CN105995640A - Processing method of quick-frozen red-spotted groupers - Google Patents

Processing method of quick-frozen red-spotted groupers Download PDF

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Publication number
CN105995640A
CN105995640A CN201610394957.8A CN201610394957A CN105995640A CN 105995640 A CN105995640 A CN 105995640A CN 201610394957 A CN201610394957 A CN 201610394957A CN 105995640 A CN105995640 A CN 105995640A
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red
weight portion
spotted
processing method
spotted grouper
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林赛建
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Putian Haiyang Food Co Ltd
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Putian Haiyang Food Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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Abstract

The invention provides a processing method of quick-frozen red-spotted groupers. The processing method comprises the following steps of under the effect of ultrasonic waves, soaking red-spotted groupers in pickling fluid, wherein the pickling fluid is prepared from sodium carbonate, tea polyphenols, chitosan, sodium tripolyphosphate, citric acid, sodium chloride and water; quick-freezing the red-spotted groupers soaked in the pickling fluid in a quick-freezing machine, so that the core temperature of bodies of the red-spotted grouper is reduced to 15 DEG C or below within 3-4 hours; and performing cold sterilization through electron beams on the quick-frozen red-spotted groupers. The processing method disclosed by the invention has the advantages that firstly the sodium carbonate, the tea polyphenols, the chitosan, the sodium tripolyphosphate, the citric acid and the sodium chloride are used as components of the pickling fluid, so that the dehydration of the red-spotted groupers and the losses of nutrient components are restrained, the fish meat of the red-spotted grouper is prevented from protein denaturation, and the mouth feel is maintained; then, the effects of the ultrasonic waves are utilized, so that the diffusion of the pickling fluid to the inner parts of the red-spotted groupers is facilitated, and the fresh keeping time is long; then, a cold sterilization technique through the electron beams is adopted, so that the original flavor and the original color of the red-spotted groupers are maintained, and the red-spotted groupers are safe to eat.

Description

A kind of processing method of quick-freezing red-spotted grouper
Technical field
The present invention relates to food processing technology field, particularly relate to the processing of a kind of quick-freezing red-spotted grouper Method.
Background technology
Red-spotted grouper is a kind of abyssal fishes, has another name called stone Canis familiaris L. public, owing to body has erythema, so obtaining bright. In red-spotted grouper body, length, flat-sided, and color variation is a lot of, the most brown or red, with striped And speckle, it is the precious famous special product in sea, Shengsi, element is praised highly for China and foreign countries gourmets.Red-spotted grouper rich in Nutrient substance-protein needed for growth promoter, protein comprises various essential amino acid, is The high-quality protein food of the mankind, also containing needed by human such as linolenic acid, arachidonic acid, linoleic acids Fatty acid and eicosapentaenoic acid, docosahexenoic acid, be not only high-quality food, health care battalion The product of supporting, additionally it is possible to antithrombotic, reduce blood viscosity, make blood pressure drops, can be used for preventing and controlling Treat the multiple diseases such as myocardial infarction, coronary heart disease, vasculitis, cerebral arteriosclerosis.
At present, market utilizes the food that red-spotted grouper is made as raw material, mainly smoked foods And quick frozen food, wherein, puckery hard, the shortcoming without fresh fragrance road of sootiness red-spotted grouper mouthfeel;And it is fast Although freezing red-spotted grouper can preserve long time, but freezing, store, thaw during, Color and luster, local flavor, quality, retentiveness and the nutrition of the flesh of fish all there occurs bigger compared with fresh fish Change.
Along with progress and the development of science, in order to improve quality and the preservation term of the erythema flesh of fish, seek Ask safe, harmless, keep the preservation technique of the original quality of fresh fish to become more and more important.This Inventor considers, it is provided that the processing method of a kind of quick-freezing red-spotted grouper, keeps the original color of red-spotted grouper Pool, local flavor and nutrient substance, safety and sanitation, instant.
Summary of the invention
Present invention solves the technical problem that the processing method being to provide a kind of quick-freezing red-spotted grouper, protect Hold the original color and luster of red-spotted grouper, local flavor and nutrient substance.
