CN103436073A - Water-based dispersion liquid dye ink for ink jetting and printing of polyester textile - Google Patents
Water-based dispersion liquid dye ink for ink jetting and printing of polyester textile Download PDFInfo
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- CN103436073A CN103436073A CN2013103240981A CN201310324098A CN103436073A CN 103436073 A CN103436073 A CN 103436073A CN 2013103240981 A CN2013103240981 A CN 2013103240981A CN 201310324098 A CN201310324098 A CN 201310324098A CN 103436073 A CN103436073 A CN 103436073A
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Abstract
The invention relates to water-based dispersion liquid dye ink for ink jetting and printing of a polyester textile. The ink comprises the following components by mass percent: 0.5-15% of dispersion dye, 0.05-5% of ionic liquid, 0.1-3% of surface tension modifier, 0.1-3% of viscosity modifier, 0.2-2% of pH modifier and the balance of deionized water. During ink preparation, auxiliary agents such as other dispersion agents and a surfactant are not required; solvent composition for preparing a co-dispersion dye is very simple, and only the ionic liquid is required in principle. The ink is simple in method and convenient to operate, and grinding in a grinding mill, nanofiltration and the like do not exist, so that the ink is green, pollution-free and environment-friendly, and has no harm to working personnel.
Description
Technical field
The invention belongs to dispersion liquid dye ink field, particularly the ink-jet printed use dispersion liquid of a kind of Polyester Textiles dye ink.
Background technology
Dispersed dye are mainly used in the dyeing (stamp) of terylene and textiles thereof, and can be used for the dyeing (stamp) of cellulose acetate and nylon fibre textiles, also can be used for transfer printing.Dispersed dye chromatogram various in style is complete at present, and excellent property, be widely used, and becomes a class with fastest developing speed in all kinds of dyestuffs.
Along with the fast development of electronic computer technology in the textile field application.In recent years, people are applied to printing in textiles by the paper inkjet technology, clothes etc.It is ink-jet printed that to have flow process short, small batch, and the advantage such as deliver goods fast, therefore, cause dyeing personage's extensive concern.Particularly, along with the decline of continuous renewal, improvement and the dyestuff price of ink-jet printing equipment, ink-jet printed technology also will be widely used.
The tinting material used in ink-jet printing ink, mainly contain two kinds of dyestuff and pigment.What type of dye ink was mainly used now is activity, acidity and substantive dyestuff, is mainly used in plain paper and prints.Pigment ink is mainly used in outdoor advertising spray-painting.Dispersed dye also extensively do not adopt in this respect, and major cause is that dispersed dye are insoluble in water, and to selecting of dispersion agent, condition is quite harsh.But the foreign matter content of existing dispersion agent is higher, and dispersion agent also must refine, and in addition, ink is processing difficulties in the course of processing in addition, easy plug, cost is high, and storage stability is poor.Can't meet our demand.
Summary of the invention
Technical problem to be solved by this invention is to provide the ink-jet printed use dispersion liquid of a kind of Polyester Textiles dye ink, when this invention prepares ink without auxiliary agents such as other dispersion agents, tensio-active agents, it is very simple that preparation is divided into loose dye solvent composition, is ionic liquid in principle; This inventive method is simple, easy to operate, do not exist in steps such as grinding machine for grinding and sodium filters, so green non-pollution, to staff and environmental friendliness.
The ink-jet printed use dispersion liquid of a kind of Polyester Textiles of the present invention dye ink, composed of the following components by mass percentage: dispersed dye: 0.5%～15%; Ionic liquid: 0.05%～5%; Surface tension modifier: 0.1%～3%; Viscosity modifier: 0.1%～3%; PH adjusting agent: 0.2%～2%; Deionized water is surplus.
Described dispersed dye are one or more in C.I. Disperse Red 92, C.I. Red 167, C.I. Red-1 200 77, C.I. Red-1 200 79, C.I. Disperse Blue-79, C.I. EX-SF DISPERSE BLUE EX-SF 300 359, C.I. EX-SF DISPERSE BLUE EX-SF 300 284, C.I. Disperse Blue-60, C.I. DISPERSE YELLOW 54, C.I. DISPERSE ORANGE 30 200 30, C.I. disperse red 73, C.I. Disperse Red 76, and the median size of dispersed dye is 50～300nm.
