CN105860671B - High abrasion code-spraying printing ink and preparation method thereof - Google Patents
High abrasion code-spraying printing ink and preparation method thereof Download PDFInfo
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- CN105860671B CN105860671B CN201610420413.4A CN201610420413A CN105860671B CN 105860671 B CN105860671 B CN 105860671B CN 201610420413 A CN201610420413 A CN 201610420413A CN 105860671 B CN105860671 B CN 105860671B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet (AREA)
Abstract
The invention discloses a kind of high abrasion code-spraying printing ink and preparation method thereof, the high abrasion code-spraying printing ink is prepared by the raw material of following weight parts：10 20 parts of aldehyde ketone resin, 15 parts of chlorinated polyether resin, 65 75 parts of 1 propyl alcohol, 10 20 parts of ethylene glycol, 0.3 0.7 parts of fluorescent colorant, 37 parts of dyestuff, 0.5 1.5 parts of antistatic agent, 0.1 1 parts of ultra-violet absorber.The code-spraying printing ink of the present invention, preparation method is simple, cost is relatively low, it is easy to use, while the performance and function for maintaining common ink, it is also equipped with certain anti-channel conflict, anti-tamper, anti-counterfeiting hiding, code-spraying printing ink provided by the present invention also has the performances such as good wear-resistant, antistatic, uvioresistant.
Description
Technical field
The present invention relates to chemical ink fields, and in particular to a kind of high abrasion code-spraying printing ink and preparation method thereof.
Background technology
For the product under high-speed production lines, when carrying out quality tracing, the printing of coding information will be carried out, in product
Then upper formation product identification carries out camera shooting acquisition for these product identifications, and by the data entry system of collection.It is existing
Code-spraying printing ink, which is all the information naked eyes that black ink spray printing comes out based on black ink, clearly to be recognized, but it is various not
With on the ground of color, especially for reflected light wavelength on the ground of the same or similar color of black, spray printing information is difficult to 100%
Ground carries out camera shooting reading, this just greatly limits the using effect of quality tracing system.
Solvent-based ink can form quick-drying film since the evaporation rate of solvent is fast in any material, fit
In the requirement of high speed continuous production.But the fluorescent material that previous solvent type fluorescent ink uses under visible light can not
See, it is difficult to take into account color discrimination performance and light excitation can photism；In addition the fluorescent ink of water-based system also can be only applied on demand
The piezoelectricity spray printing system of spray printing, is unsuitable for the piezoelectricity sprayed printed system of continuous spray printing, general to spray since the evaporation rate of water is slow
The material of print is all the material (paper products and fabric) of permeability, impermeability material (metal, plastics, covering material, on
The paper etc. of gloss oil) on spray printing information be not easy drying, and water-based system ink surface tension is big, influence it is dry after film
The performances such as adhesive force.
It is endangered caused by electrostatic to reduce, currently, people, which are typically employed in ink, adds color stuffing to inhibit quiet
The generation of charge and the leakage for promoting electrostatic charge enhance film to reduce the sheet resistance of filmogen to a certain extent
Antistatic property, still, due to class coating material self structure and color stuffing is usually small molecule, and this method is produced
Raw antistatic effect is not very ideal, and how to develop that a kind of antistatic effect is good and antistatic lasting antistatic addition
Agent, and for being all ink area worker problem encountered in ink.
Invention content
The first technical problem to be solved by the present invention be to provide it is a kind of be unlikely to deteriorate, concentration is high, the spray of the high abrasion of environmental protection
Code pad-ink.
The second technical problem to be solved by the present invention is to provide a kind of method preparing the high abrasion code-spraying printing ink.
Purpose of the present invention is to what is be achieved through the following technical solutions：
The present invention provides a kind of high abrasion code-spraying printing inks, are prepared by the raw material of following weight parts：Aldehyde ketone tree
10-20 parts of fat, 1-5 parts of chlorinated polyether resin, 65-75 parts of 1- propyl alcohol, 10-20 parts of ethylene glycol, 0.3-0.7 parts of fluorescent colorant, dyestuff
3-7 parts, 0.5-1.5 parts of antistatic agent, 0.1-1 parts of ultra-violet absorber.
