CN106046934A - Antistatic inkjet printing ink - Google Patents
Antistatic inkjet printing ink Download PDFInfo
- Publication number
- CN106046934A CN106046934A CN201610594674.8A CN201610594674A CN106046934A CN 106046934 A CN106046934 A CN 106046934A CN 201610594674 A CN201610594674 A CN 201610594674A CN 106046934 A CN106046934 A CN 106046934A
- Authority
- CN
- China
- Prior art keywords
- antistatic
- printing ink
- dimethyl
- code
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses an antistatic inkjet printing ink, prepared from the following materials according to parts by weight: 6-14 parts of acrylic resin, 68-72 parts of isopropyl acetate, 12-18 parts of ethylene glycol ether acetate, 0.4-0.6 part of a fluorescent colorant, 4-6 parts of dyestuff, 0.6-1.4 parts of a static inhibitor and 0.2-0.8 part of an ultraviolet absorber. The preparation method of the inkjet printing ink of the invention is simple, all product identifications made on base materials of various colors can be 100% accurately and clearly read, and while the performance and functionality of common ink are maintained, the ink has the good performances such as good antistatic property and ultraviolet resistance.
Description
Technical field
The present invention relates to chemical ink field, be specifically related to a kind of antistatic code-spraying printing ink.
Background technology
Along with improving constantly of people's living standard, the products quality consciousness of modern is increasingly stronger, to product information
Mark requires more and more higher, particularly the safety problem of the product such as food, medicine, cosmetics, and national governments put into effect the most successively
New laws and regulations, and this is carried out strict specification and management, the label of the product such as law-making stipulation food, medicine, cosmetics
On must indicate the explanation of the protection such as production date, lot number, shelf-life consumer rights, the quality management of enterprise itself with
Sense of self-protection and automatic management level are also improving constantly, utilize code spraying technology product is carried out quality control and with
The business that track, reinforcement sell channel management and warehousing management etc. is more universal, and code spraying technology is because of in terms of bar code printing
Flexibly, the advantage such as high efficiency, low cost be remarkably improved enterprise and the image of product, promote production marketing, improve work efficiency,
Increase Business Economic Benefit, thus the diversification the most day by day of its application, and as its main consumptive material code-spraying printing ink
Development has wide market prospect.
The ink scientific and technological content of front domestic most manufacturers itself is low, in order to share code-spraying printing ink market, one after another
With some enterprises with the development work of scientific research institutions' cooperation development novel ink, but due to R&D fund insufficient investment, research and develop energy
Power is limited, and the key technology grasped in high-tech inks field is few, and a lot of problems are difficult to effectively be solved, such as ink
Viscosity controls, the type of the dispersibility of pigment particle and the auxiliary agent such as stable, resin and the screening of solvent, surfactant excellent
Choosing, the fast light water-fast solvent resistance of the color of the consistency problem of different component and product in inking system, special to ground
The poor adhesive force etc. of non-polar substrates.
In order to reduce the harm that electrostatic is brought, at present, people are typically employed in ink interpolation color stuffing to suppress quiet
The generation of electric charge and promote the leakage of electrostatic charge, antistatic effect produced by this method is the most very good, how to develop
The antisatic additive that a kind of antistatic effect is good and antistatic is lasting, and in ink, be all ink area workers
Problem encountered.
Summary of the invention
The technical problem to be solved be to provide a kind of be unlikely to deteriorate, concentration is high, the antistatic coding of environmental protection is beaten
Printing ink.
The present invention seeks to be achieved through the following technical solutions:
The invention provides a kind of antistatic code-spraying printing ink, the raw material of following weight parts be prepared from: acrylic acid
Resin 6-14 part, isopropyl acetate 68-72 part, ethylene glycol ether acetate 12-18 part, fluorescent colorant 0.4-0.6 part, dyestuff
4-6 part, antistatic additive 0.6-1.4 part, UV absorbent 0.2-0.8 part.
Preferably, described fluorescent colorant is benzothiazole derivant, pyran derivate, thiophene derivant, hexichol first
The mixture of one or more in ketone disulfonic acid derivatives, heterocycle phenolic compound and coumarin derivative.
Preferably, described dyestuff be the one in premetallized dye, anthraquinone dye, azo dye, heterocyclic dye or
Multiple mixture.
Preferably, described antistatic additive by N-ethyl-1,2-dimethyl-propylamin, cetyl trimethylammonium bromide, ten
Dialkyl dimethyl glycine betaine mixes, described N-ethyl-1,2-dimethyl-propylamin, cetyl trimethylammonium bromide, ten
The mass ratio of dialkyl dimethyl glycine betaine is (1-3): (1-3): (1-3).
