CN105860671A - High-abrasion-resistance code-spurting printing ink and preparation method thereof - Google Patents
High-abrasion-resistance code-spurting printing ink and preparation method thereof Download PDFInfo
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- CN105860671A CN105860671A CN201610420413.4A CN201610420413A CN105860671A CN 105860671 A CN105860671 A CN 105860671A CN 201610420413 A CN201610420413 A CN 201610420413A CN 105860671 A CN105860671 A CN 105860671A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
Abstract
The invention discloses high-abrasion-resistance code-spurting printing ink and a preparation method thereof. The high-abrasion-resistance code-spurting printing ink is prepared from, by weight, 10-20 parts of keto-aldehyde resin, 1-5 parts of copolymer of vinyl chloride and vinyl isobutyl ether, 65-75 parts of 1-propyl alcohol, 10-20 parts of ethylene glycol, 0.3-0.7 parts of fluorescent coloring agent, 3-7 parts of dye, 0.5-1.5 parts of antistatic agent and 0.1-1 part of ultraviolet light absorber. The code-spurting printing ink is simple in preparation method, low in cost and convenient to use, the property and function of ordinary ink are maintained, and meanwhile certain hidden properties of the anti-channel conflict property, the tamper-proofing property and the anti-counterfeit property are achieved; the code-spurting printing ink further has the good properties such as abrasion resistance, static resistance and ultraviolet resistance.
Description
Technical field
The present invention relates to chemical ink field, be specifically related to a kind of high abrasion code-spraying printing ink and preparation method thereof.
Background technology
For the product under high-speed production lines, when carrying out quality tracing, the printing of coding information will be carried out, at product
Upper formation product identification, then carries out shooting for these product identifications and gathers, and the data entry system that will collect.Existing
Code-spraying printing ink be all black ink be main, black ink spray printing information naked eyes out can clearly be recognized, but various not
With on the ground of color, especially reflecting light length is with on the ground of the same or like color of black, and spray printing information is difficult to 100%
Ground carries out shooting and reads, and this just greatly limit the using effect of quality tracing system.
Solvent type ink is fast due to the evaporation rate of solvent, can form quick-drying film in any material, suitable
In the requirement that high-speed and continuous metaplasia is produced.But, the fluorescent material that conventional solvent-borne type fluorescent ink uses under visible light can not
See, it is difficult to take into account color discrimination performance and light excite can photism；Additionally the fluorescent ink of water-based system also can be only applied to on-demand
The piezoelectricity spray printing system of spray printing, is unsuitable for the piezoelectricity sprayed printed system of continuous spray printing, owing to evaporation of water speed is slow, typically sprays
The material of print is all the material (paper products and fabric) of permeability, impermeability material (metal, plastics, covering material, on
The paper etc. of gloss oil) upper spray printing information is difficult to be dried, and also water-based system ink surface tension is big, affects dried film
The performances such as adhesive force.
In order to reduce the harm that electrostatic is brought, at present, people are typically employed in ink interpolation color stuffing to suppress quiet
The generation of electric charge and the leakage of promotion electrostatic charge, thus reduce the sheet resistance of filmogen to a certain extent, strengthen film
Antistatic property, but, owing to reason and the color stuffing of class coating material self structure are usually little molecule, this method is produced
Raw antistatic effect is the most very good, how to develop the antistatic that a kind of antistatic effect is good and antistatic is lasting and adds
Agent, and in ink, be all ink area worker's problem encountered.
Summary of the invention
One of the technical problem to be solved be to provide a kind of be unlikely to deteriorate, concentration is high, the high abrasion spray of environmental protection
Code pad-ink.
The two of the technical problem to be solved are to provide a kind of method preparing this high abrasion code-spraying printing ink.
The present invention seeks to be achieved through the following technical solutions:
The invention provides a kind of high abrasion code-spraying printing ink, the raw material of following weight parts be prepared from: aldehyde ketone tree
Fat 10-20 part, chlorinated polyether resin 1-5 part, 1-propanol 65-75 part, ethylene glycol 10-20 part, fluorescent colorant 0.3-0.7 part, dyestuff
3-7 part, antistatic additive 0.5-1.5 part, UV absorbent 0.1-1 part.