Preferably, the fluorescent colorant is benzothiazole derivant, pyran derivate, thiophene derivant, hexichol first
One or more mixtures in ketone disulfonic acid derivatives, heterocycle phenolic compound and coumarin derivative.
Preferably, the dyestuff be premetallized dye, anthraquinone dye, azo dyes, one kind in heterocyclic dye or
A variety of mixtures.
Preferably, the antistatic agent is three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride, double ten alkyl
One or more mixtures in alkyl dimethyl ammonium chloride.
It is highly preferred that the antistatic agent is by three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride, double ten alkane
Base alkyl dimethyl ammonium chloride mixes, described three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride, double ten alkyl-dimethyls
The mass ratio of ammonium chloride is (1-3)：(1-3)：(1-3).
Preferably, the ultra-violet absorber is 2- (4,6- diphenyl -1,3,5-triazines -2- bases) -5- hexyls oxygroup -
Phenol, 2- (2H- benzotriazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2- hydroxyl -4- methoxyl group hexichol first
One or more mixtures in ketone -5- sulfonic acid.
Preferably, the ultra-violet absorber is by 2- (4,6- diphenyl -1,3,5-triazines -2- bases) -5- hexyls oxygroup -
Phenol, 2- (2H- benzotriazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2- hydroxyl -4- methoxyl group hexichol first
Ketone -5- sulfonic acid mixes, 2- (4,6- diphenyl -1,3,5-triazines -2- the bases) -5- hexyls oxygroup-phenol, 2- (2H- benzene
And triazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid matter
Amount is than being (1-3)：(1-3)：(1-3).
Preferably, the hydroxyl value of the aldehyde ketone resin is 250-300 milligrams KOH/ grams.
Preferably, the chlorinty of the chlorinated polyether resin is 40-50wt%.
The present invention also provides the preparation methods of the high abrasion code-spraying printing ink, include the following steps：According to the ratio will
Aldehyde ketone resin, chlorinated polyether resin, 1- propyl alcohol, ethylene glycol, fluorescent colorant, dyestuff, antistatic agent, ultra-violet absorber are uniformly mixed
To obtain the final product.
The code-spraying printing ink of the present invention, preparation method is simple, and cost is relatively low, easy to use, is maintaining common ink
Performance and function while, be also equipped with certain anti-channel conflict, anti-tamper, anti-counterfeiting hiding, spray provided by the present invention
Code pad-ink also has the performances such as good wear-resistant, antistatic, uvioresistant.
Specific implementation mode
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, not limits the present invention, any person skilled in the art is possibly also with the disclosure above
Technology contents be changed to the equivalent embodiment changed on an equal basis.Without departing from the concept of the present invention, according to the present invention
Technical spirit any simple modification that following embodiment is made or equivalent variations, all fall in protection scope of the present invention.
Each raw material introduction of embodiment：
Fluorescent colorant is heterocycle phenolic compound, the specific pigment provided using De Li Science and Technology Ltd.s of Peking University
The fluorescence long wave that code is DELI-3 is yellow.
Dyestuff is azo pigments, the specific light-resistant scarlet BBN that the offer of mountain flower pigment chemical industry Co., Ltd is reflected using Hangzhou.
Aldehyde ketone resin, using the aldehyde ketone resin for the model UK300 that Hindustan companies of India provide, hydroxyl value 270-
280 milligrams KOH/ grams.
Chlorinated polyether resin, using the chlorinated polyether resin for the model MP45 that BASF Corp. of Germany provides, chlorinty 44wt%.
1- propyl alcohol, No. CAS：71-23-8.
Ethylene glycol, No. CAS：107-21-1.
Three (2- amino-ethyls) amine, No. CAS：4097-89-6.
Octadecyltrimethylammonium chloride, No. CAS：112-03-8.
Didecyl Dimethy ammonium chloride, No. CAS：7173-51-5.
