CN106047074A - Cured resin modified asphalt antirust paint for ship bottoms - Google Patents

Cured resin modified asphalt antirust paint for ship bottoms Download PDF

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Publication number
CN106047074A
CN106047074A CN201610566626.8A CN201610566626A CN106047074A CN 106047074 A CN106047074 A CN 106047074A CN 201610566626 A CN201610566626 A CN 201610566626A CN 106047074 A CN106047074 A CN 106047074A
Authority
CN
China
Prior art keywords
parts
emulsion
antirust paint
modified asphalt
kieselguhr
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610566626.8A
Other languages
Chinese (zh)
Inventor
刘懿
孙巨福
戴宇钧
汪鹏程
祝盆鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Julong Car and Ship Coating Co Ltd
Original Assignee
Tianchang Julong Car and Ship Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Julong Car and Ship Coating Co Ltd filed Critical Tianchang Julong Car and Ship Coating Co Ltd
Priority to CN201610566626.8A priority Critical patent/CN106047074A/en
Publication of CN106047074A publication Critical patent/CN106047074A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a cured resin modified asphalt antirust paint for ship bottoms, and relates to the technical field of preparation of chemical coatings. The cured resin modified asphalt antirust paint is prepared from the following raw materials: 50-60 parts of epoxy resin, 25-35 parts of modified asphalt, 10-20 parts of thermoplastic acrylic resin, 6-8 parts of carbon black, 3-5 parts of zinc molybdate, 10-20 parts of precipitated barium sulphate, 3-5 parts of talcum powder, 6-8 parts of barium metaborate, 10-20 parts of an organic silicon emulsion, 10-20 parts of EVA emulsion, 10-20 parts of polyurethane emulsion, 15-25 parts of sodium polyacrylate, 2-4 parts of hexametaphosphate, 5-7 parts of denaturation diatomite and 200-220 parts of deionized water. The cured resin modified asphalt antirust paint disclosed by the invention has the benefits that the technological process of the cured resin modified asphalt antirust paint is succinct, the compounding ratio of the raw materials is reasonable, the epoxy resin and the modified asphalt are used as main materials which are used together with remaining addition agents, so that the antirust paint for the ship bottoms is obtained and directly applied to painting of the ship bottoms, the antirust paint can be quickly and completely cured, and besides, the antirust paint is antiseptic, antirust, resistant to water and high temperature, stable in properties, and not liable to come off.