Preferably, described fluorescent colorant is benzothiazole derivant, pyran derivate, thiophene derivant, hexichol first
The mixture of one or more in ketone disulfonic acid derivatives, heterocycle phenolic compound and coumarin derivative.
Preferably, described dyestuff be the one in premetallized dye, anthraquinone dye, azo dye, heterocyclic dye or
Multiple mixture.
Preferably, described antistatic additive is three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride, double ten alkyl
The mixture of one or more in alkyl dimethyl ammonium chloride.
It is highly preferred that described antistatic additive is by three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride, double ten alkane
Base alkyl dimethyl ammonium chloride mixes, described three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride, double ten alkyl-dimethyls
The mass ratio of ammonium chloride is (1-3): (1-3): (1-3).
Preferably, described UV absorbent be 2-(4,6-diphenyl-1,3,5-triazines-2-base)-5-hexyl epoxide-
Phenol, 2-(2H-benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, 2-hydroxyl-4-methoxyl group hexichol first
The mixture of one or more in ketone-5-sulfonic acid.
Preferably, described UV absorbent by 2-(4,6-diphenyl-1,3,5-triazines-2-base)-5-hexyl epoxide-
Phenol, 2-(2H-benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, 2-hydroxyl-4-methoxyl group hexichol first
Ketone-5-sulfonic acid mixes, described 2-(4,6-diphenyl-1,3,5-triazines-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzene
And triazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, the matter of BP-4
Amount ratio is (1-3): (1-3): (1-3).
Preferably, the hydroxyl value of described aldehyde ketone resin is 250-300 milligram KOH/ gram.
Preferably, the chlorinty of described chlorinated polyether resin is 40-50wt%.
Present invention also offers the preparation method of described high abrasion code-spraying printing ink, comprising the steps: will by proportioning
Aldehyde ketone resin, chlorinated polyether resin, 1-propanol, ethylene glycol, fluorescent colorant, dyestuff, antistatic additive, UV absorbent mix homogeneously
Obtain.
The code-spraying printing ink of the present invention, preparation method is simple, and cost is relatively low, easy to use, is maintaining common ink
Performance and function while, be also equipped with certain anti-channel conflict, anti-tamper, the hiding of anti-counterfeiting, spray provided by the present invention
Code pad-ink also has the performances such as good wear-resistant, antistatic, uvioresistant.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described further, the following stated, is only the preferable enforcement to the present invention
Example, not does the restriction of other forms to the present invention, and any those skilled in the art are possibly also with the disclosure above
Technology contents be changed to the Equivalent embodiments that changes on an equal basis.Every without departing from the present invention program content, according to the present invention
Technical spirit any simple modification that following example are done or equivalent variations, all fall within protection scope of the present invention.
Embodiment each raw material introduction:
Fluorescent colorant is heterocycle phenolic compound, the concrete pigment using De Li Science and Technology Ltd. of Peking University to provide
Code is that the fluorescence long wave of DELI-3 is yellow.
Dyestuff is AZOpigments, concrete uses Hangzhou to reflect the light-resistant scarlet BBN that mountain flower pigment Chemical Co., Ltd. provides.
Aldehyde ketone resin, uses the aldehyde ketone resin that model is UK300 that Hindustan company of India provides, and hydroxyl value is 270-
280 milligrams KOH/ gram.
Chlorinated polyether resin, uses the chlorinated polyether resin that model is MP45 that BASF Corp. of Germany provides, and chlorinty is 44wt%.
1-propanol, No. CAS: 71-23-8.
Ethylene glycol, No. CAS: 107-21-1.
Three (2-amino-ethyl) amine, No. CAS: 4097-89-6.
Octadecyl trimethyl ammonium chloride, No. CAS: 112-03-8.
Didecyl Dimethy ammonium chloride, No. CAS: 7173-51-5.
2-(4,6-diphenyl-1,3,5-triazines-2-base)-5-hexyl epoxide-phenol, No. CAS: 147315-50-2.
2-(2H-benzotriazole-2-base)-4,6-bis-(1-methyl isophthalic acid-phenylethyl) phenol, No. CAS: 70321-86-7.
BP-4, No. CAS: 4065-45-6.
