CN108485391A - A kind of straw ecotypic environmental protection coating material and preparation method thereof - Google Patents
A kind of straw ecotypic environmental protection coating material and preparation method thereof Download PDFInfo
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- CN108485391A CN108485391A CN201810229408.4A CN201810229408A CN108485391A CN 108485391 A CN108485391 A CN 108485391A CN 201810229408 A CN201810229408 A CN 201810229408A CN 108485391 A CN108485391 A CN 108485391A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of straw ecotypic environmental protection coating material and preparation method thereof, coating includes following components and parts by weight content：20 25 parts of lotion, 5 10 parts of natural colour sand, 23 parts of rubber powder, 0.2 0.5 parts of cellulose ether, 0.6 1.5 parts of diatomite, 0.1 0.6 parts of antimildew and antibacterial agent, 24 parts of coalescents, 24 parts of dispersant, 45 parts of antifoaming agent, 23 parts of thickener, 10 15 parts of deionized water, 45 parts of wood pulp, 0.5 0.7 parts of the rice straw that length is 0.1 0.5cm, 0.7 0.9 parts of the rice straw that length is 0.5 1cm, 0.8 1 parts of the rice straw that length is 1 1.5cm.Compared with prior art, after coating use of the present invention, concave-convex texture more true to nature can be built, it is coating anticracking, heat preservation, heat-insulated, with ecological decoration modelled after an antique, have the function of damping, decomposing formaldehyde, sterilizing deodoring, anticorrosive mildewproof, helps to improve indoor environment.
Description
Technical field
The present invention relates to a kind of coating, more particularly, to a kind of straw ecotypic environmental protection coating material and preparation method thereof.
Background technology
After grain gathers in, sheet of straw is by on-site incineration.It burns straw and both pollutes atmospheric environment, destroy ecology, change
Become soil texture, be also unfavorable for energy saving, develops a circular economy.In life, wall finiss is the master that metope is used in finishing
Final coating in one of decoration materials wanted, especially application has decoration and defencive function.What wall finiss had at present has a single function
And not environmentally friendly enough disadvantage.
With the continuous improvement of people's quality of the life, the understanding of coating is also continuously improved in people, space alteration in recent years,
People place is developed rapidly, and pseudo-classic and Chinese feature obtains more and more people and likes.In the wall decorations of people place, need more
More trend of back-to-ancients, Chinese feature and rural area wind makes environmental protection coating material by using straw, the finishing for wall can yet be regarded as it is a kind of compared with
Good outlet.
Invention content
The purpose of the present invention is exactly to solve the above-mentioned problems and provides a kind of straw ecotypic environmental protection coating material and its preparation side
Method.
The purpose of the present invention is achieved through the following technical solutions：
A kind of straw ecotypic environmental protection coating material, including following components and parts by weight content：20-25 parts of lotion, natural colour sand 5-
10 parts, 2-3 parts of rubber powder, 0.2-0.5 parts of cellulose ether, 0.6-1.5 parts of diatomite, 0.1-0.6 parts of antimildew and antibacterial agent, coalescents
2-4 parts, 2-4 parts of dispersant, 4-5 parts of antifoaming agent, 2-3 parts of thickener, 10-15 parts of deionized water, 4-5 parts of wood pulp, length be
0.7-0.9 parts of rice straw that 0.5-0.7 parts of the rice straw of 0.1-0.5cm, length are 0.5-1cm, length are 1-1.5cm's
0.8-1 parts of rice straw.
The lotion is styrene-acrylic emulsion, silicone acrylic emulsion or pure acrylate elastic emulsion.
The natural colour sand is selected from the yellow sand that granularity is 20-40 mesh.
The rubber powder is cinnamic acrylic ester or VAE rubber powders.
The cellulose ether is hydroxyethyl cellulose or methylcellulose.
The antimildew and antibacterial agent is benzimidazole methyl carbamate.
The coalescents be propandiol butyl ether, propylene glycol methyl ether acetate, butyl glycol ether or propylene glycol phenylate one
Kind is a variety of.
The dispersant is polycarboxylate sodium's anionic dispersing agents.
The thickener is polyurethanes thickener, and the antifoaming agent is metal soap antifoaming agent.
A kind of preparation method of straw ecotypic environmental protection coating material, includes the following steps：
(1) rice straw cleaned, sterilized, crush it is spare；
(2) lotion and wood pulp are mixed, natural colour sand, rubber powder and diatomite is added, stirs evenly；
(3) be added rice straw, sequentially add cellulose ether, antimildew and antibacterial agent, coalescents, dispersant, antifoaming agent,
Thickener, deionized water, stir evenly, and obtain product.
Compared with prior art, the invention has the advantages that：
1, rice straw is used in inventive formulation, rice straw is mainly in view of itself and painting by three kinds of distribution of lengths
The mixed of material dissipates, and the rice straw of three kinds of length can carry out grading, has nature rural area wind after taking thin mix with natural colour sand essence, uses
Afterwards, it is applied on wall, concave-convex texture more true to nature can be built, rice straws at different levels are distributed on surface layer, ensure that wall
Moulding.
