CN106086656A - A kind of multicomponent alloy liner plate being suitable to semi-autogenous mill use and processing technique thereof - Google Patents
A kind of multicomponent alloy liner plate being suitable to semi-autogenous mill use and processing technique thereof Download PDFInfo
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- CN106086656A CN106086656A CN201610696781.1A CN201610696781A CN106086656A CN 106086656 A CN106086656 A CN 106086656A CN 201610696781 A CN201610696781 A CN 201610696781A CN 106086656 A CN106086656 A CN 106086656A
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- liner plate
- semi
- multicomponent alloy
- autogenous mill
- processing technique
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0081—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/004—Dispersions; Precipitations
Abstract
The present invention relates to a kind of multicomponent alloy liner plate being suitable to semi-autogenous mill use and processing technique thereof, this multicomponent alloy liner plate is processed by melt iron, and the component of described melt iron mass percent is: carbon 1.1% 1.3%, silicon 0.3% 0.8%, manganese 11% 14%, chromium 0.8% 1.5%, molybdenum 0.10% 0.5%, vanadium 0.3% 0.7%, titanium 0.05% 0.2%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum.Technical scheme provides a kind of novel liner plate being suitable to large-scale semi-autogenous mill, and this liner plate meets large-scale Semi-Autogenous liner plate to wearability, the requirement of obdurability, and it uses cycle long, cheap, greatly reduces the cost in ore dressing plant.
Description
Technical field
The present invention relates to the technical field of a kind of multicomponent alloy liner plate, particularly relate to a kind of semi-autogenous mill that is suitable to and use many
Unit's alloy lining and processing technique thereof.
Background technology
At present, domestic and international large-scale semi-autogenous mill liner plate many employings high carbon chromium molybdenum alloy liner plate.High carbon chromium molybdenum alloy liner plate because of
Carbon content and alloy content are the highest, so impact flexibility all ratios are relatively low, impact value typically only has 30-40 joule, and it is second highest
Carbon chrome molybdenum liner plate, since it is desired that ensure have certain toughness of rushing, generally uses during heat treatment and air-cooled adds tempering process,
To being organized as secondary troostite, this moderate wearability of tissue hardness is poor.Owing to semi-autogenous mill diameter is the biggest, therefore partly
Autogenous grinding will be more serious than ball mill to the impact of liner plate and abrasion in operation process.So that high carbon chromium molybdenum alloy liner plate makes
There is easy fracture during with and wear no resistance, liner plate uses the cycle shorter to wait deficiency so that ore dressing plant needs frequently more rebush
Plate, greatly reduces operation rate and increases the operation cost in ore dressing plant.
Summary of the invention
The technical problem to be solved is how to provide a kind of novel liner plate being suitable to large-scale semi-autogenous mill, with
Meet large-scale Semi-Autogenous liner plate to wearability, the requirement of obdurability, and liner plate can be extended use the cycle, cheap, significantly drop
The cost in low ore dressing plant.
The technical scheme is that
A kind of multicomponent alloy liner plate being suitable to semi-autogenous mill use, is processed by melt iron, described smelting iron water quality
The component of amount percentage ratio is: carbon 1.1%-1.3%, silicon 0.3%-0.8%, manganese 11%-14%, chromium 0.8%-1.5%, molybdenum
0.10%-0.5%, vanadium 0.3%-0.7%, titanium 0.05%-0.2%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum.
Compared with prior art, the invention has the beneficial effects as follows: the multicomponent alloy liner plate of the present invention has high-wearing feature, resistance to
The feature such as impact, high-yield strength, solves semi-autogenous mill high carbon chromium molybdenum alloy liner plate in use easy fracture and resistance to
The deficiency that the mill property difference liner plate use cycle is shorter, can be widely applied to Semi-Autogenous.
The invention also discloses a kind of processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses, this processing technique
Including: (a) casting: by melt iron casting, obtain as cast condition liner plate;B as cast condition liner plate is carried out heat treatment by (), obtain
The described multicomponent alloy liner plate being suitable to semi-autogenous mill use.