Embodiment 1
High abrasion code-spraying printing ink raw material (weight portion): aldehyde ketone resin 16 parts, chlorinated polyether resin 3 parts, 1-propanol 70 parts, second
Glycol 14 parts, fluorescence long wave Huang DELI-3 0.4 part, light-resistant scarlet BBN 4 parts, 0.9 part of antistatic additive, UV absorbent 0.6
Part.
Described antistatic additive is by three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride, didecyl Dimethy
Ammonium chloride is uniformly mixed for 1:1:1 in mass ratio and obtains.
Described UV absorbent is by 2-(4,6-diphenyl-1,3,5-triazine-2-base)-5-hexyl epoxide-phenol, 2-
(2H-benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, ESCALOL 567-5-sulphur
Acid is uniformly mixed for 1:1:1 in mass ratio and obtains.
The preparation of high abrasion code-spraying printing ink: 1-propanol, ethylene glycol are uniformly mixed, obtain mixed solvent；Will
Aldehyde ketone resin add mixed solvent be stirred 40 minutes with the rotating speed of 700 revs/min, chlorinated polyether resin is added mixed solvent with
The rotating speed of 700 revs/min is stirred 10 minutes, is subsequently adding fluorescence long wave Huang DELI-3 and carries out with the rotating speed of 700 revs/min
Stir 5 minutes, add light-resistant scarlet BBN and be stirred 5 minutes with the rotating speed of 700 revs/min, add antistatic additive, purple
Ultraviolet absorbers is stirred 10 minutes with the rotating speed of 700 revs/min.Obtain the high abrasion code-spraying printing ink of embodiment 1.
Embodiment 2
Substantially the same manner as Example 1, differ only in: described antistatic additive by octadecyl trimethyl ammonium chloride,
Didecyl Dimethy ammonium chloride is uniformly mixed for 1:1 in mass ratio and obtains.The high abrasion coding obtaining embodiment 2 prints
Ink.
Embodiment 3
Substantially the same manner as Example 1, differ only in: described antistatic additive by three (2-amino-ethyl) amine, double ten
Alkyl dimethyl ammonium chloride is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the high abrasion coding type oil of embodiment 3
Ink.
Embodiment 4
Substantially the same manner as Example 1, differ only in: described antistatic additive by three (2-amino-ethyl) amine, 18
Alkyl trimethyl ammonium chloride is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the high abrasion coding type oil of embodiment 4
Ink.
Embodiment 5
Substantially the same manner as Example 1, differ only in: described UV absorbent is by 2-(2H-benzotriazole-2-
Base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, BP-4 be 1:1 in mass ratio
It is uniformly mixed and obtains.Obtain the high abrasion code-spraying printing ink of embodiment 5.
Embodiment 6
Substantially the same manner as Example 1, differ only in: described UV absorbent by 2-(4,6-diphenyl-1,3,
5-triazine-2-base)-5-hexyl epoxide-phenol, BP-4 in mass ratio for 1:1 stir
Mix homogeneously obtains.Obtain the high abrasion code-spraying printing ink of embodiment 6.
Embodiment 7
Substantially the same manner as Example 1, differ only in: described UV absorbent by 2-(4,6-diphenyl-1,3,
5-triazine-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) benzene
Phenol is uniformly mixed for 1:1 in mass ratio and obtains.Obtain the high abrasion code-spraying printing ink of embodiment 7.
Test case 1
High abrasion code-spraying printing ink embodiment 1-7 prepared, is respectively coated on the glass plate of 10 × 10cm, coating
Thickness is 12 μm, after the high voltage mercury lamp, distance 15cm irradiation 15s of 1000W solidification film；The most again by above-mentioned solid
Coating after change is respectively cut into two pieces of coated film of 3cm × 3cm, and one piece for detection coating surface resistance, another block at once
The sheet resistance of coating is detected again, to evaluate the anti-quiet of the ink of the above-mentioned antistatic additive containing polymerization activity after placing 3 months
Electrical property and the persistency of antistatic property, the ZC36 type super-high electricity that the sheet resistance of film produces with Shanghai the 6th ammeter factory
Resistance instrument measures.Concrete outcome is shown in Table 1.
