CN106012602A - 一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂 - Google Patents

一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂 Download PDF

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CN106012602A
CN106012602A CN201610337757.9A CN201610337757A CN106012602A CN 106012602 A CN106012602 A CN 106012602A CN 201610337757 A CN201610337757 A CN 201610337757A CN 106012602 A CN106012602 A CN 106012602A
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张冲
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Nantong Rich Island Bedding Development Co Ltd
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Abstract

本发明公开了一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠10‑20份，双氰胺10‑30份，十二水合硫酸铝钾1‑5份，硫酸铝铵6‑10份，聚乙烯吡啶1‑5份，蓖麻油酸钾1‑5份，乙氧基化烷基硫酸钠1‑3份，乙氧基化烷基硫酸铵1‑6份，苹果酸1‑3份，烷基糖苷1‑5份。本发明含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，对分散染料和还原染料具有扩散和稳定作用，并可缩短染料研磨时间。

Description

一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂
技术领域
本发明属于纺织助剂技术领域，更具体是涉及一种纺织用扩散剂。
背景技术
扩散剂就是日常所说的分散剂，它是染料加工和染料应用中不可缺少的助剂。有的扩散剂本身就兼有分散性和移染性等多种作用，既可作为染料加工用扩散剂，又可作为印染中的匀染剂。
分散染料和还原染料本身都不溶于水或微溶于水，合成出来的原染料颗粒较大，不能直接用于印染工业，需要进行研磨加工，使染料颗粒分散达到1 微米左右。扩散剂的加入量一般为原染料的1 ～ 3 倍，它可使染料粒子分散，有助于颗粒粉碎，阻止已粉碎的颗粒再重新聚集，保持染料散体的稳定性。扩散剂多数是各种类型的表面活性剂，包括阴离子型、阳离子型、非离子型、两性型和高分子型等。
离子型扩散剂在染料分散体中，由于溶解而电离，其亲油基趋向于染料，亲水基趋向于水，同时扩散剂的疏水部分或它的某些基团以表面吸附、介电子极化、氢键结合等形式与染料分子相吸附，因此在染料颗粒表面有一定排列方向的相同电子层，由于同电荷互相排斥，阻止染料粒子沉降，加之由于扩散剂的亲水性，在它的外层又形成水化分子层，阻止了染料分子的相互接近。此外，在水化分子层外，还有分散液中的正电荷，它们被吸引在分散剂的负电荷周围，形成双分子层，这样染料颗粒之间的距离被拉大，当染料颗粒距离很近时，范德华引力不能产生作用，扩散剂使染料保持悬浮和分散稳定性，纺织相互接近而聚集或凝聚。
在纺织品印染过程中使用的商品染料，要求具有较好的再分散性；在染浴中具有良好的热稳定性，粘度小，对混纺中的其他组分沾色少；染料的溶解度小；金属离子含量低等。这些性能除与染料结构有关外，也与扩散剂的品种有关。
发明内容
本发明的目的是提供一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，本发明对分散染料和还原染料具有扩散和稳定作用，并可缩短染料研磨时间。
本发明的目的是通过以下技术方案实现的，一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，其特征是，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 10-20份，双氰胺 10-30份，十二水合硫酸铝钾 1-5份，硫酸铝铵 6-10份，聚乙烯吡啶 1-5份，蓖麻油酸钾 1-5份，乙氧基化烷基硫酸钠 1-3份，乙氧基化烷基硫酸铵 1-6份，苹果酸 1-3份，烷基糖苷 1-5份。
优选的，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 10.4-19.5份，双氰胺 13-26份，十二水合硫酸铝钾 1.4-4.6份，硫酸铝铵 6.3-9.6份，聚乙烯吡啶 1.4-4.4份，蓖麻油酸钾 1.2-4.2份，乙氧基化烷基硫酸钠 1.4-2.8份，乙氧基化烷基硫酸铵 1.5-5.3份，苹果酸 1.2-2.8份，烷基糖苷 1.4-4.8份。
