CN106365457A - Light foaming material prepared by using calcium carbonate residue and waste glass and method - Google Patents
Light foaming material prepared by using calcium carbonate residue and waste glass and method Download PDFInfo
- Publication number
- CN106365457A CN106365457A CN201610748508.9A CN201610748508A CN106365457A CN 106365457 A CN106365457 A CN 106365457A CN 201610748508 A CN201610748508 A CN 201610748508A CN 106365457 A CN106365457 A CN 106365457A
- Authority
- CN
- China
- Prior art keywords
- calcium carbonate
- cullet
- foam material
- carbonate slag
- lightweight foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title claims abstract description 103
- 238000000034 method Methods 0.000 title claims abstract description 26
- 239000011521 glass Substances 0.000 title claims abstract description 11
- 239000002699 waste material Substances 0.000 title claims abstract description 10
- 239000000463 material Substances 0.000 title claims abstract description 9
- 238000005187 foaming Methods 0.000 title abstract 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 49
- 239000006260 foam Substances 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000003381 stabilizer Substances 0.000 claims abstract description 12
- 239000006063 cullet Substances 0.000 claims description 56
- 239000002893 slag Substances 0.000 claims description 47
- 239000006261 foam material Substances 0.000 claims description 31
- 238000010438 heat treatment Methods 0.000 claims description 18
- 230000004907 flux Effects 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- MPPQGYCZBNURDG-UHFFFAOYSA-N 2-propionyl-6-dimethylaminonaphthalene Chemical compound C1=C(N(C)C)C=CC2=CC(C(=O)CC)=CC=C21 MPPQGYCZBNURDG-UHFFFAOYSA-N 0.000 claims description 5
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 5
- 239000003337 fertilizer Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims description 4
- 239000004317 sodium nitrate Substances 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 239000005357 flat glass Substances 0.000 claims description 2
- 239000011819 refractory material Substances 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 238000001802 infusion Methods 0.000 claims 1
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 239000004088 foaming agent Substances 0.000 abstract description 4
- 238000009413 insulation Methods 0.000 abstract description 4
- 239000011159 matrix material Substances 0.000 abstract description 3
- 238000005245 sintering Methods 0.000 abstract description 3
- 239000004566 building material Substances 0.000 abstract description 2
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 239000011494 foam glass Substances 0.000 description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 3
- 239000004567 concrete Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000010881 fly ash Substances 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 2
- 239000002956 ash Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000013332 literature search Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011257 shell material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C11/00—Multi-cellular glass ; Porous or hollow glass or glass particles
- C03C11/007—Foam glass, e.g. obtained by incorporating a blowing agent and heating
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/08—Other methods of shaping glass by foaming
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
The invention relates to a light foaming material prepared by using calcium carbonate residue and waste glass and a method, and belongs to the technical field of the building materials. The method comprises the following steps: using the calcium carbonate residue and waste glass which pollute the environment as the main raw materials, respectively pre-treating, under the high temperature and high pressure and the auxiliary functions of a fluxing agent and a foam stabilizer, using the fused waste glass as a matrix, using the main component CaCO3 of the calcium carbonate residue as a foaming agent, analyzing to generate a CO2 gas under the high temperature condition, forming the stable bubbles in the fused solution of the calcium carbonate residue and the waste glass, and preparing the light foaming material through the strict sintering schedule and post-treating process. The light foaming material is extensively used for the fields, such as heat insulation, wall construction, sound absorption and noise reduction, and has the remarkable social economic and environment friendly benefits.
Description
Technical field
The present invention relates to the lightweight foam material of a kind of use Calcium Carbonate slag and cullet preparation and method, belong to Building wood
Material technical field.
Background technology
With China's rapid economic development, annual trade waste yield is huge.Calcium Carbonate Zha Shi production of phosphate fertilizer enterprise
The industrial residue producing during producing nitrophosphate fertilizer, yield is huge, pollutes environment.The chemical stability of glass is preferable,
It is widely used in modern architecture and daily life, in innocuousness.But because of its stable chemical nature, cullet is cleared up naturally
Process is slow, and a large amount of cullet are piled up and brought adverse effect to also people life, also result in the wasting of resources simultaneously.
