CN109535826A - Aqueous temperature becomes base gravure ink and combinations thereof - Google Patents
Aqueous temperature becomes base gravure ink and combinations thereof Download PDFInfo
- Publication number
- CN109535826A CN109535826A CN201811342656.6A CN201811342656A CN109535826A CN 109535826 A CN109535826 A CN 109535826A CN 201811342656 A CN201811342656 A CN 201811342656A CN 109535826 A CN109535826 A CN 109535826A
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- Prior art keywords
- aqueous
- parts
- ink
- temperature
- stabilizer
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The aqueous temperature of the present invention becomes base gravure ink, by quality ratio, the composition of every 1000 parts of parts by weight include aqueous acrylic resin 250-350 parts, 100-200 parts of aqueous PU resin, 30-50 parts of aqueous polyethylene wax, aqueous dispersion 15-25,55-75 parts of PH stabilizer, 100-300 parts of camouflage paint and residual components solution.Inventive formulation is simple, ink color changeable effect is improved by using aqueous acrylic resin and aqueous PU resin, aqueous dispersion and PH stabilizer and camouflage paint, it not only can be ageing-resistant and without organic solvent, and it is resistance to rubbing it is also excellent, degradation effect is better than the prior art, and the printing on packing box is suitble to use.
Description
Technical field
The present invention relates to ink and combinations thereof fields, specifically, it shows that a kind of aqueous temperature becomes base gravure ink and its group
Close object.
Background technique
As cry of the people to environmental protection is more more and more intense, especially atmospheric haze the problem of, it is increasingly serious, country
Enterprise's VOCs emission request will be also increasingly stringenter, Beijing, Shanghai, Zhejiang etc. prosperity city or province successively put into effect about
The requirement of VOCs discharge.
Gravure water-based ink is increasingly valued by people because it is discharged almost without volatile organic compounds VOCs
With favor.But the packing box made of water-based ink gravure may be faced and be lost at any time in road side or concentration after consumption
Burning in heaps.
And in burning process, toxic gas can be generated because packing box product surface is printed on industrial chemicals ink.This is not
The discharge of VOCs is only additionally produced, and the later period also produces certain pollution to soil.
Therefore, it is necessary to which providing the aqueous temperature of one kind becomes base gravure ink and combinations thereof to solve the above problems.
Summary of the invention
The object of the present invention is to provide a kind of aqueous temperature to become base gravure ink.
Technical solution is as follows:
A kind of aqueous temperature change base gravure ink, by quality ratio, the composition of every 1000 parts of parts by weight includes aqueous acrylic resin
250-350 parts, 100-200 parts of aqueous PU resin, 30-50 parts of aqueous polyethylene wax, aqueous dispersion 15-25, PH stabilizer 55-
75 parts, the solution of 100-300 parts of camouflage paint and residual components.
Further, solution is made of water.
Further, aqueous PH stabilizer is made of sodium hydroxide.
Further, aqueous dispersion is made of 760W dispersing agent.
The second object of the present invention is to provide a kind of temperature change gravure aqueous ink composition.
Technical solution is as follows:
A kind of temperature change gravure aqueous ink composition, ingredient are as follows: the composition of every 1000 parts of parts by weight includes watersoluble modified third
250-350 parts of diluted acid resin, 100-200 parts of aqueous PU resin, 30-50 parts of aqueous polyethylene wax, aqueous dispersion 15-25, PH
55-75 parts of stabilizer, 100-300 parts of camouflage paint, remaining is water.
Further, solution is made of water.
Further, aqueous PH stabilizer is made of sodium hydroxide.
Further, aqueous dispersion is made of 760W dispersing agent.
Inventive formulation is simple, is stablized by using aqueous acrylic resin and aqueous PU resin, aqueous dispersion and PH
Agent and camouflage paint improve ink color changeable effect, not only can it is ageing-resistant and be free of organic solvent, and it is resistance to rubbing it is also excellent, drop
It solves effect and is better than the prior art, the printing on packing box is suitble to use.