Description

A kind of animi resin modified pitch ship bottom anticorrosion paint
Technical field
The present invention relates to chemistry painting industry preparing technical field, be specifically related to a kind of animi resin modified pitch ship bottom anticorrosion paint.
Background technology
Paint is that one can firmly cover at body surface, rises and protect, decorates, indicates and the chemistry of other specific uses is mixed Compound coating.China's more authoritative " coating process " book of coating circle is defined such that " coating is a kind of material, this Material can be coated in object surface by different construction technologies, formed adhere to firmly, to have some strength, continuous print solid-state thin Film.The film common name film so formed, also known as paint film or coating.
Boats and ships, the general name of various ships.Boats and ships are to navigate by water or berth to carry out in waters transporting or the vehicles of operation, External form is usually beneficial to overcome the cleanliness envelope of fluid resistance, and material is constantly updated along with scientific and technological progress, be in early days wood, bamboo, Mostly the nature materials such as fiber crops, be steel and aluminum, glass fibre, acrylic and various composite modern age, and boats and ships hull bottom is due to often Year floats in water, is therefore easy to phenomenon corrosion occur, and therefore major part boats and ships hull bottom is all through antirust treatment, Normal mode is all to use antirust paint brushing, but owing to the formulation selection that antirust paint is actual is not reasonable, and boats and ships ship The environment that the end is positioned at is complex, and the most common antirust paint can not play good rust inhibition.
Summary of the invention:
The technical problem to be solved is to provide a kind of formula reasonable, and production technology is simple, and using effect is good Animi resin modified pitch ship bottom anticorrosion paint.
The technical problem to be solved realizes by the following technical solutions:
A kind of animi resin modified pitch ship bottom anticorrosion paint, it is characterised in that: it is made up of following raw material:
Epoxy resin 50-60 part, modified pitch 25-35 part, thermoplastic acrylic resin 10-20 part, white carbon black 6-8 part, molybdenum Acid zinc 3-5 part, blanc fixe 10-20 part, Pulvis Talci 3-5 part, barium metaborate 6-8 part, organic silicon emulsion 10-20 part, EVA breast Liquid 10-20 part, polyaminoester emulsion 10-20 part, sodium polyacrylate 15-25 part, hexa metaphosphoric acid 2-4 part, degeneration kieselguhr 5-7 part, Deionized water 200-220 part.
The preferred component of each raw material is: epoxy resin 55 parts, modified pitch 30 parts, thermoplastic acrylic resin 15 parts, charcoal Black 7 parts, zinc molybdate 4 parts, blanc fixe 15 parts, Pulvis Talci 4 parts, barium metaborate 7 parts, organic silicon emulsion 15 parts, EVA emulsion 15 Part, polyaminoester emulsion 15 parts, sodium polyacrylate 20 parts, hexa metaphosphoric acid 3 parts, 6 parts of degeneration kieselguhr, deionized water 210 parts.
Described modified pitch uses: matrix pitch 15kg, neoprene 3kg, crosslinking alkadienes 2kg；
During preparation: by matrix pitch thermal dehydration then neoprene is levigate, together with crosslinking alkadienes and matrix pitch Put in cutter, after making polrvinyl chloride be blended with Colophonium shearing under the effect of crosslinking alkadienes, the most available；
Described degeneration kieselguhr is made up of following raw material: 100 parts of kieselguhr, sodium hexameta phosphate 3 parts, 35 parts of water, hydrochloric acid 4 Part, potassium hydroxide 15 parts, Borax 2.5, Cab-O-sil 20 parts
Its preparation method is: being put into by kieselguhr in the molten device of stirring, joined by sodium hexameta phosphate in container, stirring is mixed Close, add 20 parts of water in kieselguhr, stir 5 minutes, stand swelling dispersion 40 minutes, then by 5 parts of hydrochloric acid, water, put into In stirring container, stirring, stand 30 minutes, then potassium hydroxide, Borax and remaining 10 parts of water are put into wherein, stirring is all Even, stand 45 minutes, after adding Cab-O-sil, urge dry, can be prepared by degeneration kieselguhr.
It is a further object to provide a kind of method preparing animi resin modified pitch ship bottom anticorrosion paint of the present invention, It is characterized in that comprising the following steps:
(1) select Scattered Kettle, above-mentioned epoxy resin, modified pitch and thermoplastic acrylic resin are added thereto, at a high speed After stirring, addition organic silicon emulsion, EVA emulsion and polyaminoester emulsion, mix homogeneously again, standby；
(2), after white carbon black, zinc molybdate, blanc fixe, Pulvis Talci, barium metaborate, degeneration kieselguhr being merged, ball milling mixes Closing, being milled to fineness of the particles is below 25um；
(3) after the material in above-mentioned steps 1 and 2 being merged, put in ball mill, be subsequently adding sodium polyacrylate and six inclined Phosphoric acid, controls rotating speed at 2500-3500r/min, and high speed ball milling, until fineness of the particles is less than after 20um, adds in raw material Deionized water, after continuing with rotating speed stirring 15-25min, discharging, packaging is the most available.
The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use epoxy resin, modification Colophonium, as main material, coordinates the use of remaining auxiliary agent, obtains ship bottom anticorrosion paint, directly applies to hull bottom brushing, can be quick It is fully cured, and antiseptic and rustproof, water resistant, high temperature resistant, stable performance, difficult drop-off.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment 1
Weigh: epoxy resin 50kg, modified pitch 25kg, thermoplastic acrylic resin 10kg, white carbon black 6kg, zinc molybdate 3kg, blanc fixe 10kg, Pulvis Talci 3kg, barium metaborate 6kg, organic silicon emulsion 10kg, EVA emulsion 10kg, polyurethane breast Liquid 10kg, sodium polyacrylate 15kg, hexa metaphosphoric acid 2kg, degeneration kieselguhr 5kg, deionized water 200kg.
Embodiment 2
Weigh: epoxy resin 55kg, modified pitch 30kg, thermoplastic acrylic resin 15kg, white carbon black 7kg, zinc molybdate 4kg, blanc fixe 15kg, Pulvis Talci 4kg, barium metaborate 7kg, organic silicon emulsion 15kg, EVA emulsion 15kg, polyurethane breast Liquid 15kg, sodium polyacrylate 20kg, hexa metaphosphoric acid 3kg, degeneration kieselguhr 6kg, deionized water 210kg.
The preparation method of above-described embodiment 1 or 2 is as follows:
(1) select Scattered Kettle, above-mentioned epoxy resin, modified pitch and thermoplastic acrylic resin are added thereto, at a high speed After stirring, addition organic silicon emulsion, EVA emulsion and polyaminoester emulsion, mix homogeneously again, standby；
(2), after white carbon black, zinc molybdate, blanc fixe, Pulvis Talci, barium metaborate, degeneration kieselguhr being merged, ball milling mixes Closing, being milled to fineness of the particles is below 25um；
(3) after the material in above-mentioned steps 1 and 2 being merged, put in ball mill, be subsequently adding sodium polyacrylate and six inclined Phosphoric acid, controls rotating speed at 2500-3500r/min, and high speed ball milling, until fineness of the particles is less than after 20um, adds in raw material Deionized water, after continuing with rotating speed stirring 15-25min, discharging, packaging is the most available.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (4)

