CN106009982A - Antibacterial plastic-wood material composition, antibacterial plastic-wood and method for preparing same - Google Patents
Antibacterial plastic-wood material composition, antibacterial plastic-wood and method for preparing same Download PDFInfo
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- CN106009982A CN106009982A CN201610570914.0A CN201610570914A CN106009982A CN 106009982 A CN106009982 A CN 106009982A CN 201610570914 A CN201610570914 A CN 201610570914A CN 106009982 A CN106009982 A CN 106009982A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2431/00—Characterised by the use of copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, or carbonic acid, or of a haloformic acid
- C08J2431/02—Characterised by the use of omopolymers or copolymers of esters of monocarboxylic acids
- C08J2431/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an antibacterial plastic-wood material composition, antibacterial plastic-wood and a method for preparing the same. The antibacterial plastic-wood material composition comprises a plastic-wood matrix and an antibacterial coating. The antibacterial coating is smeared on the outer surface of the plastic-wood matrix and comprises, by weight, 100 parts of water, 50-120 parts of acetic acrylic emulsion, 10-20 parts of styrene-acrylic emulsion, 1-5 parts of nanometer calcium carbonate, 30-50 parts of talc powder, 0.1-2 parts of 2, 4, 5, 6-tetrachloro-3-benzenedicarbonitrile and 0.5-1.5 parts of zinc pyrithione. The antibacterial plastic-wood material composition, the antibacterial plastic-wood and the method in designs have the advantages that effective antibacterial effects can be realized, and environmental damage effects of bacteria in environments can be reduced to a great extent.
Description
Technical field
The present invention relates to mould the production preparation field of wood, in particular it relates to antibacterial plastic-wood material compositions and
Antibacterial mould wood and preparation method thereof.
Background technology
Along with global resources are the most exhausted, social environment consciousness is the most surging, to timber in producing and living
Have higher requirement with petroleum chemicals application.Plastic-wood material as a kind of emerging environment-friendly materials, its
Main with plant fiber material as major ingredient, add plastics synthesis, form a kind of suitability and be combined widely
Material.Because it has the advantage of Plant fiber and plastics concurrently, so that range in actual use
Extremely wide.
But mould wood use during, often because of in environment bacterial content higher, so that mould wood
On be easily attached with antibacterial, and then it is relatively big to make this mould wood environmental contamination in use, and impact makes employment
Member's is healthy.
Therefore it provides one can be the most antibacterial, the antibacterial being substantially reduced in environment antibacterial is moulded what it was encroached on
Wood material compositions and antibacterial wood and preparation method thereof of moulding are the problems that the present invention needs solution badly.
Summary of the invention
For above-mentioned prior art, it is an object of the invention to overcome in prior art in the use moulding wood
Cheng Zhong, often because of in environment bacterial content higher be easily attached with antibacterial on wood so that mould, and then
Make this mould wood environmental contamination in use relatively big, affect the healthy problem of user of service, from
And provide the one can be the most antibacterial, the antibacterial plastic-wood material group that it is encroached on by the antibacterial being substantially reduced in environment
Compound and antibacterial mould wood and preparation method thereof.
To achieve these goals, the invention provides a kind of antibacterial plastic-wood material compositions, wherein, institute
State compositions to include moulding wood matrix and mould the antimicrobial coating on wood outer surface of matrix described in being applied in, wherein,
Described antimicrobial coating includes between water, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, tetrachloro
Benzene dicarbonitrile and Zinc Pyrithione；Wherein,
Relative to the described water of 100 weight portions, the content of described acrylate and vinyl acetate emulsion is 50-120 weight portion,
The content of described styrene-acrylic emulsion is 10-20 weight portion, and the content of described nano-calcium carbonate is 1-5 weight portion,
Described talcous content is 30-50 weight portion, and the content of described termil is 0.1-2 weight
Amount part, the content of described Zinc Pyrithione is 0.5-1.5 weight portion.
Present invention also offers a kind of antibacterial preparation method moulding wood, wherein, described preparation method includes:
1) by water, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, tetrachloro isophthalic diformazan
Nitrile and Zinc Pyrithione mixing, prepare antimicrobial coating M1；
2) above-mentioned prepared antimicrobial coating M1 is applied in moulds wood matrix surface, prepare and antibacterial mould wood；
Wherein,
Relative to the described water of 100 weight portions, the consumption of described acrylate and vinyl acetate emulsion is 50-120 weight portion,
The consumption of described styrene-acrylic emulsion is 10-20 weight portion, and the consumption of described nano-calcium carbonate is 1-5 weight portion,
Described talcous consumption is 30-50 weight portion, and the consumption of described termil is 0.1-2 weight
Amount part, the consumption of described Zinc Pyrithione is 0.5-1.5 weight portion.
