CN106085155A - A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint - Google Patents

A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint Download PDF

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Publication number
CN106085155A
CN106085155A CN201610563308.6A CN201610563308A CN106085155A CN 106085155 A CN106085155 A CN 106085155A CN 201610563308 A CN201610563308 A CN 201610563308A CN 106085155 A CN106085155 A CN 106085155A
Authority
CN
China
Prior art keywords
parts
chlorinated rubber
polyester resin
powder
modified chlorinated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610563308.6A
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Chinese (zh)
Inventor
刘懿
孙巨福
戴宇钧
汪鹏程
祝盆鑫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianchang Julong Car and Ship Coating Co Ltd
Original Assignee
Tianchang Julong Car and Ship Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianchang Julong Car and Ship Coating Co Ltd filed Critical Tianchang Julong Car and Ship Coating Co Ltd
Priority to CN201610563308.6A priority Critical patent/CN106085155A/en
Publication of CN106085155A publication Critical patent/CN106085155A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Paints Or Removers (AREA)

Abstract

A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint, relate to chemistry painting industry preparing technical field, be made up of following raw material: polyester resin 50 60 parts, modified chlorinated rubber 25 35 parts, thermoplastic acrylic resin 10 20 parts, 35 parts of copper sulfate, copper powder 24 parts, zinc oxide 35 parts, alum powder 68 parts, attapulgite 8 10 parts, siloxanes 57 parts, 35 parts of argentum powder, methanol 15 25 parts, Ludox 8 10 parts, lauryl alcohol 15 25 parts, propylene glycol 15 25 parts, reinforcing agent 57 parts, deionized water 150 160 parts.The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use polyester resin, modified chlorinated rubber as main material, coordinating the use of remaining auxiliary agent, obtain wear-resisting finish paint, quality is hard smooth, anticorrosive anti-wear, it is applicable to various high friction field, stable performance, difficult drop-off.

