CN1060912C - Metribuzin-amide herbicide composition and preparation thereof - Google Patents
Metribuzin-amide herbicide composition and preparation thereof Download PDFInfo
- Publication number
- CN1060912C CN1060912C CN96102443A CN96102443A CN1060912C CN 1060912 C CN1060912 C CN 1060912C CN 96102443 A CN96102443 A CN 96102443A CN 96102443 A CN96102443 A CN 96102443A CN 1060912 C CN1060912 C CN 1060912C
- Authority
- CN
- China
- Prior art keywords
- acetochlor
- piperazine humulone
- piperazine
- corn
- herbicide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention belongs to the field of agricultural chemicals. A compound provided by the present invention is composed of a triazinyl type herbicide using metribuzin and an amide herbicide type herbicide (butyl oxamine or ethyl oxamine). The compound is prepared by two kinds of agricultural chemical agents, such as emulsifiable solution and suspending emulsion, and has the advantages of providing safety for the present crops of soy beans, corn, etc. without residual herbicide damage to subsequently planted crops, enlarging wide application, preventing and removing annual monogenus and dicotyledonous weed at a time, reducing environmental pollution, providing easy use, etc., and the present invention is a favorable formula for weeding a stripping field between the soy beans and the corn.
Description
The invention belongs to pesticide field, specifically it is a kind of new herbicidal composition and preparation thereof.Said composition contains known piperazine humulone (metribuzin) and a kind of herbicide butachlor (butachlor) or Acetochlor (acetochlor) that is selected from amide-type with activity of weeding.
The piperazine humulone is the weed killer herbicide of Soybean and Other Crops based on soil treatment, but is guaranteeing under the prerequisite of effective management of weeds, employed dosage to the safety of soybean relatively poor (referring to the chief editor of medicine inspecting institute of the Ministry of Agriculture " newly organized agricultural chemicals handbook P531-534).On the contrary, if the dosage of reduction piperazine humulone does not reach the good result (light soil soybeans dosage is no more than 28 gram/mus) to weeds again.The piperazine humulone longevity of residure is short than atrazine, is difficult for being stranded in environment.1981-1987 Fank, people such as R are to the monitoring of U.S. Sydenhan River river (30-50 time/year), and the result is: the percentage that the piperazine humulone measures is 2-7%, and atrazine (atrazine) is up to 89-100% (Weed Abstracts 40:2484).Therefore improve the utilization rate of piperazine humulone, the mixture that substitutes atrazine at corn field uses, and is significant in environmental protection.Chinese patent CN1154201A discloses a kind of corn field, soybean field herbicide, wherein Acetochlor/piperazine humulone /=1/6-1/2, but piperazine humulone content is too high, easily soybean is produced poisoning and uneconomical material benefit.
The object of the present invention is to provide a kind of piperazine humulone and amide herbicide composition, it both can guarantee good preventive effect, can reduce the dosage of piperazine humulone again, improve the safety of crop, enlarge and kill the grass spectrum, weeds such as lady's-grass, lamb's-quarters, piemarker there is synergistic effect, and can be used as the use of corn field soil treatment type weed killer herbicide.Below be described in detail main contents of the present invention.
A, missible oil (emulsifiable concentrate)
Said preparation contains 5~40% piperazine humulone and 5~40% acetamide-group herbicides, 10~60%, solvent, 10~30% cosolvent, 3~10% emulsifier.
The optimization formula of said preparation contains the piperazine humulone of 10-30% and 10~30% butachlor or Acetochlor, 25~50% solvent, 15~25% cosolvent, 5~8% emulsifier.
The solvent that is fit to: arene (as dimethylbenzene, toluene, Fluhyzon etc.), chlorinated aromatic hydrocarbons or chlorinated aliphatic class (as chlorobenzene, dichloroethane or carrene, chloroform), fat hydrocarbon (as cyclohexane etc.), ketone (as acetone, MEK, methyl iso-butyl ketone (MIBK) or cyclohexanone etc.), ethers, lipid, intensive polar solvent (as dimethyl formamide and dimethyl sulfoxide (DMSO) etc.).