In view of this, the processing method that the invention provides a kind of quick-freezing red-spotted grouper, including following Step: red-spotted grouper, under the effect of ultrasound wave, is soaked in pickling liquid by step a), described Pickling liquid includes: sodium carbonate 0.2-0.4 weight portion, tea polyphenols 0.1-0.2 weight portion, chitosan 0.2-0.3 weight portion, sodium tripolyphosphate 0.2-0.3 weight portion, citric acid 0.1-0.2 weight portion, Sodium chloride 0.02-0.03 weight portion, water 90-100 weight portion;Pickling liquid is soaked by step b) After red-spotted grouper quick-freezing in instant freezer, the central temperature of red-spotted grouper fish body dropped in 3-4 hour To less than-15 DEG C;Step c) carries out electron beam cold sterilization to the red-spotted grouper after quick-freezing.
Preferably, the pretreatment of red-spotted grouper is also included: choose suitable size, fresh, nothing is rotten Red-spotted grouper, with frozen water, it is carried out drip washing, removes surface impurity;By the red-spotted grouper after drip washing Cut open the belly, remove internal organs, remove the gill, strike off the black film in tripe.
Preferably, in step a, ultrasonic power is 10-20kHz.
Preferably, in step a, ultrasonic intensity is 11-30W/cm2
Preferably, in step a, red-spotted grouper soak time in pickling liquid is 20-30 minute.
Preferably, described pickling liquid includes: sodium carbonate 0.3-0.4 weight portion, tea polyphenols 0.12-0.15 weight portion, chitosan 0.22-0.28 weight portion, sodium tripolyphosphate 0.2-0.25 weight Amount part, citric acid 0.1-0.15 weight portion, sodium chloride 0.025-0.03 weight portion, water 95-100 Weight portion.
Preferably, described pickling liquid also includes medicinal liquid 0.5-2 weight portion, and described medicinal liquid is according to as follows Prepared by method: be the Herba Apocyni veneti of 9-11:7-9:5-7:8-10, Spica Prunellae, open country by mass ratio Flos Chrysanthemi, Ramulus Uncariae Cum Uncis are pulverized, mixing, decoct 2-5 hour, obtain medicinal liquid after adding water.
Preferably, described Herba Apocyni veneti, Spica Prunellae, Flos Chrysanthemi Indici, the mass ratio of Ramulus Uncariae Cum Uncis are 10:8: 6:9.
Preferably, red-spotted grouper also includes after soaking in pickling liquid: by pickling liquid soak after red Speckle fish drains the supernatant liquid on surface.
Preferably, in step c, the dosage of electron beam cold sterilization is 6-8kGy.
The processing method that the invention provides a kind of quick-freezing red-spotted grouper, comprises the following steps: super Under the effect of sound wave, being soaked by red-spotted grouper in pickling liquid, described pickling liquid includes: sodium carbonate 0.2-0.4 weight portion, tea polyphenols 0.1-0.2 weight portion, chitosan 0.2-0.3 weight portion, trimerization Sodium phosphate 0.2-0.3 weight portion, citric acid 0.1-0.2 weight portion, sodium chloride 0.02-0.03 weight Part, water 90-100 weight portion;Red-spotted grouper quick-freezing in instant freezer after pickling liquid is soaked, The central temperature of red-spotted grouper fish body dropped to less than-15 DEG C in 3-4 hour;To the erythema after quick-freezing Fish carries out electron beam cold sterilization.Compared with prior art, first, the present invention is with sodium carbonate, tea Polyphenol, chitosan part, sodium tripolyphosphate, citric acid, sodium chloride as the composition of pickling liquid, Each interaction between component, influences each other, synergism, it is suppressed that the dehydration of red-spotted grouper and The loss of nutritional labeling, prevents red-spotted grouper fish meat protein degeneration, keeps mouthfeel, thus improves The freeze proof quality of red-spotted grouper.Secondly, utilizing the effect of ultrasound wave, beneficially pickling liquid is to erythema Fish diffusion inside, thus the red-spotted grouper good refreshing effect after pickling liquid is pickled, and fresh keeping time Long.Again, use electron beam cold sterilization technology, keep original local flavor and the color and luster of red-spotted grouper, Edible safety.
Detailed description of the invention
In order to be further appreciated by the present invention, below in conjunction with embodiment to the preferred embodiment of the invention It is described, but it is to be understood that these describe simply as further illustrating inventive feature With advantage rather than limiting to the claimed invention.