Use technique scheme provide the benefit that: the processing technique of the present invention have simple to operate, make polynary
Alloy lining has the advantages such as high-wearing feature, resistance to impact, high-yield strength.
Further, described casting method particularly includes: melt iron is cast in the resin accomplished fluently in advance from hard
Molding in sand mold chamber, removes dead head and makes as cast condition liner plate after molding.
Above-mentioned further scheme is used to provide the benefit that: the method using this casting, the multicomponent alloy of preparation
Liner plate has the features such as high-wearing feature, resistance to impact, high-yield strength, solves semi-autogenous mill high carbon chromium molybdenum alloy liner plate and makes
During with, easy fracture and the liner plate that wears no resistance use cycle shorter deficiency.
Further, described melt iron tapping temperature is 1450~1480 DEG C, and pouring temperature is 1380~1420 DEG C.
Above-mentioned further scheme is used to provide the benefit that: suitably tapping temperature and pouring temperature, beneficially molten iron
Stamp;If pouring temperature is too low, the problems such as foundry goods rarefaction defect easily occur;If temperature is too high, foundry goods group easily occurs
Knit the problems such as thick.
Further, described as cast condition liner plate heat treatment method particularly includes: be incubated after as cast condition liner plate is heated up, quench afterwards,
Last precipitation process.
Above-mentioned further scheme is used to provide the benefit that: to use this heat treatment so that the liner plate processed has
There are the advantages such as high-wearing feature, resistance to impact, high-yield strength.
Further, be incubated after described as cast condition liner plate heats up concretely comprises the following steps: the as cast condition liner plate that will make loads at heat
Reason stove, carry out time below 650 DEG C with the ramp of 50~80 DEG C/min, be warming up to 650 DEG C and be incubated 3h, 650 DEG C with
With the ramp of 100~120 DEG C/min time upper, being warming up to 1050~1070 DEG C, the time of insulation is 5~6h.
Use above-mentioned further scheme to provide the benefit that: suitably temperature retention time and holding temperature, be conducive to uniformly
Tiny austenite crystal is formed;If the time is too short, temperature is too low, easily occur austenitizing not exclusively or austenitizing not
The problem such as uniformly;If overlong time, temperature are too high, the problem that austenite crystal is thick easily occurs.
Further, described quenching, the concretely comprising the following steps of precipitation process: with 50~80 DEG C/min after as cast condition liner plate is quenched
Speed again heat up, be warmed up to 400 DEG C and when 400 DEG C be incubated 4h, last air cool down.
Above-mentioned further scheme is used to provide the benefit that: to use this temperature and cool time to be conducive to single austenite
Organizing the formation of of upper Dispersed precipitate carbide, if the time is too short or the too low meeting of holding temperature makes carbide increase, will be serious
Affect the toughness of liner plate.
Accompanying drawing explanation
Fig. 1 is the microstructure figure of multicomponent alloy liner plate of the present invention.
Detailed description of the invention
Being described principle and the feature of the present invention below in conjunction with accompanying drawing, example is served only for explaining the present invention, and
Non-for limiting the scope of the present invention.
Be suitable to, as it is shown in figure 1, a kind of, the multicomponent alloy liner plate that semi-autogenous mill uses, melt iron process, described
The component of melt iron mass percent is: carbon 1.1%-1.3%, silicon 0.3%-0.8%, manganese 11%-14%, chromium 0.8%-
1.5%, molybdenum 0.10%-0.5%, vanadium 0.3%-0.7%, titanium 0.05%-0.2%, phosphorus < 0.05%, sulfur < 0.03%.These are many
It is broken that unit's alloy lining solves high carbon chromium molybdenum alloy liner plate used by conventional semi-autogenous mill liner plate, the wearability poor use cycle
The shortcoming that shorter needs are frequently changed.This kind of material liner plate is applicable to large-scale semi-autogenous mill liner plate.This material is large-scale by half to meet
Autogenous grinding liner plate, to wearability, the requirement of obdurability, optimizes liner plate chemical composition, and potassium steel carries out alloying, add vanadium,
The alloy such as titanium, molybdenum suppresses the shortcoming that potassium steel ductility is big, and have employed unique Technology for Heating Processing, it is carried out disperse strong
Change processes, and makes liner plate impact flexibility 65-136J/cm2, use hardness to reach 52-58HRC, the key technical indexes reaches domestic and international
The advanced level of like product, price but reduces by more than 20% than high carbon chromium molybdenum alloy liner plate, can meet quality and the property of user
Can requirement.
