CN106008077A - Strawberry fertilizer capable of activating fertility of soil and preparation method of fertilizer - Google Patents
Strawberry fertilizer capable of activating fertility of soil and preparation method of fertilizer Download PDFInfo
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- CN106008077A CN106008077A CN201610324978.2A CN201610324978A CN106008077A CN 106008077 A CN106008077 A CN 106008077A CN 201610324978 A CN201610324978 A CN 201610324978A CN 106008077 A CN106008077 A CN 106008077A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Soil Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses strawberry fertilizer capable of activating fertility of soil. The fertilizer is prepared from raw materials in parts by weight as follows: 200-210 parts of a molasses alcohol waste liquid, 6-7 parts of oxygen-rich starch, 1-1.2 parts of monoammonium phosphate, 0.8-1 part of sorbitol, 10-12 parts of bran powder, 12-13 parts of humus, 20-21 parts of coco coir, 8-9 parts of seaweed meal, 8-9 parts of sawdust, 8-9 parts of turfy soil, 400-410 parts of 95% ethanol, 800-810 parts of a sodium hydroxide solution with the concentration being 0.5 mol/L, a proper amount of a hydrochloric acid solution with the concentration being 1 mol/L, a proper amount of a 50% sulfuric acid solution, 2-3 parts of rare earth oxide, 5-6 parts of polyvinyl alcohol, 0.2-0.3 parts of carbon nanotubes, 0.2-0.3 parts of beta-cyclodextrine, 0.1-0.2 parts of tea polyphenols and 1-1.2 parts of microbial powder. The quality of strawberries can be improved through chelating of amino acid prepared from the molasses alcohol waste liquid and rare earth, the mechanical strength of a film can be improved through addition of the carbon nanotubes to a film coating liquid, the slow-release property of the film can be improved through added tea polyphenols, and besides, the fertilizer can regulate and control the physical structure of the soil and the fertility of the soil and is applicable to improvement of poor and degraded soil.
Description
Technical field
The present invention relates to fertilizer processing technique field, particularly relate to a kind of can the Fructus Fragariae Ananssae fertilizer and preparation method thereof of activating soil fertility.
Background technology
Rare earth has Combined Physilogical Effects in plant growing process, both can solve soil trace element and lack problem, promote that again crop root is grown, and promotes Chlorophyll synthesis, improve photosynthesis, promote that crop root is grown, promote Chlorophyll synthesis, improve photosynthesis, promote the activity of enzyme, accelerate material to convert, improve the yield and quality of crop.But without chelating rare earth element, its crop absorption ratio is only a few one thousandth, and effect is excessively poor.Theoretical according to the coordinate bond of complex, this dvielement easily forms stable sequestration thing with some ligands.In fertilizer industry, the U.S. uses more for edetic acid (EDTA) and citric acid, EDTA all has stronger sequestration power to all of transition elements, but its price is high, manufacturing cost is high, and China was the most once advocating use humic acids as intercalating agent, production cost is made to decrease, but humic acids concentration is low, molecular weight is big, sequestration ability.Aminoacid is as ligand, in the case of without photosynthesis, directly participates in the albumen synthesis of body, compared with other intercalating agent, has more significant effect of increasing production to crops, manufacture the key technology that cheap aminoacids complex has become rare earth fertilizer to produce.
Molasses alcohol waste liquid be sugar refinery saccharified residues molasses be raw material, the high concentrated organic wastewater produced during fermenting and producing ethanol, wherein contain more organic substance, such as protein, sugar etc., if not being used and directly processing, not only result in the bigger wasting of resources, and can be because of the expense of load higher increase waste liquid of molasses alcohol.Therefore, molasses alcohol waste liquid is applied in the production of rare earth fertilizer has wide market prospect.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of can the Fructus Fragariae Ananssae fertilizer and preparation method thereof of activating soil fertility.
The present invention is achieved by the following technical solutions:
A kind of can the Fructus Fragariae Ananssae fertilizer of activating soil fertility, be prepared by the raw materials in:
Molasses alcohol waste liquid 200-210, polyoxy starch 6-7, MAP 1-1.2, Sorbitol 0.8-1, bran powder 10-12, fertile soil 12-13, coconut palm bran 20-21, Sargassum powder 8-9, wood flour 8-9, turfy soil 8-9, the ethanol 400-410 of 95%, the sodium hydroxide solution 800-810 of 0.5mol/L, the hydrochloric acid solution of 1mol/L is appropriate, the sulfuric acid solution of 50% is appropriate, rare earth oxide 2-3, polyvinyl alcohol 5-6, CNT 0.2-0.3, cycloheptaamylose 0.2-0.3, tea polyphenols 0.1-0.2, microbial germ powder 1-1.2.
