CN106116654A - Luminous phosphorous bagasse extrusion granule of inhaling is prepared porous and is catchmented the method for sponge brick - Google Patents

Luminous phosphorous bagasse extrusion granule of inhaling is prepared porous and is catchmented the method for sponge brick Download PDF

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Publication number
CN106116654A
CN106116654A CN201610518574.7A CN201610518574A CN106116654A CN 106116654 A CN106116654 A CN 106116654A CN 201610518574 A CN201610518574 A CN 201610518574A CN 106116654 A CN106116654 A CN 106116654A
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China
Prior art keywords
sponge brick
porous
bagasse
particle diameter
catchmented
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CN201610518574.7A
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CN106116654B (en
Inventor
李田泽
郭志东
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Shandong University of Technology
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Shandong University of Technology
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Priority to CN201610518574.7A priority Critical patent/CN106116654B/en
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Publication of CN106116654B publication Critical patent/CN106116654B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/02Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding chemical blowing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C11/00Details of pavings
    • E01C11/22Gutters; Kerbs ; Surface drainage of streets, roads or like traffic areas
    • E01C11/224Surface drainage of streets
    • E01C11/225Paving specially adapted for through-the-surfacing drainage, e.g. perforated, porous; Preformed paving elements comprising, or adapted to form, passageways for carrying off drainage
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C5/00Pavings made of prefabricated single units
    • E01C5/04Pavings made of prefabricated single units made of bricks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

nullThe present invention provides luminous phosphorous bagasse extrusion granule of inhaling to prepare porous and catchment the method for sponge brick,Comprise the following steps: porous is catchmented the dispensing of sponge brick: by cement 15~20wt%、Particle diameter is 250~450 m bagasse extrusion granules 45~65wt%、The sodium silicate 5~15wt% of modulus 3.2~3.5、Particle diameter is 100~200 m calcium oxide 3~5wt%、Particle diameter is 100~200 m silica flours 5~10wt%、The Maifanitum 15~30wt% of High hydrophilous resin fiber 0.5~5.0wt% and particle diameter 100~200 m samples mix homogeneously,Size mixing with the ratio of mud of 0.4~0.7,Add compound gross weight 0.2~the aluminium powder cream of 1.5%,Aluminium powder cream hydration reaction generates bubble,Form porous and expand water suction serosity,Serosity stirs in the die trial pouring sponge brick press into,Strike off、Compacting、The demoulding、Dry,Make sponge brick.

