CN106082975A - 一种纳米石英砂日用陶瓷制品 - Google Patents

一种纳米石英砂日用陶瓷制品 Download PDF

Info

Publication number
CN106082975A
CN106082975A CN201610461096.0A CN201610461096A CN106082975A CN 106082975 A CN106082975 A CN 106082975A CN 201610461096 A CN201610461096 A CN 201610461096A CN 106082975 A CN106082975 A CN 106082975A
Authority
CN
China
Prior art keywords
powder
quartz sand
polyvinyl alcohol
slurry
daily use
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610461096.0A
Other languages
English (en)
Inventor
舒小山
章建武
宫平
汤兴友
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI HANSHAN PORCELAIN Co Ltd
Original Assignee
ANHUI HANSHAN PORCELAIN Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI HANSHAN PORCELAIN Co Ltd filed Critical ANHUI HANSHAN PORCELAIN Co Ltd
Priority to CN201610461096.0A priority Critical patent/CN106082975A/zh
Publication of CN106082975A publication Critical patent/CN106082975A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/135Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352Fuel ashes, e.g. fly ash
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • C04B33/1324Recycled material, e.g. tile dust, stone waste, spent refractory material
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/36Glass starting materials for making ceramics, e.g. silica glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

本发明公开了一种纳米石英砂日用陶瓷制品,由以下重量份的原料制备制成:石英砂17‑20、焦宝石粉12‑15、钠长石13‑16、空心玻璃微珠8‑10、硅溶胶11‑13、聚乙烯醇1‑2、丙烯醇1‑2、粉煤灰40‑45、红柱石粉12‑14、镁粉2‑3、白釉球35‑40、废玻璃6‑8、麦饭石10‑14、绿茶21‑25、橙子皮14‑17、贝壳粉6‑8、虾壳粉4‑6、聚乙烯醇0.2‑0.3、磷酸三丁酯0.2‑0.3、去离子水适量;本发明的陶瓷高白高透、成本低、成型性能好,在满足日用陶瓷作为生活日常用品应有使用功能的同时,提高了产品的抗菌及保健性能,值得推广。

