CN106085575A - Water-based metal cutting fluid and preparation method thereof - Google Patents
Water-based metal cutting fluid and preparation method thereof Download PDFInfo
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- CN106085575A CN106085575A CN201610516662.3A CN201610516662A CN106085575A CN 106085575 A CN106085575 A CN 106085575A CN 201610516662 A CN201610516662 A CN 201610516662A CN 106085575 A CN106085575 A CN 106085575A
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- Prior art keywords
- parts
- agent
- water
- metalworking fluid
- active component
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- 238000002360 preparation method Methods 0.000 title claims abstract description 45
- 239000002173 cutting fluid Substances 0.000 title abstract description 19
- 229910052751 metal Inorganic materials 0.000 title abstract description 7
- 239000002184 metal Substances 0.000 title abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 108
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 50
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- 239000003995 emulsifying agent Substances 0.000 claims abstract description 38
- 239000013556 antirust agent Substances 0.000 claims abstract description 36
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims abstract description 35
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims abstract description 35
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000005642 Oleic acid Substances 0.000 claims abstract description 35
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims abstract description 35
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 241001609931 bacterium 20 Species 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 229940039696 lactobacillus Drugs 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- XRRONFCBYFZWTM-UHFFFAOYSA-N octadecanoic acid;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCCC(O)=O XRRONFCBYFZWTM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002972 pentoses Chemical class 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
Classifications
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/087—Boron oxides, acids or salts
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
-
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/144—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/40—Fatty vegetable or animal oils
- C10M2207/402—Castor oils
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/10—Amides of carbonic or haloformic acids
- C10M2215/102—Ureas; Semicarbazides; Allophanates
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
- C10M2215/226—Morpholines
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- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
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- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
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- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
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Abstract
The invention discloses a water-based metal cutting fluid and a preparation method thereof, wherein the water-based metal cutting fluid comprises the following raw materials in parts by weight: 15-30 parts of base oil; 0.5-20% of emulsifier; 3-20 parts of an antirust agent; 2-10 parts of oleic acid; 0.5-20 parts of active component; 40-50 parts of water; 0.3-0.5 part of bactericide; 1-1.5 parts of a penetrating agent; 0.02-0.1 part of defoaming agent, and the preparation method comprises the following steps: heating the base oil to 50-60 ℃, adding the emulsifier, continuously heating to 80 ℃, and stirring for 30 min; heating to 90 deg.C, and stirring for 20 min; adding active components, stirring for 30min, adding oleic acid, stirring for 20min, and cooling to 40 deg.C; and (3) obtaining a mixture, adding the mixture into a mixed solution of an antirust agent, a penetrating agent and water, stirring for 1h, then adding a bactericide and a defoaming agent, and stirring for 1-3 h to obtain the water-based metal cutting fluid. The water-based metal cutting fluid composition disclosed by the invention contains a novel active component benzotriazole derivative, and has the outstanding lubricating property and hard water resistance stability, and the benzotriazole derivative, the emulsifier, the lubricant and the defoamer play a role together.
Description
Technical field
The present invention relates to a kind of metal working fluid, especially a kind of aqua type metalworking fluid and preparation method thereof.
Background technology
Cutting fluid is a kind of important industrial type fluid, may be used for playing in metal cutting and process of metal working cold
But, lubricate and the effect that prevents workpiece from getting rusty.The metal of one fine quality should have lubrication, cool down, clean and environmental protection,
The performance such as nontoxic.Present stage Novel cutting liquid component and formula remain the focus of scientific research.As patent CN102268318B is " water base
Cutting fluid composite and preparation method thereof " disclosed in cutting fluid contain newly synthesized phosphate amine salt class active component, simultaneously with
The components such as base oil, emulsifying agent, antirust agent jointly act on and obtain the cutting fluid that resistance to hard water is strong.Patent CN1002736324A
Cutting fluid disclosed in " preparation method of a kind of rust preventive cutting fluid " contain machinery oil, oleic acid, alkenyl succinic acid, surfactant,
The components such as boric acid, mixing hydramine, have the advantage of low cost, excellent performance, environmental protection, low toxicity.
Summary of the invention
It is an object of the invention to solve at least the above and/or defect, and at least will be described later excellent is provided
Point.
In order to realize according to object of the present invention and further advantage, it is provided that a kind of aqua type metalworking fluid, its
It is characterised by, including the raw material of following weight portion: base oil 15-30 part；Emulsifying agent 0.5-20 part；Antirust agent 3-20 part；Oleic acid
2-10 part；Active component 0.5-20 part；Water 40-50 part；Antibacterial 0.3-0.5 part；Penetrating agent 1-1.5 part；Defoamer 0.02-
0.1 part.