Description

Luminous phosphorous bagasse extrusion granule of inhaling is prepared porous and is catchmented the method for sponge brick
Technical field
The present invention relates to luminous phosphorous bagasse extrusion granule of inhaling prepare porous and catchment the method for sponge brick, belong to material technology Neck.
Background technology
Due to EI Nino and La Nina Phenomenon, there is extreme change in the weather of China, and rainfall distributed pole is uneven, south North drought and waterlogging are uneven, and in same area, in 1 year, rainfall is the most unequal, and hydropenia has restricted expanding economy and the people Life, the existing precipitation of Appropriate application, road surface, community, road, the effective precipitation in public leisure square are rationally collected, store, Utilize, alleviate the use water in drought and water shortage season, significant.
Summary of the invention
Bagasse be mainly composed of cellulose, hemicellulose and lignin, bagasse fire protecting performance is good, has good resistance Combustion performance, has good mechanical processing characteristics, modified bagasse can adsorb the phosphate anion in water, and phosphate anion is to make Become the key factor of water eutrophication, additionally it is possible to the lead ion in absorption water, copper ion, chromium ion have preferable adsorption function, Bentonite is modifying agent and strong adsorbent, and the heavy metal ion in water is also had adsorption, and bentonite is modifying agent and strong suction Attached dose, the heavy metal ion in water also there is is adsorption, heavy metal ion adsorbed in water of Maifanitum, substantially wheat meal Cation in stone swaps with the heavy metal cation in water, has adsorbed the heavy metal in water through ion exchange Maifanitum Cation, the pH value of regulation water, cement is that the porous sponge brick that catchments increases mechanical strength and cementation, and polyvinyl alcohol height absorbs water Resin fibre be strong water absorbent, use dilatant slurry, reduce the density of serosity, the porous made is catchmented a face of sponge brick In dovetail channel-shaped, porous catchment sponge brick absorb moisture enter dovetail groove, flowed into collector pipe, collector pipe again by the effect of gravity The sponge brick that porous catchmented links together, in rainwater catchment to collecting-tank.
Its technical scheme is: luminous phosphorous bagasse extrusion granule of inhaling is prepared porous and catchmented the method for sponge brick, the first step, Porous is catchmented the dispensing of sponge brick: be bagasse extrusion granule 45 modified for 250~450 m by cement 15~20wt%, particle diameter ~65wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, particle diameter be 100~200 m calcium oxide 3~5wt%, particle diameter be 100 ~200 m silica flours 5~10wt%, High hydrophilous resin fiber 0.5~5.0wt% and the Maifanitum 15 of particle diameter 100~200 m~ 30wt% samples, and the percentage by weight sum of above each component is 100%;
Second step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first by particle diameter The bagasse extrusion granule being modified for 250~450 m is put in feed bin, elevator send into distributing device, and distributing device is by modification Bagasse extrusion granule is evenly distributed on governing belt balance, and the sodium silicate of modulus 3.2~3.5 is uniformly sprayed at and changes by spray thrower Property bagasse extrusion granule outer surface, with governing belt balance enter internal coiling drum agitation device, sodium silicate is inorganic bond Agent, is hydrophilic, and cohesive force is strong, intensity is higher, acid resistance, heat-resist, and hydrophilicity does not affect caking property, and compound is Cement 15~20wt%, particle diameter are bagasse extrusion granule 45~65wt%, the silicon of modulus 3.2~3.5 modified for 250~450 m Acid sodium 5~15wt%, particle diameter are that 100~200 m calcium oxide 3~5wt%, particle diameter are 100~200 m silica flours 5~10wt%, high inhale Water-resin fiber 0.5~5.0wt% and the Maifanitum 15~30wt% of particle diameter 100~200 m, by compound with 0.4~0.7 water Gray scale is sized mixing, and ash is compound, adds the aluminium powder cream that compound gross weight is 0.2~1.5%, and hydration reaction generates bubble, shape Becoming porous to expand the serosity of water suction, reduce the weight of sponge brick, polyvinyl alcohol High hydrophilous resin fiber has extremely strong water absorption, Sponge brick comprcssive strength after water suction is constant;
3rd step, porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours sponge brick into In the die trial of press, by 1.2~2.0:1 volume ratio compactings, ratio 1.2~2.0 is the volume before compacting, and ratio 1 is compacting After volume, through striking off, suppressing, the demoulding, dry, porous one face of sponge brick of catchmenting is provided with multiple groove, by solar-electricity Pond plate and LED light emitting diode are placed in groove, and the solar energy of absorption is converted to electrical power storage by solar panel, LED light emitting diode is luminous by the effect contacting of external force, as lighting installation, uses multiple flexible color, in module Can also implant different music, by wireless network regular update, when external force disappears, contact disconnects, and porous is catchmented sponge brick Another face be provided with dovetail channel-shaped, the porous moisture that sponge brick absorbs that catchments enters in dovetail groove, and collector pipe embeds dovetail groove In, rainwater catchments the collecting of sponge brick through porous, enters in dovetail groove, is flowed into collector pipe, collector pipe again by the effect of gravity The sponge brick that single porous catchmented links together, and the rainwater that collector pipe collects enters in collecting-tank.
The preparation of modified bagasse extrusion granule: first bagasse is pulverized corning footpath 200~400 m granule, then will Bagasse powder, dimethylformamide, epoxychloropropane and dimethylamine agueous solution are by 1~3:12.5~15:8~10:12~18 samplings Mix homogeneously, puts into retort, reacts 3~8 hours at 80~120 DEG C, cleans, is dried, forms modified bagasse powder, add Enter particle diameter 100~200 m bentonite, both by weight percentage 70~85wt%:15~35wt% sampling mix homogeneously, two kinds of groups The percentage by weight sum divided is 100%, and compound is pressed the ratio of mud 0.1~0.3 preparation, and compound is modified bagasse Grain powder and bentonite, ash is compound, and compound is put in screw mixer and stirred, and enters back in extruding granulator and makes Grain, makes bagasse extrusion spheroidal particle modified for particle diameter 250~450 m after drying, bagasse be mainly composed of cellulose, Hemicellulose and lignin, bagasse fire protecting performance is good, has good fire resistance, has good mechanical processing characteristics, modification Bagasse can adsorb the phosphate anion in water, and phosphate anion is the key factor causing water eutrophication, additionally it is possible to inhales Lead ion in attached water, copper ion, chromium ion have preferable adsorption function, and bentonite is modifying agent and strong adsorbent, in water Heavy metal ion also have adsorption, the component of material is different, and modified chemical property is the most different, contained N, P, K with And ash is the most different.
