CN106117886A - 一种电线防潮专用稳定剂 - Google Patents

一种电线防潮专用稳定剂 Download PDF

Info

Publication number
CN106117886A
CN106117886A CN201610543721.6A CN201610543721A CN106117886A CN 106117886 A CN106117886 A CN 106117886A CN 201610543721 A CN201610543721 A CN 201610543721A CN 106117886 A CN106117886 A CN 106117886A
Authority
CN
China
Prior art keywords
zinc
stabilizer
calcium
acid
salt main
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610543721.6A
Other languages
English (en)
Inventor
龚院明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Yesheng Plastic Co Ltd
Original Assignee
Dongguan Yesheng Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Yesheng Plastic Co Ltd filed Critical Dongguan Yesheng Plastic Co Ltd
Priority to CN201610543721.6A priority Critical patent/CN106117886A/zh
Publication of CN106117886A publication Critical patent/CN106117886A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C08K5/134—Phenols containing ester groups
    • C08K5/1345—Carboxylic esters of phenolcarboxylic acids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/282—Preventing penetration of fluid, e.g. water or humidity, into conductor or cable
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/222—Magnesia, i.e. magnesium oxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2227—Oxides; Hydroxides of metals of aluminium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/14—Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种电线防潮专用稳定剂，它是由以下质量百分比的原料组成：锌盐稳定剂：12‑30％、钙盐主稳定剂：12‑20％、水滑石：20‑50％、高级润滑剂20‑30％、抗氧化剂：5‑10％和辅助稳定剂5‑10，通过多段搅拌，在55‑65℃条件下搅拌5min‑10min；本发明旨在减少填充造成的毛细孔，从而让制品的密实度更高，达到疏水防水。

