CN106042520A - Decorative colorful patterned metal floor and manufacturing method thereof - Google Patents

Decorative colorful patterned metal floor and manufacturing method thereof Download PDF

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Publication number
CN106042520A
CN106042520A CN201610579629.5A CN201610579629A CN106042520A CN 106042520 A CN106042520 A CN 106042520A CN 201610579629 A CN201610579629 A CN 201610579629A CN 106042520 A CN106042520 A CN 106042520A
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layer
metal
decoration
floor
sensitive adhesive
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CN201610579629.5A
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CN106042520B (en
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王麒钧
王麒宁
王海人
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284—Application of adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/14—Printing or colouring
    • B32B38/145—Printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/16—Drying; Softening; Cleaning
    • B32B38/162—Cleaning
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/10—Interconnection of layers at least one layer having inter-reactive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/06—Flooring or floor layers composed of a number of similar elements of metal, whether or not in combination with other material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/554—Wear resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/726—Permeability to liquids, absorption
    • B32B2307/7265—Non-permeable

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Floor Finish (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a decorative colorful patterned metal floor and a manufacturing method thereof. The decorative colorful patterned metal floor is a decorative colorful patterned metal floor sticker product and comprises a protective film, an abrasion-resistant layer, a printing decoration layer, a metal substrate layer, a pressure-sensitive adhesive layer and organic silicon protection paper. The protective film is a PVC (polyvinyl chloride) protection film, the lower surface of the metal substrate layer is adhered to the pressure-sensitive adhesive layer, and the organic silicon protection paper is arranged on the lower surface of the pressure-sensitive adhesive layer. The abrasion-resistant layer is an Al2O3 (or SiO2) abrasion-resistant protection coating formed on the printing decoration layer by painting and thermal curing or an Al2O3 impregnated abrasion-resistant paper protection layer formed on the printing decoration layer by high-temperature pressurized fusion. The total thickness of the floor is only 100-200micron after mounting. The decorative colorful patterned metal floor has advantages of abrasion resistance, corrosion resistance, damp proofing, moth proofing, moisture resistance, freeness of deformation and mildewing, excellent antibacterial performance, simplicity and convenience in construction, fire proofing, nontoxicity, low cost and the like.

Description

A kind of chromatic pattern metal floor for decoration and manufacture method
Technical field
The present invention relates to a kind of chromatic pattern metal floor for decoration and manufacture method, belong to decorating and renovating material technology Field.
Background technology
20 end of the centurys so far, along with the fast development of real estate industry of China, various floor China with fast development it Gesture obtains spread, and indoor floor is conducive to sound-insulating and heat-insulating, improves finishing class and office comfort level of living.City at present Mainly there are wood floors and a plastic floor in floor popular on face, wherein wood floors possess class height, environmental protection, wear-resisting, anticorrosion, Maintenance mothproof, easy such as arranges at the advantage, and weak point is: permanent uses that moisture effect is poor, yielding after immersion go bad, flameproof effect Difference, price is relatively expensive；Plastic floor advantage be wear-resisting, easy to clean, water proofing property are good, maintenance is easy, construction is easy and quick, valency Lattice are cheap, and it is convenient to change after abrasion, and its weak point is: resistance to elevated temperatures is poor, and fire protecting performance is poor, have severe toxicity volatilization after catching fire Thing, is chronically in wet environment change of also impaired concurrently mildewing, and anti-microbial property is poor.
Utility model patent " a kind of Sound insulation floorings " (CN201520540310) is to include floor base sheet material layers and compound its Its multilayer material, for the purpose of sound insulation, the metal film layer Main Function that floor base sheet material layers is provided above is isolation sound, and gold Belonging to and be additionally provided with sound absorbing layer and architectural surface on face, described sound absorbing layer is the cruel soft foaming layer of poly-ammonia ", therefore this floor belongs to shelves Secondary higher plastic floor kind；Utility model patent " environment-friendly type abrasive floor patch " (CN201520711570) includes being attached at The metal pad pasting layer being provided with rollet of floor surface, is provided with fluorescent material and silica gel filler, pad pasting in described rollet The bottom surface of layer is provided with adhesive layer.From its structure, it is positioned at the metallic diaphragm on top layer directly and extraneous contact, though groove is prevented Sliding, but because metal film layer surface is not provided with any wear-resistant material layer, therefore this metallic diaphragm is easy to wear, on the other hand metal film Though layer surface is machined with rollet, but when there is accumulated water on surface, or air pressure and the change of indoor and outdoor temperature difference cause air pair During stream, water membrane can be adhered in these rollet surfaces, therefore prevents that wet and slippery effect is very limited, even can mislead user and put Pine is vigilant；Floor film disclosed in utility model patent " multifunctional floor film " (CN201520295928), functional layer includes: Nano silver copper zinc alloy layer, magnetic plastic layer, PVC foam material substrate.Weak point is: nano silver copper zinc alloy layer for Its antibacterial directly contacted has certain killing effect, but to covering the antibacterial on the antibacterial corpse died in ground floor surface, just Not having any effect, ground surface is often rubbish and a lot of place of antibacterial, and arranging of this film layer can be along with this metal floor Use, substantially do not have any effect, simply a conception of species；On the other hand, described basic unit is PVC foam material, because of The design on this floor is thicker.