Heavy metal ion adsorbed in water of Maifanitum, the substantially cation in Maifanitum and the heavy metal sun in water Ion swaps, and has adsorbed the heavy metal cation in water, the pH value of regulation water through ion exchange Maifanitum.
Calcium oxide hydration reaction, produces substantial amounts of heat, and it is as a form of gel for generating calcium hydroxide, with silicon oxide, aluminium oxide life Becoming calcium silicates, calcium oxide is activator, the activity of excited cement.
A rainwater part for accumulation is pooled in collecting-tank by the porous sponge brick that catchments by collector pipe, and another part penetrates into In soil, increasing soil water content, in summer high-temperature season, the heat on surface can also be transmitted to by the porous sponge brick that catchments In soil, sponge brick can reduce the temperature of ground surface, also can improve surface temperature, and the thermal capacity of water is big, can absorb heat and also can Heat release.
The present invention has the following advantages.
1, preparation Materials Inorganic environment-friendly materials used by sponge brick, do not result in harm, the recyclable energy of sponge brick to environment Secondary uses.
2, the resin fibre of the polyvinyl alcohol height water suction of preparation sponge brick is strong water absorbent, can absorb the water on sponge brick surface Divide and enter inside, when reaching some, fallen to entering in collector pipe by the effect of gravity.
3, in compound, add aluminium powder cream, form the serosity that porous expands, reduce the density of serosity.
4, bagasse be mainly composed of cellulose, hemicellulose and lignin, modified bagasse can adsorb in water Phosphate anion, phosphate anion is the key factor causing water eutrophication, additionally it is possible to absorption water in lead ion, copper from Son, chromium ion have preferable adsorption function.
Accompanying drawing explanation
Fig. 1 is the axle geodesic structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 2 is the end TV structure schematic diagram of the sea brick of the embodiment of the present invention.
Fig. 3 is the structural representation that the monolithic sponge brick of the embodiment of the present invention is linked together by collector pipe.
Wherein in figure 1, sponge brick 2, dovetail groove 3, collector pipe 4, LED light emitting diode 5, solar panel.
Detailed description of the invention
Embodiment.
In embodiment as shown in Figures 1 to 3, luminous phosphorous bagasse extrusion granule of inhaling is prepared porous and is catchmented sponge brick Method, the preparation of the first step, modified bagasse extrusion granule: first bagasse is pulverized corning footpath 200 m granular powder, by Caulis Sacchari sinensis Ground-slag, dimethylformamide, epoxychloropropane and dimethylamine agueous solution are pressed 1:12.5:10:15 and are sampled mix homogeneously, put into retort In, reacting 5 hours at 100 DEG C, clean, be dried, form modified bagasse powder, adding particle diameter 100 m bentonite, both press Percentage by weight 83wt%:17wt% samples mix homogeneously, is prepared by the ratio of mud 0.15 by compound, and compound is modified Caulis Sacchari sinensis Solid impurity particle powder and bentonite, compound is put in screw mixer and is stirred, and enters back into pelletize in extruding granulator, after drying Make particle diameter 400 m bagasse extrusion spheroidal particle.
Second step, porous are catchmented the dispensing of sponge brick: cement 15wt%, particle diameter are bagasse extrusion granule modified for 400 m 45wt%, the sodium silicate 15wt% of modulus 3.5, particle diameter are 150 m calcium oxide 3wt%, particle diameter is 150 m silica flour 5wt%, high water suction Resin fibre 2.0wt% and particle diameter are 100 m Maifanitum 15wt%.
3rd step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first will The bagasse extrusion granule that particle diameter is modified for 400 m is put in feed bin, elevator send into distributing device, and distributing device is sweet by modification Bagasse extrusion granule is evenly distributed on governing belt balance, and the sodium silicate of modulus 3.5 is uniformly sprayed at the sweet of modification by spray thrower The outer surface of bagasse extrusion granule, enters internal coiling drum agitation device with governing belt balance, is adjusted with the ratio of mud of 0.6 by compound Slurry, adds the aluminium powder cream that compound gross weight is 0.8%, and hydration reaction generates bubble, forms the serosity that porous expands, and reduces The weight of sponge brick, polyvinyl alcohol High hydrophilous resin fiber has extremely strong water absorption, and the sponge brick comprcssive strength after water suction is not Become.
4th step, porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours sea into In the die trial of continuous brick press, suppress by the volume ratio of 1.5:1, through striking off, suppressing, the demoulding, dry, make porous and catchment sponge Brick 1, porous 1 one faces of sponge brick of catchmenting are provided with groove, solar panel 5 and LED light emitting diode 4 are placed in groove In, the solar energy of absorption is converted to electrical power storage by solar panel 5, and LED light emitting diode 4 is acted on by external force Contact point connects luminescence, and catchment another face of sponge brick 1 of porous is provided with dovetail groove 2 shape, and porous is catchmented the water that sponge brick 1 absorbs In point entrance dovetail groove 2, being installed with collector pipe 3 in dovetail groove 2, rainwater catchments the collecting of sponge brick 1 through porous, enters swallow In stern notch 2, being flowed into collector pipe 3 again by the effect of gravity, the collector pipe 3 sponge brick 1 that single porous catchmented links together, and catchments The rainwater that pipe 3 collects enters in collecting-tank, through precipitation, filters, reuses.
The above, be only presently preferred embodiments of the present invention, is not the restriction that the present invention makees other form, appoints What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc. Effect embodiment, every without departing from technical solution of the present invention content, according to the technical spirit of type of the present invention, above example is made Any simple modification, equivalent variations and remodeling, still fall within the protection domain of type technical scheme of the present invention.