2, rice straw is preferably mixed by the effect of wood pulp, cellulose ether and rubber powder with lotion, improves coating
Adhesiveness, it is anticracking, heat preservation, heat-insulated, there is ecological decoration modelled after an antique.
3, the diatomite used in being formulated, diatomite have damping, decomposing formaldehyde, sterilizing deodoring, anti-corrosion with rice straw
Mould proof function, antimildew and antibacterial agent can penetrate into rice straw and diatomaceous gap, help avoid going mouldy for wall,
Help to improve indoor environment.
4, in being formulated, by the mutual reconciliation of each component, after film-forming, be not in albinism of saltouing, do not generate
The harmful substances such as VOC, benzene, formaldehyde heavy metal are conducive to health, and straw ecological paint is at low cost, can save people's spending,
Preparation process is simple, easy to operate simultaneously.
Specific implementation mode
With reference to specific embodiment, the present invention is described in detail, but should be in no way restrictive.
Embodiment 1
A kind of straw ecotypic environmental protection coating material, including following components：Lotion 20kg, natural colour sand 5kg, rubber powder 2kg, cellulose
Ether 0.2kg, diatomite 0.6kg, antimildew and antibacterial agent 0.1kg, coalescents 2kg, dispersant 2kg, antifoaming agent 4kg, thickener
The straw straw that rice straw 0.5kg that 2kg, deionized water 10kg, wood pulp 4kg, length are 0.1-0.5cm, length are 0.5-1cm
Stalk 0.7kg, the rice straw 0.8kg that length is 1-1.5cm.
Wherein, lotion is styrene-acrylic emulsion, and natural colour sand is selected from the yellow sand that granularity is 20-40 mesh, and rubber powder is styrene-propene
Acid esters, cellulose ether are hydroxyethyl cellulose, and antimildew and antibacterial agent is benzimidazole methyl carbamate, and coalescents are propylene glycol
Butyl ether, dispersant are polycarboxylate sodium's anionic dispersing agents, and thickener is polyurethanes thickener, and antifoaming agent disappears for metal soap
Infusion.
When preparation, as follows：
(1) rice straw cleaned, sterilized, crush it is spare；
(2) lotion and wood pulp are mixed, natural colour sand, rubber powder and diatomite is added, stirs evenly；
(3) be added rice straw, sequentially add cellulose ether, antimildew and antibacterial agent, coalescents, dispersant, antifoaming agent,
Thickener, deionized water, stir evenly, and obtain product.
Embodiment 2
A kind of straw ecotypic environmental protection coating material, including following components：Lotion 25kg, natural colour sand 10kg, rubber powder 3kg, fiber
Plain ether 0.5kg, diatomite 1.5kg, antimildew and antibacterial agent 0.6kg, coalescents 4kg, dispersant 4kg, antifoaming agent 5kg, thickener
The straw straw that rice straw 0.7kg that 3kg, deionized water 15kg, wood pulp 5kg, length are 0.1-0.5cm, length are 0.5-1cm
Stalk 0.9kg, the rice straw 1kg that length is 1-1.5cm.
Wherein, lotion is pure acrylate elastic emulsion, and natural colour sand is selected from the yellow sand that granularity is 20-40 mesh, and rubber powder is VAE glue
Powder, cellulose ether are methylcellulose, and antimildew and antibacterial agent is benzimidazole methyl carbamate, and coalescents are propylene glycol monomethyl ether
Acetate, dispersant are polycarboxylate sodium's anionic dispersing agents, and thickener is polyurethanes thickener, and antifoaming agent is metal soap
Antifoaming agent.
Preparation method is same as Example 1.
Embodiment 3
A kind of straw ecotypic environmental protection coating material, including following components：Lotion 22kg, natural colour sand 7kg, rubber powder 2.5kg, fiber
Plain ether 0.3kg, diatomite 1.3kg, antimildew and antibacterial agent 0.5kg, coalescents 3kg, dispersant 3kg, antifoaming agent 4.5kg, thickening
Rice straw 0.6kg that agent 2.5kg, deionized water 13kg, wood pulp 4.4kg, length are 0.1-0.5cm, length are 0.5-1cm's
Rice straw 0.8kg, the rice straw 0.9kg that length is 1-1.5cm.Wherein, lotion is silicone acrylic emulsion, remaining and embodiment 1
It is identical.
Embodiment 1-3 is detected by standard JG/T24-2000, the results are shown in Table 1.
1 embodiment 1-3 testing results of table
Claims (10)
1. a kind of straw ecotypic environmental protection coating material, which is characterized in that including following components and parts by weight content：20-25 parts of lotion, day
Right 5-10 parts of color sand, 2-3 parts of rubber powder, 0.2-0.5 parts of cellulose ether, 0.6-1.5 parts of diatomite, 0.1-0.6 parts of antimildew and antibacterial agent,
2-4 parts of coalescents, 2-4 parts of dispersant, 4-5 parts of antifoaming agent, 2-3 parts of thickener, 10-15 parts of deionized water, 4-5 parts of wood pulp,
0.7-0.9 parts of rice straw that 0.5-0.7 parts of the rice straw that length is 0.1-0.5cm, length are 0.5-1cm, length 1-
0.8-1 parts of the rice straw of 1.5cm.
2. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the lotion be styrene-acrylic emulsion,
Silicone acrylic emulsion or pure acrylate elastic emulsion.
3. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the natural colour sand is selected from granularity
For the yellow sand of 20-40 mesh.
4. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the rubber powder is styrene-the third
Olefin(e) acid ester or VAE rubber powders.
5. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the cellulose ether is ethoxy
Cellulose or methylcellulose.
6. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the antimildew and antibacterial agent is benzo
Imidazole carbamate methyl esters.
7. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the coalescents are propylene glycol
Butyl ether, propylene glycol methyl ether acetate, butyl glycol ether or propylene glycol phenylate it is one or more.
8. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the dispersant is sodium polycarboxylate
Salt anionic dispersant.
9. a kind of straw ecotypic environmental protection coating material according to claim 1, which is characterized in that the thickener is polyurethanes
Thickener, the antifoaming agent are metal soap antifoaming agent.
10. a kind of a kind of preparation method of straw ecotypic environmental protection coating material as described in claim 1, which is characterized in that including such as
Lower step：
(1) rice straw cleaned, sterilized, crush it is spare；
(2) lotion and wood pulp are mixed, natural colour sand, rubber powder and diatomite is added, stirs evenly；
(3) rice straw is added, sequentially adds cellulose ether, antimildew and antibacterial agent, coalescents, dispersant, antifoaming agent, thickening
Agent, deionized water, stir evenly, and obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810229408.4A CN108485391A (en) | 2018-03-20 | 2018-03-20 | A kind of straw ecotypic environmental protection coating material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810229408.4A CN108485391A (en) | 2018-03-20 | 2018-03-20 | A kind of straw ecotypic environmental protection coating material and preparation method thereof |
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| CN108485391A true CN108485391A (en) | 2018-09-04 |
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| CN201810229408.4A Pending CN108485391A (en) | 2018-03-20 | 2018-03-20 | A kind of straw ecotypic environmental protection coating material and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825158A (en) * | 2019-02-26 | 2019-05-31 | 甘肃赛德丽漆业科技有限公司 | A kind of multi-functional wheat straw paint and preparation method thereof and wall construction method |
| CN110004765A (en) * | 2019-04-16 | 2019-07-12 | 滁州卷烟材料厂 | A kind of antimildew and antibacterial type aluminium-foil paper and its production technology |
| CN110093067A (en) * | 2019-05-27 | 2019-08-06 | 浙江省一建建设集团有限公司 | A kind of exterior wall diatomite paint of the existing cob wall of repairing and reinforcement |
| CN110374282A (en) * | 2019-07-26 | 2019-10-25 | 陕西古建园林建设有限公司 | Erosion resisting wheat straw mud plastering construction method |
| CN112322084A (en) * | 2020-12-07 | 2021-02-05 | 广东嘉宝莉科技材料有限公司 | Artistic coating with ecological effect in field and garden and preparation method thereof |
| CN113470478A (en) * | 2021-07-05 | 2021-10-01 | 宋晨 | Method for making clay calligraphy |
-
2018
- 2018-03-20 CN CN201810229408.4A patent/CN108485391A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109825158A (en) * | 2019-02-26 | 2019-05-31 | 甘肃赛德丽漆业科技有限公司 | A kind of multi-functional wheat straw paint and preparation method thereof and wall construction method |
| CN109825158B (en) * | 2019-02-26 | 2020-11-13 | 甘肃赛德丽漆业科技有限公司 | Multifunctional wheat straw paint, preparation method thereof and wall construction method |
| CN110004765A (en) * | 2019-04-16 | 2019-07-12 | 滁州卷烟材料厂 | A kind of antimildew and antibacterial type aluminium-foil paper and its production technology |
| CN110004765B (en) * | 2019-04-16 | 2021-07-13 | 滁州卷烟材料厂 | Mildew-proof antibacterial aluminum-foil paper and production process thereof |
| CN110093067A (en) * | 2019-05-27 | 2019-08-06 | 浙江省一建建设集团有限公司 | A kind of exterior wall diatomite paint of the existing cob wall of repairing and reinforcement |
| CN110374282A (en) * | 2019-07-26 | 2019-10-25 | 陕西古建园林建设有限公司 | Erosion resisting wheat straw mud plastering construction method |
| CN112322084A (en) * | 2020-12-07 | 2021-02-05 | 广东嘉宝莉科技材料有限公司 | Artistic coating with ecological effect in field and garden and preparation method thereof |
| CN113470478A (en) * | 2021-07-05 | 2021-10-01 | 宋晨 | Method for making clay calligraphy |
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Application publication date: 20180904 |