CN106117885A - 一种防静电装饰板材及其生产工艺 - Google Patents

一种防静电装饰板材及其生产工艺 Download PDF

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CN106117885A
CN106117885A CN201610539980.1A CN201610539980A CN106117885A CN 106117885 A CN106117885 A CN 106117885A CN 201610539980 A CN201610539980 A CN 201610539980A CN 106117885 A CN106117885 A CN 106117885A
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王景清
谢四海
蔡静
蔡军
王玮
吴康胜
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JIANGSU GOLDEN MATERIAL TECHNOLOGY Co Ltd
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Abstract

种防静电装饰板材及其生产工艺,涉及装饰材料技术领域。按照质量份数比,由以下原料组成:PVC树脂粉:100份、稳定剂:1‑4份、内滑剂:0.5‑2份、外滑剂:0.2‑2份、加工助剂:1.0‑4.0份、发泡剂:0.1‑4份、填充剂:10‑50份、石墨烯:0.1‑2.8份。本发明克服了现有PVC板材使用过程中容易产生静电的问题,使板材的电阻率由1010欧姆左右改性为106‑107欧姆。本发明改善了PVC装饰板材强度低、耐磨性低、耐温性低、耐寒性低等问题,大大改善了PVC装饰板材的强度和实用寿命。

Description

一种防静电装饰板材及其生产工艺
技术领域
本发明涉及装饰材料技术领域,具体为一种防静电装饰板材及其生产工艺。
背景技术
由于静电的产生是不可避免的,若产生的静电没有得到及时的泄放,便可能积聚起来。积聚的静电荷构成的电场对周围空间有电场力的作用,可吸引周围微粒而引起灰尘的堆积、纤维纠结及污染物资等。当然,静电积聚最大的危害还是可产生火花放电,导致火灾、爆炸等严重事故。
20世纪中期以后,随着电阻率很高的高分子材料如塑料、橡胶等制品的广泛应用和现代,生产过程的高速化,使静电可以积聚到很高的程度。同时,静电敏感材料如轻质油品、火药、固态电子器件等生产和使用,使静电造成的危害越来越突出。静电曾使电子工业年损失达百亿美元以上。静电放电还造成火箭、卫星发射失败及干扰航天器的运行。据日本的全国火灾统计,从1962年到1971年10年间,每年因静电引起的火灾事故约为100起。
发明内容
本发明的目的是针对现有技术中存在的问题,提供一种防静电装饰板材及其生产工艺。
实现上述目的的技术方案是:一种防静电装饰板材,其特征在于:按照质量份数比,由以下原料组成:PVC树脂粉:100份、稳定剂:1.0-4.0份、内滑剂:0.5-2.0份、外滑剂:0.2-2.0份、加工助剂:1.0-4.0份、发泡剂:0.1-4.0份、填充剂:10-50份、石墨烯:0.1-2.8份。
进一步地,所述稳定剂为甲基锡稳定剂、辛基锡稳定剂、稀土稳定剂、钙锌稳定剂、钡锌稳定剂中的一种或多种。
进一步地,所述加工助剂为甲基丙烯酸甲酯-丙烯酸酯共聚物。
进一步地,所述填充剂为碳酸钙或滑石粉。
优选地,所述内滑剂的型号为G60。
所述防静电装饰板材的制备工艺,其特征在于,包括以下步骤:
a、按配料量将物料投入到高速混合机中混合,通过原料间的物理摩擦使物料温度升至100-120℃,高速混合机的转速为:2000-3000转/分钟;
b、将经高速混合后的物料送入低速混合机中再混合,使物料温度降至40-60℃,低速混合机的转速为50-500转/分钟;
c、经低速混合后的物料送入挤出机挤出塑化,再经成型模头成型为板材,其中,挤出机温度为140-200℃,模头温度为170-220℃;
d、最后采用水冷方式至常温。
进一步地,所述低速混合机的混合腔的外壁设置有水冷夹套。
优选地,步骤a中先加入PVC树脂粉,待高速混合机混合腔的温度升至45-50℃时,加入稳定剂、内滑剂、外滑剂、加工助剂、发泡剂、填充剂、石墨烯。
本发明的有益效果:
1)本发明的防静电装饰板材具有高强度耐磨性能,实用性大大增加。
2)本发明保留了现有PVC装饰板材原有成熟的工艺技术。
3)本发明改善了PVC装饰板材强度低、耐磨性低、耐温性低、耐寒性低等问题,大大改善了PVC装饰板材的强度和实用寿命。
4)本发明克服了现有PVC板材使用过程中容易产生静电的问题,使板材的电阻率由1010欧姆左右改性为106-107欧姆。
具体实施方式
为了使本发明的目的、技术方案更加清楚明白,以下结合具体实施例对本发明进行进一步详细说明。
下面对本发明一种防静电装饰板材及其生产工艺作以下详细地说明。
实施例1
一种防静电装饰板材,按照质量份数比,由以下原料组成:PVC树脂粉:100份、稳定剂:2.0份、内滑剂:0.5份、外滑剂:1.1份、加工助剂:1.0份、发泡剂:2.0份、填充剂:10份、石墨烯:0.1份。
其中,加工助剂为甲基丙烯酸甲酯-丙烯酸酯共聚物,填充剂为碳酸钙。
上述防静电装饰板材的制备工艺包括如下步骤:
a、按配料量先将PVC树脂粉投入到高速混合机搅拌,待高速混合机混合腔的温度升至45℃时,加入稳定剂、内滑剂、外滑剂、加工助剂、发泡剂、填充剂、石墨烯,通过原料间的物理摩擦使物料温度升至100℃,高速混合机的转速为:2000转/分钟;
b、将经高速混合后的物料送入低速混合机中再混合,低速混合机的混合腔的外壁设置有水冷夹套,使物料温度降至40℃,低速混合机的转速为50转/分钟;
c、经低速混合后的物料送入挤出机挤出塑化,再经成型模头成型为板材,其中,挤出机温度为140℃,模头温度为170℃;
d、最后采用水冷方式至常温。
实施例2
一种防静电装饰板材,按照质量份数比,由以下原料组成:PVC树脂粉:100份、稳定剂:1份、内滑剂:1.25份、外滑剂:0.2份、加工助剂:4.0份、发泡剂:0.1份、填充剂:50份、石墨烯:1.5份。
其中,加工助剂为甲基丙烯酸甲酯-丙烯酸酯共聚物,填充剂为滑石粉。
上述防静电装饰板材的制备工艺包括如下步骤:
a、按配料量先将PVC树脂粉投入到高速混合机搅拌,待高速混合机混合腔的温度升至50℃时,加入稳定剂、内滑剂、外滑剂、加工助剂、发泡剂、填充剂、石墨烯,通过原料间的物理摩擦使物料温度升至110℃,高速混合机的转速为:2500转/分钟;
b、将经高速混合后的物料送入低速混合机中再混合,低速混合机的混合腔的外壁设置有水冷夹套,使物料温度降至50℃,低速混合机的转速为225转/分钟;
c、经低速混合后的物料送入挤出机挤出塑化,再经成型模头成型为板材,其中,挤出机温度为170℃,模头温度为195℃;
d、最后采用水冷方式至常温。
实施例3
一种防静电装饰板材,按照质量份数比,由以下原料组成:PVC树脂粉:100份、稳定剂:4.0份、内滑剂:2.0份、外滑剂:2.0份、加工助剂:3.0份、发泡剂:4.0份、填充剂:30份、石墨烯:2.8份。
其中,加工助剂为甲基丙烯酸甲酯-丙烯酸酯共聚物,填充剂为滑石粉。
上述防静电装饰板材的制备工艺包括如下步骤:
a、按配料量先将PVC树脂粉投入到高速混合机搅拌,待高速混合机混合腔的温度升至48℃时,加入稳定剂、内滑剂、外滑剂、加工助剂、发泡剂、填充剂、石墨烯,通过原料间的物理摩擦使物料温度升至120℃,高速混合机的转速为:3000转/分钟;
b、将经高速混合后的物料送入低速混合机中再混合,述低速混合机的混合腔的外壁设置有水冷夹套,使物料温度降至60℃,低速混合机的转速为500转/分钟;
c、经低速混合后的物料送入挤出机挤出塑化,再经成型模头成型为板材,其中,挤出机温度为200℃,模头温度为220℃;
d、最后采用水冷方式至常温。
上述3个实施例中的稳定剂可以为甲基锡稳定剂、辛基锡稳定剂、稀土稳定剂、钙锌稳定剂、钡锌稳定剂中的一种或多种。
以上所述仅为本发明的实施例,并非因此限制本发明的专利范围,凡是利用本发明说明书所作的等效变换,或直接或间接运用在其他相关的技术领域,均同理包括在本发明的专利保护范围内。