The present invention will have the Calcium Carbonate slag of pollution, cullet to be prepared into lightweight foam material to environment, by Calcium Carbonate slag and
Cullet is distinguished after pretreatment, under High Temperature High Pressure and flux and foam stabilizer assosting effect, to melt cullet as matrix,
With Calcium Carbonate slag main component caco3For foaming agent, decompose under the high temperature conditions and produce co2Gas, melts in Calcium Carbonate slag cullet
Form stable bubble in melt body, and by strict sintering schedule and aftertreatment technology, prepare lightweight foam material.The present invention
Prepared Calcium Carbonate slag and cullet lightweight foam material quality meet GB " foam glass insulating product " (jct 647-
2005) prescription, has significant society, economic and environmental benefit.
Find through literature search, " method preparing foam glass using flyash and cullet " (application number:
201210368160.2), " method preparing high-intensity foam glass using red mud and cullet " (application number:
20120368246.5), " method preparing foam glass using plant ash and cullet " (application number: 201410092750.6),
A kind of " method preparing foam glass using shell and cullet " (application number: 201510073679.1) and paper " glass
The development of base composite material of waste and performance evaluation ", " coal ash phosphorus hydrochlorate foamed ceramics Study on Preparation " etc. be respectively
Prepare foamed glass using cullet with flyash, red mud, plant ash, shell, flyash and cast waste sand for primary raw material.
Patent " cullet produce foam glass technology " (application number: 201210210913.7), " a kind of cullet foam production high-strength
Light building material and preparation method " (application number: 201410424197.1) etc. with cullet as primary raw material, make in foaming agent
With under prepare lightweight foam material.The above all prepares light-weight foam using cullet and Calcium Carbonate slag for raw material with the present invention
Material is different.
By inquiring about to documents and materials, not yet find to prepare the report of lightweight foam material using Calcium Carbonate slag and cullet
Road.
Content of the invention
The invention provides the lightweight foam material of a kind of use Calcium Carbonate slag and cullet preparation and method, it is with carbonic acid
The method that calcium slag and cullet prepare lightweight foam material for primary raw material, has actively in terms of resources conservation and environmental conservation
Meaning.
The technical scheme is that: the lightweight foam material of a kind of Calcium Carbonate slag and cullet preparation, by following weight hundred
The raw material dividing ratio is made: Calcium Carbonate slag 28%~42%, cullet 45%~63%, flux 3%~8%, foam stabilizer 5%~11%.
Described Calcium Carbonate slag is the industrial residue producing during phosphatic fertilizer company produces nitrophosphate fertilizer, in light gray, is powder
Last shape granule, main component is Calcium Carbonate.
Described cullet is discarded ordinary plate glass and waste bottles glass.
Described flux is one or more of prodan, sodium carbonate, sodium nitrate.
Described foam stabilizer is one or more of sodium hexameta phosphate, antimony oxide, zinc oxide.
Described Calcium Carbonate slag and cullet prepare concretely comprising the following steps of the method for lightweight foam material:
(1) Calcium Carbonate slag pretreatment
Calcium Carbonate slag is dried, screens out particle diameter stand-by less than 0.075mm granule.
(2) cullet pretreatment
Cullet is cleaned, dries, crushing, ball-milling treatment, screen out particle diameter be less than 0.075mm granule stand-by.
(3) sinter
Above-mentioned each raw material is pressed and sets match ratio weighing weight, load in refractory-material dies after ball mill mix homogeneously, press
Procedure below is fired:
1. it is warming up to 370 DEG C~410 DEG C from room temperature with the heating rate of 3 DEG C~8 DEG C/min, be incubated 10min~30min;
2. it is warming up to 600 DEG C~750 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
3. it is warming up to 850 DEG C~950 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
4. it is cooled to 500 DEG C~650 DEG C with the rate of temperature fall of 15 DEG C~30 DEG C/min, be incubated 40min~65min;
5. room temperature is cooled to the rate of temperature fall of 0.5 DEG C~5 DEG C/min.
(4) demoulding, cutting, obtain finished product.
The invention has the beneficial effects as follows: lightweight is prepared for primary raw material with the Calcium Carbonate slag having pollution to environment, cullet
Expanded material.Calcium Carbonate slag and cullet are distinguished after pretreatment, in High Temperature High Pressure and flux and foam stabilizer assosting effect
Under, to melt cullet as matrix, with Calcium Carbonate slag main component caco3For foaming agent, decompose under the high temperature conditions and produce co2
Gas, forms stable bubble in Calcium Carbonate slag cullet molten mass, and by strict sintering schedule and aftertreatment technology,
Prepare lightweight foam material.Calcium Carbonate slag prepared by the present invention and cullet lightweight foam material quality meet GB " foam
Glass insulating product " (jct 647-2005) prescription, there is significant society, economic and environmental benefit.
