CN106116459B - 变色瓷砖及其制作方法 - Google Patents

变色瓷砖及其制作方法 Download PDF

Info

Publication number
CN106116459B
CN106116459B CN201610469155.9A CN201610469155A CN106116459B CN 106116459 B CN106116459 B CN 106116459B CN 201610469155 A CN201610469155 A CN 201610469155A CN 106116459 B CN106116459 B CN 106116459B
Authority
CN
China
Prior art keywords
parts
weight
powder
film layer
ceramic tile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201610469155.9A
Other languages
English (en)
Other versions
CN106116459A (zh
Inventor
王赞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Xishan Shenghua Wood Industry Co Ltd
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610469155.9A priority Critical patent/CN106116459B/zh
Publication of CN106116459A publication Critical patent/CN106116459A/zh
Application granted granted Critical
Publication of CN106116459B publication Critical patent/CN106116459B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352—Fuel ashes, e.g. fly ash
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/1305—Organic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/131—Inorganic additives
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5024—Silicates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/88—Metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

本发明公开了一种变色瓷砖及其制作方法，涉及建筑建材技术领域。这种变色瓷砖包括砖坯及金属颜料和\或珠光颜料的涂膜层，这种变色瓷砖的制作方法不需要经过高温（坯件大于800℃，釉面大于650℃）烧结，从而不会对能产生特殊效果的金属颜料、珠光颜料的性质产生影响，因此制作出来的变色瓷砖可以保持这些金属颜料、珠光颜料的珍珠光泽、视觉闪色效应、色彩转移效应等特殊的视觉观感效果，解决了现有瓷砖视觉观感较单一的问题。

