CN106365457A - Light foaming material prepared by using calcium carbonate residue and waste glass and method - Google Patents

Light foaming material prepared by using calcium carbonate residue and waste glass and method Download PDF

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Publication number
CN106365457A
CN106365457A CN201610748508.9A CN201610748508A CN106365457A CN 106365457 A CN106365457 A CN 106365457A CN 201610748508 A CN201610748508 A CN 201610748508A CN 106365457 A CN106365457 A CN 106365457A
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CN
China
Prior art keywords
calcium carbonate
cullet
foam material
carbonate slag
lightweight foam
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Pending
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CN201610748508.9A
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Chinese (zh)
Inventor
林志伟
郭荣鑫
颜峰
夏海廷
马倩敏
王峰宪
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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Priority to CN201610748508.9A priority Critical patent/CN106365457A/en
Publication of CN106365457A publication Critical patent/CN106365457A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C11/00Multi-cellular glass ; Porous or hollow glass or glass particles
    • C03C11/007Foam glass, e.g. obtained by incorporating a blowing agent and heating
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B19/00Other methods of shaping glass
    • C03B19/08Other methods of shaping glass by foaming

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to a light foaming material prepared by using calcium carbonate residue and waste glass and a method, and belongs to the technical field of the building materials. The method comprises the following steps: using the calcium carbonate residue and waste glass which pollute the environment as the main raw materials, respectively pre-treating, under the high temperature and high pressure and the auxiliary functions of a fluxing agent and a foam stabilizer, using the fused waste glass as a matrix, using the main component CaCO3 of the calcium carbonate residue as a foaming agent, analyzing to generate a CO2 gas under the high temperature condition, forming the stable bubbles in the fused solution of the calcium carbonate residue and the waste glass, and preparing the light foaming material through the strict sintering schedule and post-treating process. The light foaming material is extensively used for the fields, such as heat insulation, wall construction, sound absorption and noise reduction, and has the remarkable social economic and environment friendly benefits.