Table 1: antistatic property test result list position: Ω
| Sheet resistance at once | March rear surface resistance | |
| Embodiment 1 | 2.4×108 | 4.9×108 |
| Embodiment 2 | 5.4×108 | 1.6×109 |
| Embodiment 3 | 5.9×108 | 2.2×109 |
| Embodiment 4 | 5.7×108 | 1.8×109 |
| Embodiment 5 | 3.8×108 | 8.4×108 |
| Embodiment 6 | 4.5×108 | 9.9×108 |
| Embodiment 7 | 4.2×108 | 9.1×108 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride,
Didecyl Dimethy ammonium chloride compounds) antistatic property and antistatic property persistency be substantially better than embodiment 2-4 (three (2-
Amino-ethyl) amine, octadecyl trimethyl ammonium chloride, arbitrarily the two is compounding in didecyl Dimethy ammonium chloride)；Relatively implement
Example 1 and embodiment 5-7, embodiment 1 (2-(4,6-diphenyl-1,3,5-triazines-2-base)-5-hexyl epoxide-phenol, 2-(2H-
Benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, BP-4 be multiple
Join) antistatic property and antistatic property persistency be substantially better than embodiment 5-7 (2-(4,6-diphenyl-1,3,5-triazine-2-
Base)-5-hexyl epoxide-phenol, 2-(2H-benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, 2-hydroxyl
In base-4-methoxy benzophenone-5-sulfonic acid, arbitrarily the two is compounding).
Test case 2
The high abrasion code-spraying printing ink preparing embodiment 1-7, is respectively coated on the glass plate of 10cm × 10cm, is coated with
Layer thickness is 12 μm, after the high voltage mercury lamp, distance 15cm irradiation 15s of 1000W solidification film；According to GB/T
Test condition in 22771-2008 standard, carries out xenon lamp acceleration light resistance and tests film, casing air themperature 44 DEG C, relatively
Humidity 50%, irradiance 1.10W/m2, 340nm.Instrument measuring method is used to obtain the color after tanning by the sun 20 hours and 40 hours
Change △ E*, uses CIEL*a*b* color unit, D65 light source and 10 degree of viewing angles.Concrete outcome is shown in Table 2.
Table 2: xenon lamp accelerates light resistance test result table
| △E*-20h | △E*-40h | |
| Embodiment 1 | 1.48 | 2.59 |
| Embodiment 2 | 2.49 | 3.42 |
| Embodiment 3 | 2.50 | 3.75 |
| Embodiment 4 | 2.41 | 3.67 |
| Embodiment 5 | 2.82 | 4.31 |
| Embodiment 6 | 2.76 | 4.21 |
| Embodiment 7 | 2.81 | 4.32 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride,
Didecyl Dimethy ammonium chloride compounds) light fastness is substantially better than embodiment 2-4 (three (2-amino-ethyl) amine, octadecyl
In trimethyl ammonium chloride, didecyl Dimethy ammonium chloride, arbitrarily the two is compounding)；Comparing embodiment 1 and embodiment 5-7, implement
Example 1 (2-(4,6-diphenyl-1,3,5-triazine-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzotriazole-2-base)-4,6-
Two (1-methyl isophthalic acid-phenylethyl) phenol, BP-4 are compounding) light fastness persistency is bright
Show and be better than embodiment 5-7 (2-(4,6-diphenyl-1,3,5-triazine-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzo three
Azoles-2-base)-4,6-two (1-methyl isophthalic acid-phenylethyl) phenol, in BP-4 any two
Person compounds).
Test case 3
The high abrasion code-spraying printing ink preparing embodiment 1-4 carries out anti-wear performance test, and anti-wear performance presses GB/
T7706-2008 tests, and at PP ground information spray printing, loads the weight of 700 grams, comes and goes 20 times, it is determined that standard: 1-information takes off
Fall None-identified, and 2-message part comes off identification difficulty, and 3-information has and comes off but can identify, 4-information completely.Concrete outcome
It is shown in Table 3.
Table 3: anti-wear performance test result table
| Anti-wear performance | |
| Embodiment 1 | 4 |
| Embodiment 2 | 2 |
| Embodiment 3 | 3 |
| Embodiment 4 | 2 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2-amino-ethyl) amine, octadecyl trimethyl ammonium chloride,
Didecyl Dimethy ammonium chloride compounds) anti-wear performance is substantially better than embodiment 2-4 (three (2-amino-ethyl) amine, octadecyl
In trimethyl ammonium chloride, didecyl Dimethy ammonium chloride, arbitrarily the two is compounding).
