CN106098841A - 一种铜锌锡硫光电纤维的制备方法 - Google Patents
一种铜锌锡硫光电纤维的制备方法 Download PDFInfo
- Publication number
- CN106098841A CN106098841A CN201610485083.7A CN201610485083A CN106098841A CN 106098841 A CN106098841 A CN 106098841A CN 201610485083 A CN201610485083 A CN 201610485083A CN 106098841 A CN106098841 A CN 106098841A
- Authority
- CN
- China
- Prior art keywords
- copper
- parts
- prepared
- tin
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- WILFBXOGIULNAF-UHFFFAOYSA-N copper sulfanylidenetin zinc Chemical compound [Sn]=S.[Zn].[Cu] WILFBXOGIULNAF-UHFFFAOYSA-N 0.000 title claims abstract description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052802 copper Inorganic materials 0.000 claims abstract description 29
- 239000010949 copper Substances 0.000 claims abstract description 29
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims abstract description 23
- 239000002956 ash Substances 0.000 claims abstract description 23
- 238000000498 ball milling Methods 0.000 claims abstract description 22
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 16
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000001354 calcination Methods 0.000 claims abstract description 14
- 239000011812 mixed powder Substances 0.000 claims abstract description 14
- 239000002243 precursor Substances 0.000 claims abstract description 12
- 238000010041 electrostatic spinning Methods 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 8
- 229960000583 acetic acid Drugs 0.000 claims abstract description 8
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 8
- 238000007885 magnetic separation Methods 0.000 claims abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 8
- 239000008187 granular material Substances 0.000 claims description 12
- 238000009413 insulation Methods 0.000 claims description 12
- 230000020477 pH reduction Effects 0.000 claims description 12
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 10
- 239000005751 Copper oxide Substances 0.000 claims description 10
- 229910000431 copper oxide Inorganic materials 0.000 claims description 10
- 239000002893 slag Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims description 3
- 239000006193 liquid solution Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 9
