CN106393942A - Preparation process for high-glossiness hardened decorative plate - Google Patents

Preparation process for high-glossiness hardened decorative plate Download PDF

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Publication number
CN106393942A
CN106393942A CN201610800373.6A CN201610800373A CN106393942A CN 106393942 A CN106393942 A CN 106393942A CN 201610800373 A CN201610800373 A CN 201610800373A CN 106393942 A CN106393942 A CN 106393942A
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CN
China
Prior art keywords
base material
basic unit
preparation technology
hardening
dalle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610800373.6A
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Chinese (zh)
Inventor
葛亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU JOYFUL NEW MATERIAL CO Ltd
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JIANGSU JOYFUL NEW MATERIAL CO Ltd
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Priority to CN201610800373.6A priority Critical patent/CN106393942A/en
Publication of CN106393942A publication Critical patent/CN106393942A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1284Application of adhesive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/18Handling of layers or the laminate
    • B32B38/1825Handling of layers or the laminate characterised by the control or constructional features of devices for tensioning, stretching or registration
    • B32B38/1833Positioning, e.g. registration or centering
    • B32B38/1841Positioning, e.g. registration or centering during laying up

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  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a preparation process for a high-glossiness hardened decorative plate; the decorative plate comprises a base layer and a decorative layer bonded to the upper surface of the base layer; the decorative layer comprises a transparent hardened film and a PVC film; the base layer comprises a base material, and impregnated glue film paper bonded on the upper surface and the lower surface of the base material. The preparation process comprises the following steps: material loading, covering, base material pretreatment, gluing, centering, hot pressing, and plate removing. The decorative plate obtained by the process has the advantages of better scratch resistance and waterproof performance, high surface glossiness, and good fitting degree between the layers, avoids warping, falling-off and other quality problems easy to produced after long time use, thereby prolonging the service life of the product.