Claims (1)

1. luminous phosphorous bagasse extrusion granule of inhaling is prepared porous and is catchmented the method for sponge brick, comprises the following steps:
The first step, porous are catchmented the dispensing of sponge brick: be bagasse modified for 250~450 m by cement 15~20wt%, particle diameter Extrusion granule 45~65wt%, the sodium silicate 5~15wt% of modulus 3.2~3.5, particle diameter be 100~200 m calcium oxide 3~ 5wt%, particle diameter are 100~200 m silica flours 5~10wt%, High hydrophilous resin fiber 0.5~5.0wt% and particle diameter 100~200 m Maifanitum 15~30wt% samples, and the percentage by weight sum of above each component is 100%;
Second step, porous catchment sponge brick expand water suction serosity preparation: by the first step percentage by weight sample, first by particle diameter The bagasse extrusion granule being modified for 250~450 m is put in feed bin, elevator send into distributing device, and distributing device is by modification Bagasse extrusion granule is evenly distributed on governing belt balance, and the sodium silicate of modulus 3.2~3.5 is uniformly sprayed at and changes by spray thrower Property the outer surface of bagasse extrusion granule, modified bagasse extrusion granule enters internal coiling drum agitation with governing belt balance Device, sizes mixing compound with the ratio of mud of 0.4~0.7, add compound gross weight be 0.2~1.5% the stirring of aluminium powder cream all Even, aluminium powder cream hydration reaction generates bubble, forms porous and expands the serosity of water suction;
3rd step, porous are catchmented the preparation of sponge brick: the expansion water suction serosity prepared by second step stirs and pours sponge brick into In the die trial of press, through striking off, suppressing, the demoulding, drying, make porous and catchment sponge brick (1), porous is catchmented sponge brick (1) One face is provided with groove, solar panel (5) and LED light emitting diode (4) is placed in groove, solar panel (5) solar energy of absorption being converted to electrical power storage, LED light emitting diode (4) is connected luminescence by the effect of external force, many Catchment another face of sponge brick (1), hole is provided with dovetail groove (2) shape, and collector pipe (3) embeds in dovetail groove (2), and rainwater is through too much Catchmenting the collecting of sponge brick (1) in hole, enters in dovetail groove (2), then flow into collector pipe (3), and single porous is catchmented by collector pipe (3) Sponge brick (1) links together, and the rainwater that collector pipe (3) collects enters in collecting-tank.
CN201610518574.7A 2016-07-05 2016-07-05 It shines and inhales the method that phosphorous bagasse squeezes out the porous sponge brick that catchments of particle preparation Expired - Fee Related CN106116654B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110983899A (en) * 2019-12-18 2020-04-10 中建商品混凝土有限公司 Anti-blocking filtering type permeable asphalt pavement and paving method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100133166A1 (en) * 2006-09-30 2010-06-03 Beijing Rechsand Science & Technology Group Co., L Composite water permeable brick and composition for producing the same
CN104452525A (en) * 2014-11-18 2015-03-25 浙江大学宁波理工学院 Water permeable brick and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100133166A1 (en) * 2006-09-30 2010-06-03 Beijing Rechsand Science & Technology Group Co., L Composite water permeable brick and composition for producing the same
CN104452525A (en) * 2014-11-18 2015-03-25 浙江大学宁波理工学院 Water permeable brick and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110983899A (en) * 2019-12-18 2020-04-10 中建商品混凝土有限公司 Anti-blocking filtering type permeable asphalt pavement and paving method thereof
CN110983899B (en) * 2019-12-18 2022-04-15 中建商品混凝土有限公司 Anti-blocking filtering type permeable asphalt pavement and paving method thereof

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