优选的，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 12.6-19.0份，双氰胺 16-23份，十二水合硫酸铝钾 1.7-4.2份，硫酸铝铵 6.8-9.0份，聚乙烯吡啶 1.6-4.1份，蓖麻油酸钾 1.7-3.6份，乙氧基化烷基硫酸钠 1.9-2.6份，乙氧基化烷基硫酸铵 2.9-4.9份，苹果酸 1.7-2.0份，烷基糖苷 1.8-4.0份。
优选的，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 14.7-17.6份，双氰胺 18-22份，十二水合硫酸铝钾 2.2-3.8份，硫酸铝铵 7.1-8.6份，聚乙烯吡啶 2.3-3.8份，蓖麻油酸钾 2.0-3.0份，乙氧基化烷基硫酸钠 2.2-2.5份，乙氧基化烷基硫酸铵 3.1-4.0份，苹果酸 1.8-2.0份，烷基糖苷2.2-3.5份。
优选的，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 15.1-16.2份，双氰胺 19-21份，十二水合硫酸铝钾 2.8-3.4份，硫酸铝铵 7.5-8.2份，聚乙烯吡啶 2.6-3.1份，蓖麻油酸钾 2.3-2.8份，乙氧基化烷基硫酸钠 2.4-2.5份，乙氧基化烷基硫酸铵 3.4-3.8份，苹果酸 1.9-2.0份，烷基糖苷2.8-3.0份。
与现有技术相比，本发明具有以下有益效果：分散能力强，储存稳定，容易化料；对于强度和色光无影响；对分散染料和还原染料具有扩散和稳定作用，并可缩短染料研磨时间。
具体实施方式
实施例1
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 10份，双氰胺 30份，十二水合硫酸铝钾 1份，硫酸铝铵10份，聚乙烯吡啶 1份，蓖麻油酸钾 5份，乙氧基化烷基硫酸钠 1份，乙氧基化烷基硫酸铵 6份，苹果酸 1份，烷基糖苷 5份。
实施例2
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 20份，双氰胺 10份，十二水合硫酸铝钾 5份，硫酸铝铵 6份，聚乙烯吡啶 5份，蓖麻油酸钾 1份，乙氧基化烷基硫酸钠 3份，乙氧基化烷基硫酸铵 1份，苹果酸 3份，烷基糖苷 1份。
实施例3
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 19.5份，双氰胺 13份，十二水合硫酸铝钾 4.6份，硫酸铝铵 6.3份，聚乙烯吡啶 4.4份，蓖麻油酸钾 1.2份，乙氧基化烷基硫酸钠 2.8份，乙氧基化烷基硫酸铵 1.5份，苹果酸 2.8份，烷基糖苷 1.4份。
实施例4
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 10.4份，双氰胺 26份，十二水合硫酸铝钾 1.4份，硫酸铝铵 9.6份，聚乙烯吡啶 1.4份，蓖麻油酸钾 4.2份，乙氧基化烷基硫酸钠 1.4份，乙氧基化烷基硫酸铵 5.3份，苹果酸 1.2份，烷基糖苷 4.8份。
实施例5
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 12.6份，双氰胺 23份，十二水合硫酸铝钾 1.7份，硫酸铝铵 9.0份，聚乙烯吡啶 1.6份，蓖麻油酸钾 3.6份，乙氧基化烷基硫酸钠 1.9份，乙氧基化烷基硫酸铵 4.9份，苹果酸 1.7份，烷基糖苷 4.0份。
实施例6
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 19.0份，双氰胺 16份，十二水合硫酸铝钾 4.2份，硫酸铝铵 6.8份，聚乙烯吡啶4.1份，蓖麻油酸钾 1.7份，乙氧基化烷基硫酸钠 2.6份，乙氧基化烷基硫酸铵 2.9份，苹果酸 2.0份，烷基糖苷 1.8份。
实施例7
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 14.7份，双氰胺 22份，十二水合硫酸铝钾 2.2份，硫酸铝铵 8.6份，聚乙烯吡啶 2.3份，蓖麻油酸钾 3.0份，乙氧基化烷基硫酸钠 2.2份，乙氧基化烷基硫酸铵 4.0份，苹果酸 1.8份，烷基糖苷3.5份。
实施例8
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 17.6份，双氰胺 18份，十二水合硫酸铝钾 3.8份，硫酸铝铵 7.1份，聚乙烯吡啶 3.8份，蓖麻油酸钾 2.0份，乙氧基化烷基硫酸钠 2.5份，乙氧基化烷基硫酸铵 3.1份，苹果酸 2.0份，烷基糖苷2.2份。
实施例9
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 15.1份，双氰胺 21份，十二水合硫酸铝钾 2.8份，硫酸铝铵 8.2份，聚乙烯吡啶 2.6份，蓖麻油酸钾 2.8份，乙氧基化烷基硫酸钠 2.4份，乙氧基化烷基硫酸铵 3.8份，苹果酸 1.9份，烷基糖苷3.0份。
实施例10
一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，包括以下重量份的各组分：脂肪酸聚醚硫酸钠 16.2份，双氰胺 19份，十二水合硫酸铝钾 3.4份，硫酸铝铵 7.5份，聚乙烯吡啶 3.1份，蓖麻油酸钾 2.3份，乙氧基化烷基硫酸钠 2.5份，乙氧基化烷基硫酸铵 3.4份，苹果酸 2.0份，烷基糖苷2.8份。