Claims (8)

1.一种防静电装饰板材,其特征在于:按照质量份数比,由以下原料组成:PVC树脂粉:100份、稳定剂:1.0-4.0份、内滑剂:0.5-2.0份、外滑剂:0.2-2.0份、加工助剂:1.0-4.0份、发泡剂:0.1-4.0份、填充剂:10-50份、石墨烯:0.1-2.8份。
2.根据权利要求1所述的一种防静电装饰板材,其特征在于:所述稳定剂为甲基锡稳定剂、辛基锡稳定剂、稀土稳定剂、钙锌稳定剂、钡锌稳定剂中的一种或多种。
3.根据权利要求1所述的一种防静电装饰板材,其特征在于:所述加工助剂为甲基丙烯酸甲酯-丙烯酸酯共聚物。
4.根据权利要求1所述的一种防静电装饰板材,其特征在于:所述填充剂为碳酸钙或滑石粉。
5.根据权利要求1所述的一种防静电装饰板材,其特征在于:所述内滑剂的型号为G60。
6.根据权利要求1-5任一项权利要求所述的防静电装饰板材的制备工艺,其特征在于,包括以下步骤:
a、按配料量将物料投入到高速混合机中混合,通过原料间的物理摩擦使物料温度升至100-120℃,高速混合机的转速为:2000-3000转/分钟;
b、将经高速混合后的物料送入低速混合机中再混合,使物料温度降至40-60℃,低速混合机的转速为50-500转/分钟;
c、经低速混合后的物料送入挤出机挤出塑化,再经成型模头成型为板材,其中,挤出机温度为140-200℃,模头温度为170-220℃;
d、最后采用水冷方式至常温。
7.根据权利要求6所述的一种防静电装饰板材,其特征在于,所述低速混合机的混合腔的外壁设置有水冷夹套。
8.根据权利要求6所述的一种防静电装饰板材,其特征在于,步骤a中先加入PVC树脂粉,待高速混合机混合腔的温度升至45-50℃时,加入稳定剂、内滑剂、外滑剂、加工助剂、发泡剂、填充剂、石墨烯。
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Application publication date: 20161116