The problems referred to above in view of existing flooring material, it is necessary to design and a kind of there is good quarter wet and slippery, anti-wear-resisting, anti- Draw, anti-soil and fire protecting performance, good decorating effect and extremely cheap, it is possible to substitute current wood ground in some beta sites Plate or a kind of high-grade floor decorative material of plastic floor.
Summary of the invention
The problem that it is an object of the invention to propose for background technology, overcomes the shortcomings such as existing timber floor or plastic floor, Design a kind of chromatic pattern metal floor for decoration, and the method making described chromatic pattern metal floor.
In order to achieve the above object, the present invention uses below scheme:
A kind of chromatic pattern metal floor for decoration, is color metal decorative pattern " floor plaster " goods for decoration, described Metal floor is followed successively by five-layer structure from top to bottom, including: protecting film 1, the wearing layer 2 of setting thickness, the printing of setting thickness Decorative layer 3, metal substrate layer 4, Performance of Pressure Sensitive Adhesive layer 5, organosilicon protection sheet 6；Wherein: protecting film 1 and organosilicon protection sheet 6 are Temporary protective layer, wearing layer 2, printed decoration layer 3, metal substrate layer 4 and Performance of Pressure Sensitive Adhesive layer 5 are basic training ergospheres；Described Protecting film 1 is that PVC protects glued membrane；The lower surface of described metal substrate layer 4 bonds with Performance of Pressure Sensitive Adhesive layer 5；Described pressure-sensitive adhesive The lower surface connecing layer 5 is organosilicon protection sheet 6；It is characterized in that:
Described wearing layer 2 is application heat cure Al on printed decoration layer 32O3, or SiO2Wear-resistant protection coating, or Person is that high-temperature bearing merges the Al on printed decoration layer 32O3Dipping abrasion-proof paper protective layer；
Preferred: when wearing layer 2 uses Al2O3During dipping abrasion-proof paper protective layer, described PVC protection glued membrane is nonessential setting.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: the thickness of described wearing layer 2 is 10～1000 μm.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described printed decoration layer 3 Thickness is 10～1000 μm, and the pattern of printed decoration layer 3 includes but do not limits: Wood-grain-imitating pattern, marble grain pattern, carpet Stricture of vagina pattern, granite pattern；Or print out at metal substrate layer 4 upper surface with foam ink there is anaglyph pattern.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: the material of described metal substrate layer 4 Matter sets and includes but not limited to: rustless steel or aluminium alloy, ashbury metal, copper alloy；The thickness of described metal substrate layer 4 is set as 0.01～1.5mm；The upper surface of metal substrate layer 4 is: minute surface or dull surface, sand face, mill stricture of vagina or hairline face；Described metal base Layer 4 includes: metal forming (plate) or winding.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described Performance of Pressure Sensitive Adhesive layer 5 Thickness is 100～1000 μm.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described basic training ergosphere total Thickness is 100～2000 μm.
