CN105505380A - Recognizable fluorescent pigment for repairing bronze cultural relic and preparation method thereof, and method for repairing bronze cultural relic - Google Patents
Recognizable fluorescent pigment for repairing bronze cultural relic and preparation method thereof, and method for repairing bronze cultural relic Download PDFInfo
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- CN105505380A CN105505380A CN201511022311.9A CN201511022311A CN105505380A CN 105505380 A CN105505380 A CN 105505380A CN 201511022311 A CN201511022311 A CN 201511022311A CN 105505380 A CN105505380 A CN 105505380A
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- visibility pigment
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
- C09D193/02—Shellac
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/02—Use of particular materials as binders, particle coatings or suspension media therefor
- C09K11/025—Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Luminescent Compositions (AREA)
Abstract
The invention provides a recognizable fluorescent pigment for repairing a bronze cultural relic, which comprises the following components in parts by weight: 8-12 parts of surface adhesive agent, 2-4 parts of mineral pigment, 1-3 parts of organic ultraviolet fluorescent powder and 4-5 parts of solvent. When the fluorescent pigment provided by the invention is used for repairing the bronze cultural relic, the repaired part can not be easily detected under sunlight and can be easily detected under ultraviolet light, thereby solving the industrial problems of recognizability and beautiful appearance in cultural relic repair. The fluorescent pigment has the advantages of durable material color and low tendency to decolorization, and can not damage the cultural relic.
Description
Technical field
The present invention relates to historical relic recovery technique field, particularly relate to the restorative procedure that a kind of Bronze Relics repairs identifiable design high-visibility pigment and preparation method thereof and a kind of Bronze Relics.
Background technology
The Bronze Relics of China is witness and the carrier of human progress civilization, the symbol of bronze ritual vessels Chinese gift culture especially.It is huge that Bronze Relics deposits generation amount, as the device of cooking a meal in successive dynasties, feeder, drinking vessel, hydrophone, musical instrument, vehicle and horse decorations, bronze mirror, buckle, weapons, instrument and apparatus for weights and measures etc.Through spreading for a long time or burying, most of bronze historical relic all presents with fracture, incomplete form.This just needs, through professional's repair process, to restore the appearance that bronze work is original.But along with Western Modern repairs the infiltration of theory; the identifiable design principle of historical relic reparation is paid attention to day by day; but the RM that west is praised highly also does not meet China's traditional aesthetic culture; therefore " Chinese cultural relics paleovolcanic structure criterion " regulation that China publishes both should be coordinated with original part mutually through the part of repair process, identifiable design again.Present stage, good way is not yet found out to process " fusion and difference " that Bronze Relics repairs position and original paper in domestic bronze reparation field, and historical relic reparation " identifiable design " is still an industry difficult problem.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of Bronze Relics to repair the restorative procedure of identifiable design high-visibility pigment and preparation method thereof and a kind of Bronze Relics, and the reparation position of Bronze Relics is difficult to find out, identifiable design again.
The invention provides a kind of Bronze Relics and repair identifiable design high-visibility pigment, comprising:
Preferably, described organic ultraviolet fluorescent material is fluorescent blue organic ultraviolet fluorescent material.
Preferably, described surface attachment agent is shellac varnish.
Preferably, described shellac varnish is shellac ethanolic soln.
Preferably, described solvent is ethyl acetate.
Preferably, described high-visibility pigment comprises:
Present invention also offers the preparation method that a kind of preceding claim Bronze Relics repairs identifiable design high-visibility pigment, comprising:
A) surface attachment agent is mixed with mineral color, obtain the first pigment;
B) organic ultraviolet fluorescent material and solvent is even, obtain the second pigment;
C) the first pigment is mixed with the second pigment, obtain described Bronze Relics and repair identifiable design high-visibility pigment.
Preferably, described steps A) mixing temperature be 10 ~ 40 DEG C.
Present invention also offers a kind of restorative procedure of Bronze Relics, repair identifiable design high-visibility pigment for healant with above-mentioned Bronze Relics.