Description

A kind of preparation technology of high photo-hardening dalle
Technical field
The invention belongs to ornament materials production technical field is and in particular to a kind of preparation work of high photo-hardening dalle Skill.
Background technology
With the raising of living standards of the people, the aesthetic property to indoor hardware fitting and Functional Requirement more and more higher, its The dalle that middle finishing is used plays a significant role.Sheet material is widely used in the manufacture of furniture and body of wall, traditional plate Material is mainly single plank, mainboard or density board etc., also need to be poor in surface mopping, water proofing property, and welding, injury human body Health.At present, dalle is improved to mostly including decorative layer and basic unit, but its decorative layer generally uses oleum lini dough cover, becomes This is very high, and easily damaged, picture on surface also compare single it is impossible to meet the esthetic requirement of people.
In addition also have a kind of sheet material only to cover with paint, lacquer, colour wash, etc. one layer of wearproof paint in substrate surface, but presence construction be not complicated, mar-proof, And it is all unfavorable to environmental and human health impacts.In view of the foregoing it is necessary to carry out to the preparation technology of high photo-hardening dalle Improve.
Content of the invention
For solving the deficiencies in the prior art, it is an object of the invention to provide one kind has more preferably scratch-resistant and water resistance, Surface gloss is very high, and the preparation technology of the more preferable high photo-hardening dalle of the laminating degree between each layer.
In order to realize above-mentioned target, the present invention adopts the following technical scheme that:
A kind of preparation technology of high photo-hardening dalle, dalle includes basic unit and is adhered to the dress of basic unit's upper surface Decorations layer, described decorative layer includes transparent hardened film and PVC film, and described basic unit includes base material and is adhered to the upper and lower surface of base material Impregnated bond paper, preparation technology comprises the steps:
S1, feeding:In the upper surface gluing of PVC film, according to the order assembly of transparent hardened film and PVC film;
S2, laminating:Using mechanical hand, the good transparent hardened film of assembly and PVC film are sent into laminating equipment, laminating filled Decorations layer;
S3, base material pretreatment:Select base material, sanding and polishing are carried out to substrate surface using sander;
S4, gluing:In the upper and lower surface uniform gluing of base material, bonding impregnated bond paper, obtains basic unit respectively;
S5, centering:By centralising device, decorative layer be aligned is positioned over directly over basic unit;
S6, hot pressing:By decorative layer and basic unit's attaching and compacting;
S7, taking-up sheet material:Finished product is carried out deburring, inspection process after, stacking is to finished product area.
Preferably, aforementioned substrates are one of density board, PLASTIC LAMINATED, particieboard, PVC board or core-board.
More preferably, in abovementioned steps S1, the thickness of PVC film is 0.12mm~0.17mm.
It is highly preferred that in abovementioned steps S1, the thickness of transparent hardened film is 0.2mm~0.3mm.
Specifically, in abovementioned steps S1, the gluing of PVC film upper surface is transparent UV no shadow glue it is ensured that product light transmittance Unaffected.
It is further preferred that in front step S4, gluing mode is:Using glue rifle in the uniformly coating one of the upper and lower surface of base material Layer PUR glue.
More preferably, in step S4, gluing mode is:From bloom coating line equipment, including glue spreader and two-sided Roll squeezer, described glue spreader uniformly coats PUR glue on the upper and lower surface of base material, and described two-sided roll squeezer is on the upper and lower surface of base material All roll-in bonding impregnated bond papers.
It is highly preferred that distributing binder layer between aforementioned decor layer and basic unit, described adhesive layer is formed by PUR hot pressing, It is evenly applied to substrate surface before step S6.
Specifically, in abovementioned steps S6, hot compression parameterses are:Pressure 18MPa~20MPa, 110 DEG C~130 DEG C of temperature, the time 80s~99s.
It is further preferred that also including before abovementioned steps S4:Step S3 ', japanning:Apply one layer of PE paint in substrate surface Or PU paint, naturally dry.
The invention has benefit that:The dalle that the technique of the present invention obtains has preferably scratch-resistant and water proofing property Can, surface gloss is very high, adopts bloom coating line equipment in substrate surface gluing and bonding impregnated bond paper simultaneously, this Equipment can be finely adjusted by high-precision reading plotter measurement, glue-line can be thinned to 40g/m2, realize one layer very thin And uniform glue-line, not only save sizing material, reduces cost, and the laminating degree of base material and impregnated bond paper is more preferable, it is to avoid length Time the quality problems such as sticks up shell, comes off, thus extending the service life of product using rear easy appearance.
Brief description
Fig. 1 is the structural representation of a kind of high photo-hardening dalle of the present invention.
The implication of in figure reference:1st, transparent hardened film, 2, PVC film, 3, base material, 4, impregnated bond paper.