A kind of a kind of manufacture method of the chromatic pattern metal floor for decoration, it is characterised in that: by such as Lower step is carried out:
Step one: the hydroxylating of metal base upper surface and microporous
By rustless steel that thickness is 0.01～1.5mm or aluminium alloy or ashbury metal or copper alloy foil (plate) or winding metalloid Base material, goes to degrease, clean up, is then placed on and is respectively as follows: containing chemical composition and concentration
CrO3(5～250g/l) and H2SO4In the chemical oxidation solution of (5～490g/l), or
HNO3(5～250g/l) and H2O2In the chemical oxidation solution of (5～250g/l), or
NaOH(1～100g/l) chemical solution in, or (NH4)2Mo2O7And H2SO4The chemical oxidation of (5～250g/l) is molten In liquid, carry out chemical treatment, form oh group and (or) oxide-film in described metallic substrate surface and corrode micro-in a large number Hole；
Step 2: printed decoration layer
By the way of the continuous offset printing of drum-type, or trans-printing mode, the metal base handled well in step one upper One layer of decorative coating of surface printing, or there is the decorations coating of anaglyph with foam ink printing one layer；Described dress The pattern of decorations figure layer is arbitrarily set by demand；
Step 3: coating surface wearing layer
Being coated with the abrasion-resistant clear coat of a layer strong with basal body binding force on the printed decoration layer that step 2 completes, coating layer thickness sets Being set to 10～1200 μm, the component of described clear coat includes: macromolecular material and inserts, and described macromolecular material is piano Paint or polyurethane or tripolycyanamide or melamine resin；Described inserts is nanometer Al2O3Or Nano-meter SiO_22；The most right Coating is heating and curing, and forms robust surface wear-resistant layer；
Described wear resistant transparent paint or antiwear epoxy resin paint；
Step 4: protection processes
After completing to print wearing layer by step 3, paste the PVC glued membrane of last layer protectiveness in the rolling of wearing layer upper surface；It has Benefit effect is: PVC glued membrane is conducive to protecting in transport or sales process wearing layer upper surface.
Step 5: the metal base back side arranges adhesives
At metal base lower surface application (or stickup) last layer pressure sensitive adhesive；It provides the benefit that: convenient construction, is installing Inventive article: during color metal textured metal floor, can be directly laying this metal chromatic pattern after the wipe clean of ground Metal floor, then rolls with cylinder, and construction is simple and quick.It addition, this pressure sensitive adhesive in use along with Personnel walk about, and adhesive effect can be become better and better, and so can avoid the slip of metal floor.
Step 6: back-protective processes
At the lower surface of the bonding pressure sensitive adhesive of step 5, by rolling mode, one layer of organosilicon protection sheet of pressing.Its beneficial effect It is: convenient construction: as long as this layer of paper is torn and metal floor of the present invention can be bonded in ground surface；This layer is additionally had to protect Protect paper to be also convenient for the sale of described metal floor product, transport and take care of, prevent pressure sensitive adhesive from arbitrarily bonding to elsewhere.
A kind of manufacture method of the chromatic pattern metal floor for decoration, it is characterised in that: described making Method or carry out as follows:
Step one: the hydroxylating of metal base upper surface and microporous
By rustless steel that thickness is 0.01～1.5mm or aluminium alloy or ashbury metal or copper alloy foil (plate) or winding metalloid Base material, goes to degrease, clean up, is then placed on and is respectively as follows: containing chemical composition and concentration
CrO3(5～250g/l) and H2SO4In the chemical oxidation solution of (5～490g/l), or
HNO3(5～250g/l) and H2O2In the chemical oxidation solution of (5～250g/l), or
NaOH(1～100g/l) chemical solution in, or (NH4)2Mo2O7And H2SO4The chemical oxidation of (5～250g/l) is molten In liquid, carry out chemical treatment, form oh group and (or) oxide-film in described metallic substrate surface and corrode micro-in a large number Hole；
Step 2: printed decoration layer
By the way of the continuous offset printing of drum-type, or trans-printing mode, the metal base handled well in step one upper One layer of decorative coating of surface printing, or there is the decorations coating of anaglyph with foam ink printing one layer；Described dress The pattern of decorations figure layer is arbitrarily set by demand；
Step 3: in printed decoration layer surface configuration Al2O3Dipping abrasion-proof paper protective layer
On the printed decoration layer that step 2 completes, by high-temperature bearing amalgamation mode, merge one layer of Al2O3Dipping abrasion-proof paper； It provides the benefit that: strengthen the ostentatious delineation wear-resisting, anti-of colored printing, antifouling property.
Step 4: the metal base back side arranges adhesives
At metal base lower surface application (or stickup) last layer pressure sensitive adhesive；It provides the benefit that: convenient construction, is installing Inventive article: during color metal textured metal floor, can be directly laying this metal chromatic pattern after the wipe clean of ground Metal floor, then rolls with cylinder, and construction is simple and quick.It addition, this pressure sensitive adhesive in use along with Personnel walk about, and adhesive effect can be become better and better, and so can avoid the slip of metal floor.
Step 5: back-protective processes
At the lower surface of the bonding pressure sensitive adhesive of step 5, by rolling mode, one layer of organosilicon protection sheet of pressing.Its beneficial effect It is: convenient construction: as long as this layer of paper is torn and metal floor of the present invention can be bonded in ground surface；This layer is additionally had to protect Protect paper to be also convenient for the sale of described metal floor product, transport and take care of, prevent pressure sensitive adhesive from arbitrarily bonding to elsewhere.
