CN106007641A - Heat-preserving flame-retardant hollow brick and preparation method thereof - Google Patents

Heat-preserving flame-retardant hollow brick and preparation method thereof Download PDF

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Publication number
CN106007641A
CN106007641A CN201610251326.0A CN201610251326A CN106007641A CN 106007641 A CN106007641 A CN 106007641A CN 201610251326 A CN201610251326 A CN 201610251326A CN 106007641 A CN106007641 A CN 106007641A
Authority
CN
China
Prior art keywords
parts
heat
hollow brick
tailings
brick
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610251326.0A
Other languages
Chinese (zh)
Inventor
严艾青
黄奋举
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HEXIAN MINGSHENG ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Original Assignee
HEXIAN MINGSHENG ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HEXIAN MINGSHENG ENVIRONMENTAL PROTECTION MATERIAL Co Ltd filed Critical HEXIAN MINGSHENG ENVIRONMENTAL PROTECTION MATERIAL Co Ltd
Priority to CN201610251326.0A priority Critical patent/CN106007641A/en
Publication of CN106007641A publication Critical patent/CN106007641A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/52Producing shaped prefabricated articles from the material specially adapted for producing articles from mixtures containing fibres, e.g. asbestos cement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/10Forming beads
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures

Abstract

The invention discloses a heat-preserving flame-retardant hollow brick and a preparation method thereof. The heat-preserving flame-retardant hollow brick is prepared from the following raw materials in parts by weight: 13-22 parts of floating beads, 17-26 parts of industrial waste residue, 21-32 parts of epistilbite, 45-55 parts of calcium magnesium aluminate cement, 14-23 parts of asbestos tailings, 19-31 parts of salt gypsum, 16-24 parts of mountain sand, 15-25 parts of hornblende, 9-17 parts of a cork powder, 18-27 parts of phosphate tailings with high magnesium content, 14-22 parts of dolomite, 16-24 parts of ceramic polished waste, 10-15 parts of calcium metaborate, 11-18 parts of white mica, 9-16 parts of zinc phosphate, 13-19 parts of waste foam plastics, 15-20 parts of closed-cell perlite, 12-18 parts of vinyon short fiber, and a proper amount of water. At the same time, the closed-cell perlite, cork powder, waste foam plastics, floating beads, zinc phosphate, vinyon short fiber and other raw materials are added simultaneously, so the prepared hollow brick not only has excellent heat-insulation and heat-preservation properties, but also has excellent fire-preventing and flame-retardant performance.