1. an animi resin modified pitch ship bottom anticorrosion paint, it is characterised in that: it is made up of following raw material:
Epoxy resin 50-60 part, modified pitch 25-35 part, thermoplastic acrylic resin 10-20 part, white carbon black 6-8 part, zinc molybdate 3-5 part, blanc fixe 10-20 part, Pulvis Talci 3-5 part, barium metaborate 6-8 part, organic silicon emulsion 10-20 part, EVA emulsion 10-20 part, polyaminoester emulsion 10-20 part, sodium polyacrylate 15-25 part, hexa metaphosphoric acid 2-4 part, degeneration kieselguhr 5-7 part, go Ionized water 200-220 part；
Preparation method is:
(1) select Scattered Kettle, above-mentioned epoxy resin, modified pitch and thermoplastic acrylic resin are added thereto, high-speed stirred After Jun Yun, addition organic silicon emulsion, EVA emulsion and polyaminoester emulsion, mix homogeneously again, standby；
(2), after white carbon black, zinc molybdate, blanc fixe, Pulvis Talci, barium metaborate, degeneration kieselguhr being merged, ball milling mixes, ball Being milled to fineness of the particles is below 25um；
(3), after the material in above-mentioned steps 1 and 2 being merged, put in ball mill, be subsequently adding sodium polyacrylate and six inclined phosphorus Acid, controls rotating speed at 2500-3500r/min, and high speed ball milling, until fineness of the particles is less than after 20um, adds going in raw material Ionized water, after continuing with rotating speed stirring 15-25min, discharging, packaging is the most available.
A kind of animi resin modified pitch ship bottom anticorrosion paint the most according to claim 1, it is characterised in that each raw material preferred Component is: epoxy resin 55 parts, modified pitch 30 parts, thermoplastic acrylic resin 15 parts, white carbon black 7 parts, zinc molybdate 4 parts, precipitation 15 parts of barium sulfate, Pulvis Talci 4 parts, barium metaborate 7 parts, organic silicon emulsion 15 parts, EVA emulsion 15 parts, polyaminoester emulsion 15 parts, poly- Sodium acrylate 20 parts, hexa metaphosphoric acid 3 parts, 6 parts of degeneration kieselguhr, deionized water 210 parts.
A kind of animi resin modified pitch ship bottom anticorrosion paint the most according to claim 1, it is characterised in that: described modified drip Blue or green employing: matrix pitch 15kg, neoprene 3kg, crosslinking alkadienes 2kg；
During preparation: by matrix pitch thermal dehydration then neoprene is levigate, put into together with crosslinking alkadienes and matrix pitch In cutter, after making polrvinyl chloride be blended with Colophonium shearing under the effect of crosslinking alkadienes, the most available.
A kind of animi resin modified pitch ship bottom anticorrosion paint the most according to claim 1, it is characterised in that: described degeneration silicon Diatomaceous earth is made up of following raw material: 100 parts of kieselguhr, sodium hexameta phosphate 3 parts, 35 parts of water, hydrochloric acid 4 parts, potassium hydroxide 15 parts, Borax 2.5, Cab-O-sil 20 parts
Its preparation method is: is put into by kieselguhr in the molten device of stirring, is joined by sodium hexameta phosphate in container, stirring mixing, Add 20 parts of water in kieselguhr, stir 5 minutes, stand swelling dispersion 40 minutes, then by 5 parts of hydrochloric acid, water, put into stirring In container, stir, stand 30 minutes, then potassium hydroxide, Borax and remaining 10 parts of water are put into wherein, stir, Stand 45 minutes, after adding Cab-O-sil, urge dry, can be prepared by degeneration kieselguhr.
CN201610566626.8A 2016-07-18 2016-07-18 Cured resin modified asphalt antirust paint for ship bottoms Pending CN106047074A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610566626.8A CN106047074A (en) 2016-07-18 2016-07-18 Cured resin modified asphalt antirust paint for ship bottoms

