CN106747148A - Slag, carbide slag and haydite high-strength wall insulation material and preparation method thereof - Google Patents
Slag, carbide slag and haydite high-strength wall insulation material and preparation method thereof Download PDFInfo
- Publication number
- CN106747148A CN106747148A CN201611127356.7A CN201611127356A CN106747148A CN 106747148 A CN106747148 A CN 106747148A CN 201611127356 A CN201611127356 A CN 201611127356A CN 106747148 A CN106747148 A CN 106747148A
- Authority
- CN
- China
- Prior art keywords
- slag
- haydite
- powder
- carbide
- insulation material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002893 slag Substances 0.000 title claims abstract description 101
- 239000012774 insulation material Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000000843 powder Substances 0.000 claims abstract description 75
- 239000000463 material Substances 0.000 claims abstract description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000004576 sand Substances 0.000 claims abstract description 25
- 239000004816 latex Substances 0.000 claims abstract description 20
- 229920000126 latex Polymers 0.000 claims abstract description 20
- 229920003086 cellulose ether Polymers 0.000 claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 239000005997 Calcium carbide Substances 0.000 claims abstract description 13
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 haydite Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 31
- 239000002994 raw material Substances 0.000 claims description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- 238000013019 agitation Methods 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 230000010358 mechanical oscillation Effects 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 5
- 229920003023 plastic Polymers 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 4
- 239000000920 calcium hydroxide Substances 0.000 claims description 4
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 4
- 235000012241 calcium silicate Nutrition 0.000 claims description 4
- JHLNERQLKQQLRZ-UHFFFAOYSA-N calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 claims description 4
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 238000005245 sintering Methods 0.000 claims description 4
- 239000010802 sludge Substances 0.000 claims description 4
- 229910021534 tricalcium silicate Inorganic materials 0.000 claims description 4
- 235000019976 tricalcium silicate Nutrition 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019738 Limestone Nutrition 0.000 claims description 3
- 229920002522 Wood fibre Polymers 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 230000015271 coagulation Effects 0.000 claims description 3
- 238000005345 coagulation Methods 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 229910052906 cristobalite Inorganic materials 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 239000006028 limestone Substances 0.000 claims description 3
- 229920003124 powdered cellulose Polymers 0.000 claims description 3
- 235000019814 powdered cellulose Nutrition 0.000 claims description 3
- 229910052682 stishovite Inorganic materials 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 229920005992 thermoplastic resin Polymers 0.000 claims description 3
- 229910052905 tridymite Inorganic materials 0.000 claims description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 3
- 210000000481 breast Anatomy 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000004568 cement Substances 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 5
- 238000009413 insulation Methods 0.000 abstract description 4
- 239000004793 Polystyrene Substances 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 3
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 229920002223 polystyrene Polymers 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 6
- 238000012423 maintenance Methods 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 238000007781 pre-processing Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- KNKRKFALVUDBJE-UHFFFAOYSA-N 1,2-dichloropropane Chemical compound CC(Cl)CCl KNKRKFALVUDBJE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- GLVVKKSPKXTQRB-UHFFFAOYSA-N ethenyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC=C GLVVKKSPKXTQRB-UHFFFAOYSA-N 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000003562 lightweight material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000008531 maintenance mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/08—Slag cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28C—PREPARING CLAY; PRODUCING MIXTURES CONTAINING CLAY OR CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28C5/00—Apparatus or methods for producing mixtures of cement with other substances, e.g. slurries, mortars, porous or fibrous compositions
- B28C5/003—Methods for mixing
- B28C5/006—Methods for mixing involving mechanical aspects
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/92—Protection against other undesired influences or dangers
- E04B1/94—Protection against other undesired influences or dangers against fire
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
- C04B2201/32—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/244—Structural elements or technologies for improving thermal insulation using natural or recycled building materials, e.g. straw, wool, clay or used tires
Abstract
The invention discloses a kind of slag, carbide slag and haydite high-strength wall insulation material and preparation method thereof.The high-strength wall insulation material is made up of slag powders, calcium carbide ground-slag, haydite, sand, dicalcium powder, latex powder, cellulose ether, water;Its mass percent is respectively:Slag powders:10.0~50.0%;Calcium carbide ground-slag:8.0~40.0%;Haydite:30.0~60.0%;Sand:15.0~30.0%;Dicalcium powder:5.0~20.0%;Latex powder:1.5~5.0%;Cellulose ether:0.5~2.0%;Water:12.0~30.0%.The present invention can provide care action in gelling system;Materials for wall 28d compression strength can reach 25MPa, and shrink small;Replace cement as gelling system by the use of slag carbide slag, both for the recycling of carbide slag provides new way, the high energy consumption needed for production cement is saved again;Not only excellent thermal insulation performance, intensity is high, and easy construction, it is not necessary to individually construction;Material source is extensively, cheap, compared with granular polystyrene polymer thermal insulative material, the low production cost of the materials for wall.