Described can the preparation method of Fructus Fragariae Ananssae fertilizer of activating soil fertility, comprise the following steps:
(1) ethanol molasses alcohol waste liquid being added 95% and the sodium hydroxide solution of 0.5mol/L, centrifuging and taking supernatant after reacting 40 minutes, add the hydrochloric acid solution regulation pH to 4 of 1mol/L, sucking filtration, gained precipitation is dried；
(2) being mixed with rare earth oxide by step (1) gained material, the sulfuric acid solution adding 50% reacts 1 hour at 140 DEG C, is subsequently adding polyoxy starch, continues heating, is condensed into paste；
(3) by CNT and cycloheptaamylose mixed grinding 1 hour, then gained material being added appropriate deionized water ultrasonic disperse 2 hours, centrifugation, gained precipitate with deionized water washs 2-3 time, and at 75 DEG C, vacuum drying 24 hours, are ground into powder；
(4) polyvinyl alcohol is added the deionized water of 10 times, at 45 DEG C, constant temperature stirs swelling 3 hours, is then heated to 95 DEG C of stirring to polyvinyl alcohol and is completely dissolved, then adds step (3) gained material, tea polyphenols when temperature is down to 45 DEG C, it is sufficiently stirred for, obtains coating liquid；
(5) by bran powder, coconut palm bran, Sargassum powder, wood flour mixing, the regulation that adds water reaches 55-60% to water content, is subsequently adding microbial germ powder, heap vexed fermentation 25-30 days, the turning of 5-6 days period is once, then the raw material do not used with step (2) gained material and above-mentioned technique mixes, pelletize, and gained material is placed in electric drying oven with forced convection, dry to constant weight at 40 DEG C, uniformly spray coating liquid, be dried, to obtain final product.
nullThe invention have the advantage that the present invention uses molasses alcohol waste liquid as raw material，It is extracted protein therein，Again by protein and rare earth oxide mixing acid hydrolysis，Rare earth oxide is just added when protein is not hydrolyzed into aminoacid，Peptide bond chelating on the blank side chain with albumen of the track of rare earth ion，Accelerate aminoacid and depart from protein molecule,Aminoacid is shielded by the metal ion added simultaneously,Reduce amino acid whose thermal decomposition,Improve amino acid whose yield,Shorten the response time，Aminoacid improves Fructus Fragariae Ananssae quality with rare earth chelate fertilizer、Reduce persticide residue，And the present invention adds CNT in coating liquid，The mechanical strength of film can be improved，And CNT adds, and cycloheptaamylose is modified improves CNT dispersibility in water，The tea polyphenols added can introduce hydrophobic benzene radicals，Improve the hydrophobicity of film，So that water absorption rate declines，Improve the slow-releasing of film，In addition，The present invention can regulate and control soil physics structure、Soil fertility，It is applicable to degenerated soil improvement inferior.
Detailed description of the invention
A kind of can the Fructus Fragariae Ananssae fertilizer of activating soil fertility, be made up of the raw material of following weight portion (kilogram):
Molasses alcohol waste liquid 200, polyoxy starch 6, MAP 1, Sorbitol 0.8, bran powder 10, fertile soil 12, coconut palm bran 20, Sargassum powder 8, wood flour 8, the ethanol 400 of turfy soil 8,95%, the sodium hydroxide solution 800 of 0.5mol/L, 1mol/L hydrochloric acid solution sulfuric acid solution appropriate, 50% is appropriate, rare earth oxide 2, polyvinyl alcohol 5, CNT 0.2, cycloheptaamylose 0.2, tea polyphenols 0.1, microbial germ powder 1.
Described can the preparation method of Fructus Fragariae Ananssae fertilizer of activating soil fertility, comprise the following steps:
(1) ethanol molasses alcohol waste liquid being added 95% and the sodium hydroxide solution of 0.5mol/L, centrifuging and taking supernatant after reacting 40 minutes, add the hydrochloric acid solution regulation pH to 4 of 1mol/L, sucking filtration, gained precipitation is dried；
(2) being mixed with rare earth oxide by step (1) gained material, the sulfuric acid solution adding 50% reacts 1 hour at 140 DEG C, is subsequently adding polyoxy starch, continues heating, is condensed into paste；
(3) by CNT and cycloheptaamylose mixed grinding 1 hour, then gained material being added appropriate deionized water ultrasonic disperse 2 hours, centrifugation, gained precipitate with deionized water is washed 2 times, is vacuum dried 24 hours, is ground into powder at 75 DEG C；
(4) polyvinyl alcohol is added the deionized water of 10 times, at 45 DEG C, constant temperature stirs swelling 3 hours, is then heated to 95 DEG C of stirring to polyvinyl alcohol and is completely dissolved, then adds step (3) gained material, tea polyphenols when temperature is down to 45 DEG C, it is sufficiently stirred for, obtains coating liquid；
(5) by bran powder, coconut palm bran, Sargassum powder, wood flour mixing, the regulation that adds water reaches 55% to water content, is subsequently adding microbial germ powder, the vexed fermentation of heap 25 days, the turning of 5 days periods is once, then the raw material do not used with step (2) gained material and above-mentioned technique mixes, pelletize, and gained material is placed in electric drying oven with forced convection, dry to constant weight at 40 DEG C, uniformly spray coating liquid, be dried, to obtain final product.