Description

The lightweight foam material of a kind of use Calcium Carbonate slag and cullet preparation and method
Technical field
The present invention relates to the lightweight foam material of a kind of use Calcium Carbonate slag and cullet preparation and method, belong to Building wood Material technical field.
Background technology
With China's rapid economic development, annual trade waste yield is huge.Calcium Carbonate Zha Shi production of phosphate fertilizer enterprise The industrial residue producing during producing nitrophosphate fertilizer, yield is huge, pollutes environment.The chemical stability of glass is preferable, It is widely used in modern architecture and daily life, in innocuousness.But because of its stable chemical nature, cullet is cleared up naturally Process is slow, and a large amount of cullet are piled up and brought adverse effect to also people life, also result in the wasting of resources simultaneously.
The present invention will have the Calcium Carbonate slag of pollution, cullet to be prepared into lightweight foam material to environment, by Calcium Carbonate slag and Cullet is distinguished after pretreatment, under High Temperature High Pressure and flux and foam stabilizer assosting effect, to melt cullet as matrix, With Calcium Carbonate slag main component caco3For foaming agent, decompose under the high temperature conditions and produce co2Gas, melts in Calcium Carbonate slag cullet Form stable bubble in melt body, and by strict sintering schedule and aftertreatment technology, prepare lightweight foam material.The present invention Prepared Calcium Carbonate slag and cullet lightweight foam material quality meet GB " foam glass insulating product " (jct 647- 2005) prescription, has significant society, economic and environmental benefit.
Find through literature search, " method preparing foam glass using flyash and cullet " (application number: 201210368160.2), " method preparing high-intensity foam glass using red mud and cullet " (application number: 20120368246.5), " method preparing foam glass using plant ash and cullet " (application number: 201410092750.6), A kind of " method preparing foam glass using shell and cullet " (application number: 201510073679.1) and paper " glass The development of base composite material of waste and performance evaluation ", " coal ash phosphorus hydrochlorate foamed ceramics Study on Preparation " etc. be respectively Prepare foamed glass using cullet with flyash, red mud, plant ash, shell, flyash and cast waste sand for primary raw material. Patent " cullet produce foam glass technology " (application number: 201210210913.7), " a kind of cullet foam production high-strength Light building material and preparation method " (application number: 201410424197.1) etc. with cullet as primary raw material, make in foaming agent With under prepare lightweight foam material.The above all prepares light-weight foam using cullet and Calcium Carbonate slag for raw material with the present invention Material is different.
By inquiring about to documents and materials, not yet find to prepare the report of lightweight foam material using Calcium Carbonate slag and cullet Road.
Content of the invention
The invention provides the lightweight foam material of a kind of use Calcium Carbonate slag and cullet preparation and method, it is with carbonic acid The method that calcium slag and cullet prepare lightweight foam material for primary raw material, has actively in terms of resources conservation and environmental conservation Meaning.
The technical scheme is that: the lightweight foam material of a kind of Calcium Carbonate slag and cullet preparation, by following weight hundred The raw material dividing ratio is made: Calcium Carbonate slag 28%~42%, cullet 45%~63%, flux 3%~8%, foam stabilizer 5%~11%.
Described Calcium Carbonate slag is the industrial residue producing during phosphatic fertilizer company produces nitrophosphate fertilizer, in light gray, is powder Last shape granule, main component is Calcium Carbonate.
Described cullet is discarded ordinary plate glass and waste bottles glass.
Described flux is one or more of prodan, sodium carbonate, sodium nitrate.
Described foam stabilizer is one or more of sodium hexameta phosphate, antimony oxide, zinc oxide.
Described Calcium Carbonate slag and cullet prepare concretely comprising the following steps of the method for lightweight foam material:
(1) Calcium Carbonate slag pretreatment
Calcium Carbonate slag is dried, screens out particle diameter stand-by less than 0.075mm granule.
(2) cullet pretreatment
Cullet is cleaned, dries, crushing, ball-milling treatment, screen out particle diameter be less than 0.075mm granule stand-by.
(3) sinter
Above-mentioned each raw material is pressed and sets match ratio weighing weight, load in refractory-material dies after ball mill mix homogeneously, press Procedure below is fired:
1. it is warming up to 370 DEG C~410 DEG C from room temperature with the heating rate of 3 DEG C~8 DEG C/min, be incubated 10min~30min;
2. it is warming up to 600 DEG C~750 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
3. it is warming up to 850 DEG C~950 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
4. it is cooled to 500 DEG C~650 DEG C with the rate of temperature fall of 15 DEG C~30 DEG C/min, be incubated 40min~65min;
5. room temperature is cooled to the rate of temperature fall of 0.5 DEG C~5 DEG C/min.
(4) demoulding, cutting, obtain finished product.
