CN106011528A - Environment-friendly alloy pipe material used for drinking water pipe - Google Patents

Environment-friendly alloy pipe material used for drinking water pipe Download PDF

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Publication number
CN106011528A
CN106011528A CN201610334164.7A CN201610334164A CN106011528A CN 106011528 A CN106011528 A CN 106011528A CN 201610334164 A CN201610334164 A CN 201610334164A CN 106011528 A CN106011528 A CN 106011528A
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CN
China
Prior art keywords
powder
ball
tourmaline
pipe
environment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610334164.7A
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Chinese (zh)
Inventor
梅家让
陈元龙
赵升
张波
周亚峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Laian Shaihua Pipe Industry Co Ltd
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Laian Shaihua Pipe Industry Co Ltd
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Publication date
Application filed by Laian Shaihua Pipe Industry Co Ltd filed Critical Laian Shaihua Pipe Industry Co Ltd
Priority to CN201610334164.7A priority Critical patent/CN106011528A/en
Publication of CN106011528A publication Critical patent/CN106011528A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/04Alloys based on copper with zinc as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0005Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Physical Water Treatments (AREA)

Abstract

An environment-friendly alloy pipe material used for a drinking water pipe is prepared from, by weight, 100 kg of copper, 0.5 kg of nanometer titanium nitride, 1.4 kg of modified tourmaline powder, 5 kg of zinc, 0.6 kg of tungsten carbide, 3 kg of silicon carbide, 0.8 kg of ultrafine barium, 0.5 kg of zirconium oxide, 4 kg of magnesium oxide, 0.4 kg of calcinated calcium hanleite powder, 1.5 kg of aluminum, 0.05 kg of lanthanum and 0.6 kg of boron oxide. The indexes, such as strength, hardness and flexibility, of obtained alloy pipes are superior to those in the prior art, the environment-friendly alloy pipe material is good in comprehensive performance and environment-friendly and can be used as drinking water pipe fittings with the high requirement for the metal content, and the pipe fittings have the antimicrobial function.