The cosolvent that is fit to: alcohols (as methyl alcohol, ethanol, propyl alcohol, butanols, octanol etc.).
The emulsifier that is fit to: 0204 (+dialkyl benzene sulfonic acids calcium+alkylphenol polyoxyethylene), 2201 (dibutyl naphthalene sulfonic acids calcium+phenethyl phenol polyethenoxy ether), trip 2101, trip 2102.
Composition can also contain other additive such as stabilizing agent (as triphenyl phosphate, triphenyl phosphite, tributyl phosphate, BHT etc.), antifreezing agent (as ethylene glycol, glycerine, polyethylene glycol), bleeding agent, defoamer,, preservative or in order to obtain other active ingredient of special-effect.
Preparation method: with solvent and cosolvent dissolving piperazine humulone (can heating and stir in case of necessity), after treating that the piperazine humulone dissolves fully, add acetamide-group herbicides crude oil, emulsifier and other additive again, stir the back (can remove by filter sediment in case of necessity at last).
B, suspension emulsion (suspoemulsions)
Said preparation contains 5~40% piperazine humulones and 5~40% acetamide-group herbicides, 3~10% emulsifier, and 0.1~5% thickener, 0.5~5% antifreezing agent, dispersant 1~3%, surplus is a water.
The optimization formula of said preparation contains 10~30% piperazine humulones and 10~30% butachlors or Acetochlor, 5~8% emulsifier, and 0.1~3% thickener, 1~2% antifreezing agent, dispersant 1~3%, surplus is a water.
The emulsifier that is fit to: 0201B (dodecyl sodium sulfonate calcium ten dibenzyl xenol polyoxyethylene polyoxypropylene ethers)+Tween 80 (polyoxyethylene (20) sorbitan mono-oleic acid ester), trip 2101+ farming breast 500
#(dodecyl sodium sulfonate calcium), trip 2102+ farming breast 500
#
The thickener that is fit to: CMC (sodium carboxymethylcellulose), xanthans, polyvinyl alcohol, sodium alginate, diatomite, bentonite.
The dispersant that is fit to: sodium lignin sulfonate, No, NNO.
The antifreezing agent that is fit to: urea, ethylene glycol, polyethylene glycol, glycerine.
Can also contain other additive such as stabilizing agent, defoamer, preservative, bleeding agent, proportion conditioning agent in the composite preparation or in order to obtain other active ingredient of special-effect.
Preparation method: prepare material by proportioning provided by the invention, with agitator or manually stir, use colloid mill (or ball mill) to grind then, further be milled to the fineness that needs with sand mill again.
The present invention compares than prior art has following distinguishing feature:
1, reduces the dosage of piperazine humulone, improve the safety of crop.(table 1) ethysine suspension emulsion is to the antagonism (potted plant) of soybean, corn
The weed killer herbicide title | Dosage (gai/mu) | Soybean survival rate (%) | Dosage (gai/mu) | Corn survival rate (%) |
CK | - | 100 | - | 100 |
Acetochlor (X) | 40 | 93.5 | 40 | 90.6 |
Piperazine humulone (Y) | 40 | 100 | 40 | 87.2 |
Ethysine suspension emulsion (E) | 80 | 94.7 | 80 | 91.9 |
x·Y/100(Eo) | 93.5 | 93.5 | 79.0 | |
Synergy is differentiated | Antagonism | Antagonism |
Annotate: E>Eo is an antagonism, and E=Eo is addition, and E<Eo is synergy.The ratio of Acetochlor and piperazine humulone is 1: 1 in the ethysine suspension emulsion.2, enlarge grass spectrum extremely.