Specific embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is made with specific introduction.
Embodiment 1
The step of preparation process of the high photo-hardening dalle of the present embodiment is as follows:
S1, feeding:Uniformly coat one layer of UV no shadow glue in the upper surface of the PVC film for 0.15mm for the thickness, according to transparent hard Change the order assembly of film and PVC film, the wherein thickness of transparent hardened film is 0.2mm;
S2, laminating:Using mechanical hand, the good transparent hardened film of assembly and PVC film are sent into laminating equipment, laminating filled Decorations layer;
S3, base material pretreatment:Select base material, sanding and polishing are carried out to substrate surface using sander;
S4, gluing:Uniformly coat one layer of PUR glue using glue rifle on the upper and lower surface of base material, respectively bonding impregnated bond paper, Obtain basic unit;
S5, centering:Adhesive layer is evenly applied to substrate surface, then passes through centralising device, decorative layer is aligned and places Directly over basic unit;
S6, hot pressing:By decorative layer and basic unit's attaching and compacting, hot compression parameterses are:Pressure 20MPa, 110 DEG C of temperature, the time 80s;
S7, taking-up sheet material:Finished product is carried out deburring, inspection process after, stacking is to finished product area.
Embodiment 2
The preparation technology of the present embodiment is substantially similar with embodiment 1, differs primarily in that the gluing mode of step S4, specifically Step is as follows:
S1, feeding:Uniformly coat one layer of UV no shadow glue in the upper surface of the PVC film for 0.15mm for the thickness, according to transparent hard Change the order assembly of film and PVC film, the wherein thickness of transparent hardened film is 0.2mm;
S2, laminating:Using mechanical hand, the good transparent hardened film of assembly and PVC film are sent into laminating equipment, laminating filled Decorations layer;
S3, base material pretreatment:Select base material, sanding and polishing are carried out to substrate surface using sander;
S4, gluing:From bloom coating line equipment, including glue spreader and two-sided roll squeezer, described glue spreader is in base The upper and lower surface of material uniformly coats PUR glue, described two-sided roll squeezer in the equal roll-in in the upper and lower surface bonding impregnated bond paper of base material, Obtain basic unit;
S5, centering:Adhesive layer is evenly applied to substrate surface, then passes through centralising device, decorative layer is aligned and places Directly over basic unit;
S6, hot pressing:By decorative layer and basic unit's attaching and compacting, hot compression parameterses are:Pressure 20MPa, 110 DEG C of temperature, the time 80s;
S7, taking-up sheet material:Finished product is carried out deburring, inspection process after, stacking is to finished product area.
Embodiment 3:
The preparation technology of the present embodiment is substantially similar with embodiment 1, also includes to base before differring primarily in that step S4 Step S3 of material japanning ', comprise the following steps that:
S1, feeding:Uniformly coat one layer of UV no shadow glue in the upper surface of the PVC film for 0.15mm for the thickness, according to transparent hard Change the order assembly of film and PVC film, the wherein thickness of transparent hardened film is 0.2mm;
S2, laminating:Using mechanical hand, the good transparent hardened film of assembly and PVC film are sent into laminating equipment, laminating filled Decorations layer;
S3, base material pretreatment:Select base material, sanding and polishing are carried out to substrate surface using sander;
S3 ', japanning:Apply one layer of PE paint in substrate surface, naturally dry;
S4, gluing:Uniformly coat one layer of PUR glue using glue rifle on the upper and lower surface of base material, respectively bonding impregnated bond paper, Obtain basic unit;
S5, centering:Adhesive layer is evenly applied to substrate surface, then passes through centralising device, decorative layer is aligned and places Directly over basic unit;
S6, hot pressing:By decorative layer and basic unit's attaching and compacting, hot compression parameterses are:Pressure 20MPa, 110 DEG C of temperature, the time 80s;
S7, taking-up sheet material:Finished product is carried out deburring, inspection process after, stacking is to finished product area.
Embodiment 4:
The preparation technology of the present embodiment is substantially similar with embodiment 1, also includes to base before differring primarily in that step S4 Material japanning step S3 ' and step S4 in gluing mode, comprise the following steps that:
S1, feeding:Uniformly coat one layer of UV no shadow glue in the upper surface of the PVC film for 0.15mm for the thickness, according to transparent hard Change the order assembly of film and PVC film, the wherein thickness of transparent hardened film is 0.2mm;
S2, laminating:Using mechanical hand, the good transparent hardened film of assembly and PVC film are sent into laminating equipment, laminating filled Decorations layer;
S3, base material pretreatment:Select base material, sanding and polishing are carried out to substrate surface using sander;
S3 ', japanning:Apply one layer of PU paint in substrate surface, naturally dry;
S4, gluing:From bloom coating line equipment, including glue spreader and two-sided roll squeezer, described glue spreader is in base The upper and lower surface of material uniformly coats PUR glue, described two-sided roll squeezer in the equal roll-in in the upper and lower surface bonding impregnated bond paper of base material, Obtain basic unit;