The invention has the beneficial effects as follows:
(1) a kind of chromatic pattern metal floor for decoration of the present invention has: wear-resisting, anticorrosion, protection against the tide, mothproof, be not afraid of humidity, It is not afraid of into water, will not deform, will not go mouldy, the features such as anti-microbial property is good.
(2) construct simple and fast, use the most, the best with ground adhesive effect.
(3) fire prevention, nontoxic, even if running into fire, will not burn, people's life security will not be endangered, there is timber floor and moulding The advantage that adhesive floor is incomparable.
(4) ratio timber floor environmental protection, can be greatly saved the forest reserves, has the social meaning being highly profitable.
(5) low price, this metal chromatic pattern metal floor (such as can be able to be used with the thinnest metal base The 304 rustless steel winding that 0.03mm is thick) make, its cost price can be low to several yuans of every square meter, and this price advantage can So that the color metal textured metal flooring products that the inventive method is provided in megastore, public place of entertainment, beta site, face Time the ground surface such as house decorative applications promoted rapidly.
Accompanying drawing explanation
Fig. 1 is a kind of chromatic pattern metal floor schematic diagram for decoration of the embodiment of the present invention.
Description of symbols in accompanying drawing: 1 protecting film, 2 wearing layers, 3 printed decoration layers, 4 metal substrate layer, 5 pressures Quick glue adhesive linkage, 6 organosilicon protection sheets.
Detailed description of the invention
Below in conjunction with accompanying drawing, embodiments of the present invention is further illustrated, for making the purpose of the present invention, technical scheme and excellent Point is clearer, below technical scheme in the present invention be clearly and completely described, it is clear that described embodiment is this Invent a part of embodiment rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art exist Do not make the every other embodiment obtained under creative work premise, broadly fall into the scope of protection of the invention.
With reference to accompanying drawing 1, a kind of chromatic pattern metal floor for decoration of the present invention includes being sequentially distributed from top to bottom: Protecting film 1, set thickness wearing layer 2, set the printed decoration layer 3 of thickness, metal substrate layer 4, Performance of Pressure Sensitive Adhesive layer 5, have Machine silicon protection sheet 6；Wherein: protecting film 1 and organosilicon protection sheet 6 are protective layers, wearing layer 2, printed decoration layer 3, metal base Layer 4 and Performance of Pressure Sensitive Adhesive layer 5 are basic training ergospheres；Described protecting film 1 is PVC glued membrane；The lower surface of described metal substrate layer 4 with Performance of Pressure Sensitive Adhesive layer 5 bonds；The lower surface of described Performance of Pressure Sensitive Adhesive layer 5 is organosilicon protection sheet 6；Described wearing layer 2 is application And the Al that heat cure is on printed decoration layer 32O3(or SiO2) wear-resistant protection coating, or high-temperature bearing fusion is at printing dress Al on decorations layer 32O3Dipping abrasion-proof paper protective layer.When wearing layer 2 uses Al2O3During dipping abrasion-proof paper protective layer, described PVC protects Protect glued membrane can arrange.
The thickness of described wearing layer 2 is 10～1000 μm, and the thickness of described printed decoration layer 3 is 10～1000 μm, institute The thickness stating metal substrate layer 4 is 0.01～1.5mm, and the thickness of described Performance of Pressure Sensitive Adhesive layer 5 is 100～1000 μm, described base The gross thickness of this functional layer is 100～2000 μm.
The pattern of printed decoration layer 3 includes: Wood-grain-imitating pattern, marble grain pattern, carpet stricture of vagina pattern, granite figure Case；Or other imitates the pattern true to nature of natural material, or any pattern that user likes, it is also possible to be to exist with foam ink Metal substrate layer 4 upper surface prints out has anaglyph pattern.
The material of described metal substrate layer 4 sets and includes but not limited to: rustless steel or aluminium alloy, ashbury metal, copper alloy；Gold The upper surface belonging to substrate layer 4 is: minute surface or dull surface, sand face, mill stricture of vagina or hairline face；The apparent shape of metal substrate layer 4 is gold Belong to paper tinsel (plate) or coiled strip.
The manufacture method of a kind of chromatic pattern metal floor for decoration, by different embodiments, says respectively Bright as follows:
Embodiment one:
Choose 304 thick for 0.1mm rustless steel winding as base material, early stage pretreatment oil removing cleaning, drying.
Step one: substrate surface hydroxylating and microporous
The stainless steel substrate after above-mentioned process is clean, it is placed on and is respectively as follows: CrO containing chemical composition and concentration3(50g/l) And H2SO4(100g/l), in chemical oxidation solution, chemical oxidation 10min in 85 DEG C of environment of temperature, at above-mentioned stainless steel material Surface forms oh group and porous oxide film, in order to be greatly enhanced base material and its upper printing layer and it descends adhesive linkage material Adhesion.