Specific embodiment
With reference to specific embodiment, the invention will be further described, but the scope of the present invention is not limited only to embodiment
Content.
Embodiment 1: Calcium Carbonate slag and cullet lightweight foam material, it is made up of the raw material of following parts by weight: Calcium Carbonate
28 parts of slag, 63 parts of cullet, 3 parts of flux, wherein 2 parts of prodan, 1 part of sodium carbonate, 6 parts of foam stabilizer, wherein hexa metaphosphoric acid
2 parts of sodium, 3 parts of antimony oxide, 1 part of zinc oxide.
Lightweight foam material and method that a kind of described use Calcium Carbonate slag and cullet produce, methods described concrete
Step is:
Ball mill will be sent into after the Calcium Carbonate slag of pretreatment, cullet and flux, foam stabilizer metering, after mix homogeneously
Compound is loaded fireproof die, band mould sends into natural gas heating kiln.It is heated to 370 DEG C with 3 DEG C/min heating rate, insulation
30min;It is heated to 600 DEG C with 20 DEG C/min heating rate again, be incubated 30min;It is heated to 850 with 20 DEG C/min heating rate again
DEG C, it is incubated 30min;It is cooled to 650 DEG C with 15 DEG C/min rate of temperature fall, be incubated 65min;Finally with 0.5 DEG C/min rate of temperature fall
It is down to room temperature.Take out mould, the demoulding in kiln, take out that lightweight foam material is cleaved obtains finished product.
The Calcium Carbonate slag cullet lightweight foam material being obtained with method according to said ratio, its performance is as follows: density
140kg/m3, comprcssive strength 0.6mpa, rupture strength 0.6mpa, water absorption rate 0.4, moisture permeable coefficient 0.006, heat conductivity 0.060.
Embodiment 2: Calcium Carbonate slag and cullet lightweight foam material, it is made up of the raw material of following parts by weight: Calcium Carbonate
42 parts of slag, 45 parts of cullet, 8 parts of flux, wherein 6 parts of prodan, 2 parts of sodium nitrate, 5 parts of foam stabilizer, wherein hexa metaphosphoric acid
2 parts of sodium, 2 parts of antimony oxide, 1 part of zinc oxide.
Lightweight foam material and method that a kind of described use Calcium Carbonate slag and cullet produce, methods described concrete
Step is:
Ball mill will be sent into after the Calcium Carbonate slag of pretreatment, cullet and flux, foam stabilizer metering, after mix homogeneously
Compound is loaded fireproof die, band mould sends into natural gas heating kiln.It is heated to 410 DEG C with 8 DEG C/min heating rate, insulation
10min;It is heated to 750 DEG C with 35 DEG C/min heating rate again, be incubated 10min;It is heated to 950 with 35 DEG C/min heating rate again
DEG C, it is incubated 10min;It is cooled to 500 DEG C with 30 DEG C/min rate of temperature fall, be incubated 40min;Finally with 5 DEG C/min rate of temperature fall fall
To room temperature.Take out mould, the demoulding in kiln, take out that lightweight foam material is cleaved obtains finished product.
The Calcium Carbonate slag cullet lightweight foam material being obtained with method according to said ratio, its performance is as follows: density
145kg/m3, comprcssive strength 0.5mpa, rupture strength 0.5mpa, water absorption rate 0.5, moisture permeable coefficient 0.007, heat conductivity 0.061.
Embodiment 3: Calcium Carbonate slag and cullet lightweight foam material, it is made up of the raw material of following parts by weight: Calcium Carbonate
35 parts of slag, 49 parts of cullet, 5 parts of flux, wherein 2 parts of prodan, 2 parts of sodium carbonate, 1 part of sodium nitrate, 11 parts of foam stabilizer, its
3 parts of middle sodium hexameta phosphate, 4 parts of antimony oxide, 4 parts of zinc oxide.