Compared with prior art, the invention provides a kind of Bronze Relics and repair identifiable design high-visibility pigment, comprising: surface attachment agent 8 ~ 12 weight part; Mineral color 2 ~ 4 weight part; Organic ultraviolet fluorescent material 1 ~ 3 weight part; Solvent 4 ~ 5 weight part.Adopt high-visibility pigment provided by the invention to repair Bronze Relics, repair position and be difficult in the sunlight find out, more easy to identify again under UV-light, achieve historical relic and repair an identifiable design industry difficult problem attractive in appearance again.And material color is lasting, not easily decolours, and historical relic be can't harm.
Embodiment
The invention provides a kind of Bronze Relics and repair identifiable design high-visibility pigment, comprising:
Adopt high-visibility pigment provided by the invention to repair Bronze Relics, repair position and be difficult in the sunlight find out, more easy to identify again under UV-light, achieve historical relic and repair an identifiable design industry difficult problem attractive in appearance again.And material color is lasting, not easily decolours, and historical relic be can't harm.
In the present invention, described organic ultraviolet fluorescent material is preferably fluorescent blue organic ultraviolet fluorescent material, is more preferably the YG-B813 fluorescent blue organic ultraviolet fluorescent material becoming Chemical Industry Science Co., Ltd purchased from Dongguan City thousand.
The present invention is preferred, and described surface attachment agent is shellac varnish, is more preferably shellac ethanolic soln.
Its content is preferably 8 ~ 12 weight parts, is more preferably 10 weight parts.
Described solvent is preferably ethyl acetate.Its content is preferably 4 ~ 5 weight parts, is more preferably 4 weight parts.
Described mineral color is mineral dye, can be natural crystal pigment, or the chemical industry synthetic dyestuff that natural ore product is made through a series of chemical treatment processing, and the present invention there is no particular determination to this, its color can according to Bronze Relics color selecting.
The content of described mineral color is preferably 2 ~ 4 weight parts, is more preferably 3 weight parts.
Present invention also offers the preparation method that a kind of above-mentioned Bronze Relics repairs identifiable design high-visibility pigment, comprising:
A) surface attachment agent is mixed with mineral color, obtain the first pigment;
B) organic ultraviolet fluorescent material and solvent is even, obtain the second pigment;
C) the first pigment is mixed with the second pigment, obtain described Bronze Relics and repair identifiable design high-visibility pigment.
Above-mentioned steps A), B) there is no sequencing.
Preferably, above-mentioned steps A) mixing temperature be 10 ~ 40 DEG C.
Described step B) mixing temperature be preferably 10 ~ 40 DEG C.
Step C) mixing temperature be preferably 10 ~ 40 DEG C.
Above-mentioned surface attachment agent, mineral color, organic ultraviolet fluorescent material, solvent and consumption thereof are the same, do not repeat them here.
Present invention also offers a kind of restorative procedure of Bronze Relics, adopting above Bronze Relics to repair identifiable design high-visibility pigment is healant.
The present invention is preferred, the Bronze Relics containing fluorescent blue organic ultraviolet fluorescent material is adopted to repair identifiable design high-visibility pigment, take shellac varnish as surface attachment agent, ethyl acetate is solvent, and fluorescent material, shellac varnish, ethyl acetate weight ratio are (1 ~ 3): (8 ~ 12): (4 ~ 5), controlling mineral color addition is 2 ~ 4 weight parts, be difficult to find out vestige under the historical relic daylight repaired, under the UV-irradiation of wavelength 365nm, but be easy to identify, good identifiable design effect can be reached; And that the material for repairing is fast light is heat-resisting, acid and alkali-resistance stability is higher, color is lasting, not easily decolours, and historical relic be can't harm, really embody the theory that historical relic repairs discernible " fusion and difference ", this healant safety and environmental protection, does not have negative effect to historical relic and environment simultaneously.