S5, centering:Adhesive layer is evenly applied to substrate surface, then passes through centralising device, decorative layer is aligned and places Directly over basic unit;
S6, hot pressing:By decorative layer and basic unit's attaching and compacting, hot compression parameterses are:Pressure 20MPa, 130 DEG C of temperature, the time 99s;
S7, taking-up sheet material:Finished product is carried out deburring, inspection process after, stacking is to finished product area.
The high photo-hardening decorative plate structure being obtained by the various embodiments described above is completely the same, all includes basic unit and is adhered to The decorative layer of basic unit's upper surface, decorative layer includes transparent hardened film 1 and PVC film 2, and basic unit includes base material 3 and is adhered to base material 3 The impregnated bond paper 4 on upper and lower surface.Wherein, base material 3 is selected from density board, PLASTIC LAMINATED, particieboard, PVC board or core-board One kind, impregnated bond paper 4 is printed on grain pattern, and pattern has multiple, is available for user and does different choice;Bonding transparent hardened film 1 It is a kind of transparent adhesive tape with the UV of PVC film 2 no shadow glue, do not interfere with the transparency of transparent hardened film 1 and PVC film 2 so that sheet material Outward appearance and using effect are more preferable;And the presence of adhesive layer can make decorative layer and basic unit's laminating very well, so that product is difficult Peel off.
Performance detection
In order to preferably illustrate the present invention, below the performance of the dalle that each embodiment obtains is detected, specifically Including:
(1), surface abrasion resistance detection:Examination criteria is GB/T18102 2007P11, using grinding of a pair of adhesion emery cloth Emery wheel and test specimen (sheet material to be detected) friction of rotation, record plate surface appearance abrasion and wear area are no less than 2mm2When Abrasion revolution;
(2), waterproof (water suction) performance detection:Examination criteria is GB/T18102 2007P8, the thickness of measurement 3 points of test specimen Degree h1(both sides at the 25mm of test specimen bottom respectively take a bit, and the middle of test specimen bottom takes a bit);Then test specimen is dipped in temperature Spend in the distilled water tank for (20 ± 1) DEG C, test specimen is placed in the sink perpendicular to horizontal plane, and test specimen did not had water about 50mm, examination Part lower surface and bottom of gullet will have certain distance, soak time 24h ± 15min;After completing to soak, take out test specimen, wipe table Face attached water, surveys its thickness h in former measurement point2, measuring work must complete in 30min.
The thickness swelling rate of test specimen be test specimen water suction after thickness increment with water suction before thickness ratio:
D=(h2-h1)/h1× 100,
In formula:D thickness swelling rate, %;
h1Specimen thickness before immersion, mm;
h2Specimen thickness after immersion, mm.
(3), the overall laminating degree of sheet material carries out qualitative analyses by soaked test, will carry out the examination of water resistance detection Part is placed in 40 DEG C of drying baker and 120min is dried, and takes out, cooling, observes each test specimen and has or not stripping and lamination, and uses steel Board foot measures glue-line each side released part length of sample respectively.
Testing result is as follows:
Detection project Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4
Wearability (turns) 9000 9100 9300 9200
Thickness swelling rate 15% 13% 10% 8%
Stick up shell phenomenon Have No Have No
Obscission Have No No No
The performance test results of table 1 embodiment 1-4
Analyzed from table 1, the dalle of four embodiment preparations is respectively provided with good wearability and water resistance, resistance to Mill property has all reached the high standard of bussiness class (more than 9000 turns), and this is due to being bonded with decorative layer above the basic unit of sheet material, plus The strong wearability of sheet material.The thickness swelling rate of the dalle of four embodiment preparations all≤18%, meets market After base material japanning after to polishing in basic demand, especially embodiment 4, water absorbing properties as little as less than 10%, and product It is difficult to stick up shell and comes off, the sheet material after on the one hand this be because painting is more smooth, the bonding and impregnated bond paper between Degree is more preferably;Select when on the other hand, to substrate surface gluing is bloom coating line equipment, and this equipment can pass through high-precision The reading plotter measurement of degree is finely adjusted, and glue-line can be thinned to 40g/m2, realize one layer of very uniform and thin glue-line, not only Save sizing material, reduces cost, and enhance the laminating degree of base material and impregnated bond paper;Meanwhile, the presence of adhesive layer makes to fill Decorations layer and more sturdy the bonding together of basic unit, it is to avoid the long-time quality such as stick up shell, come off using rear easy appearance is asked Topic, thus extend the service life of product.
The basic principles, principal features and advantages of the present invention have been shown and described above.The technical staff of the industry should Understand, the invention is not limited in any way for above-described embodiment, all obtained by the way of equivalent or equivalent transformation Technical scheme, all falls within protection scope of the present invention.