Description

变色瓷砖及其制作方法
技术领域
本发明涉及建筑建材技术领域，尤其是一种变色瓷砖及其制作方法。
背景技术
色彩是瓷砖的重要特征，也是重要卖点之一，但是现有的瓷砖视觉观感比较单一，缺少金属色调、金属光泽、珍珠光泽、视觉闪色效应、色彩转移效应、附加色彩效应、三维空间效应、背景衬托效应等。这是由于瓷砖需要在高温下（坯件大于800℃，釉面大于650℃）进行烧结而成，而具有特殊效果的颜料如金属颜料中的铝粉、珠光颜料中的云母钛珠光粉等因其耐化学性和耐热性的限制不能通过现有的施釉、渗色等瓷砖装饰方法用于瓷砖色彩设计，即便个别云母钛珠光粉勉强可用于施釉（目前只能在釉上彩），效果却远不如将其用于溶剂型涂料，其装饰性得不到充分体现。
发明内容
本发明提供一种变色瓷砖及其制作方法，它可以解决现有瓷砖视觉观感较单一的问题，使瓷砖具有珍珠光泽、视觉闪色效应、色彩转移效应等观感。
为了解决上述问题，本发明所采用的技术方案是：这种变色瓷砖，包括砖坯及金属颜料和\或珠光颜料的涂膜层：所述砖坯包含以下重量份数的原料：粉煤灰500～600份、黏土400～450份、水泥310～320份、石英砂和\或金刚砂300～320份、矿渣和\或钢渣300～320份、甘蔗渣30～50份、树脂或者橡胶15～20份、分散剂10～15份、聚丙烯醇10～15份；
所述金属颜料的涂膜层含有质量分数为1～50%的铝、锌、铜、钛金属；
所述珠光颜料的涂膜层含有质量分数为1～50%的云母钛珠光粉和\或云母锌珠光粉；
所述分散剂是表面活性剂、无机小分子分散剂、聚合物的一种或者多种混合物。
上述技术方案中，更具体的技术方案还可以是：这种变色瓷砖的制作方法是：
A、准备砖坯的材料：先将粉煤灰500～600重量份、黏土400～450重量份、石英砂和\或金刚砂300～320重量份、矿渣和\或钢渣300～320重量份、甘蔗渣30～50重量份、树脂或者橡胶15～20重量份分别进行研磨至150～200目；
B、制作砖坯：在80～150℃环境下，取分散剂10～15重量份、聚丙烯醇10～15重量份于密炼机内加热熔融至完全熔融后，加入步骤A所得甘蔗渣粉末与树脂或者橡胶粉末进行熔融混合10～30min，再加入步骤A所得剩余材料、310～320重量份水泥和适量水搅拌均匀得浆体，使含水量达到15～20%，注入模具压制成砖坯；
C、在步骤B所得砖坯上涂覆金属颜料和\或珠光颜料的涂料层，涂覆厚度为25～150nm：这种金属颜料包含聚乙烯醇和铝、锌、铜、钛金属的一种或几种混合粉末，所述聚乙烯醇的含量为涂膜层重量的10～14%，所述金属粉末的含量为涂膜层重量的1～50%；这种包含聚乙烯醇和云母钛珠光粉和\或云母锌珠光粉，所述聚乙烯醇的含量为涂膜层重量的10～14%，所述云母钛珠光粉和\或云母锌珠光粉的含量为涂膜层重量的1～50%；
D、将步骤C所得在80～180℃下干燥1～2h；
所述分散剂是表面活性剂、无机小分子分散剂、聚合物的一种或者多种混合物。
由于采用了上述技术方案，本发明与现有技术相比具有如下有益效果：
1、本发明不需要经过高温（坯件大于800℃，釉面大于650℃）烧结，从而不会对能产生特殊效果的金属颜料、珠光颜料的性质产生影响，因此可以保持这些金属颜料、珠光颜料的珍珠光泽、视觉闪色效应、色彩转移效应等特殊的视觉观感效果，解决了现有瓷砖视觉观感较单一的问题。
2、同时，由于本发明不需要经过高温烧结，节省了能源、减轻了污染、降低了成本。
3、本发明的变色瓷砖具有较好的抗压强度和较低的吸水率，并且通过了根据《GB/T4100-2006陶瓷砖》的要求进行的实验，平均吸水率为3.24。
具体实施方式
以下具体实施例对本发明作进一步详述：
实施例一：
这种变色瓷砖，包括砖坯及金属颜料的涂膜层；
所述砖坯包含以下重量份数的原料：粉煤灰500份、黏土400份、水泥310份、石英砂300份、矿渣300份、干燥的甘蔗渣30份、环氧树脂15份、硅烷偶联剂5份、十二烷基硫酸钠5份、聚丙烯醇10份；
所述金属颜料的涂膜层含有质量分数为1%的铝金属粉末、1%的铜金属粉末和10～14%的聚乙烯醇。
制作方法是：
A、准备砖坯的材料：先将粉煤灰、黏土、石英砂、矿渣、干燥的甘蔗渣、环氧树脂分别进行研磨至150～200目；
B、制作砖坯：在150℃环境下，取硅烷偶联剂、十二烷基硫酸钠、聚丙烯醇于密炼机内加热熔融至完全熔融后，加入步骤A所得干燥的甘蔗渣粉末与环氧树脂粉末进行熔融混合10min，再加入步骤A所得剩余材料、水泥和适量水搅拌均匀得浆体，使含水量达到15%，注入模具压制成砖坯；
C、在步骤B所得砖坯上涂覆金属颜料，涂覆厚度为25nm；
D、将步骤C所得在80℃下干燥2h。
实施例二：
这种变色瓷砖，包括砖坯及珠光颜料的涂膜层；
所述砖坯包含以下重量份数的原料：粉煤灰600份、黏土450份、水泥320份、金刚砂320份、钢渣320份、干燥的甘蔗渣50份、丁苯橡胶20份、十六烷基三甲基溴化铵5份、氰酸酯5份、乙烯-乙烯醇共聚物5份、聚丙烯醇15份；
所述珠光颜料的涂膜层含有质量分数为1的云母钛珠光粉和10～14%的聚乙烯醇。
制作方法是：
A、准备砖坯的材料：先将粉煤灰、黏土、金刚砂、钢渣、干燥的甘蔗渣、丁苯橡胶分别进行研磨至150～200目；
B、制作砖坯：在150℃环境下，取十六烷基三甲基溴化铵、氰酸酯、乙烯-乙烯醇共聚物、聚丙烯醇于密炼机内加热熔融至完全熔融后，加入步骤A所得甘蔗渣粉末与丁苯橡胶粉末进行熔融混合10min，再加入步骤A所得剩余材料、水泥和适量水搅拌均匀得浆体，使含水量达到20%，注入模具压制成砖坯；
C、在步骤B所得砖坯上涂覆珠光颜料，涂覆厚度为150nm；
D、将步骤C所得在180℃下干燥1h。

Claims (2)

1.一种变色瓷砖，包括砖坯及金属颜料和\或珠光颜料的涂膜层，其特征在于：所述砖坯包含以下重量份数的原料：粉煤灰500～600份、黏土400～450份、水泥310～320份、石英砂和\或金刚砂300～320份、矿渣和\或钢渣300～320份、甘蔗渣30～50份、树脂或者橡胶15～20份、分散剂10～15份、聚丙烯醇10～15份；
所述金属颜料的涂膜层含有质量分数为1～50%的铝、锌、铜、钛金属；
所述珠光颜料的涂膜层含有质量分数为1～50%的云母钛珠光粉和\或云母锌珠光粉；
所述分散剂是表面活性剂、无机小分子分散剂、聚合物的一种或者多种混合物。
2.一种变色瓷砖的制作方法，其特征在于：
A、准备砖坯的材料：先将粉煤灰500～600重量份、黏土400～450重量份、石英砂和\或金刚砂300～320重量份、矿渣和\或钢渣300～320重量份、甘蔗渣30～50重量份、树脂或者橡胶15～20重量份分别进行研磨至150～200目；
B、制作砖坯：在80～150℃环境下，取分散剂10～15重量份、聚丙烯醇10～15重量份于密炼机内加热熔融至完全熔融后，加入步骤A所得甘蔗渣粉末与树脂或者橡胶粉末进行熔融混合10～30min，再加入步骤A所得剩余材料、310～320重量份水泥和适量水搅拌均匀得浆体，使含水量达到15～20%，注入模具压制成砖坯；
C、在步骤B所得砖坯上涂覆金属颜料和\或珠光颜料的涂料层，涂覆厚度为25～150nm：这种金属颜料包含聚乙烯醇和铝、锌、铜、钛金属的一种或几种混合粉末，所述聚乙烯醇的含量为涂膜层重量的10～14%，所述金属粉末的含量为涂膜层重量的1～50%；这种包含聚乙烯醇和云母钛珠光粉和\或云母锌珠光粉，所述聚乙烯醇的含量为涂膜层重量的10～14%，所述云母钛珠光粉和\或云母锌珠光粉的含量为涂膜层重量的1～50%；
D、将步骤C所得在80～180℃下干燥1～2h；
所述分散剂是表面活性剂、无机小分子分散剂、聚合物的一种或者多种混合物。
CN201610469155.9A 2016-06-25 2016-06-25 变色瓷砖及其制作方法 Expired - Fee Related CN106116459B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610469155.9A CN106116459B (zh) 2016-06-25 2016-06-25 变色瓷砖及其制作方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610469155.9A CN106116459B (zh) 2016-06-25 2016-06-25 变色瓷砖及其制作方法