2- (4,6- diphenyl -1,3,5-triazines -2- bases) -5- hexyls oxygroup-phenol, No. CAS：147315-50-2.
2- (2H- benzotriazole -2- bases) -4,6- bis- (1- methyl-1s-phenylethyl) phenol, No. CAS：70321-86-7.
2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid, No. CAS：4065-45-6.
Embodiment 1
High abrasion code-spraying printing ink raw material (parts by weight)：16 parts of aldehyde ketone resin, 3 parts of chlorinated polyether resin, 70 parts of 1- propyl alcohol, second
14 parts of glycol, 0.4 part of fluorescence long wave Huang DELI-3,4 parts of light-resistant scarlet BBN, 0.9 part of antistatic agent, ultra-violet absorber 0.6
Part.
The antistatic agent is by three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride, didecyl Dimethy
Ammonium chloride is 1 in mass ratio：1：1 is uniformly mixed to obtain.
The ultra-violet absorber is by 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls oxygroup-phenol, 2-
(2H- benzotriazole-2- bases)-4,6- two (1- methyl-1s-phenylethyl) phenol, ESCALOL 567-5- sulphurs
Acid is 1 in mass ratio：1：1 is uniformly mixed to obtain.
The preparation of high abrasion code-spraying printing ink：1- propyl alcohol, ethylene glycol are uniformly mixed, mixed solvent is obtained；It will
Aldehyde ketone resin be added mixed solvent be stirred 40 minutes with 700 revs/min of rotating speed, by chlorinated polyether resin be added mixed solvent with
700 revs/min of rotating speed is stirred 10 minutes, and fluorescence long wave Huang DELI-3 is then added and is carried out with 700 revs/min of rotating speed
Stirring 5 minutes, is added light-resistant scarlet BBN and is stirred 5 minutes with 700 revs/min of rotating speed, add antistatic agent, purple
Ultraviolet absorbers are stirred 10 minutes with 700 revs/min of rotating speed.Obtain the high abrasion code-spraying printing ink of embodiment 1.
Embodiment 2
It is substantially the same manner as Example 1, it differs only in：The antistatic agent by octadecyltrimethylammonium chloride,
Didecyl Dimethy ammonium chloride is 1 in mass ratio：1 is uniformly mixed to obtain.Obtain the high abrasion coding printing of embodiment 2
Ink.
Embodiment 3
It is substantially the same manner as Example 1, it differs only in：The antistatic agent is by three (2- amino-ethyls) amine, double ten
Alkyl dimethyl ammonium chloride is 1 in mass ratio：1 is uniformly mixed to obtain.Obtain the high abrasion coding type oil of embodiment 3
Ink.
Embodiment 4
It is substantially the same manner as Example 1, it differs only in：The antistatic agent is by three (2- amino-ethyls) amine, 18
Alkyl trimethyl ammonium chloride is 1 in mass ratio：1 is uniformly mixed to obtain.Obtain the high abrasion coding type oil of embodiment 4
Ink.
Embodiment 5
It is substantially the same manner as Example 1, it differs only in：The ultra-violet absorber is by 2- (2H- benzotriazole -2-
Base) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid in mass ratio be 1：1
It is uniformly mixed to obtain.Obtain the high abrasion code-spraying printing ink of embodiment 5.
Embodiment 6
It is substantially the same manner as Example 1, it differs only in：The ultra-violet absorber by 2- (diphenyl -1,3 4,6-,
5- triazine -2- bases) -5- hexyls oxygroup-phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid in mass ratio be 1：1 stirring
It is uniformly mixed and obtains.Obtain the high abrasion code-spraying printing ink of embodiment 6.
Embodiment 7
It is substantially the same manner as Example 1, it differs only in：The ultra-violet absorber by 2- (diphenyl -1,3 4,6-,
5- triazine -2- bases) -5- hexyls oxygroup-phenol, 2- (2H- benzotriazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) benzene
Phenol is 1 in mass ratio：1 is uniformly mixed to obtain.Obtain the high abrasion code-spraying printing ink of embodiment 7.