The invention has the beneficial effects as follows: lightweight is prepared for primary raw material with the Calcium Carbonate slag having pollution to environment, cullet Expanded material.Calcium Carbonate slag and cullet are distinguished after pretreatment, in High Temperature High Pressure and flux and foam stabilizer assosting effect Under, to melt cullet as matrix, with Calcium Carbonate slag main component caco3For foaming agent, decompose under the high temperature conditions and produce co2 Gas, forms stable bubble in Calcium Carbonate slag cullet molten mass, and by strict sintering schedule and aftertreatment technology, Prepare lightweight foam material.Calcium Carbonate slag prepared by the present invention and cullet lightweight foam material quality meet GB " foam Glass insulating product " (jct 647-2005) prescription, there is significant society, economic and environmental benefit.
Specific embodiment
With reference to specific embodiment, the invention will be further described, but the scope of the present invention is not limited only to embodiment Content.
Embodiment 1: Calcium Carbonate slag and cullet lightweight foam material, it is made up of the raw material of following parts by weight: Calcium Carbonate 28 parts of slag, 63 parts of cullet, 3 parts of flux, wherein 2 parts of prodan, 1 part of sodium carbonate, 6 parts of foam stabilizer, wherein hexa metaphosphoric acid 2 parts of sodium, 3 parts of antimony oxide, 1 part of zinc oxide.
Lightweight foam material and method that a kind of described use Calcium Carbonate slag and cullet produce, methods described concrete Step is:
Ball mill will be sent into after the Calcium Carbonate slag of pretreatment, cullet and flux, foam stabilizer metering, after mix homogeneously Compound is loaded fireproof die, band mould sends into natural gas heating kiln.It is heated to 370 DEG C with 3 DEG C/min heating rate, insulation 30min;It is heated to 600 DEG C with 20 DEG C/min heating rate again, be incubated 30min;It is heated to 850 with 20 DEG C/min heating rate again DEG C, it is incubated 30min;It is cooled to 650 DEG C with 15 DEG C/min rate of temperature fall, be incubated 65min;Finally with 0.5 DEG C/min rate of temperature fall It is down to room temperature.Take out mould, the demoulding in kiln, take out that lightweight foam material is cleaved obtains finished product.
The Calcium Carbonate slag cullet lightweight foam material being obtained with method according to said ratio, its performance is as follows: density 140kg/m3, comprcssive strength 0.6mpa, rupture strength 0.6mpa, water absorption rate 0.4, moisture permeable coefficient 0.006, heat conductivity 0.060.
Embodiment 2: Calcium Carbonate slag and cullet lightweight foam material, it is made up of the raw material of following parts by weight: Calcium Carbonate 42 parts of slag, 45 parts of cullet, 8 parts of flux, wherein 6 parts of prodan, 2 parts of sodium nitrate, 5 parts of foam stabilizer, wherein hexa metaphosphoric acid 2 parts of sodium, 2 parts of antimony oxide, 1 part of zinc oxide.
Lightweight foam material and method that a kind of described use Calcium Carbonate slag and cullet produce, methods described concrete Step is:
Ball mill will be sent into after the Calcium Carbonate slag of pretreatment, cullet and flux, foam stabilizer metering, after mix homogeneously Compound is loaded fireproof die, band mould sends into natural gas heating kiln.It is heated to 410 DEG C with 8 DEG C/min heating rate, insulation 10min;It is heated to 750 DEG C with 35 DEG C/min heating rate again, be incubated 10min;It is heated to 950 with 35 DEG C/min heating rate again DEG C, it is incubated 10min;It is cooled to 500 DEG C with 30 DEG C/min rate of temperature fall, be incubated 40min;Finally with 5 DEG C/min rate of temperature fall fall To room temperature.Take out mould, the demoulding in kiln, take out that lightweight foam material is cleaved obtains finished product.
The Calcium Carbonate slag cullet lightweight foam material being obtained with method according to said ratio, its performance is as follows: density 145kg/m3, comprcssive strength 0.5mpa, rupture strength 0.5mpa, water absorption rate 0.5, moisture permeable coefficient 0.007, heat conductivity 0.061.
Embodiment 3: Calcium Carbonate slag and cullet lightweight foam material, it is made up of the raw material of following parts by weight: Calcium Carbonate 35 parts of slag, 49 parts of cullet, 5 parts of flux, wherein 2 parts of prodan, 2 parts of sodium carbonate, 1 part of sodium nitrate, 11 parts of foam stabilizer, its 3 parts of middle sodium hexameta phosphate, 4 parts of antimony oxide, 4 parts of zinc oxide.
Lightweight foam material and method that a kind of described use Calcium Carbonate slag and cullet produce, methods described concrete Step is:
Ball mill will be sent into after the Calcium Carbonate slag of pretreatment, cullet and flux, foam stabilizer metering, after mix homogeneously Compound is loaded fireproof die, band mould sends into natural gas heating kiln.It is heated to 390 DEG C with 5 DEG C/min heating rate, insulation 20min;It is heated to 675 DEG C with 28 DEG C/min heating rate again, be incubated 20min;It is heated to 900 with 28 DEG C/min heating rate again DEG C, it is incubated 20min;It is cooled to 575 DEG C with 22 DEG C/min rate of temperature fall, be incubated 60min;Finally with 3 DEG C/min rate of temperature fall fall To room temperature.Take out mould, the demoulding in kiln, take out that lightweight foam material is cleaved obtains finished product.
The Calcium Carbonate slag cullet lightweight foam material being obtained with method according to said ratio, its performance is as follows: density 140kg/m3, comprcssive strength 0.5mpa, rupture strength 0.4mpa, water absorption rate 0.5, moisture permeable coefficient 0.006, heat conductivity 0.062.