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610566626.8A CN106047074A (en) 2016-07-18 2016-07-18 Cured resin modified asphalt antirust paint for ship bottoms

Publications (1)

Publication Number Publication Date
CN106047074A true CN106047074A (en) 2016-10-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107474681A (en) * 2017-07-14 2017-12-15 太仓市老船长船舶服务有限公司 A kind of ship bottom anticorrosion paint

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101153180A (en) * 2006-09-25 2008-04-02 中宏（天津）实业有限公司 Method of producing modified acrylic acid roofing waterproof paint
US20120216952A1 (en) * 2009-10-05 2012-08-30 Paula Bushendorf Polyurethane Formulation With High Green Strength and Gunnability
CN103194072A (en) * 2013-04-25 2013-07-10 交通运输部公路科学研究所 Complex modified asphalt composition and preparation method thereof
CN103602217A (en) * 2013-10-10 2014-02-26 安徽真信涂料有限公司 Asphalt rust-resisting paint for ship bottom and preparation method thereof
CN103602210A (en) * 2013-10-10 2014-02-26 安徽真信涂料有限公司 Rust-resisting paint specially used for ship ballast water tanks and preparation method thereof
CN104277664A (en) * 2014-10-20 2015-01-14 芜湖县双宝建材有限公司 Marine anticorrosive coatings

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101153180A (en) * 2006-09-25 2008-04-02 中宏（天津）实业有限公司 Method of producing modified acrylic acid roofing waterproof paint
US20120216952A1 (en) * 2009-10-05 2012-08-30 Paula Bushendorf Polyurethane Formulation With High Green Strength and Gunnability
CN103194072A (en) * 2013-04-25 2013-07-10 交通运输部公路科学研究所 Complex modified asphalt composition and preparation method thereof
CN103602217A (en) * 2013-10-10 2014-02-26 安徽真信涂料有限公司 Asphalt rust-resisting paint for ship bottom and preparation method thereof
CN103602210A (en) * 2013-10-10 2014-02-26 安徽真信涂料有限公司 Rust-resisting paint specially used for ship ballast water tanks and preparation method thereof
CN104277664A (en) * 2014-10-20 2015-01-14 芜湖县双宝建材有限公司 Marine anticorrosive coatings

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107474681A (en) * 2017-07-14 2017-12-15 太仓市老船长船舶服务有限公司 A kind of ship bottom anticorrosion paint

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Application publication date: 20161026

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