(table 2) piperazine humulone and Acetochlor are to the ED of weeds
50(potted plant)
Medicament | The piperazine humulone | Acetochlor |
The weeds title | Tong fiber crops lady's-grass black nightshade eleusine indica | Piemarker lady's-grass black nightshade eleusine indica |
ED 5O | 25.5 30.5 38.8 63.1 | >50 11.3 18.7<6.3 |
Annotate: 1. ED
50Be the dosage (gai/mu) of medicament inhibition weeds 90%, computational methods are referring to the chief editor of south China agricultural college " chemical protection of plant ".
2. the piperazine humulone is relatively poor to the eleusine indica preventive effect, and Acetochlor is relatively poor to the piemarker preventive effect, and using with can complementary defective separately, enlarges and kills the grass spectrum.
3, weeds such as lady's-grass, lamb's-quarters, piemarker there is synergistic effect, and can be used as the use of corn field soil treatment type weed killer herbicide.
The co-toxicity coefficient (potted plant) of (table 3) ethysine suspension emulsion
For the examination weeds | Acetochlor ED 50 | Piperazine humulone ED 50 | Ethysine suspension emulsion ED 50 | Co-toxicity coefficient |
Lady's-grass | 6.25 | 6.83 | 5.78 | 112.96 |
Piemarker | 10.48 | 3.79 | 4.56 | 122.10 |
Annotating (1) ethysine suspension emulsion proportioning is 1: 1. (2) ED
50Be the dosage of medicament inhibition weeds 50%, the gai/mu of unit (down together).
The co-toxicity coefficient (potted plant) of (table 4) ethysine missible oil
For examination weeds Acetochlor ED 50 piperazine humulone ED 50 ethysine suspension emulsion ED 50 co-toxicity coefficient |
Lady's-grass, lamb's-quarters 30.4 11.7 12.4 136.5 |
Annotate: the proportioning of ethysine missible oil is the co-toxicity coefficient (potted plant) of 2: 1 (table 5) fourth piperazine missible oil
For the examination weeds | Butachlor ED 50 | Piperazine humulone ED 50 | Ethysine suspension emulsion ED 50 | Co-toxicity coefficient |
Lady's-grass, lamb's-quarters | 26.3 | 26.2 | 18.3 | 143.7 |
Annotate: the proportioning of fourth piperazine missible oil is 2: 1
4, piperazine humulone and butachlor or Acetochlor are made mixture, more convenient in the use.Because the former medicine of piperazine humulone is insoluble in common organic solvents, be mixed with missible oil and acquire a certain degree of difficulty, the past generally is processed into wetting powder or dry suspending agent.But we find that piperazine humulone solvability in the compound solvent of some specific solvent such as the fragrant same clan and alcohols can improve greatly, can satisfy the requirement of preparation piperazine humulone and amide-type herbiciding composite dose (missible oil).The former medicine of piperazine humulone belongs to water insoluble solid again, and it and acetamide-group herbicides crude oil also are suitable for pesticides new formulation-suspension emulsion suspoemulsions) process or prepare.
5, good in economic efficiency.About 5~6 yuan of mu usefulness fourth piperazine or ethysine mixture cost, input-output ratio is: 1: 10~15.
Through internal authority World Patent Index (Britain Derwent), Chinese patent literature database, Weed Abstracts and U.S. chemical abstract (CA) retrieval find no all that piperazine humulone and butachlor or Acetochlor are used with and the report of mixture, therefore the present invention belongs to initiative both at home and abroad according to novelty is arranged.
Below be described in detail embodiments of the invention:
A) c a) b of missible oil))
Piperazine humulone 10% 10% 15%
Acetochlor 10% 20% 30%
Dimethylbenzene 50% 45% 25%
Methyl alcohol 25% 18% 25%
Emulsifier 2,201 5% 7% 5%
B) c a) b of suspension emulsion))
Piperazine humulone 20% 20% 20%
Butachlor 20% 20% 20%
Emulsifier travels 2,101 5% 6% 7%
Emulsifier farming breast 500 1.5% 1% 0.5%
CMC 2% 1.5% 1%
Urea 2% 2% 2%
NNO 1 1% 1%
Water surplus surplus surplus
Piperazine humulone and amide herbicide composition preparation are applicable to the weed control on multiple kinds of crops ground, as following crop: soybean, corn, peanut, potato, tomato, sugarcane, clover, asparagus, coffee etc., be particularly useful for soybean and corn intercrop ground, replenished China does not have fine herbicide at this type crop field blank.