The processing method that the embodiment of the invention discloses a kind of quick-freezing red-spotted grouper, including following step Rapid: red-spotted grouper, under the effect of ultrasound wave, is soaked in pickling liquid by step a), described in salt down Liquid processed includes: sodium carbonate 0.2-0.4 weight portion, tea polyphenols 0.1-0.2 weight portion, chitosan 0.2-0.3 weight portion, sodium tripolyphosphate 0.2-0.3 weight portion, citric acid 0.1-0.2 weight portion, Sodium chloride 0.02-0.03 weight portion, water 90-100 weight portion;Pickling liquid is soaked by step b) After red-spotted grouper quick-freezing in instant freezer, the central temperature of red-spotted grouper fish body dropped in 3-4 hour To less than-15 DEG C;Step c) carries out electron beam cold sterilization to the red-spotted grouper after quick-freezing.
Preferably, present invention additionally comprises the pretreatment of red-spotted grouper: choose suitable size, The red-spotted grouper that fresh, nothing is rotted, carries out drip washing with frozen water to it, removes surface impurity;To drench Red-spotted grouper after washing is cut open the belly, and removes internal organs, removes the gill, strikes off the black film in tripe.
In step a, under the effect of ultrasound wave, red-spotted grouper is soaked in pickling liquid.Its In, ul-trasonic irradiation is conducive to pickling liquid to red-spotted grouper diffusion inside, thus pickles through pickling liquid After red-spotted grouper good refreshing effect, and fresh keeping time is long.Ultrasonic power is preferably 10-20kH, More preferably 12-18kH;Ultrasonic intensity is preferably 11-30W/cm2, more preferably 13-20W/cm2;Red-spotted grouper soak time in pickling liquid is preferably 20-30 minute, more excellent Elect 25-30 minute as.
The present invention with sodium carbonate, tea polyphenols, chitosan, sodium tripolyphosphate, citric acid, Sodium chloride as the composition of pickling liquid, each interaction between component, influence each other, synergism, Inhibit the dehydration of red-spotted grouper and the loss of nutritional labeling, prevent red-spotted grouper fish protein qualitative change Property, keep mouthfeel and color and luster, thus improve the freeze proof quality of red-spotted grouper.
Preferably, the component ratio of pickling liquid is adjusted by the present invention, described in pickle Liquid preferably includes: sodium carbonate 0.3-0.4 weight portion, tea polyphenols 0.12-0.15 weight portion, shell are poly- Sugar 0.22-0.28 weight portion, sodium tripolyphosphate 0.2-0.25 weight portion, citric acid 0.1-0.15 Weight portion, sodium chloride 0.025-0.03 weight portion, water 95-100 weight portion.
Preferably, described pickling liquid also includes medicinal liquid 0.5-2 weight portion, and described medicinal liquid is pressed Prepare according to following method: be that the Herba Apocyni veneti of 9-11:7-9:5-7:8-10, summer are withered by mass ratio Grass, Flos Chrysanthemi Indici, Ramulus Uncariae Cum Uncis are pulverized, mixing, decoct 2-5 hour, obtain medicinal liquid after adding water.Its In, described Herba Apocyni veneti, Spica Prunellae, Flos Chrysanthemi Indici, the mass ratio of Ramulus Uncariae Cum Uncis are 10:8:6:9.
Herba Apocyni veneti has another name called wild flax, wild tea, bluish dogbane, Semen astragali sinici, red building, Herba Euphorbiae Helioscopiae fiber crops, tea Leaf stalk etc..Apocynum wild draft perennial plant for many years, it is because spreading out in Xinjiang Weili county Plain growth is golden and gains the name, and relieves inflammation or internal heat, blood pressure lowering, heart tonifying, diuresis.Control the effects such as heart disease.
Spica Prunellae is labiate Spica Prunellae. dry fruit ear.Spica Prunellae clearing away liver-fire, Disperse hepatic depression, It is usually used in Hypertension and there is the liver-heat syndromes such as headache, dizzy, tinnitus, dysphoria with smothery sensation, insomnia Person.
Flos Chrysanthemi Indici cold nature, has dispelling wind and heat pathogens, subduing swelling and detoxicating.Furuncle carbuncle, throat can be treated Swell and ache, wind-fire acute conjunctivitis, the headache disease such as dizziness.
