CN106061601B - 多功能吸附剂材料以及其用途 - Google Patents

多功能吸附剂材料以及其用途 Download PDF

Info

Publication number
CN106061601B
CN106061601B CN201480062038.XA CN201480062038A CN106061601B CN 106061601 B CN106061601 B CN 106061601B CN 201480062038 A CN201480062038 A CN 201480062038A CN 106061601 B CN106061601 B CN 106061601B
Authority
CN
China
Prior art keywords
solution
adsorbent material
species
adsorbent
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201480062038.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN106061601A (zh
Inventor
乐凡索
乐明科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Le Fansuo
Le Mingke
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from AU2013903629A external-priority patent/AU2013903629A0/en
Application filed by Individual filed Critical Individual
Publication of CN106061601A publication Critical patent/CN106061601A/zh
Application granted granted Critical
Publication of CN106061601B publication Critical patent/CN106061601B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/26Selective adsorption, e.g. chromatography characterised by the separation mechanism
    • B01D15/38Selective adsorption, e.g. chromatography characterised by the separation mechanism involving specific interaction not covered by one or more of groups B01D15/265 and B01D15/30 - B01D15/36, e.g. affinity, ligand exchange or chiral chromatography
    • B01D15/3804Affinity chromatography
    • B01D15/3828Ligand exchange chromatography, e.g. complexation, chelation or metal interaction chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004Sorbent size or size distribution, e.g. particle size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042Shaped bodies; Monolithic structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28088Pore-size distribution
    • B01J20/28092Bimodal, polymodal, different types of pores or different pore size distributions in different parts of the sorbent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3085Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204Inorganic carriers, supports or substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/32Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244Non-macromolecular compounds
    • B01J20/3246Non-macromolecular compounds having a well defined chemical structure
    • B01J20/3257Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one of the heteroatoms nitrogen, oxygen or sulfur together with at least one silicon atom, these atoms not being part of the carrier as such
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3425Regenerating or reactivating of sorbents or filter aids comprising organic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/345Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3475Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/08Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/21Cyclic compounds having at least one ring containing silicon, but no carbon in the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/28Titanium compounds
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04Treating liquids
    • G21F9/06Processing
    • G21F9/12Processing by absorption; by adsorption; by ion-exchange

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Silicon Compounds (AREA)
CN201480062038.XA 2013-09-20 2014-09-19 多功能吸附剂材料以及其用途 Active CN106061601B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AU2013903629A AU2013903629A0 (en) 2013-09-20 Multifunctional sorbent materials and uses thereof
AU2013903629 2013-09-20
PCT/AU2014/000920 WO2015039170A1 (en) 2013-09-20 2014-09-19 Multifunctional sorbent materials and uses thereof

Publications (2)

Publication Number Publication Date
CN106061601A CN106061601A (zh) 2016-10-26
CN106061601B true CN106061601B (zh) 2019-12-03

Family

ID=52687995

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480062038.XA Active CN106061601B (zh) 2013-09-20 2014-09-19 多功能吸附剂材料以及其用途

Country Status (9)

Country Link
US (1) US10058843B2 (enExample)
EP (1) EP3046666B1 (enExample)
JP (1) JP6338675B2 (enExample)
CN (1) CN106061601B (enExample)
AU (1) AU2014324073B2 (enExample)
CA (1) CA2924707C (enExample)
DK (1) DK3046666T3 (enExample)
ES (1) ES2781193T3 (enExample)
WO (1) WO2015039170A1 (enExample)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9953733B2 (en) 2012-10-25 2018-04-24 Cyclopharm Limited Radioisotope concentrator
GB201418899D0 (en) 2014-10-23 2014-12-10 Univ Hull System for radiopharmaceutical production
GB201418893D0 (en) 2014-10-23 2014-12-10 Univ Hull Monolithic body
GB201418897D0 (en) 2014-10-23 2014-12-10 Univ Hull Methods and apparatus for the analysis of compounds
CN106800659B (zh) * 2017-01-19 2018-01-09 洛阳理工学院 一种具有荧光性能的三维铅配位聚合物及其制备方法
WO2019113073A1 (en) * 2017-12-04 2019-06-13 The University Of North Carolina At Charlotte Separation media, devices and applications thereof
CN108970584A (zh) * 2018-07-16 2018-12-11 南开大学 一种去除放射性阴离子污染物的正离子共价有机纳米片的制备方法
US11135567B1 (en) * 2020-06-26 2021-10-05 The Florida International University Board Of Trustees Microcrystalline cellulose particle supported sol-gel sorbents and methods of manufacturing the same
EP4355453A1 (en) * 2021-06-15 2024-04-24 University of Maine System Board of Trustees Compositions and methods for toxic species removal from fluid
TWI802377B (zh) 2022-04-20 2023-05-11 台灣創新材料股份有限公司 用於吸附層析術的靜相媒質及其製造方法
KR20250042849A (ko) * 2022-08-19 2025-03-27 제네럴 일렉트릭 테크놀러지 게엠베하 아미노실리콘 작용기를 갖는 리간드로 기능화된 흡착제
EP4656287A1 (en) * 2023-02-27 2025-12-03 Aqas Corporation Column filler for chromatography, column for chromatography, manufacturing method for column for chromatography, chromatography analyzer, and analysis method