In order to further illustrate the present invention, below in conjunction with embodiment, the restorative procedure that Bronze Relics provided by the invention repairs identifiable design high-visibility pigment and preparation method thereof and a kind of Bronze Relics is described in detail.
Embodiment 1
By shellac varnish 10 weight part, iron oxide red mineral color 3 weight part mixes, and obtains the first pigment;
Organic ultraviolet fluorescent material 2 weight part, ethyl acetate 4 weight part mixes, and obtains the second pigment;
First pigment is mixed with the second pigment, obtains described Bronze Relics and repair identifiable design high-visibility pigment;
Described organic ultraviolet fluorescent material is the YG-B813 fluorescent blue organic ultraviolet fluorescent material becoming Chemical Industry Science Co., Ltd purchased from Dongguan City thousand.
Use NH310 type computer color difference meter to detect the high-visibility pigment of preparation and the value of chromatism of mineral color, judgment criteria is in table 1, and detected result is in table 2.
The relation of table 1 value of chromatism (Δ E) and mineral color colour-change
The change of material color | ΔE |
Trace | 0~0.5 |
Slightly | 0.5~1.5 |
Can feel | 1.5~3.0 |
Obviously | 3.0~6.0 |
Very large | 6.0~12.0 |
Completely different | More than 12.0 |
Table 2 the embodiment of the present application 1 ~ 3, comparative example 1 ~ 2 value of chromatism detected result
Writing brush is used to dip appropriate above-mentioned high-visibility pigment brushing to Bronze Relics position to be tinted, after tinting, dry.
Use the aqueous acetic acid of 0.1ml5% to drip in position of tinting, use the violet exposure of 365nm, its luminous intensity is good.
Embodiment 2
According to the preparation method of embodiment 1, prepare Bronze Relics and repair identifiable design high-visibility pigment.
Prepare burden as follows:
Shellac varnish 9 weight part;
Mineral color azurite 4 weight part;
Organic ultraviolet fluorescent material 2 weight part;
Ethyl acetate 4 weight part;
Organic ultraviolet fluorescent material is with embodiment 1.
Carry out value of chromatism detection according to the testing method of embodiment 1, the results are shown in Table 2.
Writing brush is used to dip appropriate above-mentioned high-visibility pigment brushing to Bronze Relics position to be tinted, after tinting, dry.
Use the aqueous acetic acid of 0.1ml5% to drip in position of tinting, use the violet exposure of 365nm, its luminous intensity is good.
Embodiment 3
According to the preparation method of embodiment 1, prepare Bronze Relics and repair identifiable design high-visibility pigment.
Prepare burden as follows:
Shellac varnish 10 weight part;
Mineral color azurite 3 weight part;
Organic ultraviolet fluorescent material 2 weight part;
Ethyl acetate 5 weight part;
Organic ultraviolet fluorescent material is with embodiment 1.
Carry out value of chromatism detection according to the testing method of embodiment 1, the results are shown in Table 2.
Writing brush is used to dip appropriate above-mentioned high-visibility pigment brushing to Bronze Relics position to be tinted, after tinting, dry.
Use the aqueous acetic acid of 0.1ml5% to drip in position of tinting, use the violet exposure of 365nm, its luminous intensity is good
Embodiment 4
According to the preparation method of embodiment 1, prepare high-visibility pigment.
Prepare burden as follows:
Shellac varnish 10 weight part;
Mineral color iron oxide red 3 weight part;
Fluorescein YG-H1 fluorescent material 2 weight part, (becoming Chemical Industry Science Co., Ltd purchased from Dongguan City thousand);
Ethyl acetate 4 weight part;
Carry out value of chromatism detection according to the testing method of embodiment 1, the results are shown in Table 2.
Writing brush is used to dip appropriate above-mentioned high-visibility pigment brushing to Bronze Relics position to be tinted, after tinting, dry.
Use the aqueous acetic acid of 0.1ml5% to drip in position of tinting, use the violet exposure of 365nm, its luminous intensity slightly weakens.