Present invention also offers and a kind of antibacterial mould wood according to what preparation method described above prepared.
By technique scheme, the present invention by water, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate,
Pulvis Talci, termil and Zinc Pyrithione mix according to a certain percentage, prepare antimicrobial coating,
Then above-mentioned prepared antimicrobial coating is applied in and moulds on wood outer surface of matrix, so that be coated with above-mentioned
The wood matrix of moulding of antimicrobial coating has good anti-microbial property when actually used, is substantially reduced in environment
It is encroached on by antibacterial.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched
The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
The invention provides a kind of antibacterial plastic-wood material compositions, wherein, described compositions includes moulding wood base
Body and the antimicrobial coating moulded described in being applied on wood outer surface of matrix, wherein, described antimicrobial coating include water,
Acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, termil and Zinc Pyrithione；
Wherein,
Relative to the described water of 100 weight portions, the content of described acrylate and vinyl acetate emulsion is 50-120 weight portion,
The content of described styrene-acrylic emulsion is 10-20 weight portion, and the content of described nano-calcium carbonate is 1-5 weight portion,
Described talcous content is 30-50 weight portion, and the content of described termil is 0.1-2 weight
Amount part, the content of described Zinc Pyrithione is 0.5-1.5 weight portion.
Above-mentioned design is by by water, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, tetrachloro
Isophthalodinitrile and Zinc Pyrithione mix according to a certain percentage, prepare antimicrobial coating, then by above-mentioned system
The antimicrobial coating obtained is applied in be moulded on wood outer surface of matrix, so that be coated with moulding of above-mentioned antimicrobial coating
Wood matrix has good anti-microbial property when actually used, and it is invaded by the antibacterial being substantially reduced in environment
Evil.
The present invention one preferred embodiment in, for the anti-microbial property moulding wood that makes to prepare more
Good, relative to the described water of 100 weight portions, the content of described acrylate and vinyl acetate emulsion is 80-100 weight portion,
The content of described styrene-acrylic emulsion is 13-17 weight portion, and the content of described nano-calcium carbonate is 2-4 weight portion,
Described talcous content is 35-45 weight portion, and the content of described termil is 1-2 weight
Part, the content of described Zinc Pyrithione is 0.8-1.2 weight portion.
Certainly, in order to improve the prepared serviceability moulding wood further, in a kind of enforcement being more highly preferred to
In mode, described antimicrobial coating can also include processing aid.
Described processing aid can be type commonly used in the art, such as, preferably implements in one
In mode, described processing aid can be selected from anti ultraviolet agent and/or antistatic additive.
Described nano-calcium carbonate can be Nano grade commonly used in the art, certainly, in one
In the embodiment being more highly preferred to, in order to improve anti-microbial property further, the particle diameter of described nano-calcium carbonate
For 50-500nm.
Present invention also offers a kind of antibacterial preparation method moulding wood, wherein, described preparation method includes:
1) by water, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, tetrachloro isophthalic diformazan
Nitrile and Zinc Pyrithione mixing, prepare antimicrobial coating M1；
2) above-mentioned prepared antimicrobial coating M1 is applied in moulds wood matrix surface, prepare and antibacterial mould wood；
Wherein,
Relative to the described water of 100 weight portions, the consumption of described acrylate and vinyl acetate emulsion is 50-120 weight portion,
The consumption of described styrene-acrylic emulsion is 10-20 weight portion, and the consumption of described nano-calcium carbonate is 1-5 weight portion,
Described talcous consumption is 30-50 weight portion, and the consumption of described termil is 0.1-2 weight
Amount part, the consumption of described Zinc Pyrithione is 0.5-1.5 weight portion.
In a preferred embodiment, in order to improve the prepared anti-microbial property moulding wood, phase further
For the described water of 100 weight portions, the consumption of described acrylate and vinyl acetate emulsion is 80-100 weight portion, described benzene
The consumption of acrylic emulsion is 13-17 weight portion, and the consumption of described nano-calcium carbonate is 2-4 weight portion, described
Talcous consumption is 35-45 weight portion, and the consumption of described termil is 1-2 weight portion,
The consumption of described Zinc Pyrithione is 0.8-1.2 weight portion.
Similarly, in a kind of embodiment being more highly preferred to, step 1) in can also include adding processing
Auxiliary agent mixes.
Described processing aid and described nano-calcium carbonate are as previously mentioned.
Step 1) in mixed process can according to this area routine use mode carry out, such as, one
In kind preferred embodiment, step 1) in mixed process be 100-300r/min for being placed in stir speed (S.S.)