Description

一种电线防潮专用稳定剂
技术领域
本发明涉及化学稳定剂技术领域，具体的说，尤其涉及一种电线防潮专用稳定剂。
背景技术
因PVC电线特别是软硬度在60PHR以下的有填充增塑剂线材方面最容易产生吸潮问题。如果胶粒(线材是由胶粒制成的)比重不超过1.4，一般吸潮不严重。超过1.4的比重以上的，每年在梅雨季节会产生胶粒吸潮，导致生产过程中拉线时会发泡，影响生产和质量。
发明内容
本发明的目的在于针对上述现有技术的不足，提供一种电线防潮专用稳定剂。
为了实现上述目的，本发明采用如下技术方案：
一种电线防潮专用稳定剂，其特征在于，它是由以下质量百分比的原料组成：
锌盐稳定剂：12-30％
钙盐主稳定剂：12-20％
水滑石：20-50％
高级润滑剂20-30％
抗氧化剂：5-10％
辅助稳定剂5-10，
其中，所述的锌盐主稳定剂为任意比例混合的脂肪酸类锌盐主稳定剂和苯环类锌盐主稳定剂，所述脂肪酸类锌盐主稳定剂为硬脂酸锌、棕榈酸锌、油酸锌、月桂酸锌、十七碳脂肪酸锌或十五碳脂肪酸锌的任意一种，苯环类锌盐主稳定剂为苯甲酸锌或十二烷基苯磺酸锌的任意一种；
其中，所述的钙盐主稳定剂为任意比例混合的脂肪酸类钙盐主稳定剂和苯环类钙盐主稳定剂，所述脂肪酸类钙盐主稳定剂为硬脂酸钙、棕榈酸钙、油酸钙、月桂酸钙、十七碳脂肪酸钙或十五碳脂肪酸钙的任意一种，所述苯环类钙盐主稳定剂为苯甲酸钙或十二烷基苯磺酸钙的任意一种；
其中，所述的水滑石为任意比例混合的镁铝二元水滑石和锌镁铝三元水滑石，所述镁铝二元水滑石中MgO/AL2O3的摩尔比为(4-4.5):1，所述锌镁铝三元水滑石中ZnO/MgO/AL2O3的摩尔比为1:(0.5-2):(0.5-1)；
其中，所述的高级润滑剂为硬脂酸丁酯、单硬脂酸丁酯、单硬脂酸甘油酯、季戊四醇硬脂酸酯、液体白腊、固体白腊、聚乙烯蜡、石蜡、E蜡、EG蜡、硬脂肪酸和季戊四醇中的一种或一种以上按任意比例混合的混合物；
其中，所述抗氧化剂为β-(3,5-二叔丁基-4-羟基苯基)丙酸正十八碳醇酯、三[2.4-二叔丁基苯基]亚磷酸酯和四[β-(3，5-二叔丁基-4-羟基苯基)丙酸酯]季戊四醇酯中的一种或一种以上按任意比例混合的混合物；
其中，所述辅助稳定剂为二苯甲酰甲烷、硬脂酰苯甲酰甲烷、脱氢醋酸、乙酰乙酸乙酯、1,2-环已二酮、2,3-戊二酮、2,5-己二酮和乙酰丙酮中两种或两种以上按任意比例混合的混合物；
上述一种透明环保钙锌稳定剂的制备方法，它包括以下步骤：
a、将上述配方量的水滑石先加入高速搅拌机中，在55-65℃条件下搅拌5min-10min；
b、然后继续加入上述配方量的钙盐主稳定剂、锌盐主稳定剂和高级润滑剂，在55-65℃条件下搅拌10min-20min；
c、最后加入上述配方量的抗氧化剂和辅助稳定剂，在55-65℃条件下搅拌10min-20min，冷却后得到电线防潮专用稳定剂。
上述技术方案中，所述步骤a和步骤b的温度分别控制在58-62℃。
上述技术方案中，所述步骤a和步骤b高速搅拌机的转速分别为1000-1500r/min。
本发明的有益效果在于：高级润滑剂的熔点在110度以上，具有优秀的内外滑作用，在塑料配方里用量到ZPHR时亦不会产生析出，且可以作表面处理剂对制品的填充剂进行包覆，减少填充造成的毛细孔，从而让制品的密实度更高，达到疏水防水的功能。
具体实施方式
下面结合实施例对本发明作进一步的说明。
实施实例如下：
先取30Kg镁铝二元水滑石(镁铝二元水滑石中MgO/AL2O3的摩尔比为3.0:1)和30Kg锌镁铝三元水滑石(锌镁铝三元水滑石中ZnO/MgO/AL2O3的摩尔比为2:3:2)加入高速搅拌机中，高速搅拌机的转速为1000r/min，在56℃下搅拌5min；然后继续加入12Kg硬脂酸钙、12Kg苯甲酸钙、12Kg硬脂酸锌、12Kg苯甲酸锌和12Kg硬脂酸丁酯，在转速为1000r/min和温度为56℃的条件下搅拌10min；最后加入6Kg的β-(3,5-二叔丁基-4-羟基苯基)丙酸正十八碳醇酯、3Kg二苯甲酰甲烷和2Kg乙酰乙酸乙酯3Kg，其中高速搅拌机的转速为1000r/min，在56℃下搅拌20min，冷却后得到电线防潮专用稳定剂。
本发明的高级润滑剂的熔点在110度以上，具有优秀的内外滑作用，在塑料配方里用量到ZPHR时亦不会产生析出，且可以作表面处理剂对制品的填充剂进行包覆，减少填充造成的毛细孔，从而让制品的密实度更高，达到疏水防水的功能。

Claims (4)