Description

Environmental protection alloy pipe for drinking-water pipe
Technical field
The present invention relates to drinking-water pipe technical field, be specifically related to a kind of environmental protection alloy for drinking-water pipe Tubing.
Background technology
Existing running water pipe is PPR plastic water pipe, and after using a period of time, inside pipe wall secondary pollution is serious, Be antibacterial, legionella grow ground, become new human health killer and potential life threat, unsuitable Do Household tap water pipe.
PPR water pipe is sheltered evil people and countenance evil practices, and is the prolific hotbed of antibacterial.To PPR tap water inside plumbing installations Pipe inside pipe wall dirt sampling in use for some time, testing result is: a kind of yellow embroiders tumor, includes The microorganisms such as bacillus, coccus, thin shape bacterium, substantial amounts of iron bacteria, Ai Xier escherichia coli, intestinal bacteria, Perch bacterium, acinetobacter, Aeromonas, Arthrobacter, bacillus etc. up to 31 kinds and evil At least 14 kinds of biotypes of smelly Rhodopseudomonas, even find chlorine-resistant microorganism grows such as straight chain Pseudomonas, crisp Bacillus, beautiful pipe spiral shell genus and Chlorella etc..Heterotrophic bacteria, escherichia coli, actinomyces in inside pipe wall dirt High with fungi concentration.
It is the undocumented secret of plumbing installations that PPR plastic tube is unfit to do Household tap water pipe.PPR plastic tube does not has Have self-cleaning function and tube have self-cleaning and sterilizing functions, under this specific environment of domestic water, the pollution at water source, from Come the backward technique of water factory and the outmoded unreasonable of pipe network thereof, make the PPR running water pipe of domestic become water quality two The gathering ground of secondary pollutant and bacterial growth ground, serious threat health, a Chinese portion in recent years City inhabitant statement-of-health is divided to disclose: the substantial increase of various diseases and cancer has with household tap water water quality Close, relevant with wrong choice supplying pipe.
Summary of the invention
The technical problem to be solved is to provide a kind of stable performance, being used for of length in service life The environmental protection alloy pipe of drinking-water pipe.
The technical problem to be solved realizes by the following technical solutions:
A kind of environmental protection alloy pipe for drinking-water pipe, is made up of the component of following weight: copper 100kg, Nano titanium nitride 0.5kg, modified verdelite powder 1.4kg, zinc 5kg, tungsten carbide 0.6kg, carborundum 3kg, Ultra-fine barium 0.8kg, zirconium oxide 0.5kg, magnesium oxide 4kg, calcining trautwinite powder 0.4kg, aluminum 1.5kg, Lanthanum 0.05kg, boron oxide 0.6kg;
The preparation technology of above-mentioned compo pipe is: is first melted by copper, then proceedes to be incubated 30 minutes, add Leftover materials, connect stirring 30-40 minute, are molten condition to material, then it is straight that fused solution is sent into mould Connect extrusion and make alloy bar, then alloy bar is melted, send into mould and make compo pipe;This compo pipe performance Stable, possess antibiotic effect, corrosion-resistant, intensity is high.
The preparation method of above-mentioned modified verdelite powder is as follows:
(1) collect tourmaline, tourmaline pulverizer is pulverized, crosses 60-80 mesh sieve, obtain tourmaline Powder is stand-by;
(2) take the tourmaline powder in step (1), tourmaline powder add appropriate pure water and stirs, Make material (emulsus) in the pasty state;The addition of pure water can make material become pasty state;
(3) pasty material in step (2) is put in container, be incubated with the steam pressure of 2.5-3 kilogram 3-3.5 hour, then put pressure and make pasty material recover to normality, keep 2-5 hour, the most continuously 2-3 time, prepare pressurization material;
(4) the pressurization material obtained in step (3) is dried in the drying plant of 100-105 DEG C Process, obtain dry material stand-by;
(5) dry material in step (4) is put in nylon ball grinder, with agate ball as abrading-ball, ball Material mass ratio is 7:1, under conditions of rotating speed is 150 revs/min, and continuous ball milling 3-4 hour;
(6) powder complete for ball milling is poured in powder dish together with Achates abrading-ball, dries at 80 DEG C, The powder dried is sieved, takes out Achates abrading-ball, then powder is ground, till without bigger reunion, So far, modified verdelite powder is obtained.
Modified verdelite powder is joined in alloy material, it is possible to significantly improve the anti-microbial property of alloy material, Reduce pipe inner wall bacteria breed.
The invention has the beneficial effects as follows: the intensity of the compo pipe that the present invention obtains, hardness, pliability etc. refer to Mark is better than prior art, and high comprehensive performance and environmental protection can be used as tenor requirement higher Drinking water pipe fitting;And this pipe fitting has antibiotic effect.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and effect and be readily apparent from Solve, below in conjunction with specific embodiment, the present invention is expanded on further.