Under conditions of stirring mixing.
Present invention also offers and a kind of antibacterial mould wood according to what preparation method described above prepared.
In a kind of embodiment being more highly preferred to, in order to reach as far as possible relatively on the premise of cost-effective
Good antibacterial effect, the thickness of antimicrobial coating is 0.1-1mm.
Hereinafter will be described the present invention by embodiment.In following example, described vinegar the third breast
Liquid, described styrene-acrylic emulsion, described nano-calcium carbonate, described Pulvis Talci, described termil and
Described Zinc Pyrithione is conventional commercial product.
Embodiment 1
1) 100g water, 80g acrylate and vinyl acetate emulsion, 13g styrene-acrylic emulsion, 2g nano-calcium carbonate, 35g are slided
Stone powder, 1g termil and 0.8g Zinc Pyrithione are placed in the bar that stir speed (S.S.) is 100r/min
Stirring mixing under part, prepares antimicrobial coating M1；
2) above-mentioned prepared antimicrobial coating M1 is applied in mould wood matrix surface to thickness be 0.1mm,
Prepare antibacterial mould wood A1.
Embodiment 2
1) 100g water, 100g acrylate and vinyl acetate emulsion, 17g styrene-acrylic emulsion, 4g nano-calcium carbonate, 45g are slided
Stone powder, 2g termil and 1.2g Zinc Pyrithione are placed in the bar that stir speed (S.S.) is 300r/min
Stirring mixing under part, prepares antimicrobial coating M1；
2) above-mentioned prepared antimicrobial coating M1 is applied in mould wood matrix surface to thickness be 1mm, system
Antibacterial must mould wood A2.
Embodiment 3
1) 100g water, 90g acrylate and vinyl acetate emulsion, 15g styrene-acrylic emulsion, 3g nano-calcium carbonate, 40g are slided
Stone powder, 2g termil and 1g Zinc Pyrithione are placed in the condition that stir speed (S.S.) is 200r/min
Lower stirring mixing, prepares antimicrobial coating M1；
2) above-mentioned prepared antimicrobial coating M1 is applied in mould wood matrix surface to thickness be 0.5mm,
Prepare antibacterial mould wood A3.
Embodiment 4
Being prepared according to the preparation method of embodiment 1, except for the difference that, the consumption of described acrylate and vinyl acetate emulsion is
50g, the consumption of described styrene-acrylic emulsion is 10g, and the consumption of described nano-calcium carbonate is 1g, described Talcum
The consumption of powder is 30g, and the consumption of described termil is 0.1g, the use of described Zinc Pyrithione
Amount for 0.5g, prepares and antibacterial moulds wood A4.
Embodiment 5
Being prepared according to the preparation method of embodiment 2, except for the difference that, the consumption of described acrylate and vinyl acetate emulsion is
120g, the consumption of described styrene-acrylic emulsion is 20g, and the consumption of described nano-calcium carbonate is 5g, described Talcum
The consumption of powder is 50g, and the consumption of described termil is 2g, the consumption of described Zinc Pyrithione
For 1.5g, prepare and antibacterial mould wood A5.
Comparative example 1
Being prepared according to the preparation method of embodiment 3, except for the difference that, the consumption of described acrylate and vinyl acetate emulsion is
20g, the consumption of described styrene-acrylic emulsion is 5g, and the consumption of described nano-calcium carbonate is 0.5g, described Talcum
The consumption of powder is 10g, prepares and moulds wood D1.
Comparative example 2
Being prepared according to the preparation method of embodiment 3, except for the difference that, the consumption of described acrylate and vinyl acetate emulsion is
200g, the consumption of described styrene-acrylic emulsion is 30g, and the consumption of described nano-calcium carbonate is 10g, described cunning
The consumption of stone powder is 80g, and the consumption of described termil is 5g, the use of described Zinc Pyrithione
Amount is 3g, prepares and moulds wood D2.
Comparative example 3
Mould wood matrix D3.
Test case
Above-mentioned A1-A5 and D1-D3 is respectively placed in bacterial content more in the environment of 30 days, then
Take the above-mentioned wood 1g that moulds respectively and be placed in 100g sterilized water immersion, the total plate count in detection 1g water, obtain
The result arrived is as shown in table 1.