Step 2: printed decoration layer
By the way of the continuous offset printing of drum-type at the unilateral upper surface of have passed through the stainless steel substrate that step one is handled well one (just Face) print one layer of Wood-grain-imitating patterned layer, it is dried by the requirement of ink used.
Step 3: coating surface wear-resistant protection coating
In order to strengthen the ostentatious delineation wear-resisting, anti-of above-mentioned colored printing, antifouling property, first it is coated with on above-mentioned combination with decorative surfaces The abrasion-resistant clear coat that cloth one layer is the strongest with basal body binding force, the thickness of this coating is about 500 μm, the one-tenth subpackage of this clear dope Include: macromolecular material melamine resin and inserts nano-scale alumina.Then, according to coating requirement, carry out heat cure, Form robust surface abrasion resistance protective layer.Method of the making manufacture method of above-mentioned wear resistant transparent paint and coating, solidification side Method is as follows:
(1) the preparation of melamine-formaldehyde resin adhesive, raw material and formula (mol ratio) set:
Tripolycyanamide: formaldehyde: polyvinyl alcohol: methanol=1: 3: 0.05: 6
First methanol and polyvinyl alcohol are added in reactor by setting mol amount, be warming up to 75 DEG C, be incubated the most molten to polyvinyl alcohol Solve, be subsequently adding the formaldehyde measured, adjust pH value to 9.5 with the sodium hydroxide solution that concentration is 30%, add the trimerization measured Cyanamide, reacts to water than number (measurement index of trimerization general amine-formaldehyde resins reaction end, GB/ under 89～91 DEG C of environment Be terminal when being T14732-93) 1:2.5, be cooled to 35 DEG C standby.
(2) divide by above-mentioned solid: tripolycyanamide: Al2O3The ratio of=1: 2, by the way of ultrasonic disperse, by Al2O3All In the even melamine-formaldehyde resin adhesive solution being dispersed in step (1), being wear resistant transparent paint used by the present invention, this coating is A kind of suspension, the only Extemporaneous when application.
(3), by the most ready above-mentioned wear resistant transparent paint, it is placed in a circulation stirring groove, by continuous roll coating model, The printed decoration layer surface of coatings to step 2.It is a circulation stirring groove that this step contains the container of coating, it is therefore an objective to In order to prevent Al2O3Precipitation.
(4) putting in oven by the rustless steel winding of coated wear resistant transparent paint, temperature is to carry out at 138～142 DEG C Dry solidification.
In order to both ensure the Al in above-mentioned wear-resistant paint2O3Granule does not deposits, and divides uniformly again in suspension system Dissipating, do not condense, the clear dope used by the present invention can use the viscosity that commercially available Tai Er (Dynea) chemical company develops Appropriate, special melmac.
Step 4: protection processes
Metal base semi-finished product front surface roll-in after processing through above-mentioned steps one, step 2 and step 3 is pasted one Layer PVC adhesive tape protection glued membrane.
Step 5: substrate backside arranges adhesives
Semi-finished product after metal base be have passed through above-mentioned steps one～step 4 process climb over face, at the other side surface (back of the body Face) one layer of commercially available pressure sensitive adhesive of application.
Step 6: back-protective processes
After above-mentioned metal base have passed through the process of above-mentioned steps one to step 5, it is being provided with the one side of pressure sensitive adhesive, then by rolling The mode of pressure, one layer of organosilicon protection sheet of pressing.
After above-mentioned six steps, color metal textured metal floor of the present invention i.e. completes.
Embodiment two:
Choosing aluminium alloy winding thick for 0.2mm as base material, front its gives process oil removing, cleans and dry.
Step one: substrate surface hydroxylating and microporous
The aluminum alloy base material after above-mentioned process is clean, it is placed on and is respectively as follows: NaOH(30g/l containing chemical composition and concentration) Chemical solution in, chemical attack 1min under temperature 60 C environment, above-mentioned aluminum alloy material surface formed oh group and Porous membrane layer, in order to be greatly enhanced base material and print layer and the adhesion of its lower adhesive linkage material on it.
Step 2: printed decoration layer
In the single side surface that have passed through the above-mentioned aluminum alloy base material after step one processes by the way of the continuous offset printing of drum-type (front) prints one layer of Wood-grain-imitating patterned layer, then is dried by the requirement of ink used.
