CN101914414A - Cleaning and nursing agent for sports shoes and preparation method thereof - Google Patents

Abstract

The invention discloses a cleaning and nursing agent for sports shoes and a preparation method thereof. The cleaning and nursing agent for the sports shoes of the invention consists of the following components in percentage by weight: 8 to 27 percent of sodium cocoate, 4 to 9 percent of triethanolamine, 16 to 22 percent of oleic acid, 1 to 10 percent of leather gloss agent, 0 to 3 percent of spice, 0 to 1 percent of softener, 0 to 1 percent of brightening agent and 35 to 66 percent of de-ionized water. The cleaning and nursing agent for the sports shoes of the invention is formed by mixing, combining and emulsifying the natural raw materials, so that the cleaning and nursing agent has the advantages of weak alkalinity, high permeability, water-proof effect and capability of effectively removing dirt in grains of the vamps without damaging the leather and the vamp material, nursing the vamps and increasing the glossiness and thus is an environment-friendly product.

Description

A kind of cleaning and nursing agent for sports shoes and preparation method thereof

[technical field]

The present invention relates to the leather cleaning care products, relate in particular to a kind of cleaning and nursing agent for sports shoes and preparation method thereof.

[background technology]

Because the vamp of sports shoes mostly is white, there is scraggly texture on the surface, and general cleaning maintaining agent is difficult to it is cleaned out.Cleaning and nursing agent for sports shoes on the market is generally alkaline decontamination series, will clean with big water gaging after the use, and is very big to vamp and staff injury, and cleaning and nursing agent for sports shoes decontamination on the market simultaneously is not thorough, and stain is not easy to wash; Sometimes more make spot is infiltrated the vamp top layer, in the gum shoes surfacing material hole, stay dark and gloomy vestige.

[summary of the invention]

The technical problem to be solved in the present invention provide a kind of alkalescence a little less than, cleaning and nursing agent for sports shoes that detersive power is stronger and preparation method thereof.

In order to solve the problems of the technologies described above, the technical solution used in the present invention is, a kind of cleaning and nursing agent for sports shoes is by weight percentage, composed of the following components:

Oleum Cocois resin acid sodium 8-27%;

Trolamine 4-9%;

Oleic acid 16-22%;

Leather gloss agent 1-10%;

Spices 0-3%;

Softener 0-1%;

Brightening agent 0-1%;

Deionized water 35-66%.

Described Oleum Cocois resin acid sodium is lipid acid coconut acid (2-sodium sulfonate) ethyl ester.

Described oleic acid is (Z)-9-octadecenic acid.

Described leather gloss agent is that solid content is greater than 30% carnauba wax emulsion.

Described spices is the food grade lemon flavour, and its main component is the natural lemon essential oil.

Described softener is an active matter content greater than 70% cats product.

Described brightening agent is 4,4 '-two (2-sulfonic benzo vinyl)-1,1 '-biphenyl.

Above-described cleaning and nursing agent for sports shoes, by weight percentage, preferably composed of the following components:

Oleum Cocois resin acid sodium 15-25%;

Trolamine 6-8%;

Oleic acid 19-21%;

Leather gloss agent 5-8%;

Spices 1.5-2.5%;

Softener 0.3-0.5%;

Brightening agent 0.4-0.6%;

Deionized water 35-52%.

A kind of preparation method's of above-mentioned cleaning and nursing agent for sports shoes technical scheme is may further comprise the steps:

1) takes by weighing raw material by above-mentioned weight percent;

2) Oleum Cocois resin acid sodium, oleic acid are put into the oil phase pot, under 50 ℃ of-70 ℃ of conditions, stir 5-15 minute;

3) leather gloss agent, softener, brightening agent, trolamine, deionized water are poured in the water pot, under 35 ℃ of-45 ℃ of conditions, stir 5-15 minute;

4) the vacuum emulsification pot is warming up to 65 ℃-75 ℃, and the material in water pot and the oil phase pot is changed over to, vacuumize, and the beginning stirring and emulsifying, vacuum pressure is controlled at-0.05～-0.08Mpa, stir revolution and be controlled at 3200～3800 rev/mins; The vacuum emulsification time is 15-25 minute;

5) treat to add spices when temperature drops to 35-40 ℃, stirred 3-7 minute, leave standstill then, filter.