Above-mentioned multicomponent alloy liner plate production status is the liner plate of heat treatment, including following machining process:
(a) casting: melt iron is cast in molding in the resin self-setting sand die cavity accomplished fluently in advance, removes after molding
Dead head makes as cast condition liner plate.
Wherein, melt iron tapping temperature is 1450~1480 DEG C, and pouring temperature is 1380~1420 DEG C.Resin self-setting sand
Moulding process, removes dead head and makes as cast condition liner plate after molding.Suitably tapping temperature and pouring temperature, beneficially molten iron punching
Type;If pouring temperature is too low, the problems such as foundry goods rarefaction defect easily occur;If temperature is too high, cast structure easily occurs
The problem such as thick.
Described melt iron includes the component of following mass percent: carbon 1.1%-1.3%, silicon 0.3%-0.8%, manganese
11%-14%, chromium 0.8%-1.5%, molybdenum 0.10%-0.5%, vanadium 0.3%-0.7%, titanium 0.05%-0.2%, phosphorus <
0.05%, sulfur < 0.03%, surplus is ferrum.
B as cast condition liner plate is carried out heat treatment by (): be incubated after being heated up by as cast condition liner plate, quench afterwards, last precipitation process.
What as cast condition liner plate was incubated after heating up concretely comprises the following steps: the as cast condition liner plate that will make loads heat-treatment furnace, heats up
Isothermal holding, is carried out time below 650 DEG C with the ramp of 50~80 DEG C/min, is warming up to 650 DEG C and is incubated 3h, 650
With the ramp of 100~120 DEG C/min time more than DEG C, be warming up to austenitizing insulation temperature 1050~1070 DEG C, insulation
Time be 5~6h.Suitably temperature retention time and holding temperature, is conducive to the most tiny austenite crystal to be formed;If
Time is too short, temperature is too low, easily occurs that austenitizing is incomplete or the problem such as austenitizing is uneven;If overlong time,
Temperature is too high, the problem that austenite crystal is thick easily occurs.
Quenching, the concretely comprising the following steps of precipitation process: again rise with the speed of 50~80 DEG C/min after as cast condition liner plate is quenched
Temperature, is warmed up to 400 DEG C and is incubated 4h when 400 DEG C, and last air cools down, and multicomponent alloy liner plate manufacture completes.It is worth explanation
It is to use this temperature and cool time to be conducive to organizing the formation of of Dispersed precipitate carbide on single austenite, if the time
The too low meeting of too short or holding temperature makes carbide increase, and will have a strong impact on the toughness of liner plate.
Because heat treatment process is not related to the change of component, so the as cast condition abrading-ball that obtains of step (a) and through Overheating Treatment
After the component of the multicomponent alloy liner plate of step (b) that obtains be consistent.
It is below the processing technique specific embodiment of multicomponent alloy liner plate of the present invention:
Embodiment one
A kind of processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses, including following technical process:
(a) casting:
Melt iron tapping temperature 1480 DEG C, pouring temperature 1420 DEG C.Resin self-setting sand moulding process.Remove after molding and water
Rising head makes as cast condition liner plate.
Melt iron includes the component of following mass percent: carbon 1.2%, silicon 0.45%, manganese 12.4%, chromium 1.0%, molybdenum
0.2%, vanadium 0.3%, titanium 0.1%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum.