Test case 1
High abrasion code-spraying printing ink prepared by embodiment 1-7, is respectively coated on the glass plate of 10 × 10cm, coating
Thickness is 12 μm, and cured film can be obtained after the high-pressure sodium lamp, distance 15cm irradiation 15s of 1000W；It then again will be above-mentioned solid
Coating after change is respectively cut into two pieces of coated films of 3cm × 3cm, one piece for detecting coating surface resistance at once, another piece
The sheet resistance of coating is detected after placing 3 months again, with evaluate the above-mentioned antistatic agent containing polymerization activity ink it is anti-quiet
The persistence of electrical property and antistatic property, the ZC36 types super-high that the sheet resistance of film is produced with No.6 Electric Meter Factory are electric
Instrument is hindered to measure.Concrete outcome is shown in Table 1.
Table 1：Antistatic property test result list position：Ω
| Sheet resistance at once | March rear surface resistance | |
| Embodiment 1 | 2.4×108 | 4.9×108 |
| Embodiment 2 | 5.4×108 | 1.6×109 |
| Embodiment 3 | 5.9×108 | 2.2×109 |
| Embodiment 4 | 5.7×108 | 1.8×109 |
| Embodiment 5 | 3.8×108 | 8.4×108 |
| Embodiment 6 | 4.5×108 | 9.9×108 |
| Embodiment 7 | 4.2×108 | 9.1×108 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride,
Didecyl Dimethy ammonium chloride compounds) antistatic property and antistatic property persistence be substantially better than embodiment 2-4 (three (2-
Amino-ethyl) amine, octadecyltrimethylammonium chloride, both arbitrary compounding in didecyl Dimethy ammonium chloride)；Compare implementation
Example 1 and embodiment 5-7, embodiment 1 (2- (4,6- diphenyl -1,3,5-triazines -2- bases) -5- hexyls oxygroup-phenol, 2- (2H-
Benzotriazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid be multiple
With) antistatic property and antistatic property persistence be substantially better than embodiment 5-7 (2- (4,6- diphenyl -1,3,5- triazines -2-
Base) -5- hexyls oxygroup-phenol, 2- (2H- benzotriazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2- hydroxyls
Both arbitrary compounding in base -4- methoxy benzophenone -5- sulfonic acid).
Test case 2
It to high abrasion code-spraying printing ink made from embodiment 1-7, is respectively coated on the glass plate of 10cm × 10cm, applies
Layer thickness is 12 μm, and cured film can be obtained after the high-pressure sodium lamp, distance 15cm irradiation 15s of 1000W；According to GB/T
Test condition in 22771-2008 standards carries out xenon lamp to film and light resistance is accelerated to test, 44 DEG C of babinet air themperature, relatively
Humidity 50%, irradiation level 1.10W/m2, 340nm.Exposure has been obtained using instrument measuring method 20 hours and the color after 40 hours
Change △ E*, using CIEL*a*b* color units, D65 light sources and 10 degree of viewing angles.Concrete outcome is shown in Table 2.
Table 2：Xenon lamp accelerates light resistance test result table
| △E*-20h | △E*-40h | |
| Embodiment 1 | 1.48 | 2.59 |
| Embodiment 2 | 2.49 | 3.42 |
| Embodiment 3 | 2.50 | 3.75 |
| Embodiment 4 | 2.41 | 3.67 |
| Embodiment 5 | 2.82 | 4.31 |
| Embodiment 6 | 2.76 | 4.21 |
| Embodiment 7 | 2.81 | 4.32 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride,
Didecyl Dimethy ammonium chloride compounds) light fastness is substantially better than embodiment 2-4 (three (2- amino-ethyls) amine, octadecyl
Both arbitrary compounding in trimethyl ammonium chloride, didecyl Dimethy ammonium chloride)；Comparing embodiment 1 and embodiment 5-7 is implemented
Example 1 (2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls oxygroup-phenol, 2- (2H- benzotriazole -2- bases) -4,6-
Two (1- methyl-1s-phenylethyl) phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid compounding) light fastness persistence is bright
It is aobvious to be better than embodiment 5-7 (2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls oxygroup-phenol, 2- (2H- benzos three
Azoles -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, arbitrary two in 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid
Person compounds).