The present invention adopts the emulsification of natural matter hybrid combination to form, and a little less than the alkalescence, penetrating quality is good, can effectively remove the dirt of vamp texture and not hinder leather and gum shoes surfacing material, can nurse vamp simultaneously, increase its glossiness, and waterproof action is arranged, be a kind of product of very environmental protection.

[embodiment]

For ease of the present invention is further understood, now describe the present invention in conjunction with specific embodiments: each embodiment prepares raw materials used character and originates as following table:

The component of each embodiment and content such as following table:

The preparation technology of each embodiment is as follows:

1) by last table weight percent take by weighing raw material.

2) Oleum Cocois resin acid sodium, oleic acid are put into 60 ℃ of stirrings of oil phase pot constant temperature 10 minutes.

3) emulsifying wax, softener, brightening agent, trolamine, deionized water are poured 40 ℃ of stirrings of water pot constant temperature 10 minutes into.

4) the emulsification pot of vacuum emulsification stirrer is warming up to 70 ℃, and the material in water pot and the oil phase pot changes over to, vacuumize, and the beginning stirring and emulsifying, vacuum pressure is controlled at-0.05～-0.08Mpa, stir revolution and can be controlled in 3200～3800r/ minute.The vacuum emulsification time is 20 minutes.(equipment used: TFZRJ type vacuum emulsification stirrer WENZHOU TIANFU MACHINERY CO.,LTD)

5) treat to add lemon flavour when temperature drops to 35～40 ℃, stirred 5 minutes.Leave standstill, filter can.

The spices that adopts among each embodiment is the food grade lemon flavour, and its main component is the natural lemon essential oil, and the essence of other odor types also can be used as substitute; Brightening agent adopts 4,4 '-two (2-sulfonic benzo vinyl)-1, and 1 '-biphenyl, the whitening agent of other types also can be used as substitute.The physicochemical property of embodiment and Comparative Examples method and standard relatively:

PH detects the mensuration of pressing GB/T 6368-2008 tensio-active agent, pH value of water solution, and the requirement of potentiometry is tested;

The gloss increased value is tested by 5.4 requirements of QB/T 2478-2007;

The surface discoloration test is the sense organ range estimation, with the blank sample contrast of not handled by greasy dirt.

Instrument: the Shanghai exact science PHS-3F of instrument company thunder magnetic acidometer PH meter;

The grand LQ--AA digital display whiteness instrument of admiring.

Cleaning decontamination maintenance test

Test is white ox-hide with skin, is cut into size and is 10 of the small pieces of 10cm * 10cm, and 2 of each embodiment or Comparative Examples uses clean down with brush, and stay 2 to make blank sample.

A, spot are made

1., stain materials: one in egg, edible oil 5 grams, husky 100 grams of yellow mud, Plantula Brassicae chinensis 50 grams, water 200 grams

2., spot making method: beating eggs is taken out egg white, pickles are chopped into mud, sneak into the egg white edible oil, yellow mud sand, water stir and can obtain into the greasy dirt finished product.

B, spot streak method

Get spot and evenly spread upon test and get final product, smear quantity: 50 gram/sheets with surface.

C, decontamination

Comparative Examples and embodiment sample evenly are sprayed on the greasy dirt place, brush gently one time with brush after 30 seconds, do with clean cloth sassafras then.

The sample that Comparative Examples is used is emperor's space board sneakers decontamination cleanser of ShangHai HuangYu Science Development Co., Ltd.