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1302224A (zh) * 1998-02-09 2001-07-04 工业科学技术网络公司 采用经过表面处理的干凝胶进行离子分离
US6326326B1 (en) * 1998-02-06 2001-12-04 Battelle Memorial Institute Surface functionalized mesoporous material and method of making same
CN101314653A (zh) * 2007-05-31 2008-12-03 固特异轮胎和橡胶公司 包含表面金属化的硅质填料的弹性体
CN101421012A (zh) * 2004-04-23 2009-04-29 吉恩康国际股份有限公司 使用经过硅烷处理的二氧化硅过滤介质分离样品中的组分的方法
CN101444541A (zh) * 2007-11-26 2009-06-03 中国中医科学院中药研究所 键合硅胶类复合材料在脱除中药提取液中重金属的应用
CN102056976A (zh) * 2008-05-05 2011-05-11 卡普图尔技术有限责任公司 新型交联聚合物基材、该基材的制备方法和终端用途应用
CN102428145A (zh) * 2009-03-18 2012-04-25 巴斯夫欧洲公司 改性的二氧化硅粒子和包含它们的防污聚合物组合物

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2857349B2 (ja) * 1995-05-22 1999-02-17 日本原子力研究所 99Mo−99mTcジェネレータ用Mo吸着剤およびその製造方法
EP1199336B1 (de) 2000-10-21 2014-01-15 Evonik Degussa GmbH Funktionalisierte, strukturmodifizierte Kieselsäuren
WO2002094410A1 (en) 2001-05-18 2002-11-28 University Of South Florida Sol-gel dendron separation and extraction capillary column
DE10124549A1 (de) * 2001-05-19 2002-11-28 Degussa Verfahren zur selektiven katalytischen Reduktion von Stickoxiden mit Ammoniak im mageren Abgas eines Verbrennungsprozesses
EP1422522B1 (en) * 2001-08-31 2013-10-30 Shiseido Co., Ltd. Column packing and process for production thereof
JP4035482B2 (ja) 2003-06-27 2008-01-23 キヤノン株式会社 置換アントリル誘導体およびそれを使用した有機発光素子
US7125488B2 (en) * 2004-02-12 2006-10-24 Varian, Inc. Polar-modified bonded phase materials for chromatographic separations
US7943693B2 (en) 2007-05-31 2011-05-17 The Goodyear Tire & Rubber Company Elastomers containing surface metalated siliceous fillers
US8138117B2 (en) 2009-09-08 2012-03-20 Battelle Memorial Institute Functionalized sorbent for chemical separations and sequential forming process
WO2014169982A1 (de) * 2013-04-17 2014-10-23 Merck Patent Gmbh Dünnschichtchromatopraphie-platte, verfahren zurherstellung einer solchen platte, sowie verfahren zur durchführung einer dünnschichtchromatographischen trennung

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6326326B1 (en) * 1998-02-06 2001-12-04 Battelle Memorial Institute Surface functionalized mesoporous material and method of making same
CN1302224A (zh) * 1998-02-09 2001-07-04 工业科学技术网络公司 采用经过表面处理的干凝胶进行离子分离
CN101421012A (zh) * 2004-04-23 2009-04-29 吉恩康国际股份有限公司 使用经过硅烷处理的二氧化硅过滤介质分离样品中的组分的方法
CN101314653A (zh) * 2007-05-31 2008-12-03 固特异轮胎和橡胶公司 包含表面金属化的硅质填料的弹性体
CN101444541A (zh) * 2007-11-26 2009-06-03 中国中医科学院中药研究所 键合硅胶类复合材料在脱除中药提取液中重金属的应用
CN102056976A (zh) * 2008-05-05 2011-05-11 卡普图尔技术有限责任公司 新型交联聚合物基材、该基材的制备方法和终端用途应用
CN102428145A (zh) * 2009-03-18 2012-04-25 巴斯夫欧洲公司 改性的二氧化硅粒子和包含它们的防污聚合物组合物