Biological Examples
1, synergistic effect
The effect of the mixture of piperazine humulone and acetamide-group herbicides butachlor or Acetochlor, no matter when it all greater than the summation of the effect of single time spent of each active ingredient, promptly has synergistic effect to the effects of weeds.Method of discrimination adopts the abundant method of Sun Yun (referring to Zhang Ruiting " using with and mixture of agricultural chemicals ", Chemical Industry Press, 1987, P26~28), and co-toxicity coefficient is a summation action near 100, is synergistic effect greater than 100 obviously, is antagonism less than 100 significantly.From table 3~5 as seen, ethysine, fourth piperazine mixture are 112.96~143.7 to the co-toxicity coefficient of lady's-grass, lamb's-quarters, piemarker, and synergistic effect is promptly all arranged.
2, to the safety of crop
Safety to crop is estimated with Cobly method [referring to Zhang Fayan " herbicide mixture and interaction ", agricultural chemicals collected translation, 1985,7 (3)] and selectivity index (referring to the P413 of south China agricultural college " chemical protection of plant "~415).If mixture has antagonism or selectivity index more than or equal to 2 to crop, illustrate that mixture is safe to crop, otherwise be unsafe.As seen from Table 1, ethysine mixture E>Eo, mixture has antagonism to soybean and corn.From table 6, table 7 as seen, medicament all more than or equal to 2, illustrates that it is safe that medicament uses to the selectivity index of soybean or corn and weeds on soybean and corn.
(table 6) ethysine, fourth piperazine missible oil are to the selectivity of soybean and weeds
Medicament plant ED 10 ED 50 ED 60 | Selectivity index | ||||
Ethysine missible oil (2: 1) | Soybean | 62.2 | 197.7 | 2.1 | |
Lady's-grass+lamb's-quarters | 11.5 | 29.6 | |||
Ethysine missible oil (2: 1) | Soybean | 84.7 | 283 | 2.2 | |
Lady's-grass+lamb's-quarters | 19.1 | 38.5 |
Annotate: (1) ED
10~90Be the dosage of medicament inhibition weeds 10%~90%, the gai/mu of unit (2) selectivity index=crop ED
10/ weeds ED
90
(table 7) ethysine, fourth piperazine missible oil are to the selectivity of corn and weeds
Medicament plant ED 10 ED 50 ED 60 | Selectivity index | ||||
Ethysine missible oil (2: 1) | Corn | 61.2 | 194.1 | 2.0 | |
Lady's-grass+lamb's-quarters | 11.5 | 30.6 | |||
Ethysine missible oil (2: 1) | Corn | 108.9 | 180.7 | 2.8 | |
Lady's-grass+lamb's-quarters | 19.1 | 38.5 |
3, field control effectiveness test
45% ethysine, fourth piperazine missible oil use, have crop safety Beijing area soybean and corn field, enlarge and kill the grass spectrum, preventive effect is good, can effectively prevent and kill off advantages (referring to table 8 and table 9) such as the annual single, double cotyledon weeds in field, filled up the blank of soybean, corn intercrop ground no fine herbicide, the initial stage on probation just is subjected to the welcome of peasant household deeply.Because half life period of piperazine humulone is about 28 days, to succession crop can not produce poisoning (referring to the chief editor of medicine inspecting institute of the Ministry of Agriculture " newly organized agricultural chemicals handbook P532), and acetamide-group herbicides are shorter than the half life period of piperazine humulone, more do not have residual drug injury problem.