Ramulus Uncariae Cum Uncis, another name Ramulus Uncariae Cum Uncis, to hang rattan, Wang Gambirplant Branchlet, reversal of the natural order of things perverse etc., is that Rubiaceae wild gambier is normal Green liana, climbs up by holding on to shape shrub, and stem branch square column type is very thin without hair, leaf papery ovalize, Head inflorescence.Ramulus Uncariae Cum Uncis is used as medicine with the stem branch of buckle, and it has a heat clearing away suppressing the hyperactive liver, dispelling wind and relieving convulsion effect, Also there is Ramulus Uncariae Cum Uncis and have hypotensive effect, therefore there is the highest medical value.
The present invention using Herba Apocyni veneti, Spica Prunellae, Flos Chrysanthemi Indici, Ramulus Uncariae Cum Uncis as the composition of medicinal liquid, each Interaction between component, influence each other, by the complex role between each composition, so that salting down Red-spotted grouper after system preferably has and has efficacy in lowering high blood pressure, and has certain health-care effect.
Red-spotted grouper also includes after soaking in pickling liquid: the red-spotted grouper after being soaked by pickling liquid drains The supernatant liquid on surface.
In step c, the red-spotted grouper after quick-freezing is carried out electron beam cold sterilization.Use electron beam cold Sterilization technology have easy to operate, do not heat up, non-secondary pollution, low energy consumption, safe and reliable, Can preferably keep the advantages such as the original local flavor of food, not reach owing to electron beam treatment dosage is the lowest Sterilization effect, the highest the most likely generation flavour of food products and nutritional labeling thereof affects, the present invention Preferably employ 6-8kGy dosage electron beam treatment red-spotted grouper, on the one hand keep the original local flavor of product And color and luster, on the other hand ensure its edible safety.
From above scheme it can be seen that the present invention is with sodium carbonate, tea polyphenols, chitosan, trimerization Sodium phosphate, citric acid, sodium chloride as the composition of pickling liquid, each interaction between component, phase Impact, synergism, it is suppressed that the dehydration of red-spotted grouper and the loss of nutritional labeling, prevent mutually Red-spotted grouper fish meat protein degeneration, keeps mouthfeel, thus improves the freeze proof quality of red-spotted grouper.Its Secondary, utilize the effect of ultrasound wave, beneficially pickling liquid to red-spotted grouper diffusion inside, thus through salting down Liquid processed pickle after red-spotted grouper good refreshing effect, and fresh keeping time is long.Again, electron beam is used Cold sterilization technology, keeps original local flavor and color and luster, the edible safety of red-spotted grouper.
In order to be further appreciated by the present invention, the technical side present invention provided below in conjunction with embodiment Case is described in detail, and protection scope of the present invention is not limited by the following examples.
The raw material that the embodiment of the present invention uses is commercial.
Embodiment 1
1, choose suitable size, fresh, without rot red-spotted grouper, with frozen water, it is carried out drip washing, Remove surface impurity;
2, the red-spotted grouper after drip washing is cut open the belly, remove internal organs, remove the gill, strike off the black film in tripe;
3, under the effect of ultrasound wave, red-spotted grouper step 2 obtained is soaked in pickling liquid, Described pickling liquid includes: sodium carbonate 0.4 weight portion, tea polyphenols 0.2 weight portion, chitosan 0.2 Weight portion, sodium tripolyphosphate 0.2 weight portion, citric acid 0.1 weight portion, sodium chloride 0.03 weight Amount part, water 100 weight portion, ultrasonic power is 16kHz, and ultrasonic intensity is 15W/cm2
4, the red-spotted grouper after being soaked by pickling liquid drains the supernatant liquid on surface, then in instant freezer middling speed Freeze, the central temperature of red-spotted grouper fish body was dropped to less than-15 DEG C in 3-4 hour;
5, use electron beam linear accelerator that the red-spotted grouper after quick-freezing is carried out electron beam cold sterilization, Dosage is 8kGy;
6, by the red-spotted grouper vacuum packaging after sterilization, cold preservation is in the warehouse less than-18 DEG C.