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 229960000935 dehydrated alcohol Drugs 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 229910020994 Sn-Zn Inorganic materials 0.000 description 1
- 229910009069 Sn—Zn Inorganic materials 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/0256—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by the material
- H01L31/0264—Inorganic materials
- H01L31/032—Inorganic materials including, apart from doping materials or other impurities, only compounds not provided for in groups H01L31/0272 - H01L31/0312
- H01L31/0322—Inorganic materials including, apart from doping materials or other impurities, only compounds not provided for in groups H01L31/0272 - H01L31/0312 comprising only AIBIIICVI chalcopyrite compounds, e.g. Cu In Se2, Cu Ga Se2, Cu In Ga Se2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Photovoltaic Devices (AREA)
- Hybrid Cells (AREA)
- Artificial Filaments (AREA)
Abstract
本发明涉及一种铜锌锡硫光电纤维的制备方法，属于光伏材料制备技术领域。本发明首先对废弃铜渣进行预处理，经煅烧，碾磨，磁选以及球磨得到球磨混合粉末，再将其与柠檬酸，冰醋酸进行混合后，与聚乙烯醇、乙醇胺进行加热搅拌混合，得到前驱体溶液，最后对其进行静电纺丝，即可得到铜锌锡硫光电纤维。本发明制备的铜锌锡硫光电纤维对太阳光的利用率高，光电效率达到8.5～8.8％；载流子迁移率高载流子迁移率达到30.25cm2v‑1s‑1以上。
Description
技术领域
本发明涉及一种铜锌锡硫光电纤维的制备方法，属于光伏材料制备技术领域。
背景技术
光伏材料能产生电流是因为光生伏特效应，即如果光线照射在太阳能电池上并且光在界面层被吸收，具有足够能量的光子能够在P型硅和N型硅中将电子从共价键中激发，以致产生电子－空穴对。界面层附近的电子和空穴在复合之前，将通过空间电荷的电场作用被相互分离。电子向带正电的N区和空穴向带负电的P区运动。通过界面层的电荷分离，将在P区和N区之间产生一个向外的可测试的电压。此时可在硅片的两边加上电极并接入电压表。对晶体硅太阳能电池来说，开路电压的典型数值为0.5～0.6V。通过光照在界面层产生的电子－空穴对越多，电流越大。界面层吸收的光能越多，界面层即电池面积越大，在太阳能电池中形成的电流也越大。
导电高分子材料聚对苯乙烯撑(PPV)由于具有优良的光电性质，是研究最多也是最有希望的光伏材料之一。PPV由于具有价廉、低毒、质轻、可调的光学性能、良好的成膜性能、较高的光电效率和发光性能以及很高的光吸收系数(50Onm)，是最有希望和研究得最多的光电材料，它在光伏材料和发光二极管等领域有很好的应用前景。但是，单纯PPV作为光伏材料存在对太阳光利用率不高、载流子迁移率较低、稳定性不高等缺陷，制约了其实际应用。
发明内容
本发明所要解决的技术问题：针对聚对苯乙烯作为光伏材料对太阳光的利用率不高，载流子迁移率较低、稳定性不高，制约了其实际应用得问题，本发明首先对废弃铜渣进行预处理，经煅烧，碾磨，磁选以及球磨得到球磨混合粉末，再将其与柠檬酸，冰醋酸进行混合后，与聚乙烯醇、乙醇胺进行加热搅拌混合，得到前驱体溶液，最后对其进行静电纺丝，即可得到铜锌锡硫光电纤维。本发明通过将废弃铜渣中铜锡锌氧化物与有机酸混合制备，收集有机酸解液进行制备铜锌锡硫光电纤维，有效的改善铜锌锡硫材料对太阳光的利用率，载流子迁移率高，且稳定性好，扩大了其应用范围。
为解决上述技术问题，本发明采用的技术方案是：
（1）收集炼铜厂废弃铜渣，洗净后自然晾干，随后碾磨过筛，制备得50～60目铜渣颗粒，收集铜渣颗粒，将其置于坩埚中，将坩埚移至管式炉中，对其通氧气排除空气，随后在氧气气氛下，加热升温至450～500℃，保温煅烧1～2h；
（2）待保温煅烧完成后，静置冷却至室温，随后继续碾磨并过筛，制备得65～70目氧化铜渣粉末，用磁铁对氧化铜渣粉末进行筛分，磁选完成后，将其置于球磨装置中，以无水乙醇为分散剂，球磨3～5h，随后自然晾干，制备得球磨混合粉末；
（3）按重量份数计，分别称量45～50份质量浓度30%柠檬酸溶液、25～30份冰醋酸和15～20份上述制备的球磨混合粉末置于三口烧瓶中，在45～60℃下水浴加热3～5h，随后过滤并收集滤液，制备得酸化混合液；