Description
Technical field
The present invention relates to a kind of wall heat insulation material and preparation method thereof, more particularly to a kind of high-strength wall material and its system
Preparation Method.
Background technology
At present, the substantial amounts of solid waste of the industry such as electric power, cement, steel, aluminium processed generation, and these solid waste,
Such as flyash, slag, slag, red mud, and urgently large utilization, the comprehensive regulation, reduce environmental pollution.
The wall fire-retardant heat-insulation material species for mainly using both at home and abroad is various, and organic insulation material causes fire again and again,
Flameproof effect is poor, high cost;Mineral-type fire-retardant heat-insulation material and numerous and complicated, often because price war causes high-quality fire-retardant heat-insulation material
It is unable to occuping market.Wall heat insulation material is main with the macromolecular material (sheet material that such as granular polystyrene sheet material or its pultrusion are formed
Deng), its heat preservation and soundproof effect is good, while light weight, but macromolecule wall heat insulation material has its fatal weakness:(1) it is resistance to
High-temperature behavior is poor;(2) low intensity;(3) construct complicated, therefore improve application cost.
The content of the invention
The invention technical problem to be solved is:High for current materials for wall price, fire resistance is poor and constructs numerous and diverse etc.
Problem, the present invention provides one kind by the use of inorganic coagulation material as binding agent, and materials for wall is prepared by aggregate of haydite, can solve
Certainly problem above.The present invention is intended to provide a kind of preparation method of high-strength wall material.
The technical solution adopted for the present invention to solve the technical problems is:
The present invention provides a kind of slag, carbide slag and haydite high-strength wall insulation material, by slag powders, calcium carbide ground-slag, pottery
Grain, sand, dicalcium powder, latex powder, cellulose ether, water composition;Its mass percent is respectively:Slag powders:10.0~50.0%;
Calcium carbide ground-slag:8.0~40.0%;Haydite:30.0~60.0%;Sand:15.0~30.0%;Dicalcium powder:5.0~20.0%;
Latex powder:1.5~5.0%;Cellulose ether:0.5~2.0%;Water:12.0~30.0%.
As a further improvement on the present invention, described slag powders are the granulated blast-furnace slag of ironmaking processes formation by powder
Powder is formed after mill, its main component is CaO, SiO2、Al2O3And Fe2O3, wherein tricalcium silicate and dicalcium silicate containing part
Thing phase, with hydraulic property, its density is 2.7~2.9g/cm3, maximum particle diameter be less than 0.08mm, specific surface area be 400~
450m2/kg。
As a further improvement on the present invention, described calcium carbide ground-slag is that calcium carbide reacts the product to be formed with water, industrially
From the accessory substance that production acetylene gas are produced, white powder, its main component is calcium hydroxide, displays carbide slag for many years
In the ingredients calcium carbonate containing part.
As a further improvement on the present invention, described haydite is by including clay, shale, gangue, sludge or red mud
Composition by a kind of intensity of grinding, balling-up and sintering agglomerated material high, lightweight, porous, the particle diameter of haydite is
1-5mm or 5-10mm or 10-25mm, color is kermesinus or maroon, and its bulk density is 300-900km/
m3。
As a further improvement on the present invention, the sand includes artificial sand and natural sand, and particle diameter is less than 5mm.
