CN108504228A - A kind of water nano modification acrylate insecticidal and antibacterial coating and preparation method thereof - Google Patents
A kind of water nano modification acrylate insecticidal and antibacterial coating and preparation method thereof Download PDFInfo
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- CN108504228A CN108504228A CN201810345529.5A CN201810345529A CN108504228A CN 108504228 A CN108504228 A CN 108504228A CN 201810345529 A CN201810345529 A CN 201810345529A CN 108504228 A CN108504228 A CN 108504228A
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- insecticidal
- antibacterial coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
A kind of water nano modification acrylate insecticidal and antibacterial coating of present invention offer and preparation method thereof, raw material include following components by weight：80 100 parts of acrylic acid ester emulsion, 10 15 parts of nano titania slurry, 46 parts of antimicrobial nano titanium dioxide, 6 12 parts of oligomeric acrylic acid sodium solution, 15 25 parts of titanium dioxide, 10 20 parts of powdered whiting, 8 10 parts of talcum powder, 13 parts of Belmark, 0.5 1.0 parts of dispersant, 0.2 0.5 parts of antifoaming agent, 1.0 2.5 parts of coalescents, 0.5 0.8 parts of thickener, 60 80 parts of deionized water.
Description
Technical field
The present invention relates to paint fields, and in particular to a kind of water nano modification acrylate insecticidal and antibacterial coating and its system
Preparation Method.
Background technology
Insect-disinfestation environment friendly paint is that have the function of that killing fly, mosquito, cockroach, bedbug and acarid etc. influences the pest of health
Coating, while having both dicoration.Being detected through health and epidemic prevention station proves, insect-disinfestation environment friendly paint is used for a long time to person poultry harmless, because
Insect-disinfestation environment friendly paint is rather than the smell smoked kill by contact desinsection.The coating products can spray as common coating products
Painting, roller coating, brush application, scrubbing resistance is without influencing insecticidal effect.The characteristics of insect-disinfestation environment friendly paint, is as follows：1）Insect-disinfestation environment friendly paint
Effect is peculiar, for building coating, interior wall coating significant effect；2）Insect-disinfestation environment friendly paint is bright and colourful, can decorate out graceful sage
Clean effect；3）Insect-disinfestation environment friendly paint be it is scientific and effective cut free of contamination disinsection method, meet the characteristic requirements of environmental protection coating material, be
A kind of novel building coating.
Antibiotic paint is that there is the coating of antibacterial action to be known as antibiotic paint.Being mainly characterized by for building mildew resistant paint is this kind of
Coating both has excellent fungicidal properties, but also with good decoration performance.Microorganism is widely present in nature, usual mould
Natural conditions suitable for flourish are 23 DEG C~38 DEG C of temperature, and relative humidity is 85%~100%, therefore building in warm and humid area
Build the life of the suitable mould such as metope and other regional constant temperature, the metope in constant humidity workshop, ceiling, ground, underground engineerings inside and outside object
Long, they multiply rapid and thus bear the metabolite of various enzymes, acid and toxin, to influence the appearance and quality of article,
And environment is polluted, endanger the growth of animals and plants and the health of the mankind.If, will be by mould difference using general decor coating
The erosion of degree, mould is even more serious for the erosion of organic paint coatings, can be faded, is stained with by the later coating of mold corrosion
It is dirty, so that falling off.This is because mould corrodes after film, enzyme can be secreted out of, these secretion can be decomposed further in coating
Organic binder matter becomes the nutriment of fungus growth to destroy entire coating.Especially in the feelings in southern china rainy season
Under condition, should more it pay attention to.So in many southern areas and humidity place, mould proof is part a matter of great account feelings, for building
The mould proof of object should cause enough attention, and it is to solve the problems, such as this effective measures to use mildew resistant paint brushing wall and ground
One of.Mildew resistant paint has the double effects of building decoration and mildew-proof function.When having efficient and longer extensively to mould, saccharomycete
Between sterilization and rejection ability.This kind of coating that is mainly characterized by of building mildew resistant paint not only has excellent fungicidal properties, but also tool
Standby good decoration performance.After the building surface that mould is easy in the environment grown is brushed on mildew resistant paint, building
Just it is not easy mouldy, and because building mildew resistant paint is inner, external wall, ceiling or ground for building, thus must also have
There is preferable decoration function.Typically achieved the goal by adding certain suppression mycostat in coating.
Insect-disinfestation environment friendly paint and antibiotic fungus-resisting paint coating type are various, are widely used in many fields.