Test case 3
Wear-resisting property test is carried out to high abrasion code-spraying printing ink made from embodiment 1-4, wear-resisting property presses GB/
T7706-2008 is tested, at PP ground information spray printings, the weight of 700 grams of load, and round-trip 20 times, criterion：1- information is de-
None- identified is fallen, 2- message parts fall off, and identification is difficult, and 3- information, which has, to be fallen off but can identify, 4- information completelies.Concrete outcome
It is shown in Table 3.
Table 3：Wear-resisting property test result table
| Wear-resisting property | |
| Embodiment 1 | 4 |
| Embodiment 2 | 2 |
| Embodiment 3 | 3 |
| Embodiment 4 | 2 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride,
Didecyl Dimethy ammonium chloride compounds) wear-resisting property is substantially better than embodiment 2-4 (three (2- amino-ethyls) amine, octadecyl
Both arbitrary compounding in trimethyl ammonium chloride, didecyl Dimethy ammonium chloride).
Claims (4)
1. a kind of high abrasion code-spraying printing ink, which is characterized in that be prepared by the raw material of following weight parts：Aldehyde ketone resin
10-20 parts, 1-5 parts of chlorinated polyether resin, 65-75 parts of 1- propyl alcohol, 10-20 parts of ethylene glycol, 0.3-0.7 parts of fluorescent colorant, dyestuff 3-7
Part, 0.5-1.5 parts of antistatic agent, 0.1-1 parts of ultra-violet absorber；
The antistatic agent is by three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride, didecyl Dimethy chlorination
Ammonium mixes, described three (2- amino-ethyls) amine, octadecyltrimethylammonium chloride, didecyl Dimethy ammonium chloride matter
Amount is than being (1-3)：(1-3)：(1-3)；
The ultra-violet absorber is by 2- (4,6- diphenyl -1,3,5- triazine -2- bases) -5- hexyls oxygroup-phenol, 2- (2H-
Benzotriazole -2- bases) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid be mixed
It closes, 2- (4,6- diphenyl -1,3,5-triazines -2- the bases) -5- hexyls oxygroup-phenol, 2- (2H- benzotriazole -2-
Base) -4,6- two (1- methyl-1s-phenylethyl) phenol, 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid mass ratio be (1-
3)：(1-3)：(1-3).
2. high abrasion code-spraying printing ink as described in claim 1, it is characterised in that：The fluorescent colorant is benzo thiophene
Zole derivatives, pyran derivate, thiophene derivant, benzophenone disulfonic acid derivatives, heterocycle phenolic compound and cumarin spread out
One or more mixtures in biology.
3. high abrasion code-spraying printing ink as described in claim 1, it is characterised in that：The dyestuff contaminates for metal complex
One or more mixtures in material, anthraquinone dye, azo dyes, heterocyclic dye.
4. the preparation method of high abrasion code-spraying printing ink as described in any one of claim 1-3, it is characterised in that：According to the ratio
Aldehyde ketone resin, chlorinated polyether resin, 1- propyl alcohol, ethylene glycol, fluorescent colorant, dyestuff, antistatic agent, ultra-violet absorber are mixed equal
It is even to obtain the final product.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732087A (en) * | 2011-04-14 | 2012-10-17 | 北京赛腾工业标识系统有限公司 | Anti-channel conflict code-spurting printing ink and its preparation method |
| CN105400291A (en) * | 2015-12-28 | 2016-03-16 | 北京赛腾标识系统股份公司 | Wear and sticking resistant code spraying and printing ink, and preparation method and application thereof |
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2016
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732087A (en) * | 2011-04-14 | 2012-10-17 | 北京赛腾工业标识系统有限公司 | Anti-channel conflict code-spurting printing ink and its preparation method |
| CN105400291A (en) * | 2015-12-28 | 2016-03-16 | 北京赛腾标识系统股份公司 | Wear and sticking resistant code spraying and printing ink, and preparation method and application thereof |
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