（4）按重量份数计，分别称量45～50份上述制备的酸化混合液、5～10份聚乙烯醇、10～15份乙醇胺和20～25份乙二醇甲醚置于三口烧瓶中，在45～60℃下，按1000～1100r/min磁力搅拌1～2h，随后静置冷却至室温，再在65～80℃下旋转蒸发至原体积的1/2，制备得前驱体溶液；
（5）将上述制备的前驱体溶液置于静电纺丝装置注射器中，控制注射泵流量为2～3mL/h，调整接收板收集距离为5～10cm，在电压为9～10kV下静电纺丝，收集静电纺丝纤维，将其置于90～100℃下干燥8～10h，随后静置冷却至室温，即可制备得一种铜锌锡硫光电纤维。
本发明制备的铜锌锡硫光电纤维禁宽度为1.5～1.8eV，光吸收系数为2.1×104cm-1以上，光电效率为8.5～8.8％，电阻率为4.6～4.9Ω·cm，载流子迁移率达到30.25cm2v- 1s-1以上。
本发明与其他方法相比，有益技术效果是：
（1）本发明制备的铜锌锡硫光电纤维对太阳光的利用率高，光电效率达到8.5～8.8％；
（2）本发明制备的铜锌锡硫光电纤维载流子迁移率高载流子迁移率达到30.25cm2v-1s-1以上；
（3）本发明操作步骤简单，所需成本低。
具体实施方式
首先收集炼铜厂废弃铜渣，洗净后自然晾干，随后碾磨过筛，制备得50～60目铜渣颗粒，收集铜渣颗粒，将其置于坩埚中，将坩埚移至管式炉中，对其通氧气排除空气，随后在氧气气氛下，加热升温至450～500℃，保温煅烧1～2h；待保温煅烧完成后，静置冷却至室温，随后继续碾磨并过筛，制备得65～70目氧化铜渣粉末，用磁铁对氧化铜渣粉末进行筛分，磁选完成后，将其置于球磨装置中，以无水乙醇为分散剂，球磨3～5h，随后自然晾干，制备得球磨混合粉末；按重量份数计，分别称量45～50份质量浓度30%柠檬酸溶液、25～30份冰醋酸和15～20份上述制备的球磨混合粉末置于三口烧瓶中，在45～60℃下水浴加热3～5h，随后过滤并收集滤液，制备得酸化混合液；再按重量份数计，分别称量45～50份上述制备的酸化混合液、5～10份聚乙烯醇、10～15份乙醇胺和20～25份乙二醇甲醚置于三口烧瓶中，在45～60℃下，按1000～1100r/min磁力搅拌1～2h，随后静置冷却至室温，再在65～80℃下旋转蒸发至原体积的1/2，制备得前驱体溶液；将上述制备的前驱体溶液置于静电纺丝装置注射器中，控制注射泵流量为2～3mL/h，调整接收板收集距离为5～10cm，在电压为9～10kV下静电纺丝，收集静电纺丝纤维，将其置于90～100℃下干燥8～10h，随后静置冷却至室温，即可制备得一种铜锌锡硫光电纤维。
实例1
首先收集炼铜厂废弃铜渣，洗净后自然晾干，随后碾磨过筛，制备得60目铜渣颗粒，收集铜渣颗粒，将其置于坩埚中，将坩埚移至管式炉中，对其通氧气排除空气，随后在氧气气氛下，加热升温至500℃，保温煅烧2h；待保温煅烧完成后，静置冷却至室温，随后继续碾磨并过筛，制备得70目氧化铜渣粉末，用磁铁对氧化铜渣粉末进行筛分，磁选完成后，将其置于球磨装置中，以无水乙醇为分散剂，球磨5h，随后自然晾干，制备得球磨混合粉末；按重量份数计，分别称量50份质量浓度30%柠檬酸溶液、30份冰醋酸和20份上述制备的球磨混合粉末置于三口烧瓶中，在60℃下水浴加热5h，随后过滤并收集滤液，制备得酸化混合液；再按重量份数计，分别称量50份上述制备的酸化混合液、10份聚乙烯醇、15份乙醇胺和25份乙二醇甲醚置于三口烧瓶中，在60℃下，按1100r/min磁力搅拌2h，随后静置冷却至室温，再在80℃下旋转蒸发至原体积的1/2，制备得前驱体溶液；将上述制备的前驱体溶液置于静电纺丝装置注射器中，控制注射泵流量为3mL/h，调整接收板收集距离为10cm，在电压为10kV下静电纺丝，收集静电纺丝纤维，将其置于100℃下干燥10h，随后静置冷却至室温，即可制备得一种铜锌锡硫光电纤维。
经检测，本发明制备的铜锌锡硫光电纤维禁宽度为1.8eV，光吸收系数为2.2×104cm-1，光电效率为8.5％，电阻率为4.6Ω·cm，载流子迁移率达到30.35cm2v-1s-1。
实例2
首先收集炼铜厂废弃铜渣，洗净后自然晾干，随后碾磨过筛，制备得50目铜渣颗粒，收集铜渣颗粒，将其置于坩埚中，将坩埚移至管式炉中，对其通氧气排除空气，随后在氧气气氛下，加热升温至450℃，保温煅烧1h；待保温煅烧完成后，静置冷却至室温，随后继续碾磨并过筛，制备得65目氧化铜渣粉末，用磁铁对氧化铜渣粉末进行筛分，磁选完成后，将其置于球磨装置中，以无水乙醇为分散剂，球磨3h，随后自然晾干，制备得球磨混合粉末；按重量份数计，分别称量45份质量浓度30%柠檬酸溶液、25份冰醋酸和15份上述制备的球磨混合粉末置于三口烧瓶中，在45℃下水浴加热3h，随后过滤并收集滤液，制备得酸化混合液；再按重量份数计，分别称量45份上述制备的酸化混合液、5份聚乙烯醇、10份乙醇胺和20份乙二醇甲醚置于三口烧瓶中，在45℃下，按1000r/min磁力搅拌1h，随后静置冷却至室温，再在65℃下旋转蒸发至原体积的1/2，制备得前驱体溶液；将上述制备的前驱体溶液置于静电纺丝装置注射器中，控制注射泵流量为2mL/h，调整接收板收集距离为5cm，在电压为9kV下静电纺丝，收集静电纺丝纤维，将其置于90℃下干燥8h，随后静置冷却至室温，即可制备得一种铜锌锡硫光电纤维。
经检测，本发明制备的铜锌锡硫光电纤维禁宽度为1.5eV，光吸收系数为2.3×104cm-1，光电效率为8.7％，电阻率为4.7Ω·cm，载流子迁移率达到30.32cm2v-1s-1。
实例3