Preferably, any one during described base oil is paraffin base oil, naphthenic base oils, synthetic base oil
Kind；
Described emulsifying agent is oleic acid diethyl amide, alkylolamides phosphate ester, C5-C25Fatty alcohol-polyoxyethylene ether in
Any one；
Described antirust agent is the group of one or more in citric acid, borate, hydramine, sodium benzoate, ammonium molybdate, carbamide
Close；
Described oleic acid is the group of one or more in ricinoleic acid, palmitoleic acid, oleic acid, linoleic acid, tall oil acid
Close；
Described antibacterial be containing s-triazine, isothiazolone, benzene oxygen alcohols, morpholine chemical constituent in one；
Described penetrating agent is any one in propandiol butyl ether, butyl glycol ether, diethylene glycol ether；
Described defoamer is any one in polyethers defoamer, emulsified silicone oil, phosphate ester；
Described active component is that the molecular formula of Benzotriazole Derivative is:
Wherein, X is CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH
(CH2)7COO(CH2CH2O)nOne in-, described n=1-10.
The present invention also provides for the preparation method of a kind of above-mentioned aqua type metalworking fluid, it is characterised in that including: take base
Plinth oil is heated to 50～60 DEG C, adds emulsifying agent, continues to be heated to 80 DEG C, stirs 30min；It is warmed up to 90 DEG C, continues stirring
20min；Add active component, stir 30min, add oleic acid and continue stirring 20min, cool to 40 DEG C；Obtain mixture, will be mixed
Compound adds in the mixed liquor of antirust agent, penetrating agent and water, and stirs 1h, is subsequently adding antibacterial, defoamer, stirs 1～3h,
Obtain aqua type metalworking fluid；
Preferably, the composition of aqua type metalworking fluid also includes: dispersant 0.1-0.5 part；Extreme pressure anti-wear additives 0.05-
0.1 part；Fermentation liquid 1～3 parts；Antisettling agent 1～3 parts；
Described dispersant is 1-ethyl-3-methylimidazole acetate, chlorination 1-butyl-3-Methylimidazole., 1-butyl-3-first
Any one in base tetrafluoroborate, 1-hexyl-3-methylimidazolium nitrate, 1-ethyl-3-methyllimidazolium bromide.
Described extreme pressure anti-wear additives is the one in sodium metaborate, potassium metaborate and three potassium borates；
Described antisettling agent is dodecylbenzene sodium sulfonate, quaternary ammonium salt high-molecular copolymer, anionic carboxylic acid copolymer, non-
One in ion polyurethanes.
Preferably, described antirust agent includes the raw material of following weight portion: inositol hexaphosphate 40-60 part, 1-hydroxy benzenes
And triazole 20～25 parts, Butylated hydroxyanisole 6～8 parts, polyhydric alcohol 5～8 parts, tripolycyanamide 1～3 parts, poly-aspartate 1～
3 parts, fatty acid alkanol amides 5～10 parts, oxalic acid 1～5 parts, chitosan 5～10 parts, water 50～80 parts.
Preferably, described defoamer includes the raw material of following weight portion: polypropylene glycol sodium stearate 20～30 parts, isopropyl
Alcohol 6～8 parts, epoxychloropropane 5～8 parts, liquid paraffin 10～20 parts, ethylenedistearamide 10～15 parts, calcium chloride 5～8
Part, Carboxymethyl cellulose sodium 3～5 parts, potassium iodide 1～3 parts, lecithin 1～3 parts, iron chloride 1～3 parts, water 20～30 parts.
The present invention also provides for the preparation method of a kind of above-mentioned aqua type metalworking fluid, including: take base oil and be heated to
50～60 DEG C, add emulsifying agent, continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, adds antisettling agent while stirring,
Continue stirring 20min；Add active component, stir 30min, add oleic acid and continue stirring 20min, cool to 40 DEG C；Mixed
Compound, feeds the mixture in the mixed liquor of antirust agent, penetrating agent, dispersant, fermentation liquid and water, and stirs 1h, be subsequently adding
Antibacterial, defoamer, extreme pressure anti-wear additives, stir 1～3h, obtain aqua type metalworking fluid.
Preferably, described active component is Benzotriazole Derivative, and its molecular formula is:
Wherein, X is CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH
(CH2)7COO(CH2CH2O)nOne in-, described n=1-10；
The preparation method of described active component is: by weight, 15～20 parts of 5-carboxy benzotriazoles are dissolved in 80～
In 120 parts of solvents, heating and temperature control is at 50-60 DEG C while stirring, to be dissolved uniformly after, add 40～60 parts of polymerization degree n=
One in the Polyethylene Glycol monostearate of 1-10, polyethylene glycol monooleate or Polyethylene Glycol mono laurate fat, adds
The p-methyl benzenesulfonic acid of 1.5～2 parts, is warming up to backflow, maintains reaction 1～3 hour, and in water knockout drum during anhydrous generation, decompression is steamed
Evaporate removing solvent and obtain active component.