Claims (6)

1. a kind of Calcium Carbonate slag and cullet preparation lightweight foam material it is characterised in that: former by following percentage by weight Material is made: Calcium Carbonate slag 28%~42%, cullet 45%~63%, flux 3%~8%, foam stabilizer 5%~11%.
2. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described carbon Sour calcium slag is the industrial residue producing during phosphatic fertilizer company produces nitrophosphate fertilizer, in light gray, is powdery granule, main one-tenth Dividing is Calcium Carbonate.
3. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described useless Glass is discarded ordinary plate glass or waste bottles glass.
4. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described help Flux is one or more of prodan, sodium carbonate, sodium nitrate.
5. Calcium Carbonate slag according to claim 1 and cullet preparation lightweight foam material it is characterised in that: described steady Infusion is one or more of sodium hexameta phosphate, antimony oxide, zinc oxide.
6. a kind of Calcium Carbonate slag and cullet prepare lightweight foam material method it is characterised in that: concretely comprise the following steps:
(1) Calcium Carbonate slag pretreatment
Calcium Carbonate slag is dried, screens out particle diameter stand-by less than 0.075mm granule;
(2) cullet pretreatment
Cullet is cleaned, dries, crushing, ball-milling treatment, screen out particle diameter be less than 0.075mm granule stand-by;
(3) sinter
Above-mentioned each raw material is pressed and sets match ratio weighing weight, load in refractory-material dies after ball mill mix homogeneously, press Procedure below is fired:
1. it is warming up to 370 DEG C~410 DEG C from room temperature with the heating rate of 3 DEG C~8 DEG C/min, be incubated 10min~30min;
2. it is warming up to 600 DEG C~750 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
3. it is warming up to 850 DEG C~950 DEG C with the heating rate of 20 DEG C~35 DEG C/min, be incubated 10min~30min;
4. it is cooled to 500 DEG C~650 DEG C with the rate of temperature fall of 15 DEG C~30 DEG C/min, be incubated 40min~65min;
5. room temperature is cooled to the rate of temperature fall of 0.5 DEG C~5 DEG C/min;
(4) demoulding, cutting, obtain finished product.
CN201610748508.9A 2016-08-30 2016-08-30 Light foaming material prepared by using calcium carbonate residue and waste glass and method Pending CN106365457A (en)

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Application Number Priority Date Filing Date Title
CN201610748508.9A CN106365457A (en) 2016-08-30 2016-08-30 Light foaming material prepared by using calcium carbonate residue and waste glass and method

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Publication Number Publication Date
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107673586A (en) * 2017-11-07 2018-02-09 北京科技大学 A kind of method that solid waste prepares foam glass
CN108756107A (en) * 2018-06-27 2018-11-06 燕翔 It is a kind of that sand abatvoix is covered based on mineral wool
CN111285593A (en) * 2020-03-26 2020-06-16 安徽汇昌新材料有限公司 Preparation method of foam glass special for sound absorption
CN111320394A (en) * 2020-03-24 2020-06-23 安徽汇昌新材料有限公司 Preparation method of foam glass with high abrasion resistance
CN112876072A (en) * 2021-01-27 2021-06-01 中钢集团马鞍山矿山研究总院股份有限公司 Preparation method of microporous foamed glass

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10203836A (en) * 1997-01-21 1998-08-04 Kamaike Yutaka Production of foam glass
CN101602574A (en) * 2009-07-14 2009-12-16 陕西科技大学 A kind of preparation method of high strength multicellular glass

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10203836A (en) * 1997-01-21 1998-08-04 Kamaike Yutaka Production of foam glass
CN101602574A (en) * 2009-07-14 2009-12-16 陕西科技大学 A kind of preparation method of high strength multicellular glass

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张兴法: "磷石膏综合利用副产物碳酸钙渣的再资源化", 《化工矿物与加工》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107673586A (en) * 2017-11-07 2018-02-09 北京科技大学 A kind of method that solid waste prepares foam glass
CN107673586B (en) * 2017-11-07 2020-11-17 北京科技大学 Method for preparing foam glass from solid waste
CN108756107A (en) * 2018-06-27 2018-11-06 燕翔 It is a kind of that sand abatvoix is covered based on mineral wool
CN111320394A (en) * 2020-03-24 2020-06-23 安徽汇昌新材料有限公司 Preparation method of foam glass with high abrasion resistance
CN111285593A (en) * 2020-03-26 2020-06-16 安徽汇昌新材料有限公司 Preparation method of foam glass special for sound absorption
CN112876072A (en) * 2021-01-27 2021-06-01 中钢集团马鞍山矿山研究总院股份有限公司 Preparation method of microporous foamed glass

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Application publication date: 20170201

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