CN106008758B - 聚合方法 - Google Patents
聚合方法 Download PDFInfo
- Publication number
- CN106008758B CN106008758B CN201610400577.0A CN201610400577A CN106008758B CN 106008758 B CN106008758 B CN 106008758B CN 201610400577 A CN201610400577 A CN 201610400577A CN 106008758 B CN106008758 B CN 106008758B
- Authority
- CN
- China
- Prior art keywords
- paradigmatic system
- component
- paradigmatic
- polymerization
- monomer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
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- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 44
- 239000000178 monomer Substances 0.000 claims abstract description 44
- 238000009991 scouring Methods 0.000 claims abstract description 28
- 238000011010 flushing procedure Methods 0.000 claims description 40
- 229920000642 polymer Polymers 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000002002 slurry Substances 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 7
- 238000012685 gas phase polymerization Methods 0.000 claims description 6
- 238000000605 extraction Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229940060367 inert ingredients Drugs 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 34
- 239000007789 gas Substances 0.000 description 26
- 229910052757 nitrogen Inorganic materials 0.000 description 17
- 239000011261 inert gas Substances 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 12
- 238000010926 purge Methods 0.000 description 12
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- 230000008901 benefit Effects 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
- 239000000284 extract Substances 0.000 description 5
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 206010016825 Flushing Diseases 0.000 description 3
- 238000011143 downstream manufacturing Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002685 polymerization catalyst Substances 0.000 description 3
- 239000012429 reaction media Substances 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 108091092584 GDNA Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 230000001195 anabolic effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/007—Scale prevention in the auxiliary parts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Cleaning By Liquid Or Steam (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11195903.7 | 2011-12-28 | ||
| EP11195903 | 2011-12-28 | ||
| CN201280064881.2A CN103998474B (zh) | 2011-12-28 | 2012-12-20 | 聚合方法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280064881.2A Division CN103998474B (zh) | 2011-12-28 | 2012-12-20 | 聚合方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106008758A CN106008758A (zh) | 2016-10-12 |
| CN106008758B true CN106008758B (zh) | 2019-06-28 |
Family
ID=47428658
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610400577.0A Active CN106008758B (zh) | 2011-12-28 | 2012-12-20 | 聚合方法 |
| CN201280064881.2A Active CN103998474B (zh) | 2011-12-28 | 2012-12-20 | 聚合方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280064881.2A Active CN103998474B (zh) | 2011-12-28 | 2012-12-20 | 聚合方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9376517B2 (enExample) |
| EP (1) | EP2797964B1 (enExample) |
| CN (2) | CN106008758B (enExample) |
| BR (1) | BR112014016325A8 (enExample) |
| IN (1) | IN2014CN04797A (enExample) |
| RU (2) | RU2672566C1 (enExample) |
| SG (1) | SG11201403687TA (enExample) |
| WO (1) | WO2013098197A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2672566C1 (ru) * | 2011-12-28 | 2018-11-16 | Инеос Юроуп Аг | Способ полимеризации |
| KR20160103039A (ko) | 2013-12-23 | 2016-08-31 | 이네오스 유럽 아게 | 스캐빈저 주입 |
| US9683063B2 (en) | 2013-12-23 | 2017-06-20 | Ineos Europe Ag | Process |
| EP4171791A1 (en) * | 2020-06-24 | 2023-05-03 | ExxonMobil Chemical Patents Inc. | Processes for reducing shutdown time of sub-systems in low-density polyethylene production |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3525781A (en) * | 1965-05-17 | 1970-08-25 | Phillips Petroleum Co | Block copolymers prepared by feeding batch prepolymer into a continuous reactor |
| US4855370A (en) * | 1986-10-01 | 1989-08-08 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| US5264506A (en) * | 1992-12-30 | 1993-11-23 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing sticky polymers |