Preferably, described fermentation liquid preparation method be: by weight, take starch 30～50 parts, Rhizoma amorphophalli powder 20～
30 parts, molasses 5～10 parts, bagasse 5～10 parts, fucoidin 3～5 parts, ammonium molybdate 5～8 parts, sodium selenate 3～5 parts, water 50
～80 parts, add fermentation tank and stir；Then use ultraviolet that the fermented feed liquid in fermentation tank is carried out sterilization processing, ultraviolet
Adding leaven 6～8 parts after having sterilized, and stir, then carry out first stage fermentation, fermentation jar temperature is maintained at 22
～25 DEG C, airtight stirring every day 10-15min during first stage fermentation, not can opening venting, continue 2～3 days, then enter
Row second stage is fermented, and fermentation jar temperature is maintained at 26～30 DEG C, and during second stage fermentation, every day opens fermentation tank and enters
Row venting, and stirring 5～8min simultaneously, continue 8～10 days, complete fermentation, then filter, remove filtering residue, obtain fermentation liquid；Institute
The wavelength stating ultraviolet is 180-280nm, and the ultraviolet-sterilization time is 25～30min；
Preferably, described leaven is mixed by the seed liquor of following weight portion: bacillus bifidus 15～20 parts, pentose
Lactobacillus 6～10 parts, Candida utilis 5～10 parts, white light color streptomycete 10～18 parts, trichoderma reesei 15～20 parts, unwrapping wire
Bacterium 20～25 parts.
The pH of the aqua type metalworking fluid that the present invention obtains is 6.5-8, and the use temperature of aqua type metalworking fluid is
5-50℃。
The present invention at least includes following beneficial effect: the water-base metal coolant composition of the present invention, due to containing novel
Active component Benzotriazole Derivative, together plays a role with emulsifying agent, lubricant, defoamer, have prominent lubricity and
Hard water resistance stability, is attached to effective group of antirust agent Yu emulsifying agent in a molecule by chemical synthesis simultaneously, makes
One component has emulsifying and antirust effect concurrently simultaneously.By screening best composition, obtain function admirable, low cost, environmental protection
Aqua type cutting fluid, it can significantly improve the stability of cutting fluid, illustrate that it has preferable emulsifying capacity, workpiece corrosion journey
Degree substantially alleviates, and good antirust ability has been described, hence it is evident that reduces the abrasion of workpiece, illustrates that utensil has preferable lubricity.With
Time this cutting fluid also have prevent workpiece oxidation, little to harm, be unlikely to deteriorate, reduce the processing advantage such as noise.
Part is embodied by the further advantage of the present invention, target and feature by description below, and part also will be by this
Invention research and practice and be understood by the person skilled in the art.
Detailed description of the invention:
Below in conjunction with embodiment, the present invention is described in further detail, to make those skilled in the art with reference to description
Word can be implemented according to this.
Should be appreciated that used herein such as " have ", " comprising " and " including " term do not allot one or many
Other element individual or the existence of a combination thereof or interpolation.
Embodiment 1:
A kind of aqua type metalworking fluid, including following raw material: base oil 28g；Emulsifying agent 2.5g；Antirust agent 4g；Oleic acid
4.5g；Active component 5g；Water 54.48g；Antibacterial 0.5g；Penetrating agent 1g；Defoamer 0.02g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, continues stirring 20min；Add active component, stir 30min, add
Oleic acid continues stirring 20min, cools to 40 DEG C；Obtain mixture, feed the mixture into the mixed liquor of antirust agent, penetrating agent and water
In, and stir 1h, it is subsequently adding antibacterial, defoamer, stirs 1h, obtain aqua type metalworking fluid；
Described base oil 150SN base oil；Described emulsifying agent is AEO-30；Described antirust agent is sodium benzoate and the 2g of 2g
Triethanolamine mix；Described oleic acid is palmitoleic acid OL-7519；Described antibacterial is triazine and the 0.3g of 0.2g
Quinoline mixes；Described penetrating agent is propandiol butyl ether；Described defoamer is emulsified silicone oil；
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 100mL first
In benzene, heating and temperature control is at 50-60 DEG C while stirring, to be dissolved uniformly after, add 52gEGMS (ethylene glycol monostearate
Fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, in water knockout drum during anhydrous generation, subtract
Pressure is distilled off solvent and obtains active component.
Embodiment 2:
A kind of aqua type metalworking fluid, including following raw material: base oil 29g；Emulsifying agent 3.2g；Antirust agent 6g；Oleic acid
4.7g；Active component 6g；Water 49.68g；Antibacterial 0.5g；Penetrating agent 1g；Defoamer 0.02g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, continues stirring 20min；Add active component, stir 30min, add
Oleic acid continues stirring 20min, cools to 40 DEG C；Obtain mixture, feed the mixture into the mixed liquor of antirust agent, penetrating agent and water
In, and stir 1h, it is subsequently adding antibacterial, defoamer, stirs 1h, obtain aqua type metalworking fluid；
Described base oil 150SN base oil；Described emulsifying agent is AEO-30；Described antirust agent is sodium benzoate and the 2g of 2g
Triethanolamine mix；Described oleic acid is palmitoleic acid OL-7519；Described antibacterial is triazine and the 0.3g of 0.2g
Quinoline mixes；Described penetrating agent is propandiol butyl ether；Described defoamer is emulsified silicone oil；
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 100mL first
In benzene, heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, add 52gDEGMS (diethylene glycol monostearate
Fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, in water knockout drum during anhydrous generation, subtract
Pressure is distilled off solvent and obtains active component.
