104419786A (en) * 2013-08-28 2015-03-18 青岛医防消毒专业技术中心 Improved leather nursing agent
CN105274267A (en) * 2014-07-11 2016-01-27 青岛蓝农谷农产品研究开发有限公司 Mould-proof brightening leather care agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085194A (en) * 2017-12-11 2018-05-29 定远县杰仕达体育用品有限公司 A kind of surface cleaning agent used after basketball production
CN111234941A (en) * 2020-01-19 2020-06-05 上海贝能环保科技有限公司 Environment-friendly cleaning agent and preparation method thereof

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Application publication date: 20171128