Lightweight foam material and method that a kind of described use Calcium Carbonate slag and cullet produce, methods described concrete
Step is:
Ball mill will be sent into after the Calcium Carbonate slag of pretreatment, cullet and flux, foam stabilizer metering, after mix homogeneously
Compound is loaded fireproof die, band mould sends into natural gas heating kiln.It is heated to 390 DEG C with 5 DEG C/min heating rate, insulation
20min;It is heated to 675 DEG C with 28 DEG C/min heating rate again, be incubated 20min;It is heated to 900 with 28 DEG C/min heating rate again
DEG C, it is incubated 20min;It is cooled to 575 DEG C with 22 DEG C/min rate of temperature fall, be incubated 60min;Finally with 3 DEG C/min rate of temperature fall fall
To room temperature.Take out mould, the demoulding in kiln, take out that lightweight foam material is cleaved obtains finished product.
The Calcium Carbonate slag cullet lightweight foam material being obtained with method according to said ratio, its performance is as follows: density
140kg/m3, comprcssive strength 0.5mpa, rupture strength 0.4mpa, water absorption rate 0.5, moisture permeable coefficient 0.006, heat conductivity 0.062.
Claims (6)
1. a kind of Calcium Carbonate slag and cullet preparation lightweight foam material it is characterised in that: former by following percentage by weight
Material is made: Calcium Carbonate slag 28%~42%, cullet 45%~63%, flux 3%~8%, foam stabilizer 5%~11%.
2. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described carbon
Sour calcium slag is the industrial residue producing during phosphatic fertilizer company produces nitrophosphate fertilizer, in light gray, is powdery granule, main one-tenth
Dividing is Calcium Carbonate.
3. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described useless
Glass is discarded ordinary plate glass or waste bottles glass.
4. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described help
Flux is one or more of prodan, sodium carbonate, sodium nitrate.
5. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described steady
Infusion is one or more of sodium hexameta phosphate, antimony oxide, zinc oxide.
6. a kind of Calcium Carbonate slag and cullet prepare lightweight foam material method it is characterised in that: concretely comprise the following steps:
(1) Calcium Carbonate slag pretreatment
Calcium Carbonate slag is dried, screens out particle diameter stand-by less than 0.075mm granule;
(2) cullet pretreatment
Cullet is cleaned, dries, crushing, ball-milling treatment, screen out particle diameter be less than 0.075mm granule stand-by;
(3) sinter
Above-mentioned each raw material is pressed and sets match ratio weighing weight, load in refractory-material dies after ball mill mix homogeneously, press
Procedure below is fired:
1. it is warming up to 370 DEG C~410 DEG C from room temperature with the heating rate of 3 DEG C~8 DEG C/min, be incubated 10min~30min;
2. it is warming up to 600 DEG C~750 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
3. it is warming up to 850 DEG C~950 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
4. it is cooled to 500 DEG C~650 DEG C with the rate of temperature fall of 15 DEG C~30 DEG C/min, be incubated 40min~65min;
5. room temperature is cooled to the rate of temperature fall of 0.5 DEG C~5 DEG C/min;
(4) demoulding, cutting, obtain finished product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610748508.9A CN106365457A (en) | 2016-08-30 | 2016-08-30 | Light foaming material prepared by using calcium carbonate residue and waste glass and method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610748508.9A CN106365457A (en) | 2016-08-30 | 2016-08-30 | Light foaming material prepared by using calcium carbonate residue and waste glass and method |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106365457A true CN106365457A (en) | 2017-02-01 |
Family
ID=57903663
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610748508.9A Pending CN106365457A (en) | 2016-08-30 | 2016-08-30 | Light foaming material prepared by using calcium carbonate residue and waste glass and method |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106365457A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107673586A (en) * | 2017-11-07 | 2018-02-09 | 北京科技大学 | A kind of method that solid waste prepares foam glass |
CN108756107A (en) * | 2018-06-27 | 2018-11-06 | 燕翔 | It is a kind of that sand abatvoix is covered based on mineral wool |
CN111285593A (en) * | 2020-03-26 | 2020-06-16 | 安徽汇昌新材料有限公司 | Preparation method of foam glass special for sound absorption |