Embodiment 3:
A kind of aqua type metalworking fluid, including following raw material: base oil 29g；Emulsifying agent 3.2g；Antirust agent 5g；Oleic acid
4.7g；Active component 5g；Water 51.58g；Antibacterial 0.3g；Penetrating agent 1.2g；Defoamer 0.02g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, continues stirring 20min；Add active component, stir 30min, add
Oleic acid continues stirring 20min, cools to 40 DEG C；Obtain mixture, feed the mixture into the mixed liquor of antirust agent, penetrating agent and water
In, and stir 1h, it is subsequently adding antibacterial, defoamer, stirs 2h, obtain aqua type metalworking fluid；
Described base oil 150N base oil；Described emulsifying agent is OP-4；Described antirust agent is carbamide and the 2.5g of 2.5g
Borate mixes；Described oleic acid is linoleic acid TZSW；Described antibacterial be the triazine of 0.1g and 0.2g morpholine mixing and
Become；Described penetrating agent is propandiol butyl ether；Described defoamer is emulsified silicone oil；
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 100mL first
In benzene, heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, (PEG400 list is hard to add 52gPEG400ML
Fat acid fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, treat anhydrous generation in water knockout drum
Time, decompression is distilled off solvent and obtains active component.
The reaction expression that wherein prepared by the active component of embodiment 1～3 is:
Embodiment 4:
A kind of aqua type metalworking fluid, including following raw material: base oil 29g；Emulsifying agent 4.3g；Antirust agent 3.6g；Oil
Acid 5.2g；Active component 7g；Water 49.27g；Antibacterial 0.4g；Penetrating agent 1.2g；Defoamer 0.03g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, continues stirring 20min；Add active component, stir 30min, add
Oleic acid continues stirring 20min, cools to 40 DEG C；Obtain mixture, feed the mixture into the mixed liquor of antirust agent, penetrating agent and water
In, and stir 1h, it is subsequently adding antibacterial, defoamer, stirs 1h, obtain aqua type metalworking fluid；
Described base oil 150N base oil；Described emulsifying agent is OP-4；Described antirust agent is carbamide and the 1.8g of 1.8g
Borate mixes；Described oleic acid is linoleic acid TZSW；Described antibacterial is triazine；Described penetrating agent is diethylene glycol second
Ether；Described defoamer is froth breaking king CX-170；
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 150mL water,
Heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, add 52gPEG400MO (PEG400 list olein),
Add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, obtain active component.
The reaction expression that wherein prepared by the active component of embodiment 4 is:
Embodiment 5:
A kind of aqua type metalworking fluid, including following raw material: base oil 30g；Emulsifying agent 4.3g；Antirust agent 6.4g；Oil
Acid 5.5g；Active component 5g；Water 47.07g；Antibacterial 0.4g；Penetrating agent 1.3g；Defoamer 0.03g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, continues stirring 20min；Add active component, stir 30min, add
Oleic acid continues stirring 20min, cools to 40 DEG C；Obtain mixture, feed the mixture into the mixed liquor of antirust agent, penetrating agent and water
In, and stir 1h, it is subsequently adding antibacterial, defoamer, stirs 1h, obtain aqua type metalworking fluid；
Described base oil 100SN base oil；Described emulsifying agent is MOA-3；Described antirust agent be 3.2g triethanolamine and
The borate of 3.2g mixes；Described oleic acid is stearic acid SN1801；Described antibacterial is morpholine；Described penetrating agent is diethyl
Glycol ether；Described defoamer is froth breaking king CX-170；
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 150mL water,
Heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, add 52gPEG400ML (PEG400 mono laurate
Fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, obtain active component.
Embodiment 6:
A kind of aqua type metalworking fluid, including following raw material: base oil 30g；Emulsifying agent 5.5g；Antirust agent 6g；Oleic acid
5.5g；Active component 4g；Water 47.37g；Antibacterial 0.5g；Penetrating agent 1.1g；Defoamer 0.03g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, continues stirring 20min；Add active component, stir 30min, add
Oleic acid continues stirring 20min, cools to 40 DEG C；Obtain mixture, feed the mixture into the mixed liquor of antirust agent, penetrating agent and water
In, and stir 1h, it is subsequently adding antibacterial, defoamer, stirs 2h, obtain aqua type metalworking fluid；
Described base oil 150DN base oil；Described emulsifying agent is MOA-3；Described antirust agent is triethanolamine and the 3g of 3g
Borate mix；Described oleic acid is stearic acid SN1801；Described antibacterial is triazine；Described penetrating agent is diethylene glycol
Ether；Described defoamer is froth breaking king CX-170；
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 150mL water,
Heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, add 52gPEG400ML (PEG400 mono laurate
Fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, obtain active component.