Specific embodiment
Embodiment:
Following embodiment is not intended to limit the scope of the invention for being specifically described the present invention.
Aqueous acrylic resin is provided by Shanghai Basf AG in the present invention, 760W dispersing agent by Digao chemical industry (on
Sea) Co., Ltd provides, and aqueous PU resin provides by Luo Xing Industrial Co., Ltd., and PH stabilizer (NAOH) is had by sea dog H on is suitable
It limits responsible company to provide, camouflage paint u s company provides, and aqueous polyethylene wax is provided by company, Guangzhou Longhai City.
Embodiment 1
By water-based acrylic resin (300g), aqueous PU resin (200g), camouflage paint (300 g), aqueous polyethylene wax
(50g), aqueous aliphatic dispersing agent 760(25g), PH stabilizer NAOH(75g) mixing, with (1000 turns of dispersion machine high-speed stirred
Stirring 20-30 minutes), it then goes to grind with the speed of 1L per minute with grinder again, does relevant performance after grinding 2 times and survey
Examination directly takes ink 100g to add 30g water as dilution, ink is applied to paper surface, is tested again after to be dried.
Embodiment 2
By water-based acrylic resin (250g), aqueous PU resin (200g), camouflage paint (200 g), aqueous polyethylene wax
(40g), aqueous aliphatic dispersing agent 760(15g), PH stabilizer NAOH(45g) mixing of remaining plus water, with dispersion machine high-speed stirred
(1000 turns stirring 20-50 minutes), then go to grind with grinder with the speed of 1.5L per minute again, do correlation after grinding 2 times
Performance test, directly take ink 100g add 30g water as dilution, ink is applied to paper surface, is carried out again after to be dried
Test.
Embodiment 3
By water-based acrylic resin (350g), aqueous PU resin (100g), camouflage paint (250 g), aqueous polyethylene wax
(50g), aqueous aliphatic dispersing agent 760(25g), PH stabilizer NAOH(75g) mixing of remaining plus water, with dispersion machine high-speed stirred
(1000 turns stirring 30-50 minutes), then go to grind with grinder with the speed of 1L per minute again, do after grinding 2 times relevant
Performance test directly takes ink 100g to add 30g water as dilution, ink is applied to paper surface, is surveyed again after to be dried
Examination.
Ink performance test:
Embodiment 1-3 ink is subjected to correlated performance test, and water-based ink is become as reference examples, specifically using temperature currently on the market
It the results are shown in Table 1.
The test of 1 ink performance of table:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Reference examples | |
| Resistance to rubbing | 10N, which rubs printing surface 10 times, not to fade | 10N, which rubs printing surface 10 times, not to fade | 10N, which rubs printing surface 10 times, not to fade | 10N, which rubs printing surface 10 times, to fade |
| The feature of environmental protection | Without organic volatile | Without organic volatile | Without organic volatile | There is benzene kind solvent |
| Bake and bank up with earth case | It is without exception that 80 DEG C of humidity 70 are put into aging | It is without exception that 80 DEG C of humidity 70 are put into aging | It is without exception that 80 DEG C of humidity 70 are put into aging | 80 DEG C of humidity 70 are put into aging form and aspect and shoal |
| Gloss | ≥50° | ≥50° | ≥50° | ≥50° |
As shown in Table 1, the ink coating of embodiment 1-3 is compared with reference examples ink, not only can be ageing-resistant and be free of organic solvent,
And it is resistance to rubbing it is also excellent.It can be seen that degradation effect of the present invention is better than the prior art, the printing on packing box is suitble to use.
Above-described is only some embodiments of the present invention.For the ordinary skill in the art, not
Under the premise of being detached from the invention design, various modifications and improvements can be made, these belong to protection model of the invention
It encloses.
Claims (8)
1. a kind of aqueous temperature becomes base gravure ink, it is characterised in that: by quality ratio, the composition of every 1000 parts of parts by weight includes water
Property 250-350 parts of acrylic resin, 100-200 parts of aqueous PU resin, 30-50 parts of aqueous polyethylene wax, aqueous dispersion 15-
25, PH stabilizer 55-75 parts, the solution of 100-300 parts of camouflage paint and residual components.