As a further improvement on the present invention, the dicalcium powder is heavy calcium carbonate powder, mainly with lime stone as raw material,
The white powder to be formed is processed by mechanical powder, particle diameter is 350 mesh.
As a further improvement on the present invention, it can be by high molecular polymerization breast in dispersed latex powder that the latex powder is
The powder thermoplastic resin material that liquid is processed.
As a further improvement on the present invention, the cellulose ether is using wood fibre or refines short cotton fiber as main
Raw material, it is chemically treated after, the powdered cellulose ether for reacting generated by etherifying agent.
The present invention also provides the preparation method of a kind of slag, carbide slag and haydite high-strength wall insulation material, with slag, electricity
Rock ballast, haydite, sand and auxiliary agent are raw material, by the use of inorganic coagulation material as binding agent, institute are prepared from by aggregate of haydite
State high-strength wall insulation material.
As a further improvement on the present invention, comprise the following steps:
Step 1:Haydite is pre-processed;
After haydite is soaked into 24h with running water at room temperature, surface moisture is filtered off to saturated dry surface, it is stand-by;
Step 2:Weigh mixing;
In parts by mass, the haydite 30~60 for having pre-processed, slag powders are prepared:8~40, sand 15~30, dicalcium powder 5~
20, latex powder 1.5~5.0, cellulose ether 0.5~2.0;
The raw material that will be weighed up loads in concrete mixer, 2~6min of mechanical agitation, and rotating speed is 60~80r/min;
Step 3:Add water stirring;
Water 12.0~30.0,6~8min of mechanical agitation are added in above-mentioned stirring siccative, rotating speed is 60~80r/min;
Step 4:Formed product;
The above-mentioned fresh material being stirred is fitted into the metal die of given size, after 5~15s of mechanical oscillation, with modeling
Material film covering die surface, temperature be 20 ± 1 DEG C, humidity be 80~95% fog room or curing box in conserve 24h;
Step 5:The demoulding is conserved;
After the product stripping after 24h will be conserved, feeding temperature is 20 ± 1 DEG C of fog room or continues to conserve 28 days in water
Can be used afterwards.
Beneficial effects of the present invention are as follows:
High-strength insulation wall material of the invention reaches professional standard JB149-2003 (expansion joints bellows exterior walls
Heat-insulation system) specified in heat-insulating property (thermal conductivity factor≤0.041W/ (mk)).
The aggregate of the wall heat insulation material uses haydite, because haydite is porous light-weight material, when it (inhales by pretreatment
Water) after, care action in gelling system can be provided, so as to further improve the intensity of materials for wall.Materials for wall 28d resists
Compressive Strength can reach 25MPa, and shrink small.Additionally, also having the following advantages that:
(1) with energy-conserving and environment-protective meaning
The invention replaces cement by the use of slag carbide slag as gelling system, both for the recycling of carbide slag is provided
New way, the high energy consumption needed for production cement is saved again, therefore with energy-conserving and environment-protective meaning.
(2) application value is high
Wall heat insulation material involved by the patent, not only excellent thermal insulation performance, intensity is high, and easy construction, it is not necessary to
Individually construction, therefore with application value higher.
(3) low production cost
The Binder Materials that the patent of invention is related to is slag and carbide slag, and its wide material sources is cheap, compared with granular polystyrene
Polymer thermal insulative material, the low production cost of the materials for wall.
Specific embodiment
With reference to specific embodiment, the invention will be further described, but the present invention is not limited to following examples.
Raw material used unless otherwise indicated, is building trade versatile material in embodiment, and can be by commercial channel
Buy.
The present invention is raw material using slag, carbide slag, haydite, sand and auxiliary agent, produces a kind of wall thermal insulating of high intensity
Material, the formula of the materials for wall is as follows:
Described slag powders be ironmaking processes formed granulated blast-furnace slag by forming powder after grinding, its main component
It is CaO, SiO2、Al2O3And Fe2O3, wherein the tricalcium silicate containing part and dicalcium silicate thing phase, special with certain hydraulic
Property.Its density is 2.7~2.9g/cm3, less than 0.08mm, specific surface area is 400~450m to maximum particle diameter2/kg。
Described calcium carbide ground-slag is that calcium carbide reacts the product to be formed with water, industrial to derive from what production acetylene gas were produced
Accessory substance, white powder, its main component is calcium hydroxide, displays the ingredients calcium carbonate containing part in carbide slag for many years.