Described ionic liquid is a kind of in imidazoles, pyridines, benzimidazoles ionic liquid.
Described ionic liquid is a kind of in 1-butyl-3-Methylimidazole villaumite ionic liquid, 1-ethylpyridine hydrochloride ionic liquid, benzoglyoxaline tetrafluoroborate ion liquid, 1-butyl-3-Methylimidazole bromine salt.
The affixture that described surface tension modifier is oxyethane and ethylene glycol.
Described viscosity modifier is one or more in pentanediol, triethylene glycol, TEG.
Described pH adjusting agent is one or more in sodium hydroxide, potassium hydroxide, ammonium hydroxide, trolamine.
The present invention in preparation process all the time round the obstruction and the stable storing two large problems that solve the dispersed dye ink.
The green organic solvent that the present invention is selected---ionic liquid can pass through the physical and chemical performance of the yin, yang ion of self, dispersed dye are dissolved, and stability is better.Utilizing the present invention, while preparing ink, without auxiliary agents such as other dispersion agents, tensio-active agents, prepare the ink solvent composition very simple, is ionic liquid in principle.So the simply dissolving dispersed dye, do not produce auxiliary agent and pollute.Therefore, by utilizing a kind of green organic solvent--the original advantage of ionic liquid self, can also dissolve dispersed dye by the interaction between differing molecular, thereby obtain not plug, storage stability ink-jet printing ink preferably.The inventive method technique is simple, easy to operate, does not exist and is ground in shredder and the step such as sodium filter.
Specifically, the present invention's design provides preparation method's technology of the ink-jet printed use dispersed dye of a kind of Polyester Textiles ink.Applying above-mentioned ionic liquid is that solvent is dissolved dispersed dye, and transparent, the uniform solution of dissolving rear formation added to surface tension modifier, pH adjusting agent and deionized water, forms water miscible, stability ink-jet printing ink preferably.
Production technique of the present invention is simple, in the course of processing environmentally safe, meet environment protection requirement; Prepare in the ink process and adopt ionic liquid as dissolution with solvents dispersed dye technology, effectively prevent that the cluster of dispersed dye from assembling, make the dispersed dye ink of preparation there is dispersion stabilization and stability in storage preferably.
The present invention, when preparing ink, only contains required dispersed dye, surface tension modifier, pH adjusting agent, deionized water and ionic liquid in ink.
beneficial effect
(1) when the present invention prepares ink, without auxiliary agents such as other dispersion agents, tensio-active agents, it is very simple that preparation is divided into loose dye solvent composition, is ionic liquid in principle;
(2) the inventive method is simple, easy to operate, do not exist in steps such as grinding machine for grinding and sodium filters, so green non-pollution, to staff and environmental friendliness;
(3) the present invention, by utilizing the original advantage of a kind of green organic solvent-ionic liquid self, can also be dissolved dispersed dye by the interaction between differing molecular, thereby obtains not plug, storage stability ink-jet printing ink preferably.
Embodiment
Below in conjunction with specific embodiment, further set forth the present invention.Should be understood that these embodiment only are not used in and limit the scope of the invention for the present invention is described.Should be understood that in addition those skilled in the art can make various changes or modifications the present invention after the content of having read the present invention's instruction, these equivalent form of values fall within the application's appended claims limited range equally.
Embodiment 1
The ink-jet printed use dispersed dye of a kind of Polyester Textiles ink, it is composed of the following components by mass percentage: dispersed dye C.I. Red-1 200 4.5%; 1-butyl-3-Methylimidazole villaumite ionic liquid 0.5%; The affixture 1% of surface tension modifier oxyethane and ethylene glycol; Viscosity modifier pentanediol 1%; Sodium hydroxide pH adjusting agent 0.2%; All the other are deionized water.Said components is mixed in proportion by mechanical stirring even, after forming transparent uniform solution, can make ink-jet printed use dispersed dye ink, under room temperature, place 7 days still as clear as crystal.