首先收集炼铜厂废弃铜渣，洗净后自然晾干，随后碾磨过筛，制备得55目铜渣颗粒，收集铜渣颗粒，将其置于坩埚中，将坩埚移至管式炉中，对其通氧气排除空气，随后在氧气气氛下，加热升温至470℃，保温煅烧2h；待保温煅烧完成后，静置冷却至室温，随后继续碾磨并过筛，制备得67目氧化铜渣粉末，用磁铁对氧化铜渣粉末进行筛分，磁选完成后，将其置于球磨装置中，以无水乙醇为分散剂，球磨4h，随后自然晾干，制备得球磨混合粉末；按重量份数计，分别称量47份质量浓度30%柠檬酸溶液、27份冰醋酸和17份上述制备的球磨混合粉末置于三口烧瓶中，在50℃下水浴加热4h，随后过滤并收集滤液，制备得酸化混合液；再按重量份数计，分别称量47份上述制备的酸化混合液、7份聚乙烯醇、12份乙醇胺和22份乙二醇甲醚置于三口烧瓶中，在50℃下，按1050r/min磁力搅拌1h，随后静置冷却至室温，再在70℃下旋转蒸发至原体积的1/2，制备得前驱体溶液；将上述制备的前驱体溶液置于静电纺丝装置注射器中，控制注射泵流量为2mL/h，调整接收板收集距离为7cm，在电压为8kV下静电纺丝，收集静电纺丝纤维，将其置于95℃下干燥9h，随后静置冷却至室温，即可制备得一种铜锌锡硫光电纤维。
经检测，本发明制备的铜锌锡硫光电纤维禁宽度为1.7eV，光吸收系数为2.4×104cm-1，光电效率为8.7％，电阻率为4.7Ω·cm，载流子迁移率达到30.27cm2v-1s-1以上。
Claims (1)
1.一种铜锌锡硫光电纤维的制备方法，其特征在于具体制备步骤为：
（1）收集炼铜厂废弃铜渣，洗净后自然晾干，随后碾磨过筛，制备得50～60目铜渣颗粒，收集铜渣颗粒，将其置于坩埚中，将坩埚移至管式炉中，对其通氧气排除空气，随后在氧气气氛下，加热升温至450～500℃，保温煅烧1～2h；
（2）待保温煅烧完成后，静置冷却至室温，随后继续碾磨并过筛，制备得65～70目氧化铜渣粉末，用磁铁对氧化铜渣粉末进行筛分，磁选完成后，将其置于球磨装置中，以无水乙醇为分散剂，球磨3～5h，随后自然晾干，制备得球磨混合粉末；
（3）按重量份数计，分别称量45～50份质量浓度30%柠檬酸溶液、25～30份冰醋酸和15～20份上述制备的球磨混合粉末置于三口烧瓶中，在45～60℃下水浴加热3～5h，随后过滤并收集滤液，制备得酸化混合液；
（4）按重量份数计，分别称量45～50份上述制备的酸化混合液、5～10份聚乙烯醇、10～15份乙醇胺和20～25份乙二醇甲醚置于三口烧瓶中，在45～60℃下，按1000～1100r/min磁力搅拌1～2h，随后静置冷却至室温，再在65～80℃下旋转蒸发至原体积的1/2，制备得前驱体溶液；
（5）将上述制备的前驱体溶液置于静电纺丝装置注射器中，控制注射泵流量为2～3mL/h，调整接收板收集距离为5～10cm，在电压为9～10kV下静电纺丝，收集静电纺丝纤维，将其置于90～100℃下干燥8～10h，随后静置冷却至室温，即可制备得一种铜锌锡硫光电纤维。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610485083.7A CN106098841B (zh) | 2016-06-28 | 2016-06-28 | 一种铜锌锡硫光电纤维的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610485083.7A CN106098841B (zh) | 2016-06-28 | 2016-06-28 | 一种铜锌锡硫光电纤维的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106098841A true CN106098841A (zh) | 2016-11-09 |
| CN106098841B CN106098841B (zh) | 2017-12-12 |
Family
ID=57213806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610485083.7A Active CN106098841B (zh) | 2016-06-28 | 2016-06-28 | 一种铜锌锡硫光电纤维的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106098841B (zh) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010135622A1 (en) * | 2009-05-21 | 2010-11-25 | E. I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| US8044477B1 (en) * | 2010-09-30 | 2011-10-25 | General Electric Company | Photovoltaic device and method for making |
| CN103078010A (zh) * | 2013-02-03 | 2013-05-01 | 电子科技大学 | 一种铜锌锡硫薄膜太阳能电池的全非真空工艺制备方法 |
| CN103382090A (zh) * | 2013-07-11 | 2013-11-06 | 深圳市亚太兴实业有限公司 | 一种连续制备铜锌锡硫薄膜的方法 |
| US20130302597A1 (en) * | 2012-05-09 | 2013-11-14 | Commissariat A L'energie Atomique Et Aux Ene Alt | Method for producing a film by cu2znsns4 silar |