Claims (10)

1. a kind of preparation technology of high photo-hardening dalle is it is characterised in that dalle includes basic unit and is adhered to basic unit The decorative layer of upper surface, described decorative layer includes transparent hardened film and PVC film, PVC film laminating in basic unit, described basic unit includes Base material and the impregnated bond paper being adhered to the upper and lower surface of base material, preparation technology comprises the steps:
S1, feeding:In the upper surface gluing of PVC film, according to transparent hardened film upper, PVC film under order assembly;
S2, laminating:Using mechanical hand, the good transparent hardened film of assembly and PVC film are sent into laminating equipment, laminating obtain decorative layer;
S3, base material pretreatment:Select base material, sanding and polishing are carried out to substrate surface using sander;
S4, gluing:In the upper and lower surface uniform gluing of base material, bonding impregnated bond paper, obtains basic unit respectively;
S5, centering:By centralising device, decorative layer be aligned is positioned over directly over basic unit;
S6, hot pressing:By decorative layer and basic unit's attaching and compacting;
S7, taking-up sheet material:Finished product is carried out deburring, inspection process after, stacking is to finished product area.
2. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described base material is One of density board, PLASTIC LAMINATED, particieboard, PVC board or core-board.
3. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described step S1 In, the thickness of PVC film is 0.12mm ~ 0.17mm.
4. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described step S1 In, the thickness of transparent hardened film is 0.2mm ~ 0.3mm.
5. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described step S1 In, the gluing of PVC film upper surface is transparent UV no shadow glue.
6. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described step S4 In, gluing mode is:Uniformly coat one layer of PUR glue using glue rifle on the upper and lower surface of base material.
7. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described step S4 In, gluing mode is:From bloom coating line equipment, including glue spreader and two-sided roll squeezer, described glue spreader is in base material Upper and lower surface uniformly coats PUR glue, and described two-sided roll squeezer is in the equal roll-in in the upper and lower surface bonding impregnated bond paper of base material.
8. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described decorative layer Distributing binder layer and basic unit between, described adhesive layer is formed by PUR hot pressing, is evenly applied to basic unit's table before step S6 Face.
9. a kind of preparation technology of high photo-hardening dalle according to claim 1 is it is characterised in that described step S6 In, hot compression parameterses are:Pressure 18MPa ~ 20MPa, 110 DEG C ~ 130 DEG C of temperature, time 80s ~ 99s.
10. a kind of high photo-hardening dalle according to any one of claim 1-9 preparation technology it is characterised in that Also include before described step S4:Step S3 ', japanning:Apply one layer of PE paint or PU paint in substrate surface, naturally dry.
CN201610800373.6A 2016-08-31 2016-08-31 Preparation process for high-glossiness hardened decorative plate Pending CN106393942A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107984805A (en) * 2017-12-31 2018-05-04 天津市顺通达包装制品有限公司 A kind of spool corrugated board corner protector compounding machine glue spreading apparatus with alignment function
CN110359650A (en) * 2019-07-22 2019-10-22 原阳县大诚家居材料有限公司 One kind exempting from enamel-cover and covers balustrade or guardrail and preparation method thereof
CN110450471A (en) * 2019-09-04 2019-11-15 阿姆斯壮(中国)投资有限公司 A kind of New Rigid PVC film coated plate and its processing technology
CN113829446A (en) * 2021-11-05 2021-12-24 德华兔宝宝装饰新材股份有限公司 Textile wall cloth decorative artificial board and manufacturing process thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02305635A (en) * 1989-05-19 1990-12-19 Hokusan Kk Sliced veneer decorative sheet for sewn product material
CN103358629A (en) * 2013-05-14 2013-10-23 泰州市华丽塑料有限公司 Straw wood-plastic composite board
CN104149447A (en) * 2014-07-18 2014-11-19 谭海韵 Composite decorative sheet
CN204894704U (en) * 2015-07-24 2015-12-23 明珠家具股份有限公司 Novel high-brightness composite board

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02305635A (en) * 1989-05-19 1990-12-19 Hokusan Kk Sliced veneer decorative sheet for sewn product material
CN103358629A (en) * 2013-05-14 2013-10-23 泰州市华丽塑料有限公司 Straw wood-plastic composite board
CN104149447A (en) * 2014-07-18 2014-11-19 谭海韵 Composite decorative sheet
CN204894704U (en) * 2015-07-24 2015-12-23 明珠家具股份有限公司 Novel high-brightness composite board

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107984805A (en) * 2017-12-31 2018-05-04 天津市顺通达包装制品有限公司 A kind of spool corrugated board corner protector compounding machine glue spreading apparatus with alignment function
CN110359650A (en) * 2019-07-22 2019-10-22 原阳县大诚家居材料有限公司 One kind exempting from enamel-cover and covers balustrade or guardrail and preparation method thereof
CN110450471A (en) * 2019-09-04 2019-11-15 阿姆斯壮(中国)投资有限公司 A kind of New Rigid PVC film coated plate and its processing technology
CN113829446A (en) * 2021-11-05 2021-12-24 德华兔宝宝装饰新材股份有限公司 Textile wall cloth decorative artificial board and manufacturing process thereof

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Application publication date: 20170215