Step 3: coating surface wear-resistant protection coating
In order to strengthen the ostentatious delineation wear-resisting, anti-of above-mentioned colored printing, antifouling property, first it is coated with on above-mentioned combination with decorative surfaces The abrasion-resistant clear coat that cloth one layer is the strongest with basal body binding force, the thickness of this coating is about 500 μm, and this wear resistant transparent paint is city Selling polyurethane wear resistant coating, the coating of described wear resistant transparent paint, curing are as follows:
(1) upper above-mentioned coating is placed in a circulation stirring groove, by continuous roll coating model, coatings is arrived step 2 Printed decoration layer surface.
The aluminium alloy winding of the most coated wear resistant transparent paint is in oven, according to consolidating of commercial polyurethane wear-resistant paint Change time and temperature requirement are dried solidification.
Step 4: protection processes
Semi-finished product front surface roll-in after metal base be have passed through above-mentioned steps one～step 3 process is pasted last layer PVC and is glued Adhesive tape glued membrane.
Step 5: substrate backside arranges adhesives
Semi-finished product after metal base be have passed through above-mentioned steps one～step 4 process turn over, at other side upper surface One layer of commercially available pressure sensitive adhesive of (back side) application.
Step 6: back-protective processes
After above-mentioned metal base be have passed through above-mentioned steps one～step 5 process, finally it is being provided with the one side of pressure sensitive adhesive, logical Cross the mode of rolling, one layer of organosilicon protection sheet of pressing.
After above-mentioned six steps, color metal textured metal floor of the present invention i.e. completes.
Embodiment three:
Choosing 304 thick for 0.1mm rustless steel winding as base material, early stage processes oil removing, cleans and dry.
Step one: substrate surface hydroxylating and microporous
The aluminum alloy base material after above-mentioned process is clean, it is placed on and is respectively as follows: CrO containing chemical composition and concentration3(50g/l) And H2SO4(100g/l), in chemical oxidation solution, chemical oxidation 10min at temperature 85 DEG C, in above-mentioned surface of stainless steel Form oh group and porous oxide film, in order to be greatly enhanced base material and on it, print layer and the combination of its lower adhesive linkage material Power.
Step 2: printed decoration layer
In the single side surface that have passed through the above-mentioned stainless steel substrate that step (1) is handled well by the way of the continuous offset printing of drum-type (front) prints one layer of Wood-grain-imitating patterned layer, is dried by the requirement of ink used.
Step 3: in printed decoration layer surface configuration Al2O3Wear-resistant protective layer
In order to strengthen the ostentatious delineation wear-resisting, anti-of above-mentioned colored printing, antifouling property, above-mentioned metal base is on have passed through After stating step one and step 2, then commercially available reinforced composite floorboard Al2O3The side that dipping abrasion-proof paper is merged by high-temperature bearing Formula, merges one layer of delineation protective layer wear-resisting, anti-on above-mentioned printed decoration layer.
Al2O3Abrasion-proof paper wearing coat and the hot pressing plasticizing forming method of printed decoration layer: in accordance with Al2O3Dipping abrasion-proof paper The requirement of hot press pressure and temperature is carried out plastifying bonding forming by manufacturer.
Step 4: substrate backside arranges adhesives
Semi-finished product after metal base be have passed through above-mentioned steps one～step 3 process turn over, at the other side surface (back of the body Face) one layer of commercially available pressure sensitive adhesive of application.
Step 5: back-protective processes
After above-mentioned metal base being have passed through the process of above-mentioned steps one～step 4, finally it is being provided with the one side of pressure sensitive adhesive, Again by the way of rolling, one layer of organosilicon protection sheet of pressing.
After above-mentioned five steps, color metal textured metal floor of the present invention i.e. completes.
Embodiment four:
Choose aluminium alloy winding thick for 0.2mm as base material, pre-treatment oil removing, cleaning.
Step one: substrate surface hydroxylating and microporous
The aluminum alloy base material after above-mentioned process is clean, it is placed on and is respectively as follows: NaOH(30g/l containing chemical composition and concentration) Chemical solution in, chemical oxidation 1min under temperature 50 C, form oh group and porous at above-mentioned aluminum alloy material surface Film layer, in order to be greatly enhanced base material and print layer and the adhesion of its lower adhesive linkage material on it.
Step 2: printed decoration layer
By the way of the continuous offset printing of drum-type have passed through step one process after above-mentioned aluminum alloy base material an one side on table One layer of Wood-grain-imitating patterned layer is printed in face (front), is dried by the requirement of ink used.