The reaction expression that wherein prepared by the active component of embodiment 5～6 is:
Embodiment 7:
A kind of aqua type metalworking fluid, including following raw material: base oil 30g；Emulsifying agent 2g；Antirust agent 12.2g；Oleic acid
3g；Active component 5g；Water 47.07g；Antibacterial 0.5g；Penetrating agent 1g；Defoamer 0.05g；Dispersant 0.1g；Extruding antiwear additive
0.1g；Fermentation liquid 1g；Antisettling agent 1g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, adds antisettling agent while stirring, continue stirring 20min；Add and live
Property component, stir 30min, add oleic acid continue stirring 20min, cool to 40 DEG C；Obtain mixture, feed the mixture into antirust
In the mixed liquor of agent, penetrating agent, dispersant, fermentation liquid and water, and stir 1h, be subsequently adding antibacterial, defoamer, extreme-pressure anti-wear
Agent, stirs 1～3h, obtains aqua type metalworking fluid.
Described base oil is 100SN base oil；Described emulsifying agent is MOA-3；Described antirust agent is 1.5g citric acid, 8g boron
Sand, 1.7g sodium benzoate, 1g ammonium molybdate mix；Described oleic acid is stearic acid SN1801；Described antibacterial is morpholine；Described
Penetrating agent is diethylene glycol ether；Described defoamer includes that following raw material forms: polypropylene glycol sodium stearate 30g, isopropanol 6g,
Epoxychloropropane 5g, liquid paraffin 10g, ethylenedistearamide 10g, calcium chloride 5g, Carboxymethyl cellulose sodium 3g, potassium iodide
1g, lecithin 1g, iron chloride 1g, water 20g；Described extruding antiwear additive is sodium metaborate；Described antisettling agent is detergent alkylate
Sodium sulfonate；Described dispersant is 1-ethyl-3-methylimidazole acetate.
The preparation method of described fermentation liquid is: take starch 30g, Rhizoma amorphophalli powder 20g, molasses 5g, bagasse 5g, fucoidin
3g, ammonium molybdate 5g, sodium selenate 5g, water 50g, add fermentation tank and stir；Then use ultraviolet to the fermentation in fermentation tank
Feed liquid carries out sterilization processing, and ultraviolet-sterilization adds leaven 6g after completing, and stirs, and then carries out first stage fermentation,
Fermentation jar temperature is maintained at 25 DEG C, airtight stirring every day 10min during first stage fermentation, not can opening venting, continues 2
My god, then carrying out second stage fermentation, fermentation jar temperature is maintained at 30 DEG C, and during second stage fermentation, every day opens fermentation
Tank is exitted, and stirs 5min simultaneously, continues 8 days, completes fermentation, then filters, and removes filtering residue, obtains fermentation liquid；Described
The wavelength of ultraviolet is 280nm, and the ultraviolet-sterilization time is 30min；Described leaven is mixed by following seed liquor: bifid bar
Bacterium 15g, Lactobacillus pentosus 6g, Candida utilis 5g, white light color streptomycete 10g, trichoderma reesei 15g, actinomycetes 20g.
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 150mL water,
Heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, add 52gPEG400ML (polyethylene glycol 200 mono laurate
Fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, obtain active component.
Embodiment 8:
A kind of aqua type metalworking fluid, including following raw material: base oil 28g；Emulsifying agent 5g；Antirust agent 5g；Oleic acid 3g；
Active component 5g；Water 47.07g；Antibacterial 0.5g；Penetrating agent 1g；Defoamer 0.05g；Dispersant 0.4g；Extruding antiwear additive
0.08g；Fermentation liquid 2g；Antisettling agent 2g；
The preparation method of described aqua type metalworking fluid, including: take base oil and be heated to 60 DEG C, add emulsifying agent,
Continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, adds antisettling agent while stirring, continue stirring 20min；Add and live
Property component, stir 30min, add oleic acid continue stirring 20min, cool to 40 DEG C；Obtain mixture, feed the mixture into antirust
In the mixed liquor of agent, penetrating agent, dispersant, fermentation liquid and water, and stir 1h, be subsequently adding antibacterial, defoamer, extreme-pressure anti-wear
Agent, stirs 1～3h, obtains aqua type metalworking fluid.
Described base oil is 150SN base oil；Described emulsifying agent is AEO-30；Described antirust agent includes following raw material group
Become: inositol hexaphosphate 40g, I-hydroxybenzotriazole 20g, Butylated hydroxyanisole 6g, polyhydric alcohol 5g, tripolycyanamide 1g, poly-
Aspartic acid 1g, fatty acid alkanol amides 5g, oxalic acid 1g, chitosan 5g, water 50g；Described oleic acid is stearic acid SN1801；Described
Antibacterial is morpholine；Described penetrating agent is diethylene glycol ether；Described defoamer includes that following raw material forms: polypropylene glycol is stearic
Acid sodium 30g, isopropanol 7g, epoxychloropropane 6g, liquid paraffin 15g, ethylenedistearamide 13g, calcium chloride 6g, methylol are fine
Dimension element sodium 5g, potassium iodide 2g, lecithin 2g, iron chloride 2g, water 20g；Described extruding antiwear additive is sodium metaborate；Described anti-precipitation
Agent is dodecylbenzene sodium sulfonate；Described dispersant is 1-ethyl-3-methylimidazole acetate.
