CN107779040A - A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof - Google Patents

A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof Download PDF

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Publication number
CN107779040A
CN107779040A CN201610732721.0A CN201610732721A CN107779040A CN 107779040 A CN107779040 A CN 107779040A CN 201610732721 A CN201610732721 A CN 201610732721A CN 107779040 A CN107779040 A CN 107779040A
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CN
China
Prior art keywords
paint
corrosion
water
environmental protective
ludox
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610732721.0A
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Chinese (zh)
Inventor
谢海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Champion Coating Technology Group Ltd By Share Ltd
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Jiangsu Champion Coating Technology Group Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Champion Coating Technology Group Ltd By Share Ltd filed Critical Jiangsu Champion Coating Technology Group Ltd By Share Ltd
Priority to CN201610732721.0A priority Critical patent/CN107779040A/en
Publication of CN107779040A publication Critical patent/CN107779040A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084Inorganic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention provides a kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof, belong to technical field of coatings.Include following component by weight percentage:10 ~ 45% aqueous epoxy resins, 5% ~ 20% Ludox, 5 ~ 15% anti-corrosion paint, 20% ~ 40% color stuffing, 0.5% ~ 5% auxiliary agent and 10% ~ 15% water;Above-mentioned anti-corrosion paint is trbasic zinc phosphate, modified zinc phosphate, zinc molybdate one or more arbitrary proportion mixture;Above-mentioned auxiliary agent is by wetting agent, dispersant, coalescents, pH adjusting agent, defoamer, auxiliary rheological agents mixture in any proportion.The adhesive force of this water-based anticorrosive paint and metal, antiseptic property, hardness and chemical-resistance are more excellent, and salt fog resistance can exceed that 1000 hours.

Description

A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof
Technical field
It is more particularly to a kind of to include water-based ring the invention provides a kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof The anticorrosive paint of oxygen tree fat and Ludox, belongs to technical field of coatings.
Background technology
Nowadays environmental protection is increasingly taken seriously, the development of anticorrosive paint will with it is pollution-free, nuisanceless, save the energy, Economical and efficient is principle, and waterborne metal anti-corrosive paint will substitute traditional solvent based coating, by as following anticorrosive paint Main flow.Aqueous epoxy resins equally have many advantages, such as epoxy resin, adhesive force such as excellent to metal, cement, shrinkage factor Low, acid and alkali resistance and other solvents, favorable anti-corrosion effect etc., the coating prepared using aqueous epoxy resins can equally reach preferable Antiseptic effect.Inorganic silicic acid salt sol uses in zinc-rich coating is prepared as main film forming matter, equally has Excellent antiseptic property, the moisture in alkoxy absorption air in Ludox concurrently give birth to hydrolysis, and crosslinking curing is into silicic acid The double salt of zinc-iron and zinc silicate, it is securely attached to steel surface and plays a protective role.It is in addition, organic-inorganic multiple at some Close in coating it has also been found that the addition of Ludox can greatly improve the anti-after tack of alkali resistance, hardness, high temperature of film, but by water Property epoxy and Ludox it is compound and coordinate anti-corrosion paint to be used to preparing anticorrosive paint and have no report.
The content of the invention
For problem above, the invention provides a kind of anti-corrosion Environmental Protective Water-paint, include by weight percentage Following component:10 ~ 45% aqueous epoxy resins, 5% ~ 20% Ludox, 5 ~ 15% anti-corrosion paint, 20% ~ 40% Color stuffing, 0.5% ~ 5% auxiliary agent and 10% ~ 15% water.Above-mentioned anti-corrosion paint is aluminium triphosphate, calcium ion-exchanged One or more of arbitrary proportion mixtures in pigment, trbasic zinc phosphate, modified zinc phosphate, zinc molybdate;Above-mentioned auxiliary agent is wetting Agent, dispersant, coalescents, pH conditioning agents, defoamer, the mixture of auxiliary rheological agents in any proportion;Above-mentioned color stuffing can To be the mixture of one or more of arbitrary proportions in iron oxide red, titanium dioxide, barium sulfate, talcum powder, mica powder.Water-based ring The weight of oxygen tree fat is 3-5 times of Ludox weight.
Its preparation method is:By aqueous epoxy resins, Ludox, wetting agent, dispersant, coalescents, pH conditioning agents, Defoamer and water are mixed evenly;Then anti-corrosion paint and color stuffing are added while stirring, are stirred;Rheology is added to help Agent, stir, obtain water-based anticorrosive paint.The beneficial effects of the invention are as follows:In water-based anticorrosive paint provided by the invention into Membrane substance is collectively constituted by aqueous epoxy resins and Ludox, also contains the rust resisting pigment containing zinc salt in addition, silica sol particle with Particle containing zinc salt reacts, and forms the space network of Si-O keys, while Ludox can also be sent out with steel ground Raw bonding action, the complex compound of silicic acid zinc-iron is formed, so that paint film is firmly attached to steel surface, substantially increased water-based anti- Adhesive force, antiseptic property, hardness and the chemical-resistance of rotten coating and metal, salt fog resistance can exceed that 1000 hours.Should Coating, which applies, can be used for the metal surfaces such as steel, aluminium, play protective effect well.
Embodiment:To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with specific reality Mode is applied to be described in further detail the present invention.The present embodiment be by following raw material by weight ratio made of:It is water-based Epoxy resin 45%, Ludox 9%, trbasic zinc phosphate 1%, modified zinc phosphate 1%, zinc molybdate 1%, aluminium triphosphate 3%, iron oxide red 10%, Titanium dioxide 14%, barium sulfate 3%, wetting agent 0.25%, dispersant 0.25%, coalescents 0.5%, pH adjusting agent 0.5%, defoamer 0.25%th, auxiliary rheological agents 0.25%, water 11%.Embodiment described above, the simply present invention more preferably embodiment, this area The usual variations and alternatives that are carried out in the range of technical solution of the present invention of technical staff should all be included in the protection model of the present invention In enclosing.