Step 3: in printing layer surface configuration Al2O3Wear-resistant protective layer
In order to strengthen the ostentatious delineation wear-resisting, anti-of above-mentioned colored printing, antifouling property, above-mentioned metal base is on have passed through After stating step one and step 2, then commercially available reinforced composite floorboard Al2O3The side that dipping abrasion-proof paper is merged by high-temperature bearing Formula, merges one layer of delineation protective layer wear-resisting, anti-on above-mentioned printed decoration layer.
Al2O3Abrasion-proof paper wearing coat and the hot pressing plasticizing forming method of printed decoration layer: in accordance with Al2O3Dipping abrasion-proof paper The requirement of hot press pressure and temperature is carried out plastifying bonding forming by manufacturer.
Step 4: protection processes
Semi-finished product front surface roll-in after metal base be have passed through above-mentioned steps one～step 3 process is pasted last layer PVC and is glued Adhesive tape glued membrane.
Step 5: substrate backside arranges adhesives
Metal base be have passed through above-mentioned steps 1～step 4 process after semi-finished product turn over, at other side surface (back side) One layer of commercially available pressure sensitive adhesive of application.
Step 6: back-protective processes
After above-mentioned metal base being have passed through the process of above-mentioned steps 1～step 5, finally it is being provided with the one side of pressure sensitive adhesive, then By the way of rolling, one layer of organosilicon protection sheet of pressing.
After above-mentioned six steps, color metal textured metal floor of the present invention i.e. completes.

Claims (8)

1., for a chromatic pattern metal floor for decoration, it is " floor plaster " system of the band color metal decorative pattern for decoration Product, described metal floor is followed successively by five-layer structure from top to bottom, including: protecting film 1, the wearing layer 2 of setting thickness, setting thickness Printed decoration layer 3, metal substrate layer 4, Performance of Pressure Sensitive Adhesive layer 5, organosilicon protection sheet 6；Wherein: protecting film 1 and organosilicon are protected Protecting paper 6 is protective layer, and wearing layer 2, printed decoration layer 3, metal substrate layer 4 and Performance of Pressure Sensitive Adhesive layer 5 are basic training ergospheres；Described Protecting film 1 is that PVC protects glued membrane；The lower surface of described metal substrate layer 4 bonds with Performance of Pressure Sensitive Adhesive layer 5；Described pressure-sensitive adhesive The lower surface connecing layer 5 is organosilicon protection sheet 6；It is characterized in that:
Described wearing layer 2 is application heat cure Al on printed decoration layer 32O3, or SiO2Wear-resistant protection coating, or Person is that high-temperature bearing merges the Al on printed decoration layer 32O3Dipping abrasion-proof paper protective layer；
When wearing layer 2 uses Al2O3During dipping abrasion-proof paper protective layer, described PVC protection glued membrane is nonessential setting.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described wearing layer 2 Thickness is 10～1000 μm.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described printed decoration Layer 3 thickness be 10～1000 μm, the pattern of printed decoration layer 3 includes but does not limits: Wood-grain-imitating pattern, marble grain pattern, Carpet stricture of vagina pattern, granite pattern；Or print out at metal substrate layer 4 upper surface with foam ink there is anaglyph figure Case.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described metal substrate layer The material of 4 sets and includes but not limited to: rustless steel or aluminium alloy, ashbury metal, copper alloy；The thickness of described metal substrate layer 4 sets It is set to 0.01～1.5mm；The upper surface of metal substrate layer 4 is: minute surface or dull surface, sand face, mill stricture of vagina or hairline face；Described metal Substrate layer 4 includes: metal forming (plate) or winding.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described Performance of Pressure Sensitive Adhesive The thickness of layer 5 is 100～1000 μm.
A kind of chromatic pattern metal floor for decoration, it is characterised in that: described basic training ergosphere Gross thickness be 100～2000 μm.