1.一种电线防潮专用稳定剂，其特征在于，它是由以下质量百分比的原料组成：
锌盐稳定剂：12-30％
钙盐主稳定剂：12-20％
水滑石：20-50％
高级润滑剂 20-30％
抗氧化剂：5-10％
辅助稳定剂 5-10，
其中，所述的锌盐主稳定剂为任意比例混合的脂肪酸类锌盐主稳定剂和苯环类锌盐主稳定剂，所述脂肪酸类锌盐主稳定剂为硬脂酸锌、棕榈酸锌、油酸锌、月桂酸锌、十七碳脂肪酸锌或十五碳脂肪酸锌的任意一种，苯环类锌盐主稳定剂为苯甲酸锌或十二烷基苯磺酸锌的任意一种；
其中，所述的钙盐主稳定剂为任意比例混合的脂肪酸类钙盐主稳定剂和苯环类钙盐主稳定剂，所述脂肪酸类钙盐主稳定剂为硬脂酸钙、棕榈酸钙、油酸钙、月桂酸钙、十七碳脂肪酸钙或十五碳脂肪酸钙的任意一种，所述苯环类钙盐主稳定剂为苯甲酸钙或十二烷基苯磺酸钙的任意一种；
其中，所述的水滑石为任意比例混合的镁铝二元水滑石和锌镁铝三元水滑石，所述镁铝二元水滑石中MgO/AL2O3的摩尔比为(4-4.5):1，所述锌镁铝三元水滑石中ZnO/MgO/AL2O3的摩尔比为1:(0.5-2):(0.5-1)；
其中，所述的高级润滑剂为硬脂酸丁酯、单硬脂酸丁酯、单硬脂酸甘油酯、季戊四醇硬脂酸酯、液体白腊、固体白腊、聚乙烯蜡、石蜡、E蜡、EG蜡、硬脂肪酸和季戊四醇中的一种或一种以上按任意比例混合的混合物；
其中，所述抗氧化剂为β-(3,5-二叔丁基-4-羟基苯基)丙酸正十八碳醇酯、三[2.4-二叔丁基苯基]亚磷酸酯和四[β-(3，5-二叔丁基-4-羟基苯基)丙酸酯]季戊四醇酯中的一种或一种以上按任意比例混合的混合物；
其中，所述辅助稳定剂为二苯甲酰甲烷、硬脂酰苯甲酰甲烷、脱氢醋酸、乙酰乙酸乙酯、1,2-环已二酮、2,3-戊二酮、2,5-己二酮和乙酰丙酮中两种或两种以上按任意比例混合的混合物。
2.权利要求1所述的一种透明环保钙锌稳定剂的制备方法，其特征在于；它包括以下步骤：
a、将上述配方量的水滑石先加入高速搅拌机中，在55-65℃条件下搅拌5min-10min；
b、然后继续加入上述配方量的钙盐主稳定剂、锌盐主稳定剂和高级润滑剂，在55-65℃条件下搅拌10min-20min；
c、最后加入上述配方量的抗氧化剂和辅助稳定剂，在55-65℃条件下搅拌10min-20min，冷却后得到电线防潮专用稳定剂。
3.根据权利要求2所述的一种透明环保钙锌稳定剂的制备方法，其特征在于：所述步骤a和步骤b的温度分别控制在58-62℃。
4.根据权利要求2所述的一种透明环保钙锌稳定剂的制备方法，其特征在于：所述步骤a和步骤b高速搅拌机的转速分别为1000-1500r/min。
CN201610543721.6A 2016-07-09 2016-07-09 一种电线防潮专用稳定剂 Pending CN106117886A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610543721.6A CN106117886A (zh) 2016-07-09 2016-07-09 一种电线防潮专用稳定剂

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610543721.6A CN106117886A (zh) 2016-07-09 2016-07-09 一种电线防潮专用稳定剂

Publications (1)

Publication Number Publication Date
CN106117886A true CN106117886A (zh) 2016-11-16

Family

ID=57283346

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610543721.6A Pending CN106117886A (zh) 2016-07-09 2016-07-09 一种电线防潮专用稳定剂

Country Status (1)