| WO2015145167A1 (en) * | 2014-03-28 | 2015-10-01 | Big Solar Limited | Optoelectronic device and method of producing the same |
-
2016
- 2016-06-28 CN CN201610485083.7A patent/CN106098841B/zh active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010135622A1 (en) * | 2009-05-21 | 2010-11-25 | E. I. Du Pont De Nemours And Company | Copper zinc tin chalcogenide nanoparticles |
| US8044477B1 (en) * | 2010-09-30 | 2011-10-25 | General Electric Company | Photovoltaic device and method for making |
| US20130302597A1 (en) * | 2012-05-09 | 2013-11-14 | Commissariat A L'energie Atomique Et Aux Ene Alt | Method for producing a film by cu2znsns4 silar |
| CN103078010A (zh) * | 2013-02-03 | 2013-05-01 | 电子科技大学 | 一种铜锌锡硫薄膜太阳能电池的全非真空工艺制备方法 |
| CN103382090A (zh) * | 2013-07-11 | 2013-11-06 | 深圳市亚太兴实业有限公司 | 一种连续制备铜锌锡硫薄膜的方法 |
| WO2015145167A1 (en) * | 2014-03-28 | 2015-10-01 | Big Solar Limited | Optoelectronic device and method of producing the same |
Non-Patent Citations (2)
| Title |
|---|
| 刘爱芳: "静电纺丝法制备铜锌锡硫微纳米纤维及其性能表征", 《硕士学位论文数据库》 * |
| 胡家瑞: "太阳能电池铜锌锡硫吸收层非真空法制备技术研究", 《中国优秀硕士论文全文库》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106098841B (zh) | 2017-12-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105140347B (zh) | 快速改善p型晶硅电池光致衰减的量产装置及其使用方法 | |
| CN103214038B (zh) | 碳包覆四氧化三铁-四氧化三钴复合负极材料的制备方法 | |
| CN104966763B (zh) | 一种提高钙钛矿太阳能电池效率的方法 | |
| CN105390696B (zh) | 一种高比容量锂电池负极材料的制备方法 | |
| CN110205642A (zh) | 一种太阳能装置 | |
| CN110359098A (zh) | 一种介孔碳纤维电极材料及其制备方法 | |
| CN109860402A (zh) | 一种基于低温二氧化钛介孔结构的钙钛矿太阳能电池电子传输层的制备方法及应用 | |
| CN108922968A (zh) | 一种基于无机量子点铜铟硒的钙钛矿太阳能电池及其制备方法 | |
| CN105223633A (zh) | 一种平面荧光聚光器及其制备方法 | |
| CN204966525U (zh) | 快速改善p型晶硅电池光致衰减的量产装置 | |
| CN106128772A (zh) | 一种硫化铅量子点光伏电池的制备方法 | |
| CN102324311B (zh) | 一种双功能染料敏化太阳能电池光阳极的制备方法 | |
| Chang et al. | A novel photo-thermoelectric generator integrating dye-sensitized solar cells with thermoelectric modules | |
| CN109704303A (zh) | 一种复合的生物质碳材料及其制备和在锂硒电池用涂层隔膜中的应用 | |
| CN109192532A (zh) | 一种超级电容器电极材料及其制备方法 | |
| CN106098841A (zh) | 一种铜锌锡硫光电纤维的制备方法 | |
| CN108493344A (zh) | 壳芯结构钙钛矿纳米线阵列太阳能电池 | |
| CN104600278A (zh) | 一种石墨烯/钛酸锂复合材料的制备方法及其应用 | |
| KR101723602B1 (ko) | 태양열 집열부를 구비하는 이동식 레저 겸용 태양열 온풍기 | |
| CN108023018A (zh) | 基于带隙连续可调控的倒置钙钛矿太阳电池的制备方法 | |
