CN106118824A - A kind of preparation method of solvent cutback soft film anti-rust oil - Google Patents
A kind of preparation method of solvent cutback soft film anti-rust oil Download PDFInfo
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- CN106118824A CN106118824A CN201610490632.XA CN201610490632A CN106118824A CN 106118824 A CN106118824 A CN 106118824A CN 201610490632 A CN201610490632 A CN 201610490632A CN 106118824 A CN106118824 A CN 106118824A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/08—Aldehydes; Ketones
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
- C10M2207/124—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention provides the preparation method of a kind of solvent cutback soft film anti-rust oil, first by D60 solvent naphtha, lanolin magnesium soap, sulfonation lanolin calcium soap, dibutyl phthalate, sodium citrate, barium mahogany sulfonate, petroleum sodium sulfonate, dodecenylsuccinic acid, dinonyl naphthalene sulfonate barium, zinc naphthenate, Cera Flava, trimethylolpropane trimethacrylate mixing, heating, insulated and stirred, obtains the first mixture;Again 3 mercaptopropionic acids, zinc acetylacetonate are added in ethylene glycol, be sequentially added into diethylene glycol, polyglyceryl fatty acid ester and silicone acrylic emulsion, heating, insulated and stirred, obtain the second mixture;Finally the first mixture and the second mixture are mixed, add defoamer, antioxidant, thixotropic agent, antirust agent, stir.The antirust oil of the present invention has good resistance to corrosion, and after the QPQ of 570 DEG C of salt-bath nitriding temperature of 2h processes, carbon steel 45 Steel Piston Rod While salt fog resistance etching time is up to 817h.
Description
Technical field
The invention belongs to antirust oil technical field, be specifically related to the preparation of a kind of QPQ solvent cutback soft film anti-rust oil
Method.
Background technology
QPQ technology is as the Novel clock of its basic process development based on pollution-free Quench-Polish-Quench technology technology
Face treatment technology, product after treatment has high-wearing feature, high corrosion-resistant, but also has the advantages such as deflection is little,
Through being used by increasing producer both at home and abroad.Antirust oil, as the protective material of a kind of metallic article, has with low cost, behaviour
Make easy, effective and the advantage such as easily remove, being industrially widely used, the most a large amount of producing and application.Its
Middle solvent cutback soft film anti-rust oil owing to can form one layer of good adhesion in metal surface after in use solvent volatilization
The antirust oil thin film of property, thus there is excellent rustless property, it is black that the method is particularly suited for sealing antirust indoor environment for a long time up for safekeeping
Normal complexion nonferrous metal product.Adding up according to investigations, the consumption of current solvent cutback soft film anti-rust oil accounts for whole antirust oil consumption
About 20%.
QPQ treatment process, generally as the final treatment process of product, is no longer processed.If in extreme corrosion
Under environment or long-term etching condition, QPQ processes the later stage corrosion rate of product can be accelerated, this is because at later samples table
The compound layer in face is gradually eroded, and what the corrosion resistance in sample heart portion deficiency was caused.And the product after QPQ processes
Coating solvent cutback soft film anti-rust oil after, QPQ technology be greatly improved product itself corrosion proof while, also achieve
Sealing up for safekeeping for a long time of product is antirust, can play etch-proof effect in the transport, storage process of product.Therefore, QPQ technology
In conjunction with the use of solvent cutback soft film anti-rust oil, using workpiece coating solvent cutback soft film anti-rust oil as QPQ technology
Last operation, by can further improve the corrosion resisting property of engineering goods, before machinery industry has and is widely applied very much
Scape.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art to provide the preparation of a kind of solvent cutback soft film anti-rust oil
Method, gained antirust oil has good resistance to corrosion.
The preparation method of a kind of solvent cutback soft film anti-rust oil, comprises the following steps:
Step 1, in parts by weight, by D60 solvent naphtha 10~20 parts, lanolin magnesium soap 3~8 parts, sulfonation lanolin calcium soap 2~7
Part, dibutyl phthalate 1~6 parts, sodium citrate 3~7 parts, barium mahogany sulfonate 2~5 parts, petroleum sodium sulfonate 1~6 parts, ten
Dialkylene succinic acid 3~8 parts, dinonyl naphthalene sulfonate barium 4~7 parts, zinc naphthenate 2~5 parts, Cera Flava 1~6 parts, trihydroxy methyl third
Alkane triacrylate 2~7 parts of mixing, heating, insulated and stirred, obtain the first mixture;
Step 2, in parts by weight, adds 3-mercaptopropionic acid 2~8 parts, zinc acetylacetonate 1~6 parts in ethylene glycol 5~12 parts,
Sequentially add diethylene glycol 3~6 parts, polyglyceryl fatty acid ester 3~6 parts and silicone acrylic emulsion 2~5 parts, heating, insulated and stirred,
Second mixture;
Step 3, in parts by weight, mixes the first mixture and the second mixture, adds defoamer 1~2 parts, antioxidant 1~2
Part, thixotropic agent 1~2 parts, antirust agent 1~2 parts, stir.