The preparation method of described fermentation liquid is: take starch 50g, Rhizoma amorphophalli powder 25g, molasses 8g, bagasse 8g, fucoidin
4g, ammonium molybdate 8g, sodium selenate 4g, water 60g, add fermentation tank and stir；Then use ultraviolet to the fermentation in fermentation tank
Feed liquid carries out sterilization processing, and ultraviolet-sterilization adds leaven 8g after completing, and stirs, and then carries out first stage fermentation,
Fermentation jar temperature is maintained at 23 DEG C, airtight stirring every day 10min during first stage fermentation, not can opening venting, continues 2
My god, then carrying out second stage fermentation, fermentation jar temperature is maintained at 30 DEG C, and during second stage fermentation, every day opens fermentation
Tank is exitted, and stirs 5min simultaneously, continues 8 days, completes fermentation, then filters, and removes filtering residue, obtains fermentation liquid；Described
The wavelength of ultraviolet is 280nm, and the ultraviolet-sterilization time is 30min；Described leaven is mixed by following seed liquor: bifid bar
Bacterium 20g, Lactobacillus pentosus 8g, Candida utilis 8g, white light color streptomycete 15g, trichoderma reesei 18g, actinomycetes 22g.At this
The cutting fluid of invention adds bionic acid, it is possible to significantly improve lubricity and the stability of its cutting.
The preparation method of described active component is: 5-carboxy benzotriazole 16.31g (163.14) is dissolved in 100mL first
In benzene, heating and temperature control is at 50 DEG C while stirring, to be dissolved uniformly after, add 52gDEGMS (diethylene glycol monostearate
Fat), add 0.01mol p-methyl benzenesulfonic acid, be warming up to backflow, maintain reaction 1 hour, in water knockout drum during anhydrous generation, subtract
Pressure is distilled off solvent and obtains active component.
In order to the effect of the present invention is described, inventor provides comparative experiments as follows:
Comparative example 1:
It is not added with active component, complete with embodiment 1 of remaining parameter in the preparation process of aqua type metalworking fluid
Exactly the same, technical process is the most identical.
Comparative example 2:
It is not added with active component, complete with embodiment 2 of remaining parameter in the preparation process of aqua type metalworking fluid
Exactly the same, technical process is the most identical.
Comparative example 3:
It is not added with active component, complete with embodiment 3 of remaining parameter in the preparation process of aqua type metalworking fluid
Exactly the same, technical process is the most identical.
Comparative example 4:
By active component 3g dodecyl sodium sulfate (SDS) and 4g coconut palm in the preparation process of aqua type metalworking fluid
Seed oil diglycollic amide (LDEA) replaces, and remaining parameter is identical with embodiment 4, and technical process is the most identical.
Comparative example 5:
In the preparation process of aqua type metalworking fluid by active component 2.5g diisopropanolamine (DIPA) and 2.5g peregal-
3 replace, and remaining parameter is identical with embodiment 5, and technical process is the most identical.
To embodiment 1～8 and the aqua type metalworking fluid for preparing of comparative example 1～5 carry out stability, rust-preventing characteristic and
Lubricity is tested；
The method of stability test is: take the aqua type cutting fluid 10g hardness of preparation be 500,800, the water of 1200ppm
Dilution, concussion shakes up, and takes 100mL diluent in graded tube, places 24h and observes the volume separating out soap layer.
The method of rustless property test is: take the water that aqua type cutting fluid 100g hardness the is 800ppm dilution of preparation,
Taking the alloy workpiece polished and immerse taking-up after 1min in diluent, stand in air, keeping temperature is 30 DEG C ± 2 DEG C, humidity
It is 65 ± 2%, observes workpiece corrosion situation.
The method of greasy property test is: take the water that aqua type cutting fluid 100g hardness the is 800ppm dilution of preparation,
The test of maximum nonseizure load PB value is carried out according to GB GB/T3142-1982.
Embodiment 1～5 and comparative example 1～5 stability of aqua type metalworking fluid, rust-preventing characteristic and the lubrication that prepare
Property test result as shown in table 2；
Wherein, table 1 lists embodiment 1～6 and the consumption of each composition of comparative example 1～5；
Table 1
Table 2
From Table 2, it can be seen that owing to have employed the active component of the present invention in example 1～6, its aqua type prepared is cut
Cut the stability of liquid, rust-preventing characteristic and lubricity and be significantly higher than in comparative example 1～5 the aqua type cutting fluid of preparation.Use the present invention
Obtained aqua type metalworking fluid has good rust-preventing characteristic, lubricity and stability, and indices can meet workpiece
The demand of processing.