Described haydite is formed by clay, shale, gangue, sludge or red mud etc. by grinding, balling-up and sintering
A kind of intensity agglomerated material high, lightweight, porous, the particle diameter of haydite is 1-5mm or 5-10mm or 10-25mm,
Color is kermesinus or maroon, and its bulk density is 300-900km/m3。
The sand includes artificial sand and natural sand, and particle diameter is less than 5mm.
The dicalcium powder is heavy calcium carbonate powder, mainly with lime stone as raw material, processes what is formed by mechanical powder
White powder, main component is calcium carbonate, and particle diameter is 350 mesh.
The latex powder for can in dispersed latex powder, be by high molecular polymerization emulsion by HTHP, spray drying,
The powder thermoplastic resin material that the series of process such as surface treatment are processed, mainly including EVA (vinylacetate and ethene
Emulsion copolymer powder), E/VC/VL (ethene and vinyl chloride and vinyl laurate ternary polymerization latex powder) and other types of latex
Powder.
Described cellulose ether be using wood fibre or refine short cotton fiber as primary raw material, it is chemically treated after, lead to
The powdered cellulose ether that the etherifying agents such as superchlorination ethene, propylene dichloride or ethylene oxide react generated.Mainly include
(hydroxypropyl methyl cellulose, viscosity is (22 DEG C, 2% aqueous solution) to HPMC:200000mPa.s), (carboxymethylcellulose calcium glues CMC
Spend is (22 DEG C, the surface tension of 2% aqueous solution is 71mn/n)) and other cellulose ethers.
The water is running water.
A kind of slag, carbide slag and haydite high-strength wall insulation material, its preparation method have following steps:
(1) haydite pretreatment
After haydite is soaked into 24h with running water at room temperature, surface moisture is filtered off to saturated dry surface, it is stand-by.
(2) mixing is weighed
In parts by mass, the haydite 30~60 for having pre-processed, slag powders are prepared:8~40, sand 15~30, dicalcium powder 5~
20, latex powder 1.5~5.0, cellulose ether 0.5~2.0.
The raw material that will be weighed up loads in concrete mixer, 2~6min of mechanical agitation, and rotating speed is 60~80r/min.
(3) add water stirring
Add water 12.0~30.0 (in parts by mass) in above-mentioned stirring siccative, 6~8min of mechanical agitation, rotating speed is 60
~80r/min.
(4) formed product
The above-mentioned fresh material being stirred is fitted into the metal die of given size, after 5~15s of mechanical oscillation, with modeling
Material film covering die surface, temperature be 20 ± 1 DEG C, humidity be 80~95% fog room or curing box in conserve 24h.
(5) demoulding maintenance
After the product stripping after 24h will be conserved, feeding temperature is 20 ± 1 DEG C of fog room or continues to conserve 28 days in water
Can be used afterwards.
Embodiment one
Design of a kind of utilization slag, carbide slag and haydite production high-strength wall material and preparation method thereof, the preparation side
Method has following steps:
(1) haydite pretreatment
After haydite is soaked into 24h with running water under room temperature (temperature is 20 ± 1 DEG C), excess surface moisture to saturation is filtered off
Surface dry condition, it is stand-by.
(2) mixing is weighed
In parts by mass, the haydite 40 for having pre-processed, slag powders are prepared:15, sand 25, dicalcium powder 13, latex powder 2.0,
Cellulose ether 1.2.
The raw material that will be weighed up loads in concrete mixer, and mechanical agitation 4min, rotating speed is 70r/min.
(3) add water stirring
Add water 25 (in parts by mass) in above-mentioned stirring siccative, mechanical agitation 8min, rotating speed is 70r/min.