Preferably, described UV absorbent is by octyl triazone, Diethylhexyl Butamido Triazon, 1-(4-
Anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione mixes, described octyl triazone, Diethylhexyl butamido
Base triazinone, the mass ratio of 1-(4-anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione are (1-3): (1-3): (1-
3)。
Preferably, described acrylic resin, can buy or prepare, pleasing Chemical trade such as purchase from Anji perseverance has
The trade mark of limit company is the polyurethane acrylic resin of JSMI-100, it is also possible to reference to number of patent application: 201310087629.X
Prepared by the method for middle embodiment 1.
Present invention also offers the preparation method of described antistatic code-spraying printing ink, comprising the steps: will by proportioning
Acrylic resin, isopropyl acetate, ethylene glycol ether acetate, fluorescent colorant, dyestuff, antistatic additive, UV absorbent
Mix homogeneously and get final product.
The code-spraying printing ink of the present invention, preparation method is simple, and the product identification made on assorted ground is the most permissible
100% accurately clearly reads, and while the performance maintaining common ink and function, also has good antistatic, anti-
The performances such as ultraviolet.
Detailed description of the invention
Embodiment each raw material introduction:
Fluorescent colorant is heterocycle phenolic compound, the concrete pigment using De Li Science and Technology Ltd. of Peking University to provide
Code is that the fluorescence long wave of DELI-3 is yellow.
Dyestuff is AZOpigments, concrete uses Hangzhou to reflect the light-resistant scarlet BBN that mountain flower pigment Chemical Co., Ltd. provides.
Acrylic resin, with reference to number of patent application: in 201310087629.X prepared by the method for embodiment 1.
Isopropyl acetate, No. CAS: 108-21-4.
Ethylene glycol ether acetate, No. CAS: 111-15-9.
N-ethyl-1,2-dimethyl-propylamin, No. CAS: 2738-06-9.
Cetyl trimethylammonium bromide, No. CAS: 57-09-0.
Dodecyldimethylammonium hydroxide inner salt, No. CAS: 683-10-3.
Octyl triazone, No. CAS: 88122-99-0.
Diethylhexyl Butamido Triazon, No. CAS: 154702-15-5.
1-(4-anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione, No. CAS: 70356-09-1.
Embodiment 1
Antistatic code-spraying printing ink raw material (weight portion): acrylic resin 10 parts, isopropyl acetate 70 parts, ethylene glycol ethyl ethers
Ether acetate 14 parts, fluorescence long wave Huang DELI-3 0.4 part, light-resistant scarlet BBN 4 parts, 0.6 part of antistatic additive, ultra-violet absorption
Agent 0.6 part.
Described antistatic additive is by N-ethyl-1,2-dimethyl-propylamin, cetyl trimethylammonium bromide, dodecyl
Dimethyl betaine is uniformly mixed for 1:1:1 in mass ratio and obtains.
Described UV absorbent is by octyl triazone, Diethylhexyl Butamido Triazon, 1-(4-methoxy benzene
Base)-3-(4-tert-butyl-phenyl)-1,3-propanedione is uniformly mixed for 1:1:1 in mass ratio and obtains.
The preparation of antistatic code-spraying printing ink: isopropyl acetate, ethylene glycol ether acetate are uniformly mixed,
To mixed solvent；Acrylic resin adds mixed solvent be stirred 50 minutes with the rotating speed of 700 revs/min, be subsequently adding
Fluorescence long wave Huang DELI-3 is stirred 5 minutes with the rotating speed of 700 revs/min, adds light-resistant scarlet BBN with 700 revs/min
Rotating speed be stirred 5 minutes, add antistatic additive, UV absorbent is stirred 10 points with the rotating speed of 700 revs/min
Clock.Obtain the antistatic code-spraying printing ink of embodiment 1.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described antistatic additive by cetyl trimethylammonium bromide,
Dodecyldimethylammonium hydroxide inner salt is uniformly mixed for 1:1 in mass ratio and obtains.The antistatic coding obtaining embodiment 2 prints
Ink.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described antistatic additive is by N-ethyl-1,2-dimethyl-the third
Amine, dodecyldimethylammonium hydroxide inner salt are uniformly mixed for 1:1 in mass ratio and obtain.Obtain the antistatic coding of embodiment 3
Pad-ink.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described antistatic additive is by N-ethyl-1,2-dimethyl-the third
Amine, cetyl trimethylammonium bromide are uniformly mixed for 1:1 in mass ratio and obtain.Obtain the antistatic coding of embodiment 4
Pad-ink.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described UV absorbent is by Diethylhexyl butamido base
Triazinone, 1-(4-anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione are uniformly mixed for 1:1 in mass ratio
Arrive.Obtain the antistatic code-spraying printing ink of embodiment 5.
Embodiment 6
Substantially the same manner as Example 1, differ only in: described UV absorbent is by octyl triazone, 1-(4-first
Oxygen phenyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione is uniformly mixed for 1:1 in mass ratio and obtains.Obtain embodiment 6
Antistatic code-spraying printing ink.