Embodiment 2
The ink-jet printed use dispersed dye of a kind of Polyester Textiles ink, it is composed of the following components by mass percentage: dispersed dye C.I. EX-SF DISPERSE BLUE EX-SF 300 12.2%; 1-ethylpyridine hydrochloride ionic liquid 0.1%; The affixture 1% of surface tension modifier oxyethane and ethylene glycol; Viscosity modifier triethylene glycol 1%; Sodium hydroxide pH adjusting agent 0.2%; All the other are deionized water.Said components is mixed in proportion by mechanical stirring even, after forming transparent uniform solution, can make ink-jet printed use dispersed dye ink, under room temperature, place 4 days still as clear as crystal, there is no flocculence object or Precipitation.
Embodiment 3
The ink-jet printed use dispersed dye of a kind of Polyester Textiles ink, it is composed of the following components by mass percentage: dispersed dye C.I. DISPERSE YELLOW 9.3%; Benzoglyoxaline tetrafluoroborate ion liquid 0.15%; The affixture 1% of surface tension modifier oxyethane and ethylene glycol; Viscosity modifier TEG 1%; Sodium hydroxide pH adjusting agent 0.2%; All the other are deionized water.Said components is mixed in proportion by mechanical stirring even, after forming transparent uniform solution, can make ink-jet printed use dispersed dye ink, under room temperature, place and higher transparency was still arranged in 3 days, there is no the appearance of flocculence object or deposited phenomenon.
Embodiment 4
The ink-jet printed use dispersed dye of a kind of Polyester Textiles ink, it is composed of the following components by mass percentage: dispersed dye C.I. DISPERSE ORANGE 30 200 6.8%; 1-butyl-3-Methylimidazole bromine salt ion liquid 5%; The affixture 3% of surface tension modifier oxyethane and ethylene glycol; Viscosity modifier triethylene glycol 3%; Sodium hydroxide pH adjusting agent 2%; All the other are deionized water.Said components is mixed in proportion by mechanical stirring even, after forming transparent uniform solution, can make ink-jet printed use dispersed dye ink, under room temperature, place and higher transparency was still arranged in 7 days, there is no the appearance of flocculence object or deposited phenomenon.
Claims (7)
1. the ink-jet printed use dispersion liquid of a Polyester Textiles dye ink, is characterized in that: composed of the following components by mass percentage: dispersed dye: 0.5%～15%; Ionic liquid: 0.05%～5%; Surface tension modifier: 0.1%～3%; Viscosity modifier: 0.1%～3%; PH adjusting agent: 0.2%～2%; Deionized water is surplus.
2. the ink-jet printed use dispersion liquid of a kind of Polyester Textiles according to claim 1 dye ink, it is characterized in that: described dispersed dye are one or more in C.I. Disperse Red 92, C.I. Red 167, C.I. Red-1 200 77, C.I. Red-1 200 79, C.I. Disperse Blue-79, C.I. EX-SF DISPERSE BLUE EX-SF 300 359, C.I. EX-SF DISPERSE BLUE EX-SF 300 284, C.I. Disperse Blue-60, C.I. DISPERSE YELLOW 54, C.I. DISPERSE ORANGE 30 200 30, C.I. disperse red 73, C.I. Disperse Red 76, and the median size of dispersed dye is 50～300nm.
3.. the ink-jet printed use dispersion liquid of a kind of Polyester Textiles according to claim 1 dye ink is characterized in that: described ionic liquid is a kind of in imidazoles, pyridines, benzimidazoles ionic liquid.
4. according to the ink-jet printed use dispersion liquid of the described a kind of Polyester Textiles of claim 1 or 3 dye ink, it is characterized in that: described ionic liquid is a kind of in 1-butyl-3-Methylimidazole villaumite ionic liquid, 1-ethylpyridine hydrochloride ionic liquid, benzoglyoxaline tetrafluoroborate ion liquid, 1-butyl-3-Methylimidazole bromine salt.
5. the ink-jet printed use dispersion liquid of a kind of Polyester Textiles according to claim 1 dye ink, is characterized in that: the affixture that described surface tension modifier is oxyethane and ethylene glycol.
6. the ink-jet printed use dispersion liquid of a kind of Polyester Textiles according to claim 1 dye ink, it is characterized in that: described viscosity modifier is one or more in pentanediol, triethylene glycol, TEG.