(4) formed product
The above-mentioned fresh material being stirred is fitted into the metal die of given size, it is thin with plastics after mechanical oscillation 5s
Film cover die surface, temperature be 20 ± 1 DEG C, humidity be 85% fog room or curing box in conserve 24h.
(5) demoulding maintenance
After the product stripping after 24h will be conserved, feeding temperature is 20 ± 1 DEG C of fog room or continues to conserve 28 days in water
Can be used afterwards.
Embodiment two
Design of a kind of utilization slag, carbide slag and haydite production high-strength wall material and preparation method thereof, the preparation side
Method has following steps:
(1) haydite pretreatment
After haydite is soaked into 24h with running water at room temperature, surface moisture is filtered off to saturated dry surface, it is stand-by.
(2) mixing is weighed
In parts by mass, the haydite 30 for having pre-processed, slag powders are prepared:30, sand 25, dicalcium powder 15, latex powder 2.0,
Cellulose ether 1.2.
The raw material that will be weighed up loads in concrete mixer, and mechanical agitation 4min, rotating speed is 60r/min.
(3) add water stirring
Add water 20 (in parts by mass) in above-mentioned stirring siccative, mechanical agitation 5min, rotating speed is 60r/min.
(4) formed product
The above-mentioned fresh material being stirred is fitted into the metal die of given size, it is thin with plastics after mechanical oscillation 7s
Film cover die surface, temperature be 20 ± 1 DEG C, humidity be 85% fog room or curing box in conserve 24h.
(5) demoulding maintenance
After the product stripping after 24h will be conserved, feeding temperature is 20 ± 2 DEG C of fog room or continues to conserve 28 days in water
Can be used afterwards.
Embodiment three
Design of a kind of utilization slag, carbide slag and haydite production high-strength wall material and preparation method thereof, the preparation side
Method has following steps:
(1) haydite pretreatment
After haydite is soaked into 24h with running water at room temperature, surface moisture is filtered off to saturated dry surface, it is stand-by.
(2) mixing is weighed
In parts by mass, the haydite 35 for having pre-processed, slag powders are prepared:25, sand 16, dicalcium powder 13, latex powder 2.1,
Cellulose ether 1.2.
The raw material that will be weighed up loads in concrete mixer, and mechanical agitation 5min, rotating speed is 70r/min.
(3) add water stirring
Add water 20 (in parts by mass) in above-mentioned stirring siccative, mechanical agitation 7min, rotating speed is 80r/min.
(4) formed product
The above-mentioned fresh material being stirred is fitted into the metal die of given size, it is thin with plastics after mechanical oscillation 6s
Film cover die surface, temperature be 20 ± 1 DEG C, humidity be 90% fog room or curing box in conserve 24h.
(5) demoulding maintenance
After the product stripping after 24h will be conserved, feeding temperature is 20 ± 1 DEG C of fog room or continues to conserve 28 days in water
Can be used afterwards.
Comparative example one
A kind of preparation of materials for wall, its preparation method has following steps:
(in order to be contrasted with embodiment one, in the formula of the materials for wall, the haydite unlike embodiment one is unique
Without by pre-processing, other proportionings are all identical.)
(1) stirring is weighed
In parts by mass, untreated haydite 35, slag powders are prepared:25, sand 16, dicalcium powder 13, latex powder 2.1 is fine
The plain ether 1.2 of dimension.
The raw material that will be weighed up loads in concrete mixer, and mechanical agitation 5min, rotating speed is 70r/min.
(2) add water mixing
Add water 20 (in parts by mass) in above-mentioned stirring siccative, mechanical agitation 7min, rotating speed is 80r/min.
(3) sample shaping
The above-mentioned fresh material being stirred is fitted into the metal die of given size, it is thin with plastics after mechanical oscillation 6s
Film cover die surface, temperature be 20 ± 1 DEG C, humidity be 90% fog room or curing box in conserve 24h.
(4) demoulding maintenance
After the product stripping after 24h will be conserved, feeding temperature is 20 ± 1 DEG C of fog room or continues to conserve 28 days in water
Can be used afterwards.