Embodiment 1
A kind of environmental protection alloy pipe for drinking-water pipe, is made up of the component of following weight: copper 100kg, Nano titanium nitride 0.5kg, modified verdelite powder 1.4kg, zinc 5kg, tungsten carbide 0.6kg, carborundum 3kg, Ultra-fine barium 0.8kg, zirconium oxide 0.5kg, magnesium oxide 4kg, calcining trautwinite powder 0.4kg, aluminum 1.5kg, Lanthanum 0.05kg, boron oxide 0.6kg;
The preparation technology of above-mentioned compo pipe is: is first melted by copper, then proceedes to be incubated 30 minutes, add Leftover materials, connect stirring 30-40 minute, are molten condition to material, then it is straight that fused solution is sent into mould Connect extrusion and make alloy bar, then alloy bar is melted, send into mould and make compo pipe;This compo pipe performance Stable, possess antibiotic effect, corrosion-resistant, intensity is high.
The preparation method of above-mentioned modified verdelite powder is as follows:
(1) collect tourmaline, tourmaline pulverizer is pulverized, crosses 60 mesh sieves, obtain tourmaline powder and treat With;
(2) take the tourmaline powder in step (1), tourmaline powder add appropriate pure water and stirs, Make material (emulsus) in the pasty state;The addition of pure water can make material become pasty state;
(3) pasty material in step (2) is put in container, be incubated 3 with the steam pressures of 2.5 kilograms Hour, then put pressure and make pasty material recover to normality, keep 2 hours, the most continuous 2 times, make Must be pressurizeed material;
(4) the pressurization material obtained in step (3) is carried out drying and processing in the drying plant of 100 DEG C, Obtain dry material stand-by;
(5) dry material in step (4) is put in nylon ball grinder, with agate ball as abrading-ball, ball Material mass ratio is 7:1, under conditions of rotating speed is 150 revs/min, and continuous ball milling 3 hours;
(6) powder complete for ball milling is poured in powder dish together with Achates abrading-ball, dries at 80 DEG C, The powder dried is sieved, takes out Achates abrading-ball, then powder is ground, till without bigger reunion, So far, modified verdelite powder is obtained.
Modified verdelite powder is joined in alloy material, it is possible to significantly improve the anti-microbial property of alloy material, Reduce pipe inner wall bacteria breed.
Implement 2
A kind of environmental protection alloy pipe for drinking-water pipe, is made up of the component of following weight: copper 100kg, Nano titanium nitride 0.5kg, modified verdelite powder 1.4kg, zinc 5kg, tungsten carbide 0.6kg, carborundum 3kg, Ultra-fine barium 0.8kg, zirconium oxide 0.5kg, magnesium oxide 4kg, calcining trautwinite powder 0.4kg, aluminum 1.5kg, Lanthanum 0.05kg, boron oxide 0.6kg;
The preparation technology of above-mentioned compo pipe is: is first melted by copper, then proceedes to be incubated 30 minutes, add Leftover materials, connect stirring 30-40 minute, are molten condition to material, then it is straight that fused solution is sent into mould Connect extrusion and make alloy bar, then alloy bar is melted, send into mould and make compo pipe;This compo pipe performance Stable, possess antibiotic effect, corrosion-resistant, intensity is high.
The preparation method of above-mentioned modified verdelite powder is as follows:
(1) collect tourmaline, tourmaline pulverizer is pulverized, crosses 80 mesh sieves, obtain tourmaline powder and treat With;
(2) take the tourmaline powder in step (1), tourmaline powder add appropriate pure water and stirs, Make material (emulsus) in the pasty state;The addition of pure water can make material become pasty state;
(3) pasty material in step (2) is put in container, be incubated 3.5 with the steam pressures of 3 kilograms Hour, then put pressure and make pasty material recover to normality, keep 5 hours, the most continuous 3 times, make Must be pressurizeed material;
(4) the pressurization material obtained in step (3) is carried out drying and processing in the drying plant of 105 DEG C, Obtain dry material stand-by;
(5) dry material in step (4) is put in nylon ball grinder, with agate ball as abrading-ball, ball Material mass ratio is 7:1, under conditions of rotating speed is 150 revs/min, and continuous ball milling 4 hours;
(6) powder complete for ball milling is poured in powder dish together with Achates abrading-ball, dries at 80 DEG C, The powder dried is sieved, takes out Achates abrading-ball, then powder is ground, till without bigger reunion, So far, modified verdelite powder is obtained.
Modified verdelite powder is joined in alloy material, it is possible to significantly improve the anti-microbial property of alloy material, Reduce pipe inner wall bacteria breed.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.One's own profession Skilled person will appreciate that of industry, the present invention is not restricted to the described embodiments, above-described embodiment and explanation The principle that the present invention is simply described described in book, without departing from the spirit and scope of the present invention, The present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention model In enclosing.Claimed scope is defined by appending claims and equivalent thereof.