Description

一种纳米石英砂日用陶瓷制品
技术领域
本发明涉及日用陶瓷技术领域,尤其涉及一种纳米石英砂日用陶瓷制品。
背景技术
我国不仅矿产资源丰富,同时也是世界上最大的煤炭生产国和煤炭消费国,近年来,我国火力发电发展迅速,其中大多数以煤炭为燃料,发电量达1.3亿kW•h,火力发电所占比例达到了79.6%,由此导致粉煤灰排放量逐年增加。2010年底,排放量达到近3亿吨,大量粉煤灰的排放收到了越来越广泛的关注。我国自1987年开始就对如何利用粉煤灰作为资源综合利用的突破口,对其进行综合利用,成为经济和社会发展的一项长远方针。废玻璃类物质其化学稳定性极强,不腐烂、不燃烧、不能降解,大量的废玻璃既占地,又污染环境,回收和利用是节约能源、保护环境的最佳途径,而且具有很好的经济性,玻璃的主要成分是二氧化硅,能够促进陶瓷的烧结。在陶瓷生产中,烧成温度越高,烧成时间越长,能耗就越高,据热平衡计算,烧成温度每降低100℃,则单位产品热耗可降低10%以上,烧成时间每缩短10%,则产量增加10%,热耗降低4%,所以降低烧成温度和时间具有显著的节能减排社会意义。
近20年来,陶瓷行业进入了日新月异的发展阶段,新技术、新设备的大量使用,陶瓷产量也有较大幅度增长。新型陶瓷作为一种新材料,以其优异的性能在材料领域独树一帜,受到人们的高度重视。日用陶瓷作为传统陶瓷材料在材料领域占有重要的地位,因为它涉及到人们生活的方方面面,日用陶瓷的发展随着人们生活水平的提高提出了更多的要求,其中抗菌是目前提出最普遍的要求。由于瓷器的大量需求,瓷土资源的大量开采正以惊人的速度减少,并且是不可再生资源,如果找不到替代资源,人们有可能以后会面临无资源可采的尴尬局面。杨玉卫等人在《利用粉煤灰等工业废料制备日用陶瓷的研究》一文中指出,利用火电厂排放的粉煤灰、陶瓷工业产生的大量废匣钵、废瓷粉利用正交试验设计配方,研制出清洁生产日用陶瓷的配方,其中粉煤灰、废匣钵、废瓷粉的含量分别是10%、10%、8%,应用此技术可以为企业带来可观的经济效益,为粉煤灰的资源化利用找到出口,虽然提高了社会效益和经济效益,但是很多性能没有达到人们的要求,例如抗菌、抗高温、抗冻等性能不高、使用寿命不长的缺点。
发明内容
本发明目的就是为了弥补已有技术的缺陷,提供一种纳米石英砂日用陶瓷制品。
本发明是通过以下技术方案实现的:
一种纳米石英砂日用陶瓷制品,由以下重量份的原料制备制成:石英砂17-20、焦宝石粉12-15、钠长石13-16、空心玻璃微珠8-10、硅溶胶11-13、聚乙烯醇1-2、丙烯醇1-2、粉煤灰40-45、红柱石粉12-14、镁粉2-3、白釉球35-40、废玻璃6-8、麦饭石10-14、绿茶21-25、橙子皮14-17、贝壳粉6-8、虾壳粉4-6、聚乙烯醇0.2-0.3、磷酸三丁酯0.2-0.3、去离子水适量。
所述一种纳米石英砂日用陶瓷制品,由下列具体步骤制备制成:
(1)将硅溶胶、聚乙烯醇和丙烯醇搅拌均匀,再加入浓度均为0.2mol/L的硝酸锌、硝酸钛溶液,其中硅溶胶与硝酸锌、硝酸钛溶液固液比为1:2-3:1-2,升高温度在50-60℃条件下搅拌反应2-3h,继续升高温度在60-70℃下保持30-40min,然后干燥、研磨、洗涤、过滤再经干燥后备用;
(2)将麦饭石洗净烘干后磨成细粉,将绿茶、橙子皮、贝壳粉、虾壳粉混合加到75%的乙醇溶液中,在50-60℃时煎煮20-30min,继续升温至90-100℃时煎煮10-20min,冷却至室温后进行离心分离,取其上清液浓缩后和聚乙烯醇、麦饭石粉、磷酸三丁酯球磨30-40min,结束后一边用直流电动搅拌机对浆料不断搅拌,一边喷雾干燥制成纳米麦饭石微球备用;
(3)将废玻璃清洗干净后烘干进行破碎,然后加到胶体磨中研磨过100-200目筛,将玻璃粉与粉煤灰、石英砂、焦宝石粉、空心玻璃微珠、钠长石混合得到干物料,加入占干物料总质量40-50%的去离子水,经过球磨粉碎得到过300-400目的浆料;
(4)将步骤(3)得到的浆料用磁选机进行磁选除铁,使浆料中铁的含量≤0.2%,将浆料加到成型机中干燥成型得到坯体,将坯体放入炉内温度为100-200℃的烧结炉中,在1180-1280℃温度下进行煅烧5-7h,冷却至常温后打磨刨光备用;
(5)将白釉球、红柱石粉、镁粉和步骤(1)得到的抗菌剂混合,加到球磨机中进行湿法球磨,加入物料总重量45-55%的去离子水,将球磨后的釉浆分别过200目、300目筛,去除杂质及粗颗粒,得到细釉浆,将釉浆施釉于步骤(4)制备的素坯上,在1200-1250℃下烧结4-5h;
(6)将步骤(2)制备的纳米麦饭石微球和磷酸氢铝粘结剂按照2-3:1比例混合,涂敷在步骤(5)制备的陶瓷表面,经阴干后在120-140℃下恒温2h即可得到。
本发明的优点是:本发明利用废弃资源粉煤灰作为陶瓷原料,降低了对环境的污染,并且其中氧化硅、氧化铝含量较高,颗粒比表面积大呈多孔结构,容易研磨,可以降低制品的烧成温度,达到节能的目的,废弃的玻璃在与粉煤灰烧结过程中,在低温下熔融,形成玻璃相,起到结合剂的作用,降低了烧成温度,并且提高了陶瓷表面光滑、抗冻、易清洁、抗冲击等方面的性能,将合成的抗菌剂和釉料混合施釉在陶瓷素坯表面,提高了陶瓷的抗菌性能,降低了人类患病的危险系数,并且采用绿茶、橙子皮、贝壳粉、虾壳粉煎煮提取出微量元素用麦饭石包覆形成纳米麦饭石微球,利用粘结剂粘结在陶瓷表面,通过长期受热可溶出多种对人体有益的微量元素,为人们的机体提供营养,强身健体,调节新陈代谢,对人体大有益处,本发明的陶瓷高白高透、成本低、成型性能好,在满足日用陶瓷作为生活日常用品应有使用功能的同时,提高了产品的抗菌及保健性能,值得推广。
具体实施方式
一种纳米石英砂日用陶瓷制品,由以下重量份(公斤)的原料制备制成:石英砂17、焦宝石粉12、钠长石13、空心玻璃微珠8、硅溶胶11、聚乙烯醇1、丙烯醇1、粉煤灰40、红柱石粉12、镁粉2、白釉球35、废玻璃6、麦饭石10、绿茶21、橙子皮14、贝壳粉6、虾壳粉4、聚乙烯醇0.2、磷酸三丁酯0.2、去离子水适量。
所述一种纳米石英砂日用陶瓷制品,由下列具体步骤制备制成:
(1)将硅溶胶、聚乙烯醇和丙烯醇搅拌均匀,再加入浓度均为0.2mol/L的硝酸锌、硝酸钛溶液,其中硅溶胶与硝酸锌、硝酸钛溶液固液比为1:2:1,升高温度在50℃条件下搅拌反应2h,继续升高温度在60℃下保持30min,然后干燥、研磨、洗涤、过滤再经干燥后备用;
(2)将麦饭石洗净烘干后磨成细粉,将绿茶、橙子皮、贝壳粉、虾壳粉混合加到75%的乙醇溶液中,在50℃时煎煮20min,继续升温至90℃时煎煮10min,冷却至室温后进行离心分离,取其上清液浓缩后和聚乙烯醇、麦饭石粉、磷酸三丁酯球磨30min,结束后一边用直流电动搅拌机对浆料不断搅拌,一边喷雾干燥制成纳米麦饭石微球备用;
(3)将废玻璃清洗干净后烘干进行破碎,然后加到胶体磨中研磨过100目筛,将玻璃粉与粉煤灰、石英砂、焦宝石粉、空心玻璃微珠、钠长石混合得到干物料,加入占干物料总质量40%的去离子水,经过球磨粉碎得到过300目的浆料;
(4)将步骤(3)得到的浆料用磁选机进行磁选除铁,使浆料中铁的含量≤0.2%,将浆料加到成型机中干燥成型得到坯体,将坯体放入炉内温度为100℃的烧结炉中,在1180℃温度下进行煅烧5h,冷却至常温后打磨刨光备用;
(5)将白釉球、红柱石粉、镁粉和步骤(1)得到的抗菌剂混合,加到球磨机中进行湿法球磨,加入物料总重量45%的去离子水,将球磨后的釉浆分别过200目、300目筛,去除杂质及粗颗粒,得到细釉浆,将釉浆施釉于步骤(4)制备的素坯上,在1200℃下烧结4h;
(6)将步骤(2)制备的纳米麦饭石微球和磷酸氢铝粘结剂按照2:1比例混合,涂敷在步骤(5)制备的陶瓷表面,经阴干后在120℃下恒温2h即可得到。
试验数据:
产品外观规整,釉面平整;抗热震性试验达到200℃投入20℃水中热交换一次不裂;机械强度≥140mp2;釉面维氏显微硬度≥5.9GPa;太阳光下1小时的杀菌效率≥72%;抗冲击强度≥1.6J/cm2。