Embodiment 7
Substantially the same manner as Example 1, differ only in: described UV absorbent is by octyl triazone, diethyl
Hexyl amide-based small triazinone is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the antistatic coding type oil of embodiment 7
Ink.
Test case 1
Antistatic code-spraying printing ink embodiment 1-7 prepared, is respectively coated on the glass plate of 10 × 10cm, coating
Thickness is 12 μm, after the high voltage mercury lamp, distance 15cm irradiation 15s of 1000W solidification film；The most again by above-mentioned solid
Coating after change is respectively cut into two pieces of coated film of 3cm × 3cm, and one piece for detection coating surface resistance, another block at once
The sheet resistance of coating is detected again, to evaluate the anti-quiet of the ink of the above-mentioned antistatic additive containing polymerization activity after placing 3 months
Electrical property and the persistency of antistatic property, the ZC36 type super-high electricity that the sheet resistance of film produces with Shanghai the 6th ammeter factory
Resistance instrument measures.Concrete outcome is shown in Table 1.
Table 1: antistatic property test result list position: Ω
| Sheet resistance at once | March rear surface resistance | |
| Embodiment 1 | 2.2×108 | 3.9×108 |
| Embodiment 2 | 4.8×108 | 1.2×109 |
| Embodiment 3 | 5.2×108 | 1.7×109 |
| Embodiment 4 | 4.9×108 | 1.8×109 |
| Embodiment 5 | 4.2×108 | 9.2×108 |
| Embodiment 6 | 3.8×108 | 8.6×108 |
| Embodiment 7 | 4.2×108 | 9.0×108 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (N-ethyl-1,2-dimethyl-propylamin, cetyl trimethyl
Ammonium bromide, dodecyldimethylammonium hydroxide inner salt are compounding) antistatic property and antistatic property persistency be substantially better than embodiment 2-4
(in N-ethyl-1,2-dimethyl-propylamin, cetyl trimethylammonium bromide, dodecyldimethylammonium hydroxide inner salt, arbitrarily the two is multiple
Join)；Comparing embodiment 1 and embodiment 5-7, embodiment 1 (octyl triazone, Diethylhexyl Butamido Triazon, 1-(4-
Anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione compound) antistatic property and antistatic property persistency the most excellent
In embodiment 5-7 (octyl triazone, Diethylhexyl Butamido Triazon, 1-(4-anisyl)-3-(4-tert-butyl benzene
Base) arbitrarily the two is compounding in-1,3-propanedione).
Test case 2
The antistatic code-spraying printing ink preparing embodiment 1-7, is respectively coated on the glass plate of 10cm × 10cm, is coated with
Layer thickness is 12 μm, after the high voltage mercury lamp, distance 15cm irradiation 15s of 1000W solidification film；According to GB/T
Test condition in 22771-2008 standard, carries out xenon lamp acceleration light resistance and tests film, casing air themperature 44 DEG C, relatively
Humidity 50%, irradiance 1.10W/m2, 340nm.Instrument measuring method is used to obtain the color after tanning by the sun 20 hours and 40 hours
Change △ E*, uses CIEL*a*b* color unit, D65 light source and 10 degree of viewing angles.Concrete outcome is shown in Table 2.
Table 2: xenon lamp accelerates light resistance test result
| △E*-20h | △E*-40h | |
| Embodiment 1 | 1.48 | 2.59 |
| Embodiment 2 | 2.62 | 4.02 |
| Embodiment 3 | 2.52 | 3.85 |
| Embodiment 4 | 2.40 | 4.10 |
| Embodiment 5 | 2.72 | 4.52 |
| Embodiment 6 | 2.69 | 4.36 |
| Embodiment 7 | 2.81 | 4.31 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (N-ethyl-1,2-dimethyl-propylamin, cetyl trimethyl
Ammonium bromide, dodecyldimethylammonium hydroxide inner salt are compounding) light fastness be substantially better than embodiment 2-4 (N-ethyl-1,2-dimethyl-
In propylamine, cetyl trimethylammonium bromide, dodecyldimethylammonium hydroxide inner salt, arbitrarily the two is compounding)；Comparing embodiment 1 is with real
Execute example 5-7, embodiment 1 (octyl triazone, Diethylhexyl Butamido Triazon, 1-(4-anisyl)-3-(the tertiary fourth of 4-
Base phenyl)-1,3-propanedione compounds) light fastness persistency is substantially better than embodiment 5-7 (octyl triazone, diethylhexyl
In amide-based small triazinone, 1-(4-anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione, arbitrarily the two is compounding).