Publications (2)

Publication Number Publication Date
CN106116459A CN106116459A (zh) 2016-11-16
CN106116459B true CN106116459B (zh) 2018-12-28

Family

ID=57269501

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610469155.9A Expired - Fee Related CN106116459B (zh) 2016-06-25 2016-06-25 变色瓷砖及其制作方法

Country Status (1)

Country Link
CN (1) CN106116459B (zh)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105084867A (zh) * 2015-08-05 2015-11-25 澧县新鹏陶瓷有限公司 一种以粉煤灰为主要原料的抗菌陶瓷制品及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2227699B1 (en) * 2007-12-31 2018-03-28 Korea Institute of Geoscience & Mineral Resources Apparatus for automatic control of current electrodes for electrical resistivity survey
US20110256786A1 (en) * 2010-04-15 2011-10-20 Mark Bomberg Exterior building wall insulation systems with hygro thermal wrap

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105084867A (zh) * 2015-08-05 2015-11-25 澧县新鹏陶瓷有限公司 一种以粉煤灰为主要原料的抗菌陶瓷制品及其制备方法

Also Published As

Publication number Publication date
CN106116459A (zh) 2016-11-16

Similar Documents

Publication Publication Date Title
CN103725051B (zh) 一种无机涂料的基体材料及其应用
CN104046121A (zh) 一种钢化玻璃油墨配方
CN101691455A (zh) 一种氧化铁黄颗粒状颜料及其制造方法
CN103058610A (zh) 环保多功能建筑节能无机改性柔性装饰片材及其制备方法
CN104844036A (zh) 一种人工彩砂及其制备方法
CN105419628A (zh) 一种基于正硅酸乙酯的耐高温涂料及其制备方法
CN100547038C (zh) 一种陶瓷钛硅色釉颜填料的制备方法
CN106946545A (zh) 使用工业尾料制备的用于墙体的发泡陶瓷及其制备方法
CN101580593B (zh) 一种着色溶胶-凝胶组合物的制造方法及其应用
CN102010157B (zh) 一种双组分环保型无机聚合物涂覆材料及其制备方法
CN104072086A (zh) 一种无水泥干粉装饰砂浆
CN106116459B (zh) 变色瓷砖及其制作方法
CN102249626B (zh) 一种环保多功能聚合物柔质装饰板材及其制造方法
CN108585701A (zh) 一种玻璃微珠保温砂浆及其制备方法
CN101328031A (zh) 固化剂和聚合物及方法
CN105271966B (zh) 一种防火装饰外墙板及其制备方法
DE102021118256A1 (de) Zementfreier formbeständig ausgehärteter körper, verfahren zur herstellung eines solchen körpers, zementfreie, frombeständig aushärtende mischung und verwendung von meta-kaolin in einer zementfreien mischung
JP6212300B2 (ja) 装飾材用組成物
CN108676384A (zh) 氧化铁黑着色粉末
CN101746992B (zh) 一种柔性面砖及其制备方法
CN108530949A (zh) 氧化铁绿着色粉末
CN108530951A (zh) 氧化铁绿着色粉末
JPH06293562A (ja) 人造石の製造方法
CN106587904A (zh) 隔热涂料及其制备方法
CN108047846B (zh) 一种维保用瓦片面层涂料及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20201124

Address after: 535300 class II highway around the county town of Pubei County, Qinzhou City, Guangxi Zhuang Autonomous Region (north of Xueyuan Road)

Patentee after: Guangxi Xishan Shenghua Wood Industry Co., Ltd

Address before: 543000 the Guangxi Zhuang Autonomous Region Dadong District of Wuzhou City Sports Road Wanxiu No. 1

Patentee before: Wang Zan

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20181228

Termination date: 20210625