Description

A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint
Technical field
The present invention relates to chemistry painting industry preparing technical field, be specifically related to a kind of wear-resisting type polyester resin modified chlorinated rubber Finish paint.
Background technology
Paint is that one can firmly cover at body surface, rises and protect, decorates, indicates and the chemistry of other specific uses is mixed Compound coating.China's more authoritative " coating process " book of coating circle is defined such that " coating is a kind of material, this Material can be coated in object surface by different construction technologies, formed adhere to firmly, to have some strength, continuous print solid-state thin Film.The film common name film so formed, also known as paint film or coating.
Paint, due to the difference of its application, has different component proportioning different performance, is directed in some field, rubs Wiping more serious, paint must possess anti-wear performance accordingly, and tradition its cost of wear resistant paint is of a relatively high, and its high friction Holding capacity is not the strongest, and therefore range is the most extensive.
Summary of the invention:
The technical problem to be solved is to provide a kind of formula reasonable, and production technology is simple, and performance consolidates Wear-resisting type polyester resin modified chlorinated rubber finish paint.
The technical problem to be solved realizes by the following technical solutions:
A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint, it is characterised in that: it is made up of following raw material:
Polyester resin 50-60 part, modified chlorinated rubber 25-35 part, thermoplastic acrylic resin 10-20 part, copper sulfate 3-5 Part, copper powder 2-4 part, zinc oxide 3-5 part, alum powder 6-8 part, attapulgite 8-10 part, siloxanes 5-7 part, argentum powder 3-5 part, first Alcohol 15-25 part, Ludox 8-10 part, lauryl alcohol 15-25 part, propylene glycol 15-25 part, reinforcing agent 5-7 part, deionized water 150- 160 parts.
The preferred component of each raw material is: polyester resin 55 parts, modified chlorinated rubber 30 parts, thermoplastic acrylic resin 15 Part, 4 parts of copper sulfate, copper powder 3 parts, zinc oxide 4 parts, alum powder 7 parts, attapulgite 9 parts, siloxanes 6 parts, 4 parts of argentum powder, methanol 20 Part, Ludox 9 parts, lauryl alcohol 20 parts, propylene glycol 20 parts, reinforcing agent 6 parts, deionized water 155 parts.
Described modified chlorinated rubber uses: chlorinated rubber 60 parts, ethyl acrylate 10 parts, butyl acrylate 15 difference, Butyl methacrylate 15 parts;
During preparation: all raw materials are placed in banbury jointly, intensification 120-140 DEG C, after refining 25-30min, Obtain;
Described reinforcing agent is by aqueous epoxy resins 6-8 part, methanol 1-3 part, aluminium powder 1-3 part, argentum powder 2-5 part, triethylamine After 1-3 part, calcium carbonate 8-10 part carry out mixing merging, compound and make;
It is a further object to provide a kind of method preparing animi resin modified pitch ship bottom anticorrosion paint of the present invention, It is characterized in that comprising the following steps:
(1) select Scattered Kettle, above-mentioned polyester resin, modified chlorinated rubber, thermoplastic acrylic resin are added thereto, high After speed stirs, addition methanol, lauryl alcohol and propylene glycol, mix homogeneously again, standby;
(2), after copper powder, zinc oxide, alum powder, attapulgite, siloxanes, argentum powder and reinforcing agent being merged, ball milling mixes, Being milled to fineness of the particles is below 25um;
(3), after the material in above-mentioned steps 1 and 2 being merged, put in ball mill, be subsequently adding copper sulfate and Ludox, Rotating speed is controlled at 2500-3500r/min, high speed ball milling until fineness of the particles less than after 20um, add in raw material go from Sub-water, after continuing with rotating speed stirring 15-25min, discharging, packaging is the most available.
The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, use polyester resin, modification Chlorinated rubber, as main material, coordinates the use of remaining auxiliary agent, obtains wear-resisting finish paint, and quality is hard smooth, anticorrosive anti-wear, is suitable for In various high friction fields, stable performance, difficult drop-off.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment 1
Weigh: polyester resin 50kg, modified chlorinated rubber 25kg, thermoplastic acrylic resin 10kg, copper sulfate 3kg, copper Powder 2kg, zinc oxide 3kg, alum powder 6kg, attapulgite 8kg, siloxanes 5kg, argentum powder 3kg, methanol 15kg, Ludox 8kg, the moon Cinnamic alcohol 15kg, propylene glycol 15kg, reinforcing agent 5kg, deionized water 150kg.
Embodiment 2
Weigh: polyester resin 55kg, modified chlorinated rubber 30kg, thermoplastic acrylic resin 15kg, copper sulfate 4kg, copper Powder 3kg, zinc oxide 4kg, alum powder 7kg, attapulgite 9kg, siloxanes 6kg, argentum powder 4kg, methanol 20kg, Ludox 9kg, the moon Cinnamic alcohol 20kg, propylene glycol 20kg, reinforcing agent 6kg, deionized water 155kg.
The preparation method of above-described embodiment 1 or 2 is as follows:
(1) select Scattered Kettle, above-mentioned polyester resin, modified chlorinated rubber, thermoplastic acrylic resin are added thereto, high After speed stirs, addition methanol, lauryl alcohol and propylene glycol, mix homogeneously again, standby;
(2), after copper powder, zinc oxide, alum powder, attapulgite, siloxanes, argentum powder and reinforcing agent being merged, ball milling mixes, Being milled to fineness of the particles is below 25um;
(3), after the material in above-mentioned steps 1 and 2 being merged, put in ball mill, be subsequently adding copper sulfate and Ludox, Rotating speed is controlled at 2500-3500r/min, high speed ball milling until fineness of the particles less than after 20um, add in raw material go from Sub-water, after continuing with rotating speed stirring 15-25min, discharging, packaging is the most available.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (4)