Description

A kind of heat-insulating and fire-proof hollow brick and preparation method thereof
Technical field
The present invention relates to a kind of hollow brick and preparation method thereof, be specifically related to a kind of heat-insulating and fire-proof hollow brick and preparation method thereof.
Background technology
Hollow brick is the main material of body of wall that building trade is conventional in recent years, owing to light weight, light weight, intensity are high, insulation, sound insulation and noise reduction performance is good, it is few to consume former material, environmental protection, the advantage such as pollution-free, have become as the product that first construction sector of country is recommended.In recent years along with development and the progress of entire society of building industry, improving constantly of people's living standard, increasing people require height heat-insulation and heat-preservation, flame-retardant, durable in use etc. there is multi-functional house, this just has higher requirement to the performance of hollow brick.
Summary of the invention
Present invention aim at for the deficiencies in the prior art, it is provided that a kind of heat-insulating and fire-proof hollow brick and preparation method thereof.The hollow brick that the present invention prepares has heat-insulation and heat-preservation and the anti-flammability of excellence.
For achieving the above object, the present invention adopts the following technical scheme that:
A kind of heat-insulating and fire-proof hollow brick, is made up of the raw material of following weight portion: floating bead 13-22, industrial residue 17-26, epistilbite 21-32, calcium and magnesium aluminate cement 45-55, asbestos tailings 14-23, bunt gypsum 19-31, mountain sand 16-24, hornblend 15-25, cork powder 9-17, High-Mg phosphate tailings 18-27, white clouds soil 14-22, ceramic polished slag 16-24, calcium metaborate 10-15, white mica 11-18, zinc phosphate 9-16, waste foam plastics 13-19, closed perlite 15-20, Vinyon N chopped fiber 12-18, water are appropriate.
The preparation method of a kind of heat-insulating and fire-proof hollow brick, comprises the following steps:
(1) mountain sand, hornblend, High-Mg phosphate tailings, calcium metaborate, white mica mix homogeneously are taken, it is heated to material and is completely melt into fused solution, then the fused solution obtained is put into and clear water carries out shrend, obtain the glass particle material crushed, dewatered and washed part, dry, pulverize, cross 50-100 mesh sieve, add appropriate water stirring and make the serosity that concentration is 40-50%, adding the ammonium nitrate of sodium bicarbonate and the 4-7% being equivalent to slurry weight 5-10%, then spray, atomisation pressure is 0.1-0.2kg/cm3, heating while spraying, temperature controls at 1260-1320 DEG C, can form glass microballoon in dropping process;
(2) epistilbite, asbestos tailings, white clouds slag mix homogeneously native, ceramic polished are taken, it is heated to material and is completely melt into fused solution, by high-voltage high-speed air blown, the fused solution obtained is become wadding fibrous, and jetting pressure controls at 1-1.5MPa, and air velocity controls at 5-8m/s;
(3) the wadding fibrous and remaining raw material that the glass microballoon that step (1) prepared, step (2) prepare is mixed homogeneously, and adds appropriate water, and stirring 3-6min, the moisture control of compound is at 10-15%;
(4) adding in air brick brick press compressing by the compound that step (3) prepares, briquetting pressure controls, at 8-10MPa, then the adobe after molding to be placed in outdoor natural curing, obtains required hollow brick.
Beneficial effects of the present invention:
(1) present invention adds the raw materials such as closed perlite, cork powder, waste foam plastics, floating bead, zinc phosphate, Vinyon N chopped fiber simultaneously, makes the hollow brick prepared not only have the heat preservation and insulation of excellence, also has the fire retardant performance of excellence.
(2) what hollow brick of the present invention used that the raw materials such as glass microballoon and epistilbite, asbestos tailings, white clouds soil that the raw materials such as mountain sand, hornblend, High-Mg phosphate tailings make make wadding fibrous combines well, it is possible not only to improve the resistance to compression of hollow brick, shock resistance and cracking resistance ability, it is also possible to improve the heat-insulation and heat-preservation of hollow brick.
Detailed description of the invention
A kind of heat-insulating and fire-proof hollow brick, is made up of the raw material of following weight (kg): floating bead 17, industrial residue 23, epistilbite 28, calcium and magnesium aluminate cement 50, asbestos tailings 17, bunt gypsum 25, mountain sand 20, hornblend 20, cork powder 13, High-Mg phosphate tailings 22, white clouds soil 18, ceramic polished slag 19, calcium metaborate 13, white mica 15, zinc phosphate 12, waste foam plastics 15, closed perlite 17, Vinyon N chopped fiber 16, water are appropriate.
The preparation method of a kind of heat-insulating and fire-proof hollow brick, comprises the following steps:
(1) mountain sand, hornblend, High-Mg phosphate tailings, calcium metaborate, white mica mix homogeneously are taken, it is heated to material and is completely melt into fused solution, then the fused solution obtained is put into and clear water carries out shrend, obtain the glass particle material crushed, dewatered and washed part, dry, pulverize, cross 80 mesh sieves, add appropriate water stirring and make the serosity that concentration is 45%, adding the ammonium nitrate of the sodium bicarbonate being equivalent to slurry weight 8% and 6%, then spray, atomisation pressure is 0.15kg/cm3, heating while spraying, temperature controls, at 1290 DEG C, to form glass microballoon in dropping process;
(2) epistilbite, asbestos tailings, white clouds slag mix homogeneously native, ceramic polished are taken, it is heated to material and is completely melt into fused solution, by high-voltage high-speed air blown, the fused solution obtained is become wadding fibrous, and jetting pressure controls at 1.2MPa, and air velocity controls at 7m/s;
(3) the wadding fibrous and remaining raw material that the glass microballoon that step (1) prepared, step (2) prepare is mixed homogeneously, and adds appropriate water, and stirring 5min, the moisture control of compound is 12%;
(4) adding in air brick brick press compressing by the compound that step (3) prepares, briquetting pressure controls, at 9MPa, then the adobe after molding to be placed in outdoor natural curing, obtains required hollow brick.
The main performance testing result of the hollow brick that above-described embodiment prepares is as shown in the table:
Detection project Unit Testing result
Apparent density kg/m3 1157
Comprcssive strength MPa 8.9
Heat conductivity W/(m•K) 0.136
Refractoriness 1320

Claims (2)