Embodiment 2
1, choose suitable size, fresh, without rot red-spotted grouper, with frozen water, it is carried out drip washing, Remove surface impurity;
2, the red-spotted grouper after drip washing is cut open the belly, remove internal organs, remove the gill, strike off the black film in tripe;
3, under the effect of ultrasound wave, red-spotted grouper step 2 obtained is soaked in pickling liquid, Described pickling liquid includes: sodium carbonate 0.2 weight portion, tea polyphenols 0.1 weight portion, chitosan 0.3 Weight portion, sodium tripolyphosphate 0.3 weight portion, citric acid 0.2 weight portion, sodium chloride 0.02 weight Amount part, water 100 weight portion, ultrasonic power is 10kHz, and ultrasonic intensity is 11W/cm2
4, the red-spotted grouper after being soaked by pickling liquid drains the supernatant liquid on surface, then in instant freezer middling speed Freeze, the central temperature of red-spotted grouper fish body was dropped to less than-15 DEG C in 3-4 hour;
5, use electron beam linear accelerator that the red-spotted grouper after quick-freezing is carried out electron beam cold sterilization, Dosage is 8kGy;
6, by the red-spotted grouper vacuum packaging after sterilization, cold preservation is in the warehouse less than-18 DEG C.
Embodiment 3
1, choose suitable size, fresh, without rot red-spotted grouper, with frozen water, it is carried out drip washing, Remove surface impurity;
2, the red-spotted grouper after drip washing is cut open the belly, remove internal organs, remove the gill, strike off the black film in tripe;
3, under the effect of ultrasound wave, red-spotted grouper step 2 obtained is soaked in pickling liquid, Described pickling liquid includes: sodium carbonate 0.2 weight portion, tea polyphenols 0.1 weight portion, chitosan 0.3 Weight portion, sodium tripolyphosphate 0.3 weight portion, citric acid 0.2 weight portion, sodium chloride 0.02 weight Amount part, medicinal liquid 0.5 weight portion, water 100 weight portion, ultrasonic power is 10kHz, ultrasonic Intensity of wave is 11W/cm2, described medicinal liquid is prepared as follows:
It is the Herba Apocyni veneti of 10:8:6:9, Spica Prunellae, Flos Chrysanthemi Indici, Ramulus Uncariae Cum Uncis pulverizing by mass ratio, Mixing, decocts 3 hours after adding water, obtains medicinal liquid;
4, the red-spotted grouper after being soaked by pickling liquid drains the supernatant liquid on surface, then in instant freezer middling speed Freeze, the central temperature of red-spotted grouper fish body was dropped to less than-15 DEG C in 3-4 hour;
5, use electron beam linear accelerator that the red-spotted grouper after quick-freezing is carried out electron beam cold sterilization, Dosage is 8kGy;
6, by the red-spotted grouper vacuum packaging after sterilization, cold preservation is in the warehouse less than-18 DEG C.
The property indices of the red-spotted grouper after the quick-freezing of embodiment of the present invention 1-3 is measured, its In:
According to agricultural standard " the mensuration shearing force algoscopy of meat tenderness " (NY/T1180-2006) Measure the tenderness of fresh-keeping red-spotted grouper;
Use weight to reduce method and measure red-spotted grouper percentage of water loss;
According to national standard " the analysis method of meat and meat products sanitary standard " (GB/T 5009.44-2003) measure the TVB-N content of fresh-keeping red-spotted grouper;
According to national standard " national food safety standard food microbiological examination coliform Counting " (GB/T4789.3-2010) measure the coliform group count of fresh-keeping red-spotted grouper;
According to agricultural standard " pollution-free food sea water shellfish " (NY/T1329-2007) to fresh-keeping red Speckle fish carries out subjective appreciation.
Red-spotted grouper mouthfeel after quick-freezing of the present invention is fresh and tender, and color and luster is normal, and software is flexible, quality Higher.Further, the red-spotted grouper after quick-freezing of the present invention, T-VBN and coliform are below state Family's standard, has edible safety.
The explanation of above example is only intended to help to understand that the method for the present invention and core thereof are thought Think.It should be pointed out that, for those skilled in the art, without departing from this On the premise of bright principle, it is also possible to the present invention is carried out some improvement and modification, these improve and Modify in the protection domain also falling into the claims in the present invention.