The final multicomponent alloy liner plate for preparing includes the component of following mass percent: carbon 1.2%, silicon 0.45%, manganese
12.4%, chromium 1.0%, molybdenum 0.2%, vanadium 0.3%, titanium 0.1%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum;
B as cast condition liner plate is carried out heat treatment by (): as cast condition liner plate loads heat-treatment furnace, heating and heat preservation, and austenitizing is incubated
Temperature 1050 DEG C, is incubated 5h, quenching, precipitation process, completes the manufacture of multicomponent alloy liner plate.
Embodiment two
A kind of processing technique being suitable to the austenic globe body abrading-ball that semi-autogenous mill uses, including following technical process:
(a) casting:
Melt iron tapping temperature 1470 DEG C, pouring temperature 1400 DEG C.Resin self-setting sand moulding process.Remove after molding and water
Rising head makes as cast condition liner plate.
Melt iron includes the component of following mass percent: carbon 1.1%, silicon 0.6%, manganese 11.8%, chromium 1.2%, molybdenum
0.3%, vanadium 0.45%, titanium 0.15%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum.
The final multicomponent alloy liner plate for preparing includes the component of following mass percent: carbon 1.1%, silicon 0.6%, manganese
11.8%, chromium 1.2%, molybdenum 0.3%, vanadium 0.45%, titanium 0.15%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum;
B as cast condition liner plate is carried out heat treatment by (): as cast condition liner plate loads heat-treatment furnace, heating and heat preservation, and austenitizing is incubated
Temperature 1070 DEG C, is incubated 5h, quenching, precipitation process, completes the manufacture of multicomponent alloy liner plate.
Embodiment three
A kind of processing technique being suitable to the austenic globe body abrading-ball that semi-autogenous mill uses, including following technical process:
(a) casting:
Melt iron tapping temperature 1450 DEG C, pouring temperature 1380 DEG C.Resin self-setting sand moulding process.Remove after molding and water
Rising head makes as cast condition liner plate.
Melt iron includes the component of following mass percent: carbon 1.3%, silicon 0.5%, manganese 13%, chromium 1.5%, molybdenum
0.3%, vanadium 0.5%, titanium 0.15%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum.
The final multicomponent alloy liner plate for preparing includes the component of following mass percent: carbon 1.3%, silicon 0.5%, manganese 13%,
Chromium 1.5%, molybdenum 0.3%, vanadium 0.5%, titanium 0.15%, phosphorus < 0.05%, sulfur < 0.03%, surplus is ferrum;
B as cast condition liner plate is carried out heat treatment by (): as cast condition liner plate loads heat-treatment furnace, heating and heat preservation, and austenitizing is incubated
Temperature 1070 DEG C, is incubated 6h, quenching, precipitation process, completes the manufacture of multicomponent alloy liner plate.
The multicomponent alloy liner plate of embodiment one to embodiment three is carried out Mechanics Performance Testing, simultaneously by high carbon chromium molybdenum alloy
Liner plate is as a control group.
One, detection method: with reference to inspection method commonly used in the art.
1, hardness detection method: cut open by liner plate, tests hardness number by Rockwell hardness experimental machine, and centre hardness is heart portion
Hardness minimum, appearance hardness is hardness peak at distance appearance 1~2mm.
2, impact value detection method: line cuts through the centre of sphere and removes 10 × 10 × 55 impact specimens, impact test machine testing impacts
Value.
Two, testing result:
High carbon chromium molybdenum alloy liner plate sample block inspection result is as follows:
Multicomponent alloy liner plate sample block inspection result is as follows:
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (7)
1. one kind is suitable to the multicomponent alloy liner plate that semi-autogenous mill uses, it is characterised in that processed by melt iron, described molten
The component of ironmaking water quality percentage ratio is: carbon 1.1%-1.3%, silicon 0.3%-0.8%, manganese 11%-14%, chromium 0.8%-
1.5%, molybdenum 0.10%-0.5%, vanadium 0.3%-0.7%, titanium 0.05%-0.2%, phosphorus < 0.05%, sulfur < 0.03%, surplus
For ferrum.