In existing coating it is most of be all single effect insecticidal paint and antibiotic fungus-resisting paint it is relatively more, there are no a qualification,
Security performance is high, existing insecticidal effect, also water nano modification acrylate insecticidal and antibacterial coating with antibacterial and mouldproof
Sale.
Invention content
The purpose of the present invention provides a kind of water nano modification acrylate insecticidal and antibacterial painting aiming at existing issue
Material, a kind of water nano modification acrylate insecticidal and antibacterial coating add nanometer two using acrylic acid ester emulsion as film forming matter
Titania slurry, antimicrobial nano titanium dioxide, titanium dioxide, powdered whiting, talcum powder and the oligomerisation of propene with insecticidal effect
Simultaneously part of auxiliary is added in acid sodium solution and Belmark, a kind of water nano modification acrylate insecticidal and antibacterial being prepared
Coating.A kind of this kind of water nano modification acrylate insecticidal and antibacterial coating not only have good low-temperature stability, water resistance,
Alkali resistance, abrasion resistance, weatherability, polluting proofing property and ageing resistance, and with antibacterial bacteriostatic, antibacterial and mouldproof, high-decoration,
The advantages that breathing damping, environmentally protective and insecticidal and antibacterial.
Another object of the present invention is to provide a kind of water nano modification acrylate insecticidal and antibacterial coating and its preparations
Method, it is easy to operate, it can extensive use.
The technical solution adopted in the present invention is as follows to achieve the above object：A kind of water nano modification acrylate desinsection
Antibiotic paint, raw material include following components by weight：80-100 parts of acrylic acid ester emulsion, nano titania slurry 10-
15 parts, 4-6 parts of antimicrobial nano titanium dioxide, 6-12 parts of oligomeric acrylic acid sodium solution, 15-25 parts of titanium dioxide, powdered whiting 10-
20 parts, 8-10 parts of talcum powder, 1-3 parts of Belmark, 0.5-1.0 parts of dispersant, 0.2-0.5 parts of antifoaming agent, coalescents
1.0-2.5 parts, 0.5-0.8 parts of thickener, 60-80 parts of deionized water.
Further, the titanium dioxide is rutile type titanium white.
Further, the talcum powder is superfine talcum powder.
Further, the dispersant be sodium tripolyphosphate, calgon, sodium pyrophosphate, lauryl sodium sulfate,
It is one or more in neopelex, methyl anyl alcohol, polyacrylamide.
Further, the antifoaming agent is organic silicon antifoaming agent, mineral oil defoaming agent or combinations thereof.
Further, the thickener is methylcellulose, hydroxypropyl methyl cellulose, polyacrylamide, polyethylene
It is one or more in alcohol, polyvinylpyrrolidone, polyethylene glycol oxide, polyacrylic acid or Sodium Polyacrylate.
Further, preparation method includes the following steps：
S10, required various materials are weighed as required；
S11, quantitative nano material is added in certain density dispersing aid, it is pre-dispersed with ultrasonic wave separating apparatus；
S12, Jiang Shui, the various auxiliary agents pre-processed, scattered nano material are put into high speed dispersor and disperse；
S13, antimicrobial nano titanium dioxide, titanium dioxide, powdered whiting, talcum powder is added, after high speed dispersion is uniform, into sand
Grinding machine is ground to suitable fineness；
S14, it is eventually adding acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, Belmark, low speed dispersion mixing is uniformly
It can be to get to required this kind of water nano modification acrylate insecticidal and antibacterial coating.
It is compared with the prior art, the invention has the advantages that：
1, nano titania slurry and antimicrobial nano titanium dioxide are added in the present invention has shielding ultraviolet rays effect strong, prevents
The only infringement of ultraviolet light improves the service life of coating.Meanwhile higher hardness, density, dielectric constant and refractive index,
The covering power and tinting strength, tinting power of coating are helped to improve, and has good reflex to the heat radiation in sunlight；The nanometer two
Titania slurry cooperation antimicrobial nano titanium dioxide makes coating have efficiency light caloytic action so that the coating has good virtue
The functions such as fragrance, scrub resistance and antibiotic and sterilizing；
2, after nano-titanium dioxide is added in invention, the scattered property of light of nano material is good, and granularity is small and is evenly distributed, and applies
Material covering power is significantly improved, and improves the workability of coating.And the aqueous of composite nano titanium dioxide added is built
Building coating has sterilizing function, and the coating containing nano-titanium dioxide is after ultraviolet light irradiates 20-30min, to Staphylococcus aureus
Bacterium, Escherichia coli bactericidal effect are preferable；
3, a kind of water nano that the oligomeric acrylic acid sodium solution and Belmark added in the present invention prepares gained is modified third
Olefin(e) acid ester insecticidal and antibacterial coating, can expel, tag various pests of going out quick and durablely, and more more environmentally-friendly than common coating
It is nontoxic；
4, a kind of water nano modification acrylate insecticidal and antibacterial coating of the invention not only has good armaticity, water-fast
Property, alkali resistance, abrasion resistance, weatherability, polluting proofing property and ageing resistance, but also with antibacterial bacteriostatic, antibacterial and mouldproof, high dress
The advantages that decorations property, breathing damping, environmentally protective and insecticidal and antibacterial.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.The specific embodiments described herein are merely illustrative of the present invention, is not used to limit
The present invention.