Claims (3)
1. an antistatic code-spraying printing ink, it is characterised in that be prepared from by the raw material of following weight parts: acrylic resin
6-14 part, isopropyl acetate 68-72 part, ethylene glycol ether acetate 12-18 part, fluorescent colorant 0.4-0.6 part, dyestuff 4-6
Part, antistatic additive 0.6-1.4 part, UV absorbent 0.2-0.8 part.
Described antistatic additive is by N-ethyl-1,2-dimethyl-propylamin, cetyl trimethylammonium bromide, dimethyl
Base glycine betaine mixes, described N-ethyl-1,2-dimethyl-propylamin, cetyl trimethylammonium bromide, dimethyl
The mass ratio of base glycine betaine is (1-3): (1-3): (1-3).
Described UV absorbent is by octyl triazone, Diethylhexyl Butamido Triazon, 1-(4-anisyl)-3-
(4-tert-butyl-phenyl)-1,3-propanedione mixes, described octyl triazone, Diethylhexyl Butamido Triazon, 1-
The mass ratio of (4-anisyl)-3-(4-tert-butyl-phenyl)-1,3-propanedione is (1-3): (1-3): (1-3).
2. antistatic code-spraying printing ink as claimed in claim 1, it is characterised in that: described fluorescent colorant is benzo thiophene
Zole derivatives, pyran derivate, thiophene derivant, benzophenone disulfonic acid derivatives, heterocycle phenolic compound and coumarin spread out
The mixture of one or more in biology.
3. antistatic code-spraying printing ink as claimed in claim 1 or 2, it is characterised in that: described dyestuff is metal complex
The mixture of one or more in dyestuff, anthraquinone dye, azo dye, heterocyclic dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610594674.8A CN106046934A (en) | 2016-07-26 | 2016-07-26 | Antistatic inkjet printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610594674.8A CN106046934A (en) | 2016-07-26 | 2016-07-26 | Antistatic inkjet printing ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106046934A true CN106046934A (en) | 2016-10-26 |
Family
ID=57417806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610594674.8A Pending CN106046934A (en) | 2016-07-26 | 2016-07-26 | Antistatic inkjet printing ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106046934A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101870834A (en) * | 2010-06-18 | 2010-10-27 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
-
2016
- 2016-07-26 CN CN201610594674.8A patent/CN106046934A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101870834A (en) * | 2010-06-18 | 2010-10-27 | 北京赛腾工业标识系统有限公司 | Code-spraying printing ink |
Non-Patent Citations (1)
| Title |
|---|
| 王少君等: "《印刷油墨生产技术》", 31 May 2004, 化学工业出版社第1版 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103396699B (en) | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof | |
| CN101845263A (en) | UV (Ultraviolet) curing coatings with high weatherability | |
| CN105694631B (en) | A kind of stain resistant aqueous glaze and preparation method thereof, application | |
| CN106120388A (en) | High-fixation digital textile printing ink composition | |
| TW299288B (en) | ||
| CN109486407A (en) | A kind of dedicated polyurethane paint of Recombinant Wood and preparation method thereof | |
| CN103881416B (en) | Dispers ozoic dyestuff compositions, dye preparations and its preparation method and application | |
| CN106046934A (en) | Antistatic inkjet printing ink | |
| CN109504177A (en) | A kind of lettering pen printing ink composition of lightfast antioxidant | |
| US3475187A (en) | Edible indelible ink for pharmaceutical pellets | |
| CN103525293A (en) | Non-yellowing UV (Ultraviolet) gloss oil as well as preparation method thereof | |
| CN104175666B (en) | Intercept ultraviolet color anti-fog fenestrated membrane | |
| CN103911037B (en) | The mute black ink of silk screen printing | |
| JP2014105228A (en) | Multicolored pattern paint and multicolored pattern coating film | |
| CN105907171B (en) | A kind of UV resistant heat resistance accessory and the base gravure ink composition for layer of PVC comprising it | |
| CN106009915A (en) | Heat-resistant code spurting printing ink | |
| CN103614006B (en) | A kind of Ge Lisi for PU American and European style and preparation method thereof | |
| CN105860671A (en) | High-abrasion-resistance code-spurting printing ink and preparation method thereof | |
| CN104175665A (en) | Colored heat insulation window film for blocking ultraviolet light | |
| CN109135400A (en) | The application of red sorghum pigment, water stain and preparation method thereof and aqueous woodware paint | |
| CN103952033B (en) | A kind of general ink and preparation method thereof and using method | |
| CN105838148A (en) | Antistatic code-spurting printing ink and preparation method thereof | |
| CN105505380A (en) | Recognizable fluorescent pigment for repairing bronze cultural relic and preparation method thereof, and method for repairing bronze cultural relic | |
| CN105985680A (en) | Glass UV-cured printing ink and preparation method thereof | |
| CN102585615B (en) | A kind of have the Plastic ornament materials of color fiber points and the preparation method of material thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161026 |