2. the aqueous temperature of one kind according to claim 1 becomes base gravure ink, it is characterised in that: solution is made of water.
3. the aqueous temperature of one kind according to claim 2 becomes base gravure ink, it is characterised in that: aqueous PH stabilizer is by hydroxide
Sodium is constituted.
4. the aqueous temperature of one kind according to claim 3 becomes base gravure ink, it is characterised in that: aqueous dispersion is dispersed by 760W
Agent is constituted.
5. a kind of temperature becomes gravure aqueous ink composition, it is characterised in that: ingredient is as follows: the composition packet of every 1000 parts of parts by weight
The property of water-bearing is acrylic resin 250-350 parts modified, 100-200 parts of aqueous PU resin, and 30-50 parts of aqueous polyethylene wax, aqueous point
Powder 15-25,55-75 parts of PH stabilizer, 100-300 parts of camouflage paint, remaining is solvent.
6. a kind of temperature according to claim 5 becomes gravure aqueous ink composition, it is characterised in that: solution is made of water.
7. a kind of temperature according to claim 6 becomes gravure aqueous ink composition, it is characterised in that: aqueous PH stabilizer by
Sodium hydroxide is constituted.
8. a kind of temperature according to claim 7 becomes gravure aqueous ink composition, it is characterised in that: aqueous dispersion by
760W dispersing agent is constituted.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811342656.6A CN109535826A (en) | 2018-11-13 | 2018-11-13 | Aqueous temperature becomes base gravure ink and combinations thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811342656.6A CN109535826A (en) | 2018-11-13 | 2018-11-13 | Aqueous temperature becomes base gravure ink and combinations thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109535826A true CN109535826A (en) | 2019-03-29 |
Family
ID=65846866
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811342656.6A Pending CN109535826A (en) | 2018-11-13 | 2018-11-13 | Aqueous temperature becomes base gravure ink and combinations thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109535826A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2595495A (en) * | 2020-05-28 | 2021-12-01 | Alphabond Tech Ltd | Composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038410A (en) * | 2015-09-15 | 2015-11-11 | 东莞市润丽华实业有限公司 | Anti-counterfeiting and temperature-changing printing ink |
| CN106046932A (en) * | 2016-05-31 | 2016-10-26 | 广东玉兰集团股份有限公司 | Temperature sensitive ink and preparation method, temperature sensitive wallpaper and preparation method of wallpaper |
| CN107987615A (en) * | 2018-01-09 | 2018-05-04 | 永发印务(东莞)有限公司 | A kind of water-based stereo anti-fake color shifting ink of Quick Response Code |
| CN108546452A (en) * | 2018-04-17 | 2018-09-18 | 中山创美涂料有限公司 | A kind of aqueous gravure Yellow ink of flexible PVC decorating film and preparation method thereof |
-
2018
- 2018-11-13 CN CN201811342656.6A patent/CN109535826A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105038410A (en) * | 2015-09-15 | 2015-11-11 | 东莞市润丽华实业有限公司 | Anti-counterfeiting and temperature-changing printing ink |
| CN106046932A (en) * | 2016-05-31 | 2016-10-26 | 广东玉兰集团股份有限公司 | Temperature sensitive ink and preparation method, temperature sensitive wallpaper and preparation method of wallpaper |
| CN107987615A (en) * | 2018-01-09 | 2018-05-04 | 永发印务(东莞)有限公司 | A kind of water-based stereo anti-fake color shifting ink of Quick Response Code |
| CN108546452A (en) * | 2018-04-17 | 2018-09-18 | 中山创美涂料有限公司 | A kind of aqueous gravure Yellow ink of flexible PVC decorating film and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 印刷工业出版社编辑部: "《油墨生产及应用技术》", 30 November 2011, 印刷工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2595495A (en) * | 2020-05-28 | 2021-12-01 | Alphabond Tech Ltd | Composition |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190329 |