| CN107359252A (zh) | 一种晶体均一型钙钛矿薄膜的制备方法 | |
| CN113991006B (zh) | 一种光热-热电充电器件及其制备方法 | |
| CN107705993B (zh) | 染料敏化太阳电池氧化铜纳米棒阵列对电极及其制备方法 | |
| CN107055489B (zh) | 一种制备纳米线编织球状硒化锑钠离子电池负极材料的方法 | |
| CN104577046A (zh) | 一种石墨烯/钛酸锂复合材料的应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170908 Address after: 362300 Nanan Province, Quanzhou City, the town of high-tech park Applicant after: NAN'AN QUANHONG INCUBATOR MANAGEMENT CO.,LTD. Address before: 213164 Jiangsu city in Changzhou Province, Zhonglou District Baiyun Dongyuan building 6 Room 401 a unit Applicant before: Chen Jianfeng |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190115 Address after: Room 302, No. 13, Changxin Apartment, Wuxi New District, Jiangsu Province Patentee after: Yu Tao Address before: 510000 B1B2, one, two, three and four floors of the podium building 231 and 233, science Avenue, Guangzhou, Guangdong. Patentee before: BOAO ZONGHENG NETWORK TECHNOLOGY Co.,Ltd. Effective date of registration: 20190115 Address after: 510000 B1B2, one, two, three and four floors of the podium building 231 and 233, science Avenue, Guangzhou, Guangdong. Patentee after: BOAO ZONGHENG NETWORK TECHNOLOGY Co.,Ltd. Address before: 362300 Luncang Town High-tech Park, Nanan City, Quanzhou City, Fujian Province Patentee before: NAN'AN QUANHONG INCUBATOR MANAGEMENT CO.,LTD. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190422 Address after: Room 402, No. 40, Ercun, Qiaoqiao, Nanchang District, Wuxi City, Jiangsu Province Co-patentee after: Yang Xun Patentee after: Shen Zhihui Co-patentee after: Yu Xiaochun Co-patentee after: Xu Lijia Co-patentee after: Yu Lin Co-patentee after: Yu Tao Co-patentee after: Wang Ganhua Address before: Room 302, No. 13, Changxin Apartment, Wuxi New District, Jiangsu Province Patentee before: Yu Tao |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190605 Address after: 214000 Chengnan Road, Wuxi New District, Jiangsu Province 209-3 Patentee after: WUXI CHAOZHOU TECHNOLOGY Co.,Ltd. Address before: Room 402, No. 40, Ercun, Qiaoqiao, Nanchang District, Wuxi City, Jiangsu Province Co-patentee before: Yang Xun Patentee before: Shen Zhihui Co-patentee before: Yu Xiaochun Co-patentee before: Xu Lijia Co-patentee before: Yu Lin Co-patentee before: Yu Tao Co-patentee before: Wang Ganhua |
|
| TR01 | Transfer of patent right |