7. the ink-jet printed use dispersion liquid of a kind of Polyester Textiles according to claim 1 dye ink, it is characterized in that: described pH adjusting agent is one or more in sodium hydroxide, potassium hydroxide, ammonium hydroxide, trolamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2013103240981A CN103436073A (en) | 2013-07-30 | 2013-07-30 | Water-based dispersion liquid dye ink for ink jetting and printing of polyester textile |
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| CN2013103240981A CN103436073A (en) | 2013-07-30 | 2013-07-30 | Water-based dispersion liquid dye ink for ink jetting and printing of polyester textile |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694795A (en) * | 2013-12-30 | 2014-04-02 | 珠海保税区天然宝杰数码科技材料有限公司 | Disperse dye ink-jet ink and preparation method thereof |
| CN106189360A (en) * | 2016-08-04 | 2016-12-07 | 菲诺染料化工(无锡)有限公司 | Environment-friendly type dispersed ruby blending ingredients and disperse dyes |
| JP2016216699A (en) * | 2015-05-15 | 2016-12-22 | セイコーエプソン株式会社 | Inkjet ink composition |
| US10100214B2 (en) | 2015-05-15 | 2018-10-16 | Seiko Epson Corporation | Ink composition for ink jet |
| CN109199884A (en) * | 2018-10-12 | 2019-01-15 | 辽宁石化职业技术学院 | A kind of ion liquid type coloring agent |
| CN111434850A (en) * | 2019-01-15 | 2020-07-21 | 上海安诺其数码科技有限公司 | Preparation method of disperse dye inkjet ink for digital printing |
| CN113289304A (en) * | 2021-06-17 | 2021-08-24 | 深圳联众安消防科技有限公司 | Smoke-inhibiting perfluorohexanone fire extinguishing agent and preparation method thereof |
| CN115387137A (en) * | 2022-10-09 | 2022-11-25 | 内蒙古工业大学 | Modified chlorophyll dye transfer printing method for polyester fabric |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US6048388A (en) * | 1998-06-29 | 2000-04-11 | Schwarz; William M. | Ink compositions containing ionic liquid solvents |
| CN102127333A (en) * | 2011-01-12 | 2011-07-20 | 郑州鸿盛数码科技股份有限公司 | Direct ink-jet printing disperse dye ink and use method thereof |
| CN102776790A (en) * | 2012-07-10 | 2012-11-14 | 东华大学 | Waterless dyeing method of dispersed dye |
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2013
- 2013-07-30 CN CN2013103240981A patent/CN103436073A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6048388A (en) * | 1998-06-29 | 2000-04-11 | Schwarz; William M. | Ink compositions containing ionic liquid solvents |
| CN102127333A (en) * | 2011-01-12 | 2011-07-20 | 郑州鸿盛数码科技股份有限公司 | Direct ink-jet printing disperse dye ink and use method thereof |
| CN102776790A (en) * | 2012-07-10 | 2012-11-14 | 东华大学 | Waterless dyeing method of dispersed dye |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694795A (en) * | 2013-12-30 | 2014-04-02 | 珠海保税区天然宝杰数码科技材料有限公司 | Disperse dye ink-jet ink and preparation method thereof |
| JP2016216699A (en) * | 2015-05-15 | 2016-12-22 | セイコーエプソン株式会社 | Inkjet ink composition |
| US10100214B2 (en) | 2015-05-15 | 2018-10-16 | Seiko Epson Corporation | Ink composition for ink jet |
| CN106189360A (en) * | 2016-08-04 | 2016-12-07 | 菲诺染料化工(无锡)有限公司 | Environment-friendly type dispersed ruby blending ingredients and disperse dyes |
| CN109199884A (en) * | 2018-10-12 | 2019-01-15 | 辽宁石化职业技术学院 | A kind of ion liquid type coloring agent |
| CN111434850A (en) * | 2019-01-15 | 2020-07-21 | 上海安诺其数码科技有限公司 | Preparation method of disperse dye inkjet ink for digital printing |
| CN113289304A (en) * | 2021-06-17 | 2021-08-24 | 深圳联众安消防科技有限公司 | Smoke-inhibiting perfluorohexanone fire extinguishing agent and preparation method thereof |
| CN115387137A (en) * | 2022-10-09 | 2022-11-25 | 内蒙古工业大学 | Modified chlorophyll dye transfer printing method for polyester fabric |
| CN115387137B (en) * | 2022-10-09 | 2023-10-13 | 内蒙古工业大学 | Modified chlorophyll dye transfer printing method for polyester fabric |
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Application publication date: 20131211 |