Embodiment 1
A kind of water nano modification acrylate insecticidal and antibacterial coating, raw material include following components by weight：Acrylate
80 parts of lotion, 10 parts of nano titania slurry, 4 parts of antimicrobial nano titanium dioxide, 6 parts of oligomeric acrylic acid sodium solution, titanium dioxide
15 parts, 10 parts of powdered whiting, 8 parts of talcum powder, 1 part of Belmark, 0.5 part of dispersant, 0.2 part of antifoaming agent, coalescents
1.0 parts, 0.5 part of thickener, 60 parts of deionized water.
The titanium dioxide is rutile type titanium white.
The talcum powder is superfine talcum powder.
The dispersant is calgon.
The antifoaming agent is organic silicon antifoaming agent.
The thickener is methylcellulose.
Preparation method includes the following steps：
S10, required various materials are weighed as required；
S11, quantitative nano material is added in certain density dispersing aid, it is pre-dispersed with ultrasonic wave separating apparatus；
S12, Jiang Shui, the various auxiliary agents pre-processed, scattered nano material are put into high speed dispersor and disperse；
S13, antimicrobial nano titanium dioxide, titanium dioxide, powdered whiting, talcum powder is added, after high speed dispersion is uniform, into sand
Grinding machine is ground to suitable fineness；
S14, it is eventually adding acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, Belmark, low speed dispersion mixing is uniformly
It can be to get to required this kind of water nano modification acrylate insecticidal and antibacterial coating.
Embodiment 2
A kind of water nano modification acrylate insecticidal and antibacterial coating, raw material include following components by weight：Acrylate
100 parts of lotion, 15 parts of nano titania slurry, 6 parts of antimicrobial nano titanium dioxide, 12 parts of oligomeric acrylic acid sodium solution, titanium white
25 parts of powder, 20 parts of powdered whiting, 10 parts of talcum powder, 3 parts of Belmark, 1.0 parts of dispersant, 0.5 part of antifoaming agent, film forming
2.5 parts of auxiliary agent, 0.8 part of thickener, 80 parts of deionized water.
The titanium dioxide is rutile type titanium white.
The talcum powder is superfine talcum powder.
The dispersant is sodium tripolyphosphate.
The antifoaming agent is mineral oil defoaming agent.
The thickener is hydroxypropyl methyl cellulose.
Preparation method includes the following steps：
S10, required various materials are weighed as required；
S11, quantitative nano material is added in certain density dispersing aid, it is pre-dispersed with ultrasonic wave separating apparatus；
S12, Jiang Shui, the various auxiliary agents pre-processed, scattered nano material are put into high speed dispersor and disperse；
S13, antimicrobial nano titanium dioxide, titanium dioxide, powdered whiting, talcum powder is added, after high speed dispersion is uniform, into sand
Grinding machine is ground to suitable fineness；
S14, it is eventually adding acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, Belmark, low speed dispersion mixing is uniformly
It can be to get to required this kind of water nano modification acrylate insecticidal and antibacterial coating.
Embodiment 3
A kind of water nano modification acrylate insecticidal and antibacterial coating, raw material include following components by weight：Acrylate
90 parts of lotion, 12 parts of nano titania slurry, 5 parts of antimicrobial nano titanium dioxide, 9 parts of oligomeric acrylic acid sodium solution, titanium dioxide
18 parts, 15 parts of powdered whiting, 9 parts of talcum powder, 2 parts of Belmark, 0.6 part of dispersant, 0.3 part of antifoaming agent, coalescents
1.5 parts, 0.6 part of thickener, 70 parts of deionized water.
The titanium dioxide is rutile type titanium white.
The talcum powder is superfine talcum powder.
The dispersant is sodium pyrophosphate.
The antifoaming agent is organic silicon antifoaming agent.
The thickener is polyacrylamide.