2. being suitable to a processing technique for the multicomponent alloy liner plate that semi-autogenous mill uses as claimed in claim 1, its feature exists
In, this processing technique includes:
A () casting: by melt iron casting, obtains as cast condition liner plate;
B as cast condition liner plate is carried out heat treatment by (), obtain described in be suitable to semi-autogenous mill use multicomponent alloy liner plate.
The processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses the most according to claim 2, it is characterised in that
Described casting method particularly includes: melt iron is cast in molding in the resin self-setting sand die cavity accomplished fluently in advance, molding
After remove dead head and make as cast condition liner plate.
The processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses the most according to claim 3, it is characterised in that
Described melt iron tapping temperature is 1450~1480 DEG C, and pouring temperature is 1380~1420 DEG C.
The processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses the most according to claim 2, it is characterised in that
Described as cast condition liner plate heat treatment method particularly includes: be incubated after as cast condition liner plate is heated up, quench afterwards, last precipitation process.
The processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses the most according to claim 5, it is characterised in that
What described as cast condition liner plate was incubated after heating up concretely comprises the following steps: the as cast condition liner plate that will make loads heat-treatment furnace, time below 650 DEG C
Carry out with the ramp of 50~80 DEG C/min, be warming up to 650 DEG C and be incubated 3h, time more than 650 DEG C with 100~120 DEG C/
The ramp of min, is warming up to 1050~1070 DEG C, and the time of insulation is 5~6h.
The processing technique being suitable to the multicomponent alloy liner plate that semi-autogenous mill uses the most according to claim 5, it is characterised in that
Described quenching, the concretely comprising the following steps of precipitation process: again heat up with the speed of 50~80 DEG C/min after being quenched by as cast condition liner plate, rise
Temperature to 400 DEG C insulation 4h, the cooling of last air when 400 DEG C.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107779781A (en) * | 2017-10-25 | 2018-03-09 | 江苏京成机械制造有限公司 | A kind of ore-benificiating ball grinder liner plate manufacture method |
CN115852235A (en) * | 2022-12-07 | 2023-03-28 | 中国铁建高新装备股份有限公司 | Method for alloying high-tensile-strength high-manganese steel |
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CN1136086A (en) * | 1996-01-25 | 1996-11-20 | 西安电力机械厂 | Wearproof alloy with high manganese content |
CN101961668A (en) * | 2010-10-28 | 2011-02-02 | 淮阴工学院 | Ball mill groove type lining plate capable of fixing material cushion layer and manufacturing method thereof |
CN102242314A (en) * | 2011-01-17 | 2011-11-16 | 王军祥 | Multiple alloy toughened and wear-resistant middle-manganese steel and preparation technology thereof |
CN102534405A (en) * | 2011-12-07 | 2012-07-04 | 铜陵安东铸钢有限责任公司 | High manganese steel and preparation method thereof |
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JPH01234548A (en) * | 1988-03-15 | 1989-09-19 | Japan Steel Works Ltd:The | High-toughness roll for rolling |
CN1136086A (en) * | 1996-01-25 | 1996-11-20 | 西安电力机械厂 | Wearproof alloy with high manganese content |
CN101961668A (en) * | 2010-10-28 | 2011-02-02 | 淮阴工学院 | Ball mill groove type lining plate capable of fixing material cushion layer and manufacturing method thereof |
CN102242314A (en) * | 2011-01-17 | 2011-11-16 | 王军祥 | Multiple alloy toughened and wear-resistant middle-manganese steel and preparation technology thereof |
CN102534405A (en) * | 2011-12-07 | 2012-07-04 | 铜陵安东铸钢有限责任公司 | High manganese steel and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107779781A (en) * | 2017-10-25 | 2018-03-09 | 江苏京成机械制造有限公司 | A kind of ore-benificiating ball grinder liner plate manufacture method |
CN115852235A (en) * | 2022-12-07 | 2023-03-28 | 中国铁建高新装备股份有限公司 | Method for alloying high-tensile-strength high-manganese steel |
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