Knowable to embodiment one, two, three and the gained end properties of comparative example one are contrasted, three heat conduction systems of embodiment
Number is satisfied by the thermal conductivity factor required by professional standard JB149-2003, and the compression strength of all embodiments reaches 25MPa;By
Comparative example one and the contrast of embodiment one understand that the materials for wall 180d shrinkages formed by pre-processing haydite are embodiments one
4 times, 28d self-constriction amounts are 5 times of embodiment one, therefore, haydite by the amount of contraction of materials for wall can be reduced after pretreatment,
The intensity of materials for wall is improved simultaneously.
The measured data contrast of the embodiment one, two, three of table 1 and comparative example
Inspection project | Comparative example one | Embodiment one | Embodiment two | Embodiment three |
180d is dry to shrink (%) | 400×10-6 | 100×10-6 | 120×10-6 | 110×10-6 |
28d self-constrictions (%) | 100×10-6 | 20×10-6 | 22×10-6 | 21×10-6 |
28d compression strength (MPa) | 25.3 | 28.2 | 25.7 | 26.3 |
Thermal conductivity factor (W/ (mk)) | 0.036 | 0.036 | 0.040 | 0.041 |
As seen from the above table:Embodiment one, two, three and the product thermal conductivity factor of comparative example production meet professional standard
The requirement of JB149-2003 defineds.
Slag used by the present invention is granulated blast-furnace slag, is the waste residue melted in ironmaking processes by shape after Water Quenching
Into shot-like particle.Slag used by the present invention refers to the slag powders that foregoing granulated blast-furnace slag is formed after grinding.Its
Main component is silica, calcium oxide and iron oxide etc.;Because the formation of slag is due to being formed in high temperature ironmaking processes,
Therefore there be substantial amounts of tricalcium silicate and dicalcium silicate isoreactivity hydraulicity thing phase in its inside, and the material assigns slag powders has water
Rigid feature.
The industrial residue produced after calcium carbide hydrolysis during carbide slag production acetylene gas, main component is calcium hydroxide,
Belong to trade waste.Invention has both saved cost by the use of slag and carbide slag both industrial wastes as Binder Materials, and
Environment is effectively protected, while producing a kind of materials for wall of function admirable again, it may be said that achieve many things at one stroke.
In invention, Binder Materials is slag and carbide slag.By carbide slag activated slag activity, hydraulic cement material is formed
Material.
Invent the main aggregate by the use of haydite as materials for wall.Haydite is clay, shale, gangue, sludge, red mud etc.
By a kind of intensity of grinding, balling-up and sintering material high, lightweight, porous, the particle diameter of haydite is 1-5mm, 5-
10mm.
The Main Function of haydite is used by of the invention:(1) as the main aggregate of materials for wall;(2) due to haydite weight
Gently, the deadweight of materials for wall can be mitigated;(3) intensity of materials for wall is improved using maintenance mechanism in haydite;(4) due to haydite
It is hollow porous, can assign materials for wall good heat preservation and soundproof performance.
Therefore by the use of slag, carbide slag and haydite as the main raw material(s) of materials for wall, will reduce production cost, together
When assign materials for wall multifunctional high-performance characteristic.
Materials for wall involved in the present invention, is purely prepared from using inorganic material, and its fire resistance is excellent;Due to pottery
Grain intensity is high, and with interior care action, solves the high-strength low shortcoming of materials for wall;The materials for wall is easy to use simultaneously,
It is easy to cutting, it is not necessary to individually construction.Additionally, the present invention produces materials for wall by the use of red mud and slag as main raw material(s),
The two can be solved and bring huge environmental pollution.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention.It is all in essence of the invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (10)
1. slag, carbide slag and haydite high-strength wall insulation material, it is characterised in that:By slag powders, calcium carbide ground-slag, haydite, sand
Son, dicalcium powder, latex powder, cellulose ether, water composition;Its mass percent is respectively:Slag powders:10.0~50.0%;Calcium carbide
Ground-slag:8.0~40.0%;Haydite:30.0~60.0%;Sand:15.0~30.0%;Dicalcium powder:5.0~20.0%;Latex
Powder:1.5~5.0%;Cellulose ether:0.5~2.0%;Water:12.0~30.0%.
2. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:Described
Slag powders be ironmaking processes formed granulated blast-furnace slag by forming powder after grinding, its main component be CaO, SiO2、
Al2O3And Fe2O3, wherein the tricalcium silicate containing part and dicalcium silicate thing phase, with hydraulic property, its density is 2.7~
2.9g/cm3, less than 0.08mm, specific surface area is 400~450m to maximum particle diameter2/kg。
3. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:Described
Calcium carbide ground-slag is that calcium carbide reacts the product to be formed with water, the industrial accessory substance produced from production acetylene gas, white powder
End, its main component is calcium hydroxide, displays the ingredients calcium carbonate containing part in carbide slag for many years.
4. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:Described
Haydite is strong by one kind of grinding, balling-up and sintering by the composition including clay, shale, gangue, sludge or red mud
High, lightweight, the porous agglomerated material of degree, the particle diameter of haydite is 1-5mm or 5-10mm or 10-25mm, and color is
Kermesinus or maroon, its bulk density are 300-900km/m3。
5. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:The sand
Attached bag includes artificial sand and natural sand, and particle diameter is less than 5mm.
6. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:It is described heavy
Calcium powder is heavy calcium carbonate powder, mainly with lime stone as raw material, the white powder to be formed is processed by mechanical powder, and particle diameter is
350 mesh.
7. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:The breast
It can be the powder thermoplastic resin material processed by high molecular polymerization emulsion in dispersed latex powder that rubber powder is.
8. slag according to claim 1, carbide slag and haydite high-strength wall insulation material, it is characterised in that:The fibre
The plain ether of dimension is using wood fibre or refines short cotton fiber as primary raw material, it is chemically treated after, reacted by etherifying agent
The powdered cellulose ether for being generated.
9. the preparation method of slag, carbide slag and haydite high-strength wall insulation material, it is characterised in that:With slag, carbide slag, pottery
Grain, sand and auxiliary agent are raw material, by the use of inorganic coagulation material as binding agent, the high-strength wall with haydite as aggregate is prepared from
Body insulation material.
10. the preparation method of slag according to claim 9, carbide slag and haydite high-strength wall insulation material, its feature
It is:Comprise the following steps:
Step 1:Haydite is pre-processed;
After haydite is soaked into 24h with running water at room temperature, surface moisture is filtered off to saturated dry surface, it is stand-by;
Step 2:Weigh mixing;
In parts by mass, the haydite 30~60 for having pre-processed, slag powders are prepared:8~40, sand 15~30, dicalcium powder 5~20,
Latex powder 1.5~5.0, cellulose ether 0.5~2.0;
The raw material that will be weighed up loads in concrete mixer, 2~6min of mechanical agitation, and rotating speed is 60~80r/min;
Step 3:Add water stirring;
Water 12.0~30.0,6~8min of mechanical agitation are added in above-mentioned stirring siccative, rotating speed is 60~80r/min;
Step 4:Formed product;
The above-mentioned fresh material being stirred is fitted into the metal die of given size, it is thin with plastics after 5~15s of mechanical oscillation
Film cover die surface, temperature be 20 ± 1 DEG C, humidity be 80~95% fog room or curing box in conserve 24h;
Step 5:The demoulding is conserved;
After the product stripping after 24h will be conserved, feeding temperature for 20 ± 1 DEG C fog room or after continuing to conserve 28 days in the water i.e.