Also Published As

Publication number Publication date
EP3046666B1 (en) 2019-12-11
WO2015039170A1 (en) 2015-03-26
CN106061601A (zh) 2016-10-26
ES2781193T3 (es) 2020-08-31
US10058843B2 (en) 2018-08-28
CA2924707A1 (en) 2015-03-26
DK3046666T3 (da) 2020-03-16
AU2014324073A1 (en) 2016-04-14
EP3046666A4 (en) 2017-05-03
EP3046666A1 (en) 2016-07-27
JP6338675B2 (ja) 2018-06-06
AU2014324073B2 (en) 2017-08-24
CA2924707C (en) 2019-08-20
JP2016538128A (ja) 2016-12-08
US20160228849A1 (en) 2016-08-11

Similar Documents

Publication Publication Date Title
CN106061601B (zh) 多功能吸附剂材料以及其用途
Giret et al. Selective separation and preconcentration of scandium with mesoporous silica
Bibby et al. Mercury (II) ion adsorption behavior in thiol-functionalized mesoporous silica microspheres
Tan et al. Eu (III) sorption to TiO2 (anatase and rutile): batch, XPS, and EXAFS studies
CN1729146B (zh) 表面活性氧化钛产品的制备方法和该产品在水处理技术中的用途
CN109070053A (zh) 用于色谱分离的具有受控孔隙度的多孔材料;其制备方法;以及其用途
De Decker et al. Carbamoylmethylphosphine oxide-functionalized MIL-101 (Cr) as highly selective uranium adsorbent
JP7028931B2 (ja) 放射性核種吸着剤、その製造方法及びそれを用いた放射性核種の除去方法
CN102458649B (zh) 新型吸附剂、其制备方法及其用途
WO2012115273A1 (en) Method for extraction and separation of lanthanoid elements and actinoid elements, and means for extraction and separation of lanthanoid elements and actinoid elements
Chakravarty et al. Role of nanoporous materials in radiochemical separations for biomedical applications
Sheha et al. Adsorption and diffusion of cesium ions in zirconium (IV) iodomolybdate exchanger
Chakravarty et al. Practicality of tetragonal nano-zirconia as a prospective sorbent in the preparation of 99Mo/99mTc generator for biomedical applications
Li et al. Twofold interpenetrated cationic metal–organic framework with hydrophobic channels for effectively trapping toxic oxo-anions
CN103071457B (zh) 凝胶型碘离子吸附剂、其制备方法及应用
CA2791751C (en) Sorbent material
CA3007460A1 (en) Treatment method of radioactive waste water containing radioactive cesium and radioactive strontium
Singh et al. Lanthanum Cerate Microspheres for Efficient Fluoride Removal from Wastewater
JPS5845705A (ja) 酸素酸のチタン酸への吸着速度の向上方法
Kononenko et al. Manganese oxide-based granular sorbent for the removal of strontium radionuclides from radioactively contaminated natural water
Ghamry et al. Employment of Co (II)–Fe (III) layered double hydroxide as magnetic adsorbent for rapid recovery of molybdenum-99
US20070009409A1 (en) 212Bi or 213Bi Generator from supported parent isotope
JP2022033711A (ja) 金属含有液の処理方法、及び有機溶剤の製造方法
Ram et al. Usefulness of nano-zirconia for purification and concentration of 125I solution for medical applications
Moreno-Gil et al. Comparison of the sorption behavior of 99Mo by Ti-, Si-, Ti-Si-xerogels and commercial sorbents

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
TA01 Transfer of patent application right
TA01 Transfer of patent application right

Effective date of registration: 20180212

Address after: New South Wales Australia

Applicant after: Le Fansuo

Applicant after: Le Mingke

Address before: New South Wales Australia

Applicant before: Maddie, Tektronix Inc

GR01 Patent grant
GR01 Patent grant