Further, described defoamer is emulsified silicone oil.
Further, described antioxidant be 2,6 ditertiary butyl p cresol, 4,4-di-2-ethylhexylphosphine oxide-2,6-di-tert-butylphenol or
One in 3,5-di-tert-butyl-hydroxy phenyl propionic ester.
Further, described thixotropic agent is castor oil hydrogenated or polyamide wax.
Further, in step 1, heating-up temperature is 70~80 DEG C, and temperature retention time is 1~3h.
Further, in step 2, heating-up temperature is 50~70 DEG C, and temperature retention time is 1~3h.
The antirust oil of the present invention has good resistance to corrosion, at the QPQ of 570 DEG C of salt-bath nitriding temperature of 2h
After reason, carbon steel 45 Steel Piston Rod While salt fog resistance etching time is up to 817h.
Detailed description of the invention
Embodiment 1
The preparation method of a kind of solvent cutback soft film anti-rust oil, comprises the following steps:
Step 1, in parts by weight, by D60 solvent naphtha 10 parts, lanolin magnesium soap 3 parts, sulfonation lanolin calcium soap 2 parts, O-phthalic
Dibutyl phthalate 1 part, sodium citrate 3 parts, barium mahogany sulfonate 2 parts, petroleum sodium sulfonate 1 part, dodecenylsuccinic acid 3 parts, dinonyl
Naphthalene sulfonate barium 4 parts, zinc naphthenate 2 parts, 1 part of Cera Flava, trimethylolpropane trimethacrylate 2 parts mixing, heating, insulated and stirred,
Obtain the first mixture;
Step 2, in parts by weight, adds 3-mercaptopropionic acid 2 parts, zinc acetylacetonate 1 part in ethylene glycol 5 parts, sequentially adds
Diethylene glycol 3 parts, polyglyceryl fatty acid ester 3 parts and silicone acrylic emulsion 2 parts, heating, insulated and stirred, obtain the second mixture;
Step 3, in parts by weight, mixes the first mixture and the second mixture, adds defoamer 1 part, 1 part of antioxidant, touches
Become agent 1 part, antirust agent 1 part, stir.
Further, described defoamer is emulsified silicone oil, and antioxidant is 2,6 ditertiary butyl p cresol, and thixotropic agent is hydrogenation
Oleum Ricini;In step 1, heating-up temperature is 70 DEG C, and temperature retention time is 3h;In step 2, heating-up temperature is 50 DEG C, and temperature retention time is 3h.
Gained antirust oil has good resistance to corrosion, after the QPQ of 570 DEG C of salt-bath nitriding temperature of 2h processes
Carbon steel 45 Steel Piston Rod While salt fog resistance etching time is up to 829h.
Embodiment 2
The preparation method of a kind of solvent cutback soft film anti-rust oil, comprises the following steps:
Step 1, in parts by weight, by D60 solvent naphtha 14 parts, lanolin magnesium soap 6 parts, sulfonation lanolin calcium soap 5 parts, O-phthalic
Dibutyl phthalate 3 parts, sodium citrate 6 parts, barium mahogany sulfonate 3 parts, petroleum sodium sulfonate 3 parts, dodecenylsuccinic acid 5 parts, dinonyl
Naphthalene sulfonate barium 6 parts, zinc naphthenate 3 parts, 3 parts of Cera Flava, trimethylolpropane trimethacrylate 5 parts mixing, heating, insulated and stirred,
Obtain the first mixture;
Step 2, in parts by weight, adds 3-mercaptopropionic acid 5 parts, zinc acetylacetonate 3 parts in ethylene glycol 9 parts, sequentially adds
Diethylene glycol 5 parts, polyglyceryl fatty acid ester 4 parts and silicone acrylic emulsion 3 parts, heating, insulated and stirred, obtain the second mixture;
Step 3, in parts by weight, mixes the first mixture and the second mixture, adds defoamer 1 part, 1 part of antioxidant, touches
Become agent 1 part, antirust agent 1 part, stir.