1. a heat-insulating and fire-proof hollow brick, it is characterized in that, be made up of the raw material of following weight portion: floating bead 13-22, industrial residue 17-26, epistilbite 21-32, calcium and magnesium aluminate cement 45-55, asbestos tailings 14-23, bunt gypsum 19-31, mountain sand 16-24, hornblend 15-25, cork powder 9-17, High-Mg phosphate tailings 18-27, white clouds soil 14-22, ceramic polished slag 16-24, calcium metaborate 10-15, white mica 11-18, zinc phosphate 9-16, waste foam plastics 13-19, closed perlite 15-20, Vinyon N chopped fiber 12-18, water are appropriate.
2. the preparation method of a heat-insulating and fire-proof hollow brick as claimed in claim 1, it is characterised in that comprise the following steps:
(1) mountain sand, hornblend, High-Mg phosphate tailings, calcium metaborate, white mica mix homogeneously are taken, it is heated to material and is completely melt into fused solution, then the fused solution obtained is put into and clear water carries out shrend, obtain the glass particle material crushed, dewatered and washed part, dry, pulverize, cross 50-100 mesh sieve, add appropriate water stirring and make the serosity that concentration is 40-50%, adding the ammonium nitrate of sodium bicarbonate and the 4-7% being equivalent to slurry weight 5-10%, then spray, atomisation pressure is 0.1-0.2kg/cm3, heating while spraying, temperature controls at 1260-1320 DEG C, can form glass microballoon in dropping process;
(2) epistilbite, asbestos tailings, white clouds slag mix homogeneously native, ceramic polished are taken, it is heated to material and is completely melt into fused solution, by high-voltage high-speed air blown, the fused solution obtained is become wadding fibrous, and jetting pressure controls at 1-1.5MPa, and air velocity controls at 5-8m/s;
(3) the wadding fibrous and remaining raw material that the glass microballoon that step (1) prepared, step (2) prepare is mixed homogeneously, and adds appropriate water, and stirring 3-6min, the moisture control of compound is at 10-15%;
(4) adding in air brick brick press compressing by the compound that step (3) prepares, briquetting pressure controls, at 8-10MPa, then the adobe after molding to be placed in outdoor natural curing, obtains required hollow brick.
CN201610251326.0A 2016-04-21 2016-04-21 Heat-preserving flame-retardant hollow brick and preparation method thereof Pending CN106007641A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610251326.0A CN106007641A (en) 2016-04-21 2016-04-21 Heat-preserving flame-retardant hollow brick and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610251326.0A CN106007641A (en) 2016-04-21 2016-04-21 Heat-preserving flame-retardant hollow brick and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106007641A true CN106007641A (en) 2016-10-12

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CN (1) CN106007641A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106892606A (en) * 2017-03-31 2017-06-27 安徽中煦环保新材料科技有限公司 A kind of environment-friendlyflame-retardant flame-retardant material and preparation method thereof
CN107098649A (en) * 2017-05-27 2017-08-29 明光市泰丰新材料有限公司 One kind contains the anti-aging hollow brick of floating bead and its preparation technology
CN107721459A (en) * 2017-10-23 2018-02-23 贵州省建筑材料科学研究设计院有限责任公司 A kind of industrial residue Self-thermal-insulation hollow brick and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041578A (en) * 2007-03-06 2007-09-26 刘泳霞 Light-weight aggregate concrete and formwork wall member produced therefrom
CN101050129A (en) * 2007-05-09 2007-10-10 徐振飞 Heat preservation and energy saving type lightweight, gas filled wall bricks, and preparation method

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041578A (en) * 2007-03-06 2007-09-26 刘泳霞 Light-weight aggregate concrete and formwork wall member produced therefrom
CN101050129A (en) * 2007-05-09 2007-10-10 徐振飞 Heat preservation and energy saving type lightweight, gas filled wall bricks, and preparation method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106892606A (en) * 2017-03-31 2017-06-27 安徽中煦环保新材料科技有限公司 A kind of environment-friendlyflame-retardant flame-retardant material and preparation method thereof
CN107098649A (en) * 2017-05-27 2017-08-29 明光市泰丰新材料有限公司 One kind contains the anti-aging hollow brick of floating bead and its preparation technology
CN107721459A (en) * 2017-10-23 2018-02-23 贵州省建筑材料科学研究设计院有限责任公司 A kind of industrial residue Self-thermal-insulation hollow brick and preparation method thereof

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Application publication date: 20161012

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