Claims (1)

1. the environmental protection alloy pipe for drinking-water pipe, it is characterised in that by the component of following weight Make: copper 100kg, Nano titanium nitride 0.5kg, modified verdelite powder 1.4kg, zinc 5kg, tungsten carbide 0.6kg, Carborundum 3kg, ultra-fine barium 0.8kg, zirconium oxide 0.5kg, magnesium oxide 4kg, calcining trautwinite powder 0.4kg, Aluminum 1.5kg, lanthanum 0.05kg, boron oxide 0.6kg;
The preparation method of above-mentioned modified verdelite powder is as follows:
(1) collect tourmaline, tourmaline pulverizer is pulverized, crosses 60-80 mesh sieve, obtain tourmaline Powder is stand-by;
(2) take the tourmaline powder in step (1), tourmaline powder add appropriate pure water and stirs, Make material in the pasty state;
(3) pasty material in step (2) is put in container, be incubated with the steam pressure of 2.5-3 kilogram 3-3.5 hour, then put pressure and make pasty material recover to normality, keep 2-5 hour, the most continuously 2-3 time, prepare pressurization material;
(4) the pressurization material obtained in step (3) is dried in the drying plant of 100-105 DEG C Process, obtain dry material stand-by;
(5) dry material in step (4) is put in nylon ball grinder, with agate ball as abrading-ball, ball Material mass ratio is 7:1, under conditions of rotating speed is 150 revs/min, and continuous ball milling 3-4 hour;
(6) powder complete for ball milling is poured in powder dish together with Achates abrading-ball, dries at 80 DEG C, The powder dried is sieved, takes out Achates abrading-ball, then powder is ground, till without bigger reunion, So far, modified verdelite powder is obtained.
CN201610334164.7A 2016-05-18 2016-05-18 Environment-friendly alloy pipe material used for drinking water pipe Pending CN106011528A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610334164.7A CN106011528A (en) 2016-05-18 2016-05-18 Environment-friendly alloy pipe material used for drinking water pipe

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Application Number Priority Date Filing Date Title
CN201610334164.7A CN106011528A (en) 2016-05-18 2016-05-18 Environment-friendly alloy pipe material used for drinking water pipe

Publications (1)

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CN106011528A true CN106011528A (en) 2016-10-12

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007068470A1 (en) * 2005-12-14 2007-06-21 Gebr. Kemper Gmbh + Co. Kg Metallwerke Low-migration copper alloy
CN101818285A (en) * 2010-04-12 2010-09-01 浙江佳鑫铜业有限公司 Brass alloy for environment-friendly drinking water pipe and pipe workpiece thereof
CN102312121A (en) * 2010-06-29 2012-01-11 天津市金龙焊接材料有限公司 Free-cutting and corrosion-resistant lead-free brass alloy
CN102978434A (en) * 2012-12-13 2013-03-20 北京科技大学 Short fiber-particle synergetically-reinforced copper-based composite material and preparation method thereof
CN103725922A (en) * 2014-01-16 2014-04-16 九星控股集团有限公司 Lead-free silicon brass alloy and preparation method
CN103911525A (en) * 2014-03-25 2014-07-09 安新县华昌合金厂 Waste regenerated lead-free brass alloy and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007068470A1 (en) * 2005-12-14 2007-06-21 Gebr. Kemper Gmbh + Co. Kg Metallwerke Low-migration copper alloy
CN101818285A (en) * 2010-04-12 2010-09-01 浙江佳鑫铜业有限公司 Brass alloy for environment-friendly drinking water pipe and pipe workpiece thereof
CN102312121A (en) * 2010-06-29 2012-01-11 天津市金龙焊接材料有限公司 Free-cutting and corrosion-resistant lead-free brass alloy
CN102978434A (en) * 2012-12-13 2013-03-20 北京科技大学 Short fiber-particle synergetically-reinforced copper-based composite material and preparation method thereof
CN103725922A (en) * 2014-01-16 2014-04-16 九星控股集团有限公司 Lead-free silicon brass alloy and preparation method
CN103911525A (en) * 2014-03-25 2014-07-09 安新县华昌合金厂 Waste regenerated lead-free brass alloy and preparation method thereof

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Application publication date: 20161012