Described above to the disclosed embodiments, makes professional and technical personnel in the field be capable of Or the use present invention.Those skilled in the art are come by the multiple amendment to these embodiments Saying and will be apparent from, generic principles defined herein can be without departing from the present invention's In the case of spirit or scope, realize in other embodiments.Therefore, the present invention will not be by It is limited to the embodiments shown herein, and is to fit to and principles disclosed herein and new The widest scope that grain husk feature is consistent.

Claims (10)

1. the processing method of a quick-freezing red-spotted grouper, it is characterised in that comprise the following steps:
Step a) is under the effect of ultrasound wave, being soaked in pickling liquid by red-spotted grouper, described pickling liquid includes: sodium carbonate 0.2-0.4 weight portion, tea polyphenols 0.1-0.2 weight portion, chitosan 0.2-0.3 weight portion, sodium tripolyphosphate 0.2-0.3 weight portion, citric acid 0.1-0.2 weight portion, sodium chloride 0.02-0.03 weight portion, water 90-100 weight portion;
Step b) is by the red-spotted grouper quick-freezing in instant freezer after pickling liquid immersion, and the central temperature of red-spotted grouper fish body dropped to less than-15 DEG C in 3-4 hour;
Step c) carries out electron beam cold sterilization to the red-spotted grouper after quick-freezing.
Processing method the most according to claim 1, it is characterised in that also include the pretreatment of red-spotted grouper:
Choose suitable size, fresh, without the red-spotted grouper rotted, with frozen water, it is carried out drip washing, removes surface impurity;
Red-spotted grouper after drip washing is cut open the belly, removes internal organs, remove the gill, strike off the black film in tripe.
Processing method the most according to claim 1, it is characterised in that in step a, ultrasonic power is 10-20kHz.
Processing method the most according to claim 1, it is characterised in that in step a, ultrasonic intensity is 11-30W/cm2
Processing method the most according to claim 1, it is characterised in that in step a, red-spotted grouper soak time in pickling liquid is 20-30 minute.
Processing method the most according to claim 1, it is characterised in that described pickling liquid includes:
Sodium carbonate 0.3-0.4 weight portion, tea polyphenols 0.12-0.15 weight portion, chitosan 0.22-0.28 weight portion, sodium tripolyphosphate 0.2-0.25 weight portion, citric acid 0.1-0.15 weight portion, sodium chloride 0.025-0.03 weight portion, water 95-100 weight portion.
Processing method the most according to claim 1, it is characterised in that described pickling liquid also includes medicinal liquid 0.5-2 weight portion, described medicinal liquid is prepared as follows:
It is the Herba Apocyni veneti of 9-11:7-9:5-7:8-10, Spica Prunellae, Flos Chrysanthemi Indici, Ramulus Uncariae Cum Uncis pulverizing by mass ratio, mixing, decoct 2-5 hour after adding water, obtain medicinal liquid.
Processing method the most according to claim 7, it is characterised in that described Herba Apocyni veneti, Spica Prunellae, Flos Chrysanthemi Indici, the mass ratio of Ramulus Uncariae Cum Uncis are 10:8:6:9.
Processing method the most according to claim 1, it is characterised in that red-spotted grouper also includes after soaking in pickling liquid:
Red-spotted grouper after being soaked by pickling liquid drains the supernatant liquid on surface.
Processing method the most according to claim 1, it is characterised in that in step c, the dosage of electron beam cold sterilization is 6-8kGy.
CN201610394957.8A 2016-06-05 2016-06-05 Processing method of quick-frozen red-spotted groupers Pending CN105995640A (en)

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CN107242281A (en) * 2017-07-13 2017-10-13 安徽红云食品有限公司 A kind of method of freezing of liquor-saturated fish
CN107259302A (en) * 2017-07-31 2017-10-20 浙江香海食品股份有限公司 The processing method of lower temperature vacuum frying little yellow croaker and fried little yellow croaker
CN111642557A (en) * 2020-05-11 2020-09-11 广州市博仕奥生化技术研究有限公司 Antifreezing agent and using method thereof
CN111990614A (en) * 2020-07-14 2020-11-27 福建海文铭海洋科技发展有限公司 Preparation method of Fotiaoqiang
CN112772876A (en) * 2021-01-13 2021-05-11 湖北清江鲟龙渔业有限公司 Preparation method of sturgeon floss

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Application publication date: 20161012