Embodiment 5
According to the preparation method of embodiment 1, prepare high-visibility pigment.
Prepare burden as follows:
Shellac varnish 10 weight part;
Mineral color iron oxide red 3 weight part;
Fluorescent yellow YG-HL1 fluorescent material 2 weight part, (becoming Chemical Industry Science Co., Ltd purchased from Dongguan City thousand);
Ethyl acetate 4 weight part;
Carry out value of chromatism detection according to the testing method of embodiment 1, the results are shown in Table 2.
Writing brush is used to dip appropriate above-mentioned high-visibility pigment brushing to Bronze Relics position to be tinted, after tinting, dry.
Use the aqueous acetic acid of 0.1ml5% to drip in position of tinting, use the violet exposure of 365nm, its luminous intensity weakens.
From above-described embodiment, the present invention adopts specific fluorescent powder to prepare Bronze Relics and repairs identifiable design high-visibility pigment, little with mineral color primary colors aberration, and color is lasting, not easily decolours.
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (9)
1. Bronze Relics repairs an identifiable design high-visibility pigment, comprising:
2. high-visibility pigment according to claim 1, is characterized in that, described organic ultraviolet fluorescent material is fluorescent blue organic ultraviolet fluorescent material.
3. high-visibility pigment according to claim 1, is characterized in that, described surface attachment agent is shellac varnish.
4. high-visibility pigment according to claim 3, is characterized in that, described shellac varnish is shellac ethanolic soln.
5. high-visibility pigment according to claim 1, is characterized in that, described solvent is ethyl acetate.
6. high-visibility pigment according to claim 1, is characterized in that, comprising:
7. the Bronze Relics described in any one of claim 1 ~ 6 repairs a preparation method for identifiable design high-visibility pigment, comprising:
A) surface attachment agent is mixed with mineral color, obtain the first pigment;
B) organic ultraviolet fluorescent material and solvent is even, obtain the second pigment;
C) the first pigment is mixed with the second pigment, obtain described Bronze Relics and repair identifiable design high-visibility pigment.
8. preparation method according to claim 7, is characterized in that, described steps A) mixing temperature be 10 ~ 40 DEG C.
9. a restorative procedure for Bronze Relics, repairs identifiable design high-visibility pigment for healant with the Bronze Relics described in any one of claim 1 ~ 6.
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CN201511022311.9A CN105505380B (en) | 2015-12-29 | 2015-12-29 | A kind of Bronze Relics reparation can recognize that fluorescent pigment and preparation method thereof and a kind of restorative procedure of Bronze Relics |
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CN201511022311.9A CN105505380B (en) | 2015-12-29 | 2015-12-29 | A kind of Bronze Relics reparation can recognize that fluorescent pigment and preparation method thereof and a kind of restorative procedure of Bronze Relics |
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CN105505380B CN105505380B (en) | 2018-03-13 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106245437A (en) * | 2016-07-24 | 2016-12-21 | 中国科学技术大学 | Fluorescent paint, recognizable fluorescence paper using and preparation method thereof is can recognize that for paper relics reparation |
CN113390841A (en) * | 2021-06-15 | 2021-09-14 | 北京万象博众系统集成有限公司 | Jade color 3D imaging agent, preparation method thereof and jade 3D imaging method |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106245437A (en) * | 2016-07-24 | 2016-12-21 | 中国科学技术大学 | Fluorescent paint, recognizable fluorescence paper using and preparation method thereof is can recognize that for paper relics reparation |
CN106245437B (en) * | 2016-07-24 | 2018-08-21 | 中国科学技术大学 | Fluorescent paint, recognizable fluorescence paper and preparation method thereof are can recognize that for paper relics reparation |
CN113390841A (en) * | 2021-06-15 | 2021-09-14 | 北京万象博众系统集成有限公司 | Jade color 3D imaging agent, preparation method thereof and jade 3D imaging method |
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