Although embodiment of the present invention are disclosed as above, but it is not restricted in description and embodiment listed
Using, it can be applied to various applicable the field of the invention completely, for those skilled in the art, and can be easily
Realizing other amendment, therefore under the general concept limited without departing substantially from claim and equivalency range, the present invention does not limit
In specific details with shown here as the example with description.
Claims (10)
1. an aqua type metalworking fluid, it is characterised in that include the raw material of following weight portion: base oil 15-30 part；Emulsifying
Agent 0.5-20 part；Antirust agent 3-20 part；Oleic acid 2-10 part；Active component 0.5-20 part；Water 40-50 part；Antibacterial 0.3-0.5
Part；Penetrating agent 1-1.5 part；Defoamer 0.02-0.1 part.
2. aqua type metalworking fluid as claimed in claim 1, it is characterised in that
Described base oil is any one in paraffin base oil, naphthenic base oils, synthetic base oil；
Described emulsifying agent is oleic acid diethyl amide, alkylolamides phosphate ester, C5-C25Fatty alcohol-polyoxyethylene ether in appoint
Meaning one；
Described antirust agent is the combination of one or more in citric acid, borate, hydramine, sodium benzoate, ammonium molybdate, carbamide；
Described oleic acid is the combination of one or more in ricinoleic acid, palmitoleic acid, oleic acid, linoleic acid, tall oil acid；
Described antibacterial be containing s-triazine, isothiazolone, benzene oxygen alcohols, morpholine chemical constituent in one；
Described penetrating agent is any one in propandiol butyl ether, butyl glycol ether, diethylene glycol ether；
Described defoamer is any one in polyethers defoamer, emulsified silicone oil, phosphate ester；
Described active component is that the molecular formula of Benzotriazole Derivative is:
Wherein, X is CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH (CH2)7COO(CH2CH2O)nOne in-, described n=1-10.
3. the preparation method of an aqua type metalworking fluid as claimed in claim 1 or 2, it is characterised in that including: take base
Plinth oil is heated to 50～60 DEG C, adds emulsifying agent, continues to be heated to 80 DEG C, stirs 30min；It is warmed up to 90 DEG C, continues stirring
20min；Add active component, stir 30min, add oleic acid and continue stirring 20min, cool to 40 DEG C；Obtain mixture, will be mixed
Compound adds in the mixed liquor of antirust agent, penetrating agent and water, and stirs 1h, is subsequently adding antibacterial, defoamer, stirs 1～3h,
Obtain aqua type metalworking fluid.
4. aqua type metalworking fluid as claimed in claim 1, it is characterised in that also include: dispersant 0.1-0.5 part；Pole
Pressure antiwear additive 0.05-0.1 part；Fermentation liquid 1～3 parts；Antisettling agent 1～3 parts；
Described dispersant is 1-ethyl-3-methylimidazole acetate, chlorination 1-butyl-3-Methylimidazole., 1-butyl-3-methyl miaow
Any one in azoles tetrafluoroborate, 1-hexyl-3-methylimidazolium nitrate, 1-ethyl-3-methyllimidazolium bromide.
Described extreme pressure anti-wear additives is the one in sodium metaborate, potassium metaborate and three potassium borates；
Described antisettling agent is dodecylbenzene sodium sulfonate, quaternary ammonium salt high-molecular copolymer, anionic carboxylic acid copolymer, nonionic
One in polyurethanes.
5. aqua type metalworking fluid as claimed in claim 1, it is characterised in that described antirust agent includes following weight portion
Raw material: inositol hexaphosphate 40-60 part, I-hydroxybenzotriazole 20～25 parts, Butylated hydroxyanisole 6～8 parts, polyhydric alcohol 5
～8 parts, tripolycyanamide 1～3 parts, poly-aspartate 1～3 parts, fatty acid alkanol amides 5～10 parts, oxalic acid 1～5 parts, chitosan
5～10 parts, water 50～80 parts.
6. aqua type metalworking fluid as claimed in claim 1, it is characterised in that described defoamer includes following weight portion
Raw material: polypropylene glycol sodium stearate 20～30 parts, isopropanol 6～8 parts, epoxychloropropane 5～8 parts, liquid paraffin 10～20 parts,
Ethylenedistearamide 10～15 parts, calcium chloride 5～8 parts, Carboxymethyl cellulose sodium 3～5 parts, potassium iodide 1～3 parts, lecithin 1
～3 parts, iron chloride 1～3 parts, water 20～30 parts.
7. the preparation method of the aqua type metalworking fluid as described in any one of claim 4～6, it is characterised in that bag
Include: take base oil and be heated to 50～60 DEG C, add emulsifying agent, continue to be heated to 80 DEG C, stir 30min；It is warmed up to 90 DEG C, while stir
Mix limit and add antisettling agent, continue stirring 20min；Add active component, stir 30min, add oleic acid and continue stirring 20min,
Cool to 40 DEG C；Obtain mixture, feed the mixture in the mixed liquor of antirust agent, penetrating agent, dispersant, fermentation liquid and water,
And stir 1h, it is subsequently adding antibacterial, defoamer, extreme pressure anti-wear additives, stirs 1～3h, obtain aqua type metalworking fluid.