Table 1
| Numbering | Total plate count (cfu) |
| A1 | 15 |
| A2 | 19 |
| A3 | 16 |
| A4 | 35 |
| A5 | 32 |
| D1 | ＞ 100 |
| D2 | ＞ 100 |
| D3 | ＞ 100 |
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality
Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention
Case carries out multiple simple variant, and these simple variant belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special
Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not
The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its
Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. an antibacterial plastic-wood material compositions, it is characterised in that described compositions includes moulding wood matrix
Be applied in described in mould wood outer surface of matrix on antimicrobial coating, wherein, described antimicrobial coating include water,
Acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, termil and Zinc Pyrithione；
Wherein,
Relative to the described water of 100 weight portions, the content of described acrylate and vinyl acetate emulsion is 50-120 weight portion,
The content of described styrene-acrylic emulsion is 10-20 weight portion, and the content of described nano-calcium carbonate is 1-5 weight portion,
Described talcous content is 30-50 weight portion, and the content of described termil is 0.1-2 weight
Amount part, the content of described Zinc Pyrithione is 0.5-1.5 weight portion.
Compositions the most according to claim 1, wherein, relative to the described water of 100 weight portions,
The content of described acrylate and vinyl acetate emulsion is 80-100 weight portion, and the content of described styrene-acrylic emulsion is 13-17 weight portion,
The content of described nano-calcium carbonate is 2-4 weight portion, and described talcous content is 35-45 weight portion,
The content of described termil is 1-2 weight portion, and the content of described Zinc Pyrithione is 0.8-1.2
Weight portion.
Compositions the most according to claim 1 and 2, wherein, described antimicrobial coating also includes adding
Work auxiliary agent；
Preferably, described processing aid is selected from anti ultraviolet agent and/or antistatic additive.
Compositions the most according to claim 1 and 2, wherein, the particle diameter of described nano-calcium carbonate
For 50-500nm.
5. the antibacterial preparation method moulding wood, it is characterised in that described preparation method includes:
1) by water, acrylate and vinyl acetate emulsion, styrene-acrylic emulsion, nano-calcium carbonate, Pulvis Talci, tetrachloro isophthalic diformazan
Nitrile and Zinc Pyrithione mixing, prepare antimicrobial coating M1；
2) above-mentioned prepared antimicrobial coating M1 is applied in moulds wood matrix surface, prepare and antibacterial mould wood；
Wherein,
Relative to the described water of 100 weight portions, the consumption of described acrylate and vinyl acetate emulsion is 50-120 weight portion,
The consumption of described styrene-acrylic emulsion is 10-20 weight portion, and the consumption of described nano-calcium carbonate is 1-5 weight portion,
Described talcous consumption is 30-50 weight portion, and the consumption of described termil is 0.1-2 weight
Amount part, the consumption of described Zinc Pyrithione is 0.5-1.5 weight portion.
Preparation method the most according to claim 5, wherein, described in 100 weight portions
Water, the consumption of described acrylate and vinyl acetate emulsion is 80-100 weight portion, and the consumption of described styrene-acrylic emulsion is 13-17 weight
Amount part, the consumption of described nano-calcium carbonate is 2-4 weight portion, and described talcous consumption is 35-45 weight
Amount part, the consumption of described termil is 1-2 weight portion, and the consumption of described Zinc Pyrithione is
0.8-1.2 weight portion.
7. according to the preparation method described in claim 5 or 6, wherein, step 1) in also include add
Processing aid mixes；
Preferably, described processing aid is selected from anti ultraviolet agent and/or antistatic additive；
It is further preferable that the particle diameter of described nano-calcium carbonate is 50-500nm.
8. according to the preparation method described in claim 5 or 6, wherein, step 1) in mixed process be
Being placed in stir speed (S.S.) is stirring mixing under conditions of 100-300r/min.
9. antibacterial mould wood according to what the preparation method described in any one in claim 5-8 prepared for one kind.
The most according to claim 9 antibacterial moulding wood, wherein, the thickness of antimicrobial coating is 0.1-1mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610570914.0A CN106009982A (en) | 2016-07-20 | 2016-07-20 | Antibacterial plastic-wood material composition, antibacterial plastic-wood and method for preparing same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610570914.0A CN106009982A (en) | 2016-07-20 | 2016-07-20 | Antibacterial plastic-wood material composition, antibacterial plastic-wood and method for preparing same |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
| CN203201109U (en) * | 2013-04-07 | 2013-09-18 | 领亿新材料(福建)科技有限公司 | Environment-friendly PE (Polyethylene) wood-plastic floor board with high strength |
-
2016
- 2016-07-20 CN CN201610570914.0A patent/CN106009982A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
| CN203201109U (en) * | 2013-04-07 | 2013-09-18 | 领亿新材料(福建)科技有限公司 | Environment-friendly PE (Polyethylene) wood-plastic floor board with high strength |
Non-Patent Citations (1)
| Title |
|---|
| 林宣益: "《乳胶漆》", 31 July 2004, 化学工业出版社 * |
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