1. a wear-resisting type polyester resin modified chlorinated rubber finish paint, it is characterised in that: it is made up of following raw material:
Polyester resin 50-60 part, modified chlorinated rubber 25-35 part, thermoplastic acrylic resin 10-20 part, copper sulfate 3-5 part, Copper powder 2-4 part, zinc oxide 3-5 part, alum powder 6-8 part, attapulgite 8-10 part, siloxanes 5-7 part, argentum powder 3-5 part, methanol 15-25 part, Ludox 8-10 part, lauryl alcohol 15-25 part, propylene glycol 15-25 part, reinforcing agent 5-7 part, deionized water 150- 160 parts;
Preparation method is:
(1) select Scattered Kettle, above-mentioned polyester resin, modified chlorinated rubber, thermoplastic acrylic resin are added thereto, high-speed stirring After mixing uniformly, addition methanol, lauryl alcohol and propylene glycol, mix homogeneously again, standby;
(2), after copper powder, zinc oxide, alum powder, attapulgite, siloxanes, argentum powder and reinforcing agent being merged, ball milling mixes, ball milling It is below 25um to fineness of the particles;
(3) after the material in above-mentioned steps 1 and 2 being merged, put in ball mill, be subsequently adding copper sulfate and Ludox, will turn Speed controls at 2500-3500r/min, and high speed ball milling, until fineness of the particles is less than after 20um, adds the deionized water in raw material, After continuing with rotating speed stirring 15-25min, discharging, packaging is the most available.
A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint the most according to claim 1, it is characterised in that each raw material Preferred component be: polyester resin 55 parts, modified chlorinated rubber 30 parts, thermoplastic acrylic resin 15 parts, 4 parts of copper sulfate, copper 3 parts of powder, zinc oxide 4 parts, alum powder 7 parts, attapulgite 9 parts, siloxanes 6 parts, 4 parts of argentum powder, methanol 20 parts, Ludox 9 part, month Cinnamic alcohol 20 parts, propylene glycol 20 parts, reinforcing agent 6 parts, deionized water 155 parts.
A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint the most according to claim 1, it is characterised in that: described Modified chlorinated rubber uses: chlorinated rubber 60 parts, ethyl acrylate 10 parts, butyl acrylate 15 difference, butyl methacrylate 15 parts;
During preparation: all raw materials are placed in banbury jointly, intensification 120-140 DEG C, after refining 25-30min, Arrive.
A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint the most according to claim 1, it is characterised in that: described Reinforcing agent is by aqueous epoxy resins 6-8 part, methanol 1-3 part, aluminium powder 1-3 part, argentum powder 2-5 part, triethylamine 1-3 part, calcium carbonate 8- After 10 parts carry out mixing merging, compound and make.
CN201610563308.6A 2016-07-18 2016-07-18 A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint Pending CN106085155A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610563308.6A CN106085155A (en) 2016-07-18 2016-07-18 A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610563308.6A CN106085155A (en) 2016-07-18 2016-07-18 A kind of wear-resisting type polyester resin modified chlorinated rubber finish paint

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106733545A (en) * 2016-11-30 2017-05-31 贵州开磷集团股份有限公司 A kind of steel structure surface method for anticorrosion-treating
CN107903723A (en) * 2017-11-29 2018-04-13 南京金三力橡塑有限公司 A kind of rubber roller vulcanization anti-corrosion material and preparation method thereof and application method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875798A (en) * 2010-05-31 2010-11-03 刘昆虎 Metal surface imitation exterior paint
CN104059511A (en) * 2013-03-18 2014-09-24 福建省腾龙工业公司 Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof
CN104910812A (en) * 2015-05-26 2015-09-16 江苏高科物流科技股份有限公司 Water-resistant paint
CN105038335A (en) * 2015-07-08 2015-11-11 刘晓东 Room-temperature curable inorganic coating and manufacturing method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875798A (en) * 2010-05-31 2010-11-03 刘昆虎 Metal surface imitation exterior paint
CN104059511A (en) * 2013-03-18 2014-09-24 福建省腾龙工业公司 Quick-drying primer-topcoat two-in-one steel member paint and preparation method thereof
CN104910812A (en) * 2015-05-26 2015-09-16 江苏高科物流科技股份有限公司 Water-resistant paint
CN105038335A (en) * 2015-07-08 2015-11-11 刘晓东 Room-temperature curable inorganic coating and manufacturing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106733545A (en) * 2016-11-30 2017-05-31 贵州开磷集团股份有限公司 A kind of steel structure surface method for anticorrosion-treating
CN107903723A (en) * 2017-11-29 2018-04-13 南京金三力橡塑有限公司 A kind of rubber roller vulcanization anti-corrosion material and preparation method thereof and application method

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Application publication date: 20161109

RJ01 Rejection of invention patent application after publication