7. the manufacture method of an a kind of chromatic pattern metal floor for decoration as claimed in claim 1, it is characterised in that: Carry out as follows:
Step one: the hydroxylating of metal base upper surface and microporous
By rustless steel that thickness is 0.01～2mm or aluminium alloy or ashbury metal or copper alloy foil (plate) or winding metalloid base Material, goes to degrease, clean up, is then placed on and is respectively as follows: containing chemical composition and concentration
CrO3(5～250g/l) and H2SO4In the chemical oxidation solution of (5～490g/l), or
HNO3(5～250g/l) and H2O2In the chemical oxidation solution of (5～250g/l), or
NaOH(1～100g/l) chemical solution in, or (NH4)2Mo2O7And H2SO4The chemical oxidation solution of (5～250g/l) In, carry out chemical treatment, form oh group and (or) oxide-film in described metallic substrate surface and corrode micropore in a large number；
Step 2: printed decoration layer
By the way of the continuous offset printing of drum-type, or trans-printing mode, the metal base handled well in step one upper One layer of decorative coating of surface printing, or there is the decorations coating of anaglyph with foam ink printing one layer；Described dress The pattern of decorations figure layer is arbitrarily set by demand；
Step 3: coating surface wearing layer
Being coated with the abrasion-resistant clear coat of a layer strong with basal body binding force on the printed decoration layer that step 2 completes, coating layer thickness sets Being set to 10～1200 μm, the component of described clear coat includes: macromolecular material and inserts, and described macromolecular material is piano Paint or polyurethane or tripolycyanamide or melamine resin；Described inserts is nanometer Al2O3Or Nano-meter SiO_22；The most right Coating is heating and curing, and forms robust surface wear-resistant layer；
Described wear resistant transparent paint or antiwear epoxy resin paint；
Step 4: protection processes
After completing to print wearing layer by step 3, paste the PVC glued membrane of last layer protectiveness in the rolling of wearing layer upper surface；
Step 5: the metal base back side arranges adhesives
At metal base lower surface application (or stickup) last layer pressure sensitive adhesive；
Step 6: back-protective processes
At the lower surface of the bonding pressure sensitive adhesive of step 5, by rolling mode, one layer of organosilicon protection sheet of pressing.
A kind of manufacture method of the chromatic pattern metal floor for decoration, it is characterised in that: described Manufacture method or carry out as follows:
Step one: the hydroxylating of metal base upper surface and microporous
By rustless steel that thickness is 0.01～2mm or aluminium alloy or ashbury metal or copper alloy foil (plate) or winding metalloid base Material, goes to degrease, clean up, is then placed on and is respectively as follows: containing chemical composition and concentration
CrO3(5～250g/l) and H2SO4In the chemical oxidation solution of (5～490g/l), or
HNO3(5～250g/l) and H2O2In the chemical oxidation solution of (5～250g/l), or
NaOH(1～100g/l) chemical solution in, or (NH4)2Mo2O7And H2SO4The chemical oxidation solution of (5～250g/l) In, carry out chemical treatment, form oh group and (or) oxide-film in described metallic substrate surface and corrode micropore in a large number；
Step 2: printed decoration layer
By the way of the continuous offset printing of drum-type, or trans-printing mode, the metal base handled well in step one upper One layer of decorative coating of surface printing, or there is the decorations coating of anaglyph with foam ink printing one layer；Described dress The pattern of decorations figure layer is arbitrarily set by demand；
Step 3: in printed decoration layer surface configuration Al2O3Dipping abrasion-proof paper protective layer
On the printed decoration layer that step 2 completes, by high-temperature bearing amalgamation mode, merge one layer of Al2O3Dipping abrasion-proof paper；
Step 4: the metal base back side arranges adhesives
At metal base lower surface application (or stickup) last layer pressure sensitive adhesive；
Step 5: back-protective processes
At the lower surface of the bonding pressure sensitive adhesive of step 5, by rolling mode, one layer of organosilicon protection sheet of pressing.
CN201610579629.5A 2016-07-22 2016-07-22 A kind of chromatic pattern metal floor for being used to decorate and preparation method Active CN106042520B (en)

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CN107542232A (en) * 2017-10-20 2018-01-05 湖州悦锦阁木业有限公司 Anti-skidding staircase boards
CN109281449A (en) * 2018-09-19 2019-01-29 福建捷嘉实业有限公司 Exposed multi-functional self-adhered flexible tapestry brick
CN109868971A (en) * 2019-03-12 2019-06-11 浙江晶通塑胶有限公司 A kind of magnesium oxide plate water-proof floor
CN110344563A (en) * 2018-04-04 2019-10-18 赵培东 Groups of diversification figure line series plastic plate based article and its production method
CN110722845A (en) * 2019-10-23 2020-01-24 苏州欧邦塑胶有限公司 Alloy stainless steel film and production method thereof
CN113216558A (en) * 2021-04-29 2021-08-06 陈明寿 PVC floor paste and manufacturing process thereof

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CN2858848Y (en) * 2005-08-23 2007-01-17 程智勇 Geothermal heat resistant anticracking wooden composite floor block
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CN107542232A (en) * 2017-10-20 2018-01-05 湖州悦锦阁木业有限公司 Anti-skidding staircase boards
CN110344563A (en) * 2018-04-04 2019-10-18 赵培东 Groups of diversification figure line series plastic plate based article and its production method
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CN113216558A (en) * 2021-04-29 2021-08-06 陈明寿 PVC floor paste and manufacturing process thereof

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