Country Link
CN (1) CN106117886A (zh)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107778727A (zh) * 2017-11-27 2018-03-09 东莞市烨青电业有限公司 一种pvc微发泡地板环保钙锌稳定剂及其制备方法
CN108164879A (zh) * 2018-01-11 2018-06-15 东莞市尚诺新材料有限公司 一种新能源充电电缆用环保稳定剂
CN108467553A (zh) * 2018-03-20 2018-08-31 山东三义实业股份有限公司 用于wpc地板加工的环保钙锌复合稳定剂
CN109575481A (zh) * 2018-12-19 2019-04-05 嘉兴若天新材料科技有限公司 一种pvc地板耐磨层用环保热稳定剂
CN110283375A (zh) * 2019-07-26 2019-09-27 内蒙古佳运通智能环保新材料有限公司 一种钙锌复合热稳定抗降解助剂及其制备方法和应用
CN110372972A (zh) * 2019-07-25 2019-10-25 东莞市柯益信息技术有限公司 一种多功能环保钙锌电线电缆用热稳定剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967253A (zh) * 2010-10-26 2011-02-09 湘乡市贝特尔塑胶有限公司 一种环保型pvc钙锌复合稳定剂
CN102321276A (zh) * 2011-07-29 2012-01-18 广东若天新材料科技有限公司 一种透明环保钙锌稳定剂及其制备方法
CN102321312A (zh) * 2011-07-29 2012-01-18 广东若天新材料科技有限公司 一种pvc管材用环保钙锌稳定剂及其制备方法
CN102391592A (zh) * 2011-07-29 2012-03-28 广东若天新材料科技有限公司 一种pvc压延膜用环保钙锌稳定剂及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967253A (zh) * 2010-10-26 2011-02-09 湘乡市贝特尔塑胶有限公司 一种环保型pvc钙锌复合稳定剂
CN102321276A (zh) * 2011-07-29 2012-01-18 广东若天新材料科技有限公司 一种透明环保钙锌稳定剂及其制备方法
CN102321312A (zh) * 2011-07-29 2012-01-18 广东若天新材料科技有限公司 一种pvc管材用环保钙锌稳定剂及其制备方法
CN102391592A (zh) * 2011-07-29 2012-03-28 广东若天新材料科技有限公司 一种pvc压延膜用环保钙锌稳定剂及其制备方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107778727A (zh) * 2017-11-27 2018-03-09 东莞市烨青电业有限公司 一种pvc微发泡地板环保钙锌稳定剂及其制备方法
CN108164879A (zh) * 2018-01-11 2018-06-15 东莞市尚诺新材料有限公司 一种新能源充电电缆用环保稳定剂
CN108467553A (zh) * 2018-03-20 2018-08-31 山东三义实业股份有限公司 用于wpc地板加工的环保钙锌复合稳定剂
CN109575481A (zh) * 2018-12-19 2019-04-05 嘉兴若天新材料科技有限公司 一种pvc地板耐磨层用环保热稳定剂
CN110372972A (zh) * 2019-07-25 2019-10-25 东莞市柯益信息技术有限公司 一种多功能环保钙锌电线电缆用热稳定剂及其制备方法
CN110283375A (zh) * 2019-07-26 2019-09-27 内蒙古佳运通智能环保新材料有限公司 一种钙锌复合热稳定抗降解助剂及其制备方法和应用

Similar Documents

Publication Publication Date Title
CN106117886A (zh) 一种电线防潮专用稳定剂
CN102391592B (zh) 一种pvc压延膜用环保钙锌稳定剂及其制备方法
CN104387616A (zh) 复合Ca/Zn稳定剂及其制备方法以及环保型材
CN101575422A (zh) 一种环保型钙锌复合液体稳定剂的制备方法
CN102604271A (zh) 一种聚氯乙烯制品用镁锌复合热稳定剂及其制备方法
US20200181362A1 (en) Plasticizer Composition, Resin Composition, and Method of Preparing the Same
CN103497446A (zh) 一种环保聚氯乙烯耐抽提防渗透膜及其制备方法
EP3327075A1 (en) Plasticizer composition, resin composition, and preparation methods therefor
CN103467884A (zh) 一种高耐候环保白色共挤pvc改性材料及其制备方法
TWI722212B (zh) 塑化劑組成物、樹脂組成物、及其製備方法
CN104877179B (zh) 一种有机复合热稳定剂及其制备方法
CN110698867A (zh) 一种鞋材用钙锌稳定剂的制备方法
CN106432971A (zh) 一种新型环保发泡pvc专用脲嘧啶锌复合稳定剂的制备与应用
CN108003389A (zh) 一种钙锌复合稳定剂
CN105524368A (zh) 一种机器人线缆专用聚氯乙烯护套材料及制备方法
KR102405076B1 (ko) 가소제 조성물, 수지 조성물 및 이들의 제조 방법
CN106752757A (zh) 耐腐蚀纯聚酯粉末涂料及制备方法
CN101274994A (zh) 氯乙烯系树脂用稳定剂组合物
CN109467839A (zh) 一种耐低温耐热长期寿命的pvc汽车线电缆料
CN104479246A (zh) 一种新型环保型材配方及其制备方法
CN104140614A (zh) 一种高速电梯电缆用耐油耐高低温弹性体的制备方法
CN104262845A (zh) 一种环保的pvc/pmma合金材料及其制备方法
CN106167590A (zh) 一种含纳米碳纤维的高强高弹pvc‑nbr复合发泡板及其制备方法
CN103319811A (zh) 一种有机盐热稳定剂的合成方法
CN105038027B (zh) 金属氧化物‑己六醇复合物热稳定剂、制备方法及在pvc中的应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161116

RJ01 Rejection of invention patent application after publication