Preparation method includes the following steps：
S10, required various materials are weighed as required；
S11, quantitative nano material is added in certain density dispersing aid, it is pre-dispersed with ultrasonic wave separating apparatus；
S12, Jiang Shui, the various auxiliary agents pre-processed, scattered nano material are put into high speed dispersor and disperse；
S13, antimicrobial nano titanium dioxide, titanium dioxide, powdered whiting, talcum powder is added, after high speed dispersion is uniform, into sand
Grinding machine is ground to suitable fineness；
S14, it is eventually adding acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, Belmark, low speed dispersion mixing is uniformly
It can be to get to required this kind of water nano modification acrylate insecticidal and antibacterial coating.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (7)
1. a kind of water nano modification acrylate insecticidal and antibacterial coating, which is characterized in that its raw material includes following by weight
Component：It is 80-100 parts of acrylic acid ester emulsion, 10-15 parts of nano titania slurry, 4-6 parts of antimicrobial nano titanium dioxide, oligomeric
6-12 parts of sodium acrylate solution, 15-25 parts of titanium dioxide, 10-20 parts of powdered whiting, 8-10 parts of talcum powder, Belmark 1-3
Part, 0.5-1.0 parts of dispersant, 0.2-0.5 parts of antifoaming agent, 1.0-2.5 parts of coalescents, 0.5-0.8 parts of thickener, go from
Sub- water 60-80 parts.
2. according to a kind of water nano modification acrylate insecticidal and antibacterial coating described in claim 1, it is characterised in that：Institute
The titanium dioxide stated is rutile type titanium white.
3. according to a kind of water nano modification acrylate insecticidal and antibacterial coating described in claim 1, it is characterised in that：Institute
The talcum powder stated is superfine talcum powder.
4. according to a kind of water nano modification acrylate insecticidal and antibacterial coating described in claim 1, it is characterised in that：Institute
The dispersant stated is sodium tripolyphosphate, calgon, sodium pyrophosphate, lauryl sodium sulfate, neopelex, first
It is one or more in base amylalcohol, polyacrylamide.
5. according to a kind of water nano modification acrylate insecticidal and antibacterial coating described in claim 1, it is characterised in that：Institute
The antifoaming agent stated is organic silicon antifoaming agent, mineral oil defoaming agent or combinations thereof.
6. according to a kind of water nano modification acrylate insecticidal and antibacterial coating described in claim 1, it is characterised in that：Institute
The thickener stated is methylcellulose, hydroxypropyl methyl cellulose, polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, gathers
It is one or more in ethylene oxide, polyacrylic acid or Sodium Polyacrylate.
7. according to a kind of water nano modification acrylate insecticidal and antibacterial coating described in claim 1, it is characterised in that：Its
Preparation method includes the following steps：
S10, required various materials are weighed as required；
S11, quantitative nano material is added in certain density dispersing aid, it is pre-dispersed with ultrasonic wave separating apparatus；
S12, Jiang Shui, the various auxiliary agents pre-processed, scattered nano material are put into high speed dispersor and disperse；
S13, antimicrobial nano titanium dioxide, titanium dioxide, powdered whiting, talcum powder is added, after high speed dispersion is uniform, into sand
Grinding machine is ground to suitable fineness；
S14, it is eventually adding acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, Belmark, low speed dispersion mixing is uniformly
It can be to get to required this kind of water nano modification acrylate insecticidal and antibacterial coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810345529.5A CN108504228A (en) | 2018-04-17 | 2018-04-17 | A kind of water nano modification acrylate insecticidal and antibacterial coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810345529.5A CN108504228A (en) | 2018-04-17 | 2018-04-17 | A kind of water nano modification acrylate insecticidal and antibacterial coating and preparation method thereof |
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| CN108504228A true CN108504228A (en) | 2018-09-07 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111909436A (en) * | 2020-08-28 | 2020-11-10 | 新乡亿博环保科技有限公司 | Environment-friendly garbage collection barrel and preparation method thereof |
| CN111944186A (en) * | 2020-08-28 | 2020-11-17 | 新乡亿博环保科技有限公司 | Durable anti-aging rural septic tank and preparation method thereof |
-
2018
- 2018-04-17 CN CN201810345529.5A patent/CN108504228A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111909436A (en) * | 2020-08-28 | 2020-11-10 | 新乡亿博环保科技有限公司 | Environment-friendly garbage collection barrel and preparation method thereof |
| CN111944186A (en) * | 2020-08-28 | 2020-11-17 | 新乡亿博环保科技有限公司 | Durable anti-aging rural septic tank and preparation method thereof |
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Application publication date: 20180907 |