Claims (2)

1.一种纳米石英砂日用陶瓷制品,其特征在于,由以下重量份的原料制备制成:石英砂17-20、焦宝石粉12-15、钠长石13-16、空心玻璃微珠8-10、硅溶胶11-13、聚乙烯醇1-2、丙烯醇1-2、粉煤灰40-45、红柱石粉12-14、镁粉2-3、白釉球35-40、废玻璃6-8、麦饭石10-14、绿茶21-25、橙子皮14-17、贝壳粉6-8、虾壳粉4-6、聚乙烯醇0.2-0.3、磷酸三丁酯0.2-0.3、去离子水适量。
2.根据权利要求1所述一种纳米石英砂日用陶瓷制品,其特征在于,由下列具体步骤制备制成:
(1)将硅溶胶、聚乙烯醇和丙烯醇搅拌均匀,再加入浓度均为0.2mol/L的硝酸锌、硝酸钛溶液,其中硅溶胶与硝酸锌、硝酸钛溶液固液比为1:2-3:1-2,升高温度在50-60℃条件下搅拌反应2-3h,继续升高温度在60-70℃下保持30-40min,然后干燥、研磨、洗涤、过滤再经干燥后备用;
(2)将麦饭石洗净烘干后磨成细粉,将绿茶、橙子皮、贝壳粉、虾壳粉混合加到75%的乙醇溶液中,在50-60℃时煎煮20-30min,继续升温至90-100℃时煎煮10-20min,冷却至室温后进行离心分离,取其上清液浓缩后和聚乙烯醇、麦饭石粉、磷酸三丁酯球磨30-40min,结束后一边用直流电动搅拌机对浆料不断搅拌,一边喷雾干燥制成纳米麦饭石微球备用;
(3)将废玻璃清洗干净后烘干进行破碎,然后加到胶体磨中研磨过100-200目筛,将玻璃粉与粉煤灰、石英砂、焦宝石粉、空心玻璃微珠、钠长石混合得到干物料,加入占干物料总质量40-50%的去离子水,经过球磨粉碎得到过300-400目的浆料;
(4)将步骤(3)得到的浆料用磁选机进行磁选除铁,使浆料中铁的含量≤0.2%,将浆料加到成型机中干燥成型得到坯体,将坯体放入炉内温度为100-200℃的烧结炉中,在1180-1280℃温度下进行煅烧5-7h,冷却至常温后打磨刨光备用;
(5)将白釉球、红柱石粉、镁粉和步骤(1)得到的抗菌剂混合,加到球磨机中进行湿法球磨,加入物料总重量45-55%的去离子水,将球磨后的釉浆分别过200目、300目筛,去除杂质及粗颗粒,得到细釉浆,将釉浆施釉于步骤(4)制备的素坯上,在1200-1250℃下烧结4-5h;
(6)将步骤(2)制备的纳米麦饭石微球和磷酸氢铝粘结剂按照2-3:1比例混合,涂敷在步骤(5)制备的陶瓷表面,经阴干后在120-140℃下恒温2h即可得到。
CN201610461096.0A 2016-06-23 2016-06-23 一种纳米石英砂日用陶瓷制品 Withdrawn CN106082975A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610461096.0A CN106082975A (zh) 2016-06-23 2016-06-23 一种纳米石英砂日用陶瓷制品