Claims (5)

1.一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，其特征是，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 10-20份，双氰胺 10-30份，十二水合硫酸铝钾 1-5份，硫酸铝铵 6-10份，聚乙烯吡啶 1-5份，蓖麻油酸钾 1-5份，乙氧基化烷基硫酸钠 1-3份，乙氧基化烷基硫酸铵 1-6份，苹果酸 1-3份，烷基糖苷 1-5份。
2. 根据权利要求1所述的一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，其特征是，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 10.4-19.5份，双氰胺 13-26份，十二水合硫酸铝钾 1.4-4.6份，硫酸铝铵 6.3-9.6份，聚乙烯吡啶 1.4-4.4份，蓖麻油酸钾 1.2-4.2份，乙氧基化烷基硫酸钠 1.4-2.8份，乙氧基化烷基硫酸铵 1.5-5.3份，苹果酸 1.2-2.8份，烷基糖苷 1.4-4.8份。
3. 根据权利要求1所述的一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，其特征是，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 12.6-19.0份，双氰胺 16-23份，十二水合硫酸铝钾 1.7-4.2份，硫酸铝铵 6.8-9.0份，聚乙烯吡啶 1.6-4.1份，蓖麻油酸钾 1.7-3.6份，乙氧基化烷基硫酸钠 1.9-2.6份，乙氧基化烷基硫酸铵 2.9-4.9份，苹果酸 1.7-2.0份，烷基糖苷 1.8-4.0份。
4. 根据权利要求1所述的一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，其特征是，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 14.7-17.6份，双氰胺 18-22份，十二水合硫酸铝钾 2.2-3.8份，硫酸铝铵 7.1-8.6份，聚乙烯吡啶 2.3-3.8份，蓖麻油酸钾 2.0-3.0份，乙氧基化烷基硫酸钠 2.2-2.5份，乙氧基化烷基硫酸铵 3.1-4.0份，苹果酸 1.8-2.0份，烷基糖苷2.2-3.5份。
5. 根据权利要求1所述的一种含脂肪酸聚醚硫酸钠与双氰胺的纺织用分散剂，其特征是，所述分散剂包括以下重量份的各组分：脂肪酸聚醚硫酸钠 15.1-16.2份，双氰胺 19-21份，十二水合硫酸铝钾 2.8-3.4份，硫酸铝铵 7.5-8.2份，聚乙烯吡啶 2.6-3.1份，蓖麻油酸钾 2.3-2.8份，乙氧基化烷基硫酸钠 2.4-2.5份，乙氧基化烷基硫酸铵 3.4-3.8份，苹果酸 1.9-2.0份，烷基糖苷2.8-3.0份。
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