CN111320394A (en) * | 2020-03-24 | 2020-06-23 | 安徽汇昌新材料有限公司 | Preparation method of foam glass with high abrasion resistance |
CN112876072A (en) * | 2021-01-27 | 2021-06-01 | 中钢集团马鞍山矿山研究总院股份有限公司 | Preparation method of microporous foamed glass |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10203836A (en) * | 1997-01-21 | 1998-08-04 | Kamaike Yutaka | Production of foam glass |
CN101602574A (en) * | 2009-07-14 | 2009-12-16 | 陕西科技大学 | A kind of preparation method of high strength multicellular glass |
-
2016
- 2016-08-30 CN CN201610748508.9A patent/CN106365457A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH10203836A (en) * | 1997-01-21 | 1998-08-04 | Kamaike Yutaka | Production of foam glass |
CN101602574A (en) * | 2009-07-14 | 2009-12-16 | 陕西科技大学 | A kind of preparation method of high strength multicellular glass |
Non-Patent Citations (1)
Title |
---|
张兴法: "磷石膏综合利用副产物碳酸钙渣的再资源化", 《化工矿物与加工》 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107673586A (en) * | 2017-11-07 | 2018-02-09 | 北京科技大学 | A kind of method that solid waste prepares foam glass |
CN107673586B (en) * | 2017-11-07 | 2020-11-17 | 北京科技大学 | Method for preparing foam glass from solid waste |
CN108756107A (en) * | 2018-06-27 | 2018-11-06 | 燕翔 | It is a kind of that sand abatvoix is covered based on mineral wool |
CN111320394A (en) * | 2020-03-24 | 2020-06-23 | 安徽汇昌新材料有限公司 | Preparation method of foam glass with high abrasion resistance |
CN111285593A (en) * | 2020-03-26 | 2020-06-16 | 安徽汇昌新材料有限公司 | Preparation method of foam glass special for sound absorption |
CN112876072A (en) * | 2021-01-27 | 2021-06-01 | 中钢集团马鞍山矿山研究总院股份有限公司 | Preparation method of microporous foamed glass |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106365457A (en) | Light foaming material prepared by using calcium carbonate residue and waste glass and method | |
CN113968701B (en) | CO (carbon monoxide) 2 Light concrete for driving consolidation and preparation method thereof | |
CN105130324B (en) | Manufacture method for autoclaved fly-ash aerated concrete block | |
CN103011882B (en) | Inorganic heat-insulating material with three-level hole structure and preparation method of inorganic heat-insulating material | |
CN103880289A (en) | Multifunctional environment-friendly foam glass product and preparation method thereof | |
CN104445956B (en) | Method for preparing porous glass ceramics by waste glass through low-temperature melting and high temperature foaming | |
CN104609888A (en) | Production process of foamed ceramics | |
CN110183099A (en) | A kind of manufacturing method of expanded porous glass particle | |
CN108484115A (en) | A kind of porous material prepared using solid waste | |
CN108395271A (en) | Full waste residue foamed ceramics of coal gangue-fly ash-silica sand tailing system and preparation method thereof | |
CN108821621A (en) | A kind of light high-strength haydite and preparation method | |
CN112552072A (en) | Construction waste regenerated foamed ceramic and preparation method thereof | |
CN103936454A (en) | Porous thermal insulation ceramic using gold copper mine tailings as raw material and preparation method thereof | |
CN104003749A (en) | Electrolytic manganese slag closed type porous material and in-situ foaming preparation method | |
CN107746215A (en) | A kind of mineral polymer foam concrete and preparation method | |
CN106278176B (en) | A kind of high-strength ceramic granule and preparation method thereof | |
CN115677248B (en) | Carbon-fixing lightweight aggregate and preparation method thereof | |
CN104211429B (en) | A kind of combined light heat-insulating sound-insulating brick | |
CN103172253B (en) | A kind of method of utilizing the spontaneous brewed standby froth inorganic stock of gangue cenosphere | |
CN105417958B (en) | A kind of method that high-intensity foam glass material is prepared using copper tailing | |
CN104909663B (en) | A kind of materials recycling phase transformation cement foaming insulation board and preparation method thereof | |
CN103833290B (en) | What utilize foam cement waste material to prepare is non-burning brick and preparation method thereof | |
CN101781125B (en) | Light building material produced by using phosphorus chemical industrial waste residual | |
CN106007641A (en) | Heat-preserving flame-retardant hollow brick and preparation method thereof | |
CN106518138B (en) | A kind of preparation method of foam ceramic thermal insulation building block |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170201 |
|
RJ01 | Rejection of invention patent application after publication |