The material property of embodiment and Comparative Examples contrasts as following table:

The Oleum Cocois resin acid sodium that above embodiment uses is a kind of with the anionic surface of natural coconut oleic acid as raw material.Promoting agent has gentleness, utmost point low irritant, easy biological degradation characteristic; , the influence that its foam performance is splendid, be not subjected to hard water and alkali soap; Because its characteristic is extremely gentle, preserve moisture, rich fat is good, so can play the effect of maintaining leather; Trolamine is an organic bases, warm in nature and, strengthen cleaning function and non-corrosiveness, do not decrease Textileather; Oleic acid has good detergency ability and water-repellancy, and non-stimulated toxicological harmless is stronger with trolamine compatibility clean effect; The carnauba wax emulsion is a leather gloss agent, can improve the filling properties of fat agent simultaneously, improves the penetrating quality of fatting agent in hide fiber, increases the water resistance of leather; Lemon flavour can improve product odour, gives the relaxed and joyful sensation of people; Softener: make leather hand feeling smooth, soft, plentiful; Brightening agent: make leather more glossy.

Material property contrast table according to embodiment and Comparative Examples can see that the performance of each embodiment obviously is better than Comparative Examples.Wherein, embodiment 2 and 3 not only alkalescence a little less than, need not water after the use and clean, vamp and staff are not produced injury, and have good detergency ability, can go out the sports shoes surface blot rapidly, improving the vamp outward appearance, increase the vamp glossiness, is the product of the environmental protection and energy saving of a anhydrous cleaning.

Claims (9)

1. a cleaning and nursing agent for sports shoes is characterized in that, and is by weight percentage, composed of the following components:

Oleum Cocois resin acid sodium 8-27%;

Trolamine 4-9%;

Oleic acid 16-22%;

Leather gloss agent 1-10%;

Spices 0-3%;

Softener 0-1%;

Brightening agent 0-1%;

Deionized water 35-66%.

2. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, described Oleum Cocois resin acid sodium is lipid acid coconut acid (2-sodium sulfonate) ethyl ester.

3. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, described oleic acid is (Z)-9-octadecenic acid.

4. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, described leather gloss agent is that solid content is greater than 30% carnauba wax emulsion.

5. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, described spices is the food grade lemon flavour, and its main component is the natural lemon essential oil.

6. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, described softener is an active matter content greater than 70% cats product.

7. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, described brightening agent is 4,4 '-two (2-sulfonic benzo vinyl)-1,1 '-biphenyl.

8. cleaning and nursing agent for sports shoes according to claim 1 is characterized in that, and is by weight percentage, composed of the following components:

Oleum Cocois resin acid sodium 15-25%;

Trolamine 6-8%;

Oleic acid 19-21%;

Leather gloss agent 5-8%;

Spices 1.5-2.5%;

Softener 0.3-0.5%;

Brightening agent 0.4-0.6%;

Deionized water 35-52%.

9. the preparation method of the described cleaning and nursing agent for sports shoes of claim 1 is characterized in that, may further comprise the steps:

1) takes by weighing raw material by the described weight percent of claim 1;

2) Oleum Cocois resin acid sodium, oleic acid are put into the oil phase pot, under 50 ℃ of-70 ℃ of conditions, stir 5-15 minute;

3) leather gloss agent, softener, brightening agent, trolamine, deionized water are poured in the water pot, under 35 ℃ of-45 ℃ of conditions, stir 5-15 minute;

4) the vacuum emulsification pot is warming up to 65 ℃-75 ℃, and the material in water pot and the oil phase pot is changed over to, vacuumize, and the beginning stirring and emulsifying, vacuum pressure is controlled at-0.05～-0.08Mpa, stir revolution and be controlled at 3200～3800 rev/mins; The vacuum emulsification time is 15-25 minute;

5) treat to add spices when temperature drops to 35-40 ℃, stirred 3-7 minute, leave standstill then, filter.