8. the preparation method of aqua type metalworking fluid as claimed in claim 7, it is characterised in that described active component is benzene
And triazole derivatives, its molecular formula is:
Wherein, X is CH3(CH2)16COO(CH2CH2O)n-、CH3(CH2)10COO(CH2CH2O)n-、CH3(CH2)7CH=CH (CH2)7COO(CH2CH2O)nOne in-, described n=1-10；
The preparation method of described active component is: by weight, and 15～20 parts of 5-carboxy benzotriazoles are dissolved in 80～120 parts
In solvent, heating and temperature control is at 50-60 DEG C while stirring, to be dissolved uniformly after, add 40～60 parts of polymerization degree n=1-10's
One in Polyethylene Glycol monostearate, polyethylene glycol monooleate or Polyethylene Glycol mono laurate fat, adds 1.5～2
The p-methyl benzenesulfonic acid of part, is warming up to backflow, maintains reaction 1～3 hour, and in water knockout drum during anhydrous generation, decompression is distilled off
Solvent obtains active component.
9. the preparation method of aqua type metalworking fluid as claimed in claim 7, it is characterised in that described fermentation liquid system
Preparation Method is: by weight, takes starch 30～50 parts, Rhizoma amorphophalli powder 20～30 parts, molasses 5～10 parts, bagasse 5～10 parts, brown
Polysaccharides 3～5 parts, ammonium molybdate 5～8 parts, sodium selenate 3～5 parts, water 50～80 parts, add fermentation tank and stir；Then use
Ultraviolet carries out sterilization processing to the fermented feed liquid in fermentation tank, and ultraviolet-sterilization adds leaven 6～8 parts after completing, and stirs
Uniformly, then carrying out first stage fermentation, fermentation jar temperature is maintained at 22～25 DEG C, and during first stage fermentation, every day is close
Closing stirring 10-15min, not can opening venting, continue 2～3 days, then carry out second stage fermentation, fermentation jar temperature is maintained at 26
～30 DEG C, during second stage fermentation, every day opens fermentation tank and exits, and stirring 5～8min simultaneously, continues 8～10
My god, complete fermentation, then filter, remove filtering residue, obtain fermentation liquid；The wavelength of described ultraviolet is 180-280nm, ultraviolet-sterilization
Time is 25～30min.
10. the preparation method of aqua type metalworking fluid as claimed in claim 9, it is characterised in that described leaven by with
The seed liquor of lower weight portion mixes: bacillus bifidus 15～20 parts, Lactobacillus pentosus 6～10 parts, Candida utilis 5～10
Part, white light color streptomycete 10～18 parts, trichoderma reesei 15～20 parts, actinomycetes 20～25 parts.
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| CN107119282A (en) * | 2017-06-22 | 2017-09-01 | 杭州五源科技实业有限公司 | A kind of preparation and application of neutral without phosphorus rust remover |
| CN107164062A (en) * | 2017-07-05 | 2017-09-15 | 奎克化学（中国）有限公司 | A kind of metal working fluid and its preparation method and application |
| CN107164062B (en) * | 2017-07-05 | 2020-11-10 | 奎克化学（中国）有限公司 | Metal working fluid and preparation method and application thereof |
| CN107523403A (en) * | 2017-07-27 | 2017-12-29 | 江苏捷达油品有限公司 | High rust-preventing characteristic cutting fluid |
| CN111511884A (en) * | 2017-10-10 | 2020-08-07 | 海浚国际贸易有限公司 | Production of fluids |
| TWI793193B (en) * | 2017-10-10 | 2023-02-21 | 海浚國際貿易有限公司 | Fabrication fluids |
| CN107868693A (en) * | 2017-11-24 | 2018-04-03 | 重庆信人科技发展有限公司 | A kind of strong inhibition micro-emulsion cutting fluid |
| CN108559604A (en) * | 2018-05-21 | 2018-09-21 | 九江职业技术学院 | A kind of cutter high-efficiency environment friendly cutting fluid and preparation method thereof |
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| CN109233951A (en) * | 2018-09-14 | 2019-01-18 | 大连理工大学 | One step prepares the water-soluble lubricating liquid method containing carbon dots |
| CN109594094A (en) * | 2018-12-25 | 2019-04-09 | 泰伦特生物工程股份有限公司 | General easy to handle environmentally-friendly water-based emulsification antirust agent of one kind and preparation method thereof |
| CN111826225A (en) * | 2019-04-17 | 2020-10-27 | 陕西省石油化工研究设计院 | Special cooling liquid for samarium cobalt permanent magnet processing and preparation method thereof |
| CN110982602A (en) * | 2019-12-23 | 2020-04-10 | 联泓(江苏)新材料研究院有限公司 | Biological stable low-oil-content microemulsion and preparation method and application thereof |
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