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610461096.0A CN106082975A (zh) 2016-06-23 2016-06-23 一种纳米石英砂日用陶瓷制品

Publications (1)

Publication Number Publication Date
CN106082975A true CN106082975A (zh) 2016-11-09

Family

ID=57253203

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610461096.0A Withdrawn CN106082975A (zh) 2016-06-23 2016-06-23 一种纳米石英砂日用陶瓷制品

Country Status (1)

Country Link
CN (1) CN106082975A (zh)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1038445A (zh) * 1988-06-11 1990-01-03 山东大学 麦饭石水容器内壁敷料制备及其烧成工艺
CN102875105A (zh) * 2012-09-04 2013-01-16 青岛保利康新材料有限公司 一种环保型建筑材料

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1038445A (zh) * 1988-06-11 1990-01-03 山东大学 麦饭石水容器内壁敷料制备及其烧成工艺
CN102875105A (zh) * 2012-09-04 2013-01-16 青岛保利康新材料有限公司 一种环保型建筑材料

Similar Documents

Publication Publication Date Title
CN105837174A (zh) 一种耐火型日用陶瓷制品
CN101805209A (zh) 利用废瓷制得的亚光瓷釉及其生产方法
CN105906308A (zh) 一种改进的高强度日用陶瓷
CN105837175A (zh) 一种抗菌日用陶瓷
CN104291801A (zh) 一种远红外线陶瓷材料及其制作工艺
CN103951382A (zh) 一种高耐候陶瓷砖及其制备方法
CN106116512A (zh) 一种养生抗菌日用陶瓷制品
CN106082974A (zh) 一种易清洁的日用陶瓷制品
CN106431450B (zh) 一种改性硫酸钙晶须增强的陶瓷砖
CN105906316A (zh) 一种不易脆不开裂的日用陶瓷
CN105906312A (zh) 一种具有抗震性能的日用陶瓷
CN106116549A (zh) 一种具有保健功能的日用陶瓷制品
CN106116513A (zh) 一种耐腐蚀性高的日用陶瓷制品
CN106082968A (zh) 一种添加粉煤灰的日用陶瓷制品
CN106116454A (zh) 一种不易脏污的日用陶瓷制品
CN106116455A (zh) 一种对人体无害的日用陶瓷制品
CN106116483A (zh) 一种低成本的日用陶瓷制品
CN105906313A (zh) 一种耐磨损抗冲击生活日用陶瓷
CN105198393A (zh) 高发射率红外节能复相陶瓷材料及其制备方法
CN105924130A (zh) 一种高强度耐冲击生活日用陶瓷
CN105906317A (zh) 一种耐高温高强度生活日用陶瓷
CN104086207A (zh) 一种隔热保温陶瓷板的生产工艺
CN105837176A (zh) 一种抗高温撕裂性能好的日用陶瓷
CN108675779A (zh) 一种复合铝铬砖及其制备方法
CN108558353A (zh) 一种硅藻土环保保温砖及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20161109

WW01 Invention patent application withdrawn after publication