Further, described defoamer is emulsified silicone oil, and antioxidant is 4,4-di-2-ethylhexylphosphine oxide-2,6-di-tert-butylphenol, touches
Change agent is polyamide wax;In step 1, heating-up temperature is 70 DEG C, and temperature retention time is 3h;In step 2, heating-up temperature is 50 DEG C, insulation
Time is 3h.
Gained antirust oil has good resistance to corrosion, after the QPQ of 570 DEG C of salt-bath nitriding temperature of 2h processes
Carbon steel 45 Steel Piston Rod While salt fog resistance etching time is up to 835h.
Embodiment 3
The preparation method of a kind of solvent cutback soft film anti-rust oil, comprises the following steps:
Step 1, in parts by weight, by D60 solvent naphtha 18 parts, lanolin magnesium soap 4 parts, sulfonation lanolin calcium soap 6 parts, O-phthalic
Dibutyl phthalate 4 parts, sodium citrate 5 parts, barium mahogany sulfonate 3 parts, petroleum sodium sulfonate 5 parts, dodecenylsuccinic acid 7 parts, dinonyl
Naphthalene sulfonate barium 5 parts, zinc naphthenate 4 parts, 5 parts of Cera Flava, trimethylolpropane trimethacrylate 6 parts mixing, heating, insulated and stirred,
Obtain the first mixture;
Step 2, in parts by weight, adds 3-mercaptopropionic acid 7 parts, zinc acetylacetonate 5 parts in ethylene glycol 9 parts, sequentially adds
Diethylene glycol 5 parts, polyglyceryl fatty acid ester 5 parts and silicone acrylic emulsion 4 parts, heating, insulated and stirred, obtain the second mixture;
Step 3, in parts by weight, mixes the first mixture and the second mixture, adds defoamer 1 part, 1 part of antioxidant, touches
Become agent 1 part, antirust agent 1 part, stir.
Further, described defoamer is emulsified silicone oil, and antioxidant is 2,6 ditertiary butyl p cresol, and thixotropic agent is hydrogenation
Oleum Ricini or polyamide wax;In step 1, heating-up temperature is 70 DEG C, and temperature retention time is 3h;In step 2, heating-up temperature is 50 DEG C, protects
The temperature time is 3h.
Gained antirust oil has good resistance to corrosion, after the QPQ of 570 DEG C of salt-bath nitriding temperature of 2h processes
Carbon steel 45 Steel Piston Rod While salt fog resistance etching time is up to 817h.
Embodiment 4
The preparation method of a kind of solvent cutback soft film anti-rust oil, comprises the following steps:
Step 1, in parts by weight, by D60 solvent naphtha 20 parts, lanolin magnesium soap 8 parts, sulfonation lanolin calcium soap 7 parts, O-phthalic
Dibutyl phthalate 6 parts, sodium citrate 7 parts, barium mahogany sulfonate 5 parts, petroleum sodium sulfonate 6 parts, dodecenylsuccinic acid 8 parts, dinonyl
Naphthalene sulfonate barium 7 parts, zinc naphthenate 5 parts, 6 parts of Cera Flava, trimethylolpropane trimethacrylate 7 parts mixing, heating, insulated and stirred,
Obtain the first mixture;
Step 2, in parts by weight, adds 3-mercaptopropionic acid 8 parts, zinc acetylacetonate 6 parts in ethylene glycol 12 parts, sequentially adds
Diethylene glycol 6 parts, polyglyceryl fatty acid ester 6 parts and silicone acrylic emulsion 5 parts, heating, insulated and stirred, obtain the second mixture;
Step 3, in parts by weight, mixes the first mixture and the second mixture, adds defoamer 2 parts, 2 parts of antioxidant, touches
Become agent 2 parts, antirust agent 2 parts, stir.
Further, described defoamer is emulsified silicone oil, and antioxidant is 2,6 ditertiary butyl p cresol, and thixotropic agent is hydrogenation
Oleum Ricini or polyamide wax;In step 1, heating-up temperature is 80 DEG C, and temperature retention time is 1h;In step 2, heating-up temperature is 70 DEG C, protects
The temperature time is 1h.
Gained antirust oil has good resistance to corrosion, after the QPQ of 570 DEG C of salt-bath nitriding temperature of 2h processes
Carbon steel 45 Steel Piston Rod While salt fog resistance etching time is up to 821h.