| EP1623999A1 (en) | 1993-04-26 | 2006-02-08 | ExxonMobil Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5332793A (en) * | 1993-06-28 | 1994-07-26 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene/propylene copolymer rubbers |
| US5376742A (en) * | 1993-09-23 | 1994-12-27 | Quantum Chemical Corporation | Monomer recovery in gas phase fluid bed olefin polymerization |
| FR2730999B1 (fr) | 1995-02-24 | 1997-04-18 | Bp Chemicals Snc | Appareillage et procede de polymerisation d'olefine en phase gazeuse |
| US5672666A (en) * | 1995-06-05 | 1997-09-30 | Exxon Chemical Patents Inc. | Process for transitioning between incompatible polymerization catalysts |
| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| CA2313244A1 (en) | 1997-12-08 | 1999-06-17 | Steven P. Diefenbach | Catalyst compositions of enhanced productivity |
| FI111953B (fi) * | 1998-11-12 | 2003-10-15 | Borealis Tech Oy | Menetelmä ja laite polymerointireaktoreiden tyhjentämiseksi |
| MXPA01006188A (es) | 1998-12-17 | 2005-04-19 | Univation Tech Llc | Modificador de catalizador y su uso en la polimerizacion de olefina (s). |
| US20040138057A1 (en) | 1998-12-21 | 2004-07-15 | Wenzel Timothy T. | Catalyst composition and methods for its preparation and use in a polymerization process |
| BR9906022A (pt) * | 1999-12-30 | 2001-09-25 | Opp Petroquimica S A | Processo para a produção controlada de polietileno e seus copolìmeros |
| US6713573B2 (en) * | 2000-11-30 | 2004-03-30 | Univation Technologies, Llc | Catalyst modifiers and their use in the polymerization of olefin(s) |
| ITME20020007A1 (it) * | 2002-06-10 | 2003-12-10 | Marcello Ferrara | Metodo, impianto, prodotti chimici e sistema di monitoraggio per la pulizia di apparecchiature petrolifere e la loro bonifica a gas free. |
| EP1660231B1 (en) * | 2004-02-13 | 2007-04-18 | Total Petrochemicals Research Feluy | Method and apparatus for preparing and supplying catalyst slurry to a polymerisation reactor |
| US7531606B2 (en) | 2004-05-26 | 2009-05-12 | Chevron Phillips Chemical Company Lp | Method for operating a gas phase polymerization reactor |
| US7323523B2 (en) | 2004-12-07 | 2008-01-29 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
| EP2054781B1 (en) * | 2006-08-25 | 2017-10-04 | Chevron Phillips Chemical Company Lp | Method and apparatus for managing volatile organic content in polyolefin |
| MX2009002495A (es) * | 2006-09-07 | 2009-05-22 | Univation Tech Llc | Metodos para determinacion en linea del grado de pegajosidad de resina usando un modelo para la reduccion de la temperatura de inicio de fusion. |
| US8124696B2 (en) * | 2009-11-20 | 2012-02-28 | Univation Technologies, Llc | Method of using an upper discharge in a fluidized bed reactor and system thereof |
| CN102421804B (zh) | 2009-04-24 | 2014-10-15 | 尤尼威蒂恩技术有限公司 | 在开路循环中用喷气压缩机使净化床再生 |
| CN101735348A (zh) * | 2009-12-30 | 2010-06-16 | 浙江大学 | 一种用于制备聚乙烯的双串联反应器工艺 |
| RU2672566C1 (ru) * | 2011-12-28 | 2018-11-16 | Инеос Юроуп Аг | Способ полимеризации |
-
2012
- 2012-12-20 RU RU2017126631A patent/RU2672566C1/ru active
- 2012-12-20 BR BR112014016325A patent/BR112014016325A8/pt not_active Application Discontinuation
- 2012-12-20 CN CN201610400577.0A patent/CN106008758B/zh active Active
- 2012-12-20 WO PCT/EP2012/076431 patent/WO2013098197A1/en not_active Ceased
- 2012-12-20 SG SG11201403687TA patent/SG11201403687TA/en unknown
- 2012-12-20 US US14/368,397 patent/US9376517B2/en active Active
- 2012-12-20 RU RU2014130907A patent/RU2626962C2/ru active
- 2012-12-20 EP EP12805712.2A patent/EP2797964B1/en not_active Revoked
- 2012-12-20 CN CN201280064881.2A patent/CN103998474B/zh active Active
- 2012-12-20 IN IN4797CHN2014 patent/IN2014CN04797A/en unknown
-
2016
- 2016-06-23 US US15/190,576 patent/US9868802B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20140343242A1 (en) | 2014-11-20 |
| EP2797964B1 (en) | 2016-07-13 |
| CN103998474A (zh) | 2014-08-20 |
| CN103998474B (zh) | 2016-07-06 |
| RU2672566C1 (ru) | 2018-11-16 |
| US9868802B2 (en) | 2018-01-16 |
| US20160297908A1 (en) | 2016-10-13 |
| US9376517B2 (en) | 2016-06-28 |
| RU2014130907A (ru) | 2016-02-20 |
| CN106008758A (zh) | 2016-10-12 |
| BR112014016325A2 (pt) | 2017-06-13 |
| BR112014016325A8 (pt) | 2017-07-04 |
| SG11201403687TA (en) | 2014-07-30 |
| EP2797964A1 (en) | 2014-11-05 |
| IN2014CN04797A (enExample) | 2015-09-18 |
| WO2013098197A1 (en) | 2013-07-04 |
| RU2626962C2 (ru) | 2017-08-02 |
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| GR01 | Patent grant | ||
| GR01 | Patent grant |