Can be used.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109987904A (en) * | 2019-05-06 | 2019-07-09 | 徐州天道装饰工程有限责任公司 | A kind of fabricating technology of brick setting material |
CN110002808A (en) * | 2019-05-17 | 2019-07-12 | 辽宁工程技术大学 | A kind of alkali-activated material solidification iron tailings sand and preparation method thereof and application method |
CN110803892A (en) * | 2019-11-29 | 2020-02-18 | 南京绿色增材智造研究院有限公司 | Light insulation board and preparation method thereof |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100567734B1 (en) * | 2004-12-01 | 2006-04-04 | 현대산업개발 주식회사 | The construction method of inner wall using dry-light insulating panels for thermal insulation in bathroom wall envelope |
CN101525217A (en) * | 2009-04-21 | 2009-09-09 | 常州工程职业技术学院 | Environmental-friendly clinker-free cement and preparation method thereof |
CN101928127A (en) * | 2010-08-30 | 2010-12-29 | 武汉海剑工贸有限责任公司 | Super-light aggregate concrete for long-distance homogeneous pumping construction and preparation method thereof |
CN102358688A (en) * | 2011-08-23 | 2012-02-22 | 马鞍山科达机电有限公司 | Lightweight high-strength press molding block, and production method thereof |
CN104150821A (en) * | 2014-07-16 | 2014-11-19 | 广西大学 | Ceramsite recycled concrete as well as hollow block masonry and preparation method thereof |
CN104310906A (en) * | 2014-10-16 | 2015-01-28 | 成都建工成新混凝土工程有限公司 | Structural lightweight aggregate concrete |
CN104945007A (en) * | 2015-06-12 | 2015-09-30 | 中民筑友有限公司 | Precast aerated ceramsite concrete component and preparation method thereof |
CN105541227A (en) * | 2015-12-25 | 2016-05-04 | 河南兴安新型建筑材料有限公司 | Yellow River sand masonry thermal-insulation mortar and preparation method of Yellow River sand masonry thermal-insulation mortar |
-
2016
- 2016-12-09 CN CN201611127356.7A patent/CN106747148A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100567734B1 (en) * | 2004-12-01 | 2006-04-04 | 현대산업개발 주식회사 | The construction method of inner wall using dry-light insulating panels for thermal insulation in bathroom wall envelope |
CN101525217A (en) * | 2009-04-21 | 2009-09-09 | 常州工程职业技术学院 | Environmental-friendly clinker-free cement and preparation method thereof |
CN101928127A (en) * | 2010-08-30 | 2010-12-29 | 武汉海剑工贸有限责任公司 | Super-light aggregate concrete for long-distance homogeneous pumping construction and preparation method thereof |
CN102358688A (en) * | 2011-08-23 | 2012-02-22 | 马鞍山科达机电有限公司 | Lightweight high-strength press molding block, and production method thereof |
CN104150821A (en) * | 2014-07-16 | 2014-11-19 | 广西大学 | Ceramsite recycled concrete as well as hollow block masonry and preparation method thereof |
CN104310906A (en) * | 2014-10-16 | 2015-01-28 | 成都建工成新混凝土工程有限公司 | Structural lightweight aggregate concrete |
CN104945007A (en) * | 2015-06-12 | 2015-09-30 | 中民筑友有限公司 | Precast aerated ceramsite concrete component and preparation method thereof |
CN105541227A (en) * | 2015-12-25 | 2016-05-04 | 河南兴安新型建筑材料有限公司 | Yellow River sand masonry thermal-insulation mortar and preparation method of Yellow River sand masonry thermal-insulation mortar |
Non-Patent Citations (2)
Title |
---|
刘文斌,徐永红: "电石渣激发矿渣活性的研究", 《粉煤灰》 * |
唐笑: "大流动性结构轻集料混凝土性能研究", 《中国优秀硕士学位论文全文数据库工程科技Ⅱ辑》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109987904A (en) * | 2019-05-06 | 2019-07-09 | 徐州天道装饰工程有限责任公司 | A kind of fabricating technology of brick setting material |
CN110002808A (en) * | 2019-05-17 | 2019-07-12 | 辽宁工程技术大学 | A kind of alkali-activated material solidification iron tailings sand and preparation method thereof and application method |
CN110803892A (en) * | 2019-11-29 | 2020-02-18 | 南京绿色增材智造研究院有限公司 | Light insulation board and preparation method thereof |
CN110803892B (en) * | 2019-11-29 | 2021-08-06 | 南京绿色增材智造研究院有限公司 | Light insulation board and preparation method thereof |
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