Claims (6)
1. the preparation method of a solvent cutback soft film anti-rust oil, it is characterised in that: comprise the following steps:
Step 1, in parts by weight, by D60 solvent naphtha 10~20 parts, lanolin magnesium soap 3~8 parts, sulfonation lanolin calcium soap 2~7
Part, dibutyl phthalate 1~6 parts, sodium citrate 3~7 parts, barium mahogany sulfonate 2~5 parts, petroleum sodium sulfonate 1~6 parts, ten
Dialkylene succinic acid 3~8 parts, dinonyl naphthalene sulfonate barium 4~7 parts, zinc naphthenate 2~5 parts, Cera Flava 1~6 parts, trihydroxy methyl third
Alkane triacrylate 2~7 parts of mixing, heating, insulated and stirred, obtain the first mixture;
Step 2, in parts by weight, adds 3-mercaptopropionic acid 2~8 parts, zinc acetylacetonate 1~6 parts in ethylene glycol 5~12 parts,
Sequentially add diethylene glycol 3~6 parts, polyglyceryl fatty acid ester 3~6 parts and silicone acrylic emulsion 2~5 parts, heating, insulated and stirred,
Second mixture;
Step 3, in parts by weight, mixes the first mixture and the second mixture, adds defoamer 1~2 parts, antioxidant 1~2
Part, thixotropic agent 1~2 parts, antirust agent 1~2 parts, stir.
The preparation method of solvent cutback soft film anti-rust oil the most according to claim 1, it is characterised in that: described defoamer
For emulsified silicone oil.
The preparation method of solvent cutback soft film anti-rust oil the most according to claim 1, it is characterised in that: described antioxidant
For DBPC 2,6 ditertiary butyl p cresol, 4,4-di-2-ethylhexylphosphine oxide-2,6-di-tert-butylphenol or 3,5-di-tert-butyl-hydroxy phenyl propanoic acid
One in ester.
The preparation method of solvent cutback soft film anti-rust oil the most according to claim 1, it is characterised in that: described thixotropic agent
For castor oil hydrogenated or polyamide wax.
The preparation method of solvent cutback soft film anti-rust oil the most according to claim 1, it is characterised in that: step 1 adds
Hot temperature is 70~80 DEG C, and temperature retention time is 1~3h.
The preparation method of solvent cutback soft film anti-rust oil the most according to claim 1, it is characterised in that: step 2 adds
Hot temperature is 50~70 DEG C, and temperature retention time is 1~3h.
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Cited By (5)
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---|---|---|---|---|
CN107345170A (en) * | 2017-07-12 | 2017-11-14 | 安徽凯密克企业管理咨询有限公司 | A kind of preparation method of car parts antirust oil |
CN111423817A (en) * | 2020-05-28 | 2020-07-17 | 眉山市三泰铁路车辆配件有限公司 | Special gas QPQ coupling agent for cast iron product and preparation method thereof |
CN112063437A (en) * | 2020-08-24 | 2020-12-11 | 上海斯瑞文特种油品科技有限公司 | Long-acting antirust oil capable of realizing rapid water replacement and preparation method thereof |
CN113025411A (en) * | 2021-03-18 | 2021-06-25 | 成都伍田机械技术有限责任公司 | Quick-drying soft film anti-rust oil special for QPQ and preparation method thereof |
CN113122352A (en) * | 2021-04-20 | 2021-07-16 | 中国石油化工股份有限公司 | Safe protective penetrating oil and preparation method thereof |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107345170A (en) * | 2017-07-12 | 2017-11-14 | 安徽凯密克企业管理咨询有限公司 | A kind of preparation method of car parts antirust oil |
CN111423817A (en) * | 2020-05-28 | 2020-07-17 | 眉山市三泰铁路车辆配件有限公司 | Special gas QPQ coupling agent for cast iron product and preparation method thereof |
CN112063437A (en) * | 2020-08-24 | 2020-12-11 | 上海斯瑞文特种油品科技有限公司 | Long-acting antirust oil capable of realizing rapid water replacement and preparation method thereof |
CN113025411A (en) * | 2021-03-18 | 2021-06-25 | 成都伍田机械技术有限责任公司 | Quick-drying soft film anti-rust oil special for QPQ and preparation method thereof |
CN113122352A (en) * | 2021-04-20 | 2021-07-16 | 中国石油化工股份有限公司 | Safe protective penetrating oil and preparation method thereof |
CN113122352B (en) * | 2021-04-20 | 2022-12-20 | 中国石油化工股份有限公司 | Safe protective penetrating oil and preparation method thereof |
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