Claims (5)

1. a kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof, include following component by weight percentage:10~ 45% aqueous epoxy resins, 5% ~ 20% Ludox, 5 ~ 15% anti-corrosion paint, 20% ~ 40% color stuffing, 0.5% ~ 5% Auxiliary agent and 10% ~ 15% water;Described anti-corrosion paint is that trbasic zinc phosphate, modified zinc phosphate, zinc molybdate are one or more of any Scalemic thereof;Described auxiliary agent be by wetting agent, dispersant, coalescents, pH conditioning agents, defoamer, auxiliary rheological agents by appoint Meaning scalemic thereof.
2. anti-corrosion Environmental Protective Water-paint according to claim 1, it is characterised in that:Described color stuffing is iron oxide The mixture of one or more of arbitrary proportions in red, titanium dioxide, barium sulfate, talcum powder, mica powder.
3. water-based anticorrosive paint according to claim 2, it is characterised in that:Also contain trimerization phosphorus in described anti-corrosion paint Any or both arbitrary proportion mixture of sour aluminium, calcium ion-exchanged pigment.
4. anti-corrosion Environmental Protective Water-paint according to claim 1, it is characterised in that:The weight of aqueous epoxy resins is 3 ~ 5 times of Ludox weight.
5. a kind of preparation method of anti-corrosion Environmental Protective Water-paint, comprises the following steps:By aqueous epoxy resins, Ludox, profit Humectant, dispersant, coalescents, pH adjusting agent, defoamer and water are mixed evenly;Then anti-corrosion face is added while stirring Material and color stuffing, stir;Auxiliary rheological agents are added, stirs, obtains water-based anticorrosive paint.
CN201610732721.0A 2016-08-27 2016-08-27 A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof Pending CN107779040A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610732721.0A CN107779040A (en) 2016-08-27 2016-08-27 A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610732721.0A CN107779040A (en) 2016-08-27 2016-08-27 A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107779040A true CN107779040A (en) 2018-03-09

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610732721.0A Pending CN107779040A (en) 2016-08-27 2016-08-27 A kind of anti-corrosion Environmental Protective Water-paint and preparation method thereof

Country Status (1)

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CN (1) CN107779040A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108546448A (en) * 2018-05-09 2018-09-18 淮南师范学院 The synthesis of undecylenic alcohol maleic acid ammonium and the preparation process of nano anticorrosive coating
CN111303670A (en) * 2018-12-11 2020-06-19 哈米尔顿森德斯特兰德公司 Chromium-free corrosion inhibiting coating
CN112126317A (en) * 2020-09-28 2020-12-25 山东七维新材料有限公司 Low-temperature-resistant novel water-based epoxy coating and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108546448A (en) * 2018-05-09 2018-09-18 淮南师范学院 The synthesis of undecylenic alcohol maleic acid ammonium and the preparation process of nano anticorrosive coating
CN111303670A (en) * 2018-12-11 2020-06-19 哈米尔顿森德斯特兰德公司 Chromium-free corrosion inhibiting coating
CN112126317A (en) * 2020-09-28 2020-12-25 山东七维新材料有限公司 Low-temperature-resistant novel water-based epoxy coating and preparation method thereof

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Application publication date: 20180309

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