It is used for the fertilizer of the present invention planting Fructus Fragariae Ananssae experiment, selects 5 mu of planting bases, use the fertilizer of the present invention; as experimental group, 5 mu of base planting requirements routinely of matched group execute common fertilizer, and other condition is identical; experiment proves; the Fructus Fragariae Ananssae of experimental group plantation, in the case of reaching equal production volume, greatly reduces Fertilizer application amount, and raw material is easy to get simultaneously; cost of material ratio is relatively low; save labour, protect environment, on year-on-year basis economic raising 21.2%.
Claims (2)
1. one kind can the Fructus Fragariae Ananssae fertilizer of activating soil fertility, it is characterised in that be prepared by the raw materials in:
Molasses alcohol waste liquid 200-210, polyoxy starch 6-7, MAP 1-1.2, Sorbitol 0.8-1, bran powder 10-12, fertile soil 12-13, coconut palm bran 20-21, Sargassum powder 8-9, wood flour 8-9, turfy soil 8-9, the ethanol 400-410 of 95%, the sodium hydroxide solution 800-810 of 0.5mol/L, the hydrochloric acid solution of 1mol/L is appropriate, the sulfuric acid solution of 50% is appropriate, rare earth oxide 2-3, polyvinyl alcohol 5-6, CNT 0.2-0.3, cycloheptaamylose 0.2-0.3, tea polyphenols 0.1-0.2, microbial germ powder 1-1.2.
The most according to claim 1 can the preparation method of Fructus Fragariae Ananssae fertilizer of activating soil fertility, it is characterised in that comprise the following steps:
(1) ethanol molasses alcohol waste liquid being added 95% and the sodium hydroxide solution of 0.5mol/L, centrifuging and taking supernatant after reacting 40 minutes, add the hydrochloric acid solution regulation pH to 4 of 1mol/L, sucking filtration, gained precipitation is dried；
(2) being mixed with rare earth oxide by step (1) gained material, the sulfuric acid solution adding 50% reacts 1 hour at 140 DEG C, is subsequently adding polyoxy starch, continues heating, is condensed into paste；
(3) by CNT and cycloheptaamylose mixed grinding 1 hour, then gained material being added appropriate deionized water ultrasonic disperse 2 hours, centrifugation, gained precipitate with deionized water washs 2-3 time, and at 75 DEG C, vacuum drying 24 hours, are ground into powder；
(4) polyvinyl alcohol is added the deionized water of 10 times, at 45 DEG C, constant temperature stirs swelling 3 hours, is then heated to 95 DEG C of stirring to polyvinyl alcohol and is completely dissolved, then adds step (3) gained material, tea polyphenols when temperature is down to 45 DEG C, it is sufficiently stirred for, obtains coating liquid；
(5) by bran powder, coconut palm bran, Sargassum powder, wood flour mixing, the regulation that adds water reaches 55-60% to water content, is subsequently adding microbial germ powder, heap vexed fermentation 25-30 days, the turning of 5-6 days period is once, then the raw material do not used with step (2) gained material and above-mentioned technique mixes, pelletize, and gained material is placed in electric drying oven with forced convection, dry to constant weight at 40 DEG C, uniformly spray coating liquid, be dried, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610324978.2A CN106008077A (en) | 2016-05-17 | 2016-05-17 | Strawberry fertilizer capable of activating fertility of soil and preparation method of fertilizer |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610324978.2A CN106008077A (en) | 2016-05-17 | 2016-05-17 | Strawberry fertilizer capable of activating fertility of soil and preparation method of fertilizer |
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| CN106008077A true CN106008077A (en) | 2016-10-12 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106588326A (en) * | 2016-12-07 | 2017-04-26 | 滁州市施集茶场 | Waste newspaper fertilizer capable of improving soil aeration for tea tree and preparation method of waste newspaper fertilizer for tea tree |
| CN107056514A (en) * | 2017-06-27 | 2017-08-18 | 青岛大学 | A kind of special chelating fertilizer of strawberry |
| CN108329103A (en) * | 2018-03-26 | 2018-07-27 | 深圳市芭田生态工程股份有限公司 | The sweetened fertilizer additive of crop and sweetened fertilizer |
Citations (1)
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| CN105439713A (en) * | 2015-12-11 | 2016-03-30 | 马鞍山科邦生态肥有限公司 | Microbial fertilizer for activating soil fertility and preparation method thereof |
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2016
- 2016-05-17 CN CN201610324978.2A patent/CN106008077A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105439713A (en) * | 2015-12-11 | 2016-03-30 | 马鞍山科邦生态肥有限公司 | Microbial fertilizer for activating soil fertility and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106588326A (en) * | 2016-12-07 | 2017-04-26 | 滁州市施集茶场 | Waste newspaper fertilizer capable of improving soil aeration for tea tree and preparation method of waste newspaper fertilizer for tea tree |
| CN107056514A (en) * | 2017-06-27 | 2017-08-18 | 青岛大学 | A kind of special chelating fertilizer of strawberry |
| CN108329103A (en) * | 2018-03-26 | 2018-07-27 | 深圳市芭田生态工程股份有限公司 | The sweetened fertilizer additive of crop and sweetened fertilizer |
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Application publication date: 20161012 |