The herbicidal effect (Beijing Tong County, 1994 year July) of (table 8) two kinds of mixtures in soybean and corn field
Crop species | Medicament kind | Dose (gram/mu) | Chief of the Xiongnu in Acient China's leaf weeds | Two in the leaf weeds | ||||||
Strain number/chi 2 | Preventive effect (%) | Gram/chi 2 | Preventive effect (%) | Strain number/chi 2 | Preventive effect (%) | Gram/chi 2 | Preventive effect (%) | |||
Soybean | 45% ethysine missible oil | 100 150 | 5.7 5.3 | 92.2 92.7 | 22.0 10.3 | 93.4 96.9 | 3.7 5.7 | 91.1 86.2 | 9.6 9.0 | 97.0 97.2 |
45 fourth noise made in coughing or vomiting missible oil | 100 150 | 16.0 10.3 | 78.0 85.8 | 83 0 17.0 | 75.1 94.9 | 4.0 2.7 | 90.2 93.5 | 15.2 1.2 | 95.2 99.6 | |
CK | / | 72.7 | / | 333.3 | / | 41.0 | / | 316.7 | / | |
Corn | 45% ethysine missible oil | 100 150 | 8.0 5.0 | 90.6 94.1 | 7.7 7.7 | 98.1 98.1 | 0.5 0.3 | 90.6 94.4 | 0.8 0.2 | 81.3 96.7 |
45% fourth piperazine missible oil | 100 150 | 16.7 4.7 | 80.3 94.5 | 40.7 8.8 | 89.9 97.8 | 0.7 0.6 | 87.6 88.7 | 0.3 0.2 | 92.4 95.8 | |
40% second green bristlegrass mixture | 150 | 3.0 | 96.5 | 11.8 | 97.1 | 0.7 | 87.4 | 1.3 | 70.4 | |
CK | / | 84.7 | / | 402.3 | / | 5.3 | / | 4.5 | / |
Claims (3)
1, a kind of piperazine humulone and Acetochlor compound herbicide agent emulsifiable solution is characterized in that this missible oil contains piperazine humulone and the 5-40% Acetochlor of 5-40%, and wherein the ratio of piperazine humulone and Acetochlor was less than 2: 1.
2, a kind of piperazine humulone and Acetochlor suspension emulsion is characterized in that this suspension emulsion contains the piperazine humulone of 5-40% and the Acetochlor of 5-40%.
3, suspension emulsion according to claim 2 is characterized in that this suspension emulsion contains piperazine humulone and the 5-40% Acetochlor of 5-40%, 3-10% emulsifier 0201B+ Tween 80, trip 2101+ farming breast 500
#, trip 2102+ farming breast 500
#A kind of, a kind of in 0.1-5% thickener CMC, xanthans, polyvinyl alcohol, sodium alginate, diatomite, the bentonite; A kind of in 0.5-5% antifreezing agent urea, ethylene glycol, polyethylene glycol, the glycerine, a kind of among 1-3% dispersant sodium lignin sulfonate, NO, the NNO, surplus is a water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN96102443A CN1060912C (en) | 1996-03-05 | 1996-03-05 | Metribuzin-amide herbicide composition and preparation thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN96102443A CN1060912C (en) | 1996-03-05 | 1996-03-05 | Metribuzin-amide herbicide composition and preparation thereof |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN00109812A Division CN1092925C (en) | 2000-07-07 | 2000-07-07 | Metribuzin-amide herbicide composition and preparation thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1148465A CN1148465A (en) | 1997-04-30 |
CN1060912C true CN1060912C (en) | 2001-01-24 |
Family
ID=5117562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN96102443A Expired - Fee Related CN1060912C (en) | 1996-03-05 | 1996-03-05 | Metribuzin-amide herbicide composition and preparation thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1060912C (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104106576B (en) * | 2014-06-12 | 2017-01-04 | 广东中迅农科股份有限公司 | A kind of containing metazachlor with the Herbicidal combinations of metribuzin |