Claims (8)
1. a high abrasion code-spraying printing ink, it is characterised in that be prepared from by the raw material of following weight parts: aldehyde ketone resin
10-20 part, chlorinated polyether resin 1-5 part, 1-propanol 65-75 part, ethylene glycol 10-20 part, fluorescent colorant 0.3-0.7 part, dyestuff 3-7
Part, antistatic additive 0.5-1.5 part, UV absorbent 0.1-1 part.
2. high abrasion code-spraying printing ink as claimed in claim 1, it is characterised in that: described antistatic additive is three (2-ammonia
Base ethyl) amine, octadecyl trimethyl ammonium chloride, the mixture of one or more in didecyl Dimethy ammonium chloride.
3. high abrasion code-spraying printing ink as claimed in claim 2, it is characterised in that: described antistatic additive is by three (2-ammonia
Base ethyl) amine, octadecyl trimethyl ammonium chloride, didecyl Dimethy ammonium chloride mixes, described three (2-amino second
Base) amine, octadecyl trimethyl ammonium chloride, the mass ratio of didecyl Dimethy ammonium chloride be (1-3): (1-3): (1-3).
4. the high abrasion code-spraying printing ink as according to any one of claim 1-3, it is characterised in that: described ultraviolet is inhaled
Receipts agent is 2-(4,6-diphenyl-1,3,5-triazine-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzotriazole-2-base)-4,
Mixing of one or more in 6-bis-(1-methyl isophthalic acid-phenylethyl) phenol, BP-4
Compound.
5. high abrasion code-spraying printing ink as claimed in claim 4, it is characterised in that: described UV absorbent is by 2-
(4,6-diphenyl-1,3,5-triazine-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzotriazole-2-base)-4,6-two (1-first
Base-1-phenylethyl) phenol, BP-4 mix, described 2-(4,6-diphenyl-
1,3,5-triazine-2-base)-5-hexyl epoxide-phenol, 2-(2H-benzotriazole-2-base)-4,6-two (1-methyl isophthalic acid-phenyl second
Base) phenol, the mass ratio of BP-4 be (1-3): (1-3): (1-3).
6. the high abrasion code-spraying printing ink as according to any one of claim 1-3, it is characterised in that: described fluorescent color
Agent is benzothiazole derivant, pyran derivate, thiophene derivant, benzophenone disulfonic acid derivatives, heterocycle phenolic compound
Mixture with one or more in coumarin derivative.
7. the high abrasion code-spraying printing ink as according to any one of claim 1-3, it is characterised in that: described dyestuff is gold
Belong to the mixture of one or more in complex dyestuff, anthraquinone dye, azo dye, heterocyclic dye.
8. the preparation method of high abrasion code-spraying printing ink as according to any one of claim 1-7, it is characterised in that: by proportioning
By aldehyde ketone resin, chlorinated polyether resin, 1-propanol, ethylene glycol, fluorescent colorant, dyestuff, antistatic additive, UV absorbent mixing all
Even and get final product.
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| CN201610420413.4A CN105860671B (en) | 2016-06-13 | 2016-06-13 | High abrasion code-spraying printing ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280709A (en) * | 2016-11-08 | 2017-01-04 | 冯晋 | A kind of environment-protecting asepsis pad-ink and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732087A (en) * | 2011-04-14 | 2012-10-17 | 北京赛腾工业标识系统有限公司 | Anti-channel conflict code-spurting printing ink and its preparation method |
| CN105400291A (en) * | 2015-12-28 | 2016-03-16 | 北京赛腾标识系统股份公司 | Wear and sticking resistant code spraying and printing ink, and preparation method and application thereof |
-
2016
- 2016-06-13 CN CN201610420413.4A patent/CN105860671B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732087A (en) * | 2011-04-14 | 2012-10-17 | 北京赛腾工业标识系统有限公司 | Anti-channel conflict code-spurting printing ink and its preparation method |
| CN105400291A (en) * | 2015-12-28 | 2016-03-16 | 北京赛腾标识系统股份公司 | Wear and sticking resistant code spraying and printing ink, and preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280709A (en) * | 2016-11-08 | 2017-01-04 | 冯晋 | A kind of environment-protecting asepsis pad-ink and preparation method thereof |
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