CN109430298A (en) * | 2018-12-29 | 2019-03-08 | 南京高正农用化工有限公司 | A kind of big granula of paddy field weed-killer and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4150968A (en) * | 1978-02-01 | 1979-04-24 | Mobay Chemical Corporation | Emulsifiable liquid concentrates containing 4-amino-6-t-butyl-3-(methylthio)-1,2,4-triazin-5-one and 2-chloro-N-(2,6-diethylphenyl)-N-methoxymethylacetamide |
US4381194A (en) * | 1981-02-09 | 1983-04-26 | Westvaco Corporation | Alkali lignin based pesticide phytotoxicity reducing composition |
CN1154201A (en) * | 1996-01-12 | 1997-07-16 | 大连经济技术开发区新星农药技术研究所 | Herbicide for maize field and soya-bean field |
-
1996
- 1996-03-05 CN CN96102443A patent/CN1060912C/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4150968A (en) * | 1978-02-01 | 1979-04-24 | Mobay Chemical Corporation | Emulsifiable liquid concentrates containing 4-amino-6-t-butyl-3-(methylthio)-1,2,4-triazin-5-one and 2-chloro-N-(2,6-diethylphenyl)-N-methoxymethylacetamide |
US4381194A (en) * | 1981-02-09 | 1983-04-26 | Westvaco Corporation | Alkali lignin based pesticide phytotoxicity reducing composition |
CN1154201A (en) * | 1996-01-12 | 1997-07-16 | 大连经济技术开发区新星农药技术研究所 | Herbicide for maize field and soya-bean field |
Also Published As
Publication number | Publication date |
---|---|
CN1148465A (en) | 1997-04-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101066055A (en) | Pesticide composition containing emamectin benzoate | |
CN1568145A (en) | Pesticide formulation composed of natural components | |
CN107668063A (en) | Pesticidal combination containing Biphenthrin and Rynaxypyr | |
CN101911955B (en) | Biogenic acaricidal water suspension composition and preparation method thereof | |
CN105685121A (en) | Botanical pesticide and preparation method thereof | |
CN1060912C (en) | Metribuzin-amide herbicide composition and preparation thereof | |
CN103380783B (en) | A kind of high-efficient pesticide composition | |
CN1078808C (en) | Plant pesticide | |
CN1092925C (en) | Metribuzin-amide herbicide composition and preparation thereof | |
CN110024803B (en) | Spirotetramat-containing insecticidal composition and preparation thereof | |
CN1957708A (en) | Pesticides composition of Avermectini and Fenbutatin Oxide | |
CN100399900C (en) | Pesticide composition containing avermectin and butyl ether urea and its application | |
CN1151723C (en) | Insecticide compounded with nimbin and rotenone | |
CN114680120A (en) | Insecticidal composition containing emamectin benzoate and cinnamaldehyde | |
CN110742099A (en) | Soil pesticide with slow release function and preparation method thereof | |
CN1111003C (en) | Compound herbicide suspending agent composition for wet-field | |
CN111011401A (en) | Mosquito killing medicament and preparation process thereof | |
CN109793000A (en) | A kind of 16% emamectin benzoate and indoxacarb mixing missible oil and preparation method thereof | |
CN107743973A (en) | A kind of composition pesticide containing Osthole | |
CN108812676A (en) | A kind of miticide composition and preparation method thereof | |
CN111248204B (en) | Insecticidal composition for preventing and treating flea beetles of radish strips | |
CN1243668A (en) | Mixture of benazolin-ethyl, quizalofop-p-ethyl and ethametsulfron and preparing process thereof | |
CN103109846B (en) | Dichlorovos kadethrine compounded pesticide | |
CN107372522A (en) | A kind of composition pesticide containing fenazaquin | |
CN101053326A (en) | Compound aid composition suiting for preparing micro emulsion of sesquiterenes |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C06 | Publication | ||
PB01 | Publication | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |