CN105970600A - 一种纳米ZnO处理抗菌性织物的整理剂及其制备方法 - Google Patents
一种纳米ZnO处理抗菌性织物的整理剂及其制备方法 Download PDFInfo
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Abstract
本发明公开了一种纳米ZnO处理抗菌性织物的整理剂及其制备方法,包括纳米ZnO分散液42‑368份,纳米ZnO分散液包括以下重量组分:纳米ZnO粉体10‑150份、去离子水25‑200份、分散剂2‑10份、偶联剂5‑8份,该抗菌性织物通过以下步骤制得:S1:称量,通过使用分析天平称取一定量的纳米ZnO粉体,去离子水、分散剂和偶联剂均按照所需要的比例取出,备用;S2:在定量的纳米ZnO粉体中滴加备用的分散剂以及偶联剂,得到初制液体;S3:将初制液体放在水浴锅中,设置温度40℃,并高速搅拌10min,得到中制液体;本发明利用纳米ZnO具有优异的特性,通过制备纳米ZnO分散液,然后将纺织品浸渍其中,同时对生产过程中的工艺参数的调整与改进,研制处具有高度抗菌性功能的织物。
Description
技术领域
本发明涉及抗菌性织物技术领域,具体为一种纳米ZnO处理抗菌性织物的整理剂及其制备方法。
背景技术
随着工业的迅速发展和人民生活水平的提高,抗菌问题越来越引起人们的重视。在现实生活中,人们不可避免地要接触到各种各样的细菌、真菌等微生物。这些微生物在合适的环境条件下会迅速生长繁殖,并通过接触传播疾病、影响人们的身体健康。日常生活中,纺织品是这些微生物的良好生存之地,是疾病的重要传播源,因此抗菌纺织品将受到世界各国的高度关注,在卫生保健获得重视和提升生活品质两大前提之下,抗菌纺织品将成为未来开创商机之产品,开发具有抗菌功能的纺织品乃为发展方向之一,所以加强纺织品的抗菌研究开发有着极其重要的意义。纳米ZnO是重要的无机功能材料,在电子、橡胶、涂料、印染、医药和化工等行业都有重要的应用.同时,纳米ZnO具有优异的紫外屏蔽、红外吸收和光催化性能,将其应用在织物上可赋予织物抗菌功能。
发明内容
本发明的目的在于提供一种纳米ZnO处理抗菌性织物的整理剂及其制备方法,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:一种纳米ZnO处理抗菌性织物的整理剂,包括纳米ZnO分散液42-368份,纳米ZnO分散液包括以下重量组分:纳米ZnO粉体10-150份、去离子水25-200份、分散剂2-10份、偶联剂5-8份。
优选的,所述分散剂为液体PAAS分散剂,且分散剂以一滴为一份。
优选的,所述偶联剂为液体KH-570型偶联剂,且偶联剂以一滴为一份。
一种纳米ZnO处理抗菌性织物的制备方法,该抗菌性织物通过以下步骤制得:
S1:称量:通过使用分析天平称取一定量的纳米ZnO粉体,去离子水、分散剂和偶联剂均按照所需要的比例取出,备用;
S2:在定量的纳米ZnO粉体中滴加备用的分散剂以及偶联剂,得到初制液体;
S3:将初制液体放在水浴锅中,设置温度40℃,并高速搅拌10min,得到中制液体;
S4:把中制液体放置到超声波中,超声10-15min,得到纳米ZnO分散液;
S5:将织物试样放入到纳米ZnO分散液,控制温度为40℃,浴比为1:60,保持纳米ZnO分散液没过织物试样,并同时使用振荡器对其进行振荡10-15min;
S6:采用二浸二轧的上浆工序对植物进行上浆,控制轧余率为70%,得到初制织物;
S7:在烘干设备中对初制织物进行预烘,设置烘干时间为5min,得到中制织物;
S8:将中制织物放置到烘焙设备中,焙烘3min,再将其放置到超声波中洗涤5次,晾干,至此,抗菌性织物制备完成。
与现有技术相比,本发明的有益效果是:通过滴加分散剂PAAS来调节纳米ZnO粒子在分散液中的粒子大小与分布,使纳米ZnO具有了很好的水分散性。通过滴加偶联剂KH-570,使纳米ZnO通过KH-570与织物形成牢固的化学交联,提高了纳米颗粒在织物表面的附着力;使纳米ZnO通过KH-570与真丝形成牢固的化学交联。采用纳米ZnO分散液浸渍处理的方法使织物具备抗菌性,工艺简单、实施方便,生产成本低,总的来说,本发明利用纳米ZnO具有优异的特性,通过制备纳米ZnO分散液,然后将纺织品浸渍其中,同时对生产过程中的工艺参数的调整与改进,研制处具有高度抗菌性功能的织物。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
实施例一:
本发明提供一种技术方案:一种纳米ZnO处理抗菌性织物的整理剂,包括纳米ZnO分散液42份,纳米ZnO分散液包括以下重量组分:纳米ZnO粉体10份、去离子水25份、分散剂2份、偶联剂5份。
该抗菌性织物通过以下步骤制得:
S1:称量:通过使用分析天平称取一定量的纳米ZnO粉体,去离子水、分散剂和偶联剂均按照所需要的比例取出,备用,所述分散剂为液体PAAS分散剂,且分散剂以一滴为一份,所述偶联剂为液体KH-570型偶联剂,且偶联剂以一滴为一份;
S2:在定量的纳米ZnO粉体中滴加备用的分散剂以及偶联剂,得到初制液体;
S3:将初制液体放在水浴锅中,设置温度40℃,并高速搅拌10min,得到中制液体;
S4:把中制液体放置到超声波中,超声10min,得到纳米ZnO分散液;
S5:将织物试样放入到纳米ZnO分散液,控制温度为40℃,浴比为1:60,保持纳米ZnO分散液没过织物试样,并同时使用振荡器对其进行振荡10min;
S6:采用二浸二轧的上浆工序对植物进行上浆,控制轧余率为70%,得到初制织物;
S7:在烘干设备中对初制织物进行预烘,设置烘干时间为5min,得到中制织物;
S8:将中制织物放置到烘焙设备中,焙烘3min,再将其放置到超声波中洗涤5次,晾干,至此,抗菌性织物制备完成。
实施例二:
本发明提供一种技术方案:一种纳米ZnO处理抗菌性织物的整理剂,包括纳米ZnO分散液161份,纳米ZnO分散液包括以下重量组分:纳米ZnO粉体50份、去离子水100份、分散剂5份、偶联剂6份。
该抗菌性织物通过以下步骤制得:
S1:称量:通过使用分析天平称取一定量的纳米ZnO粉体,去离子水、分散剂和偶联剂均按照所需要的比例取出,备用,所述分散剂为液体PAAS分散剂,且分散剂以一滴为一份,所述偶联剂为液体KH-570型偶联剂,且偶联剂以一滴为一份;
S2:在定量的纳米ZnO粉体中滴加备用的分散剂以及偶联剂,得到初制液体;
S3:将初制液体放在水浴锅中,设置温度40℃,并高速搅拌10min,得到中制液体;
S4:把中制液体放置到超声波中,超声13min,得到纳米ZnO分散液;
S5:将织物试样放入到纳米ZnO分散液,控制温度为40℃,浴比为1:60,保持纳米ZnO分散液没过织物试样,并同时使用振荡器对其进行振荡13min;
S6:采用二浸二轧的上浆工序对植物进行上浆,控制轧余率为70%,得到初制织物;
S7:在烘干设备中对初制织物进行预烘,设置烘干时间为5min,得到中制织物;
S8:将中制织物放置到烘焙设备中,焙烘3min,再将其放置到超声波中洗涤5次,晾干,至此,抗菌性织物制备完成。
工作原理:为获得高性能抗菌织物,关键是控制纳米ZnO分散液中粒子的粒径大小、分布以及纳米颗粒与织物的结合力。而为了获得水中分散性好的ZnO粒子需要滴加分散剂;为了提高ZnO纳米粒子与织物的结合力需要滴加偶联剂。通过添加分散剂和偶联剂,使纳米ZnO粒子能够均匀地分布在水溶液中,同时能有效地的附着在织物的表面,从而赋予织物良好的抗菌性能。另外采用的工艺和实施方式极为简单,性价比高,具有较大意义和广阔的应用前景。
本发明的主要性能指标如下:
抗菌标准FZ/T73023-2006;
大肠杆菌抑菌圈直径≥5mm;
金黄色葡萄球菌抑菌圈直径≥5mm。
本发明的优点在于:
(1)通过滴加分散剂PAAS来调节纳米ZnO粒子在分散液中的粒子大小与分布;因为PAAS分子链上含有较多的羧酸钠亲水基,亲水基吸附在纳米ZnO表面,使其表面张力大大降低,有效地减弱了聚集;另外,在纳米ZnO表面形成一层负电保护层,负电荷间的排斥力阻止了微粒间的碰撞,而且PAAS多余的亲水基伸向外面,从而使纳米ZnO具有了很好的水分散性。
(2)通过滴加偶联剂KH-570,使纳米ZnO通过KH-570与织物形成牢固的化学交联,提高了纳米颗粒在织物表面的附着力;硅烷偶联剂水解生成的硅醇与水溶液体系中的羟基反应,生成硅氧负离子,硅氧负离子对另一个硅烷偶联剂中的硅进行亲核进攻,生成二聚体,当体系中存—R基是一类非水解又可与有机高分子结合的基团,从而使纳米ZnO通过KH-570与真丝形成牢固的化学交联。
(3)采用纳米ZnO分散液浸渍处理的方法使织物具备抗菌性,工艺简单、实施方便,生产成本低。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。
Claims (4)
1.一种纳米ZnO处理抗菌性织物的整理剂,其特征在于:包括纳米ZnO分散液42-368份,纳米ZnO分散液包括以下重量组分:纳米ZnO粉体10-150份、去离子水25-200份、分散剂2-10份、偶联剂5-8份。
2.根据权利要求1所述的一种纳米ZnO处理抗菌性织物的整理剂,其特征在于:所述分散剂为液体PAAS分散剂,且分散剂以一滴为一份。
3.根据权利要求1所述的一种纳米ZnO处理抗菌性织物的整理剂,其特征在于:所述偶联剂为液体KH-570型偶联剂,且偶联剂以一滴为一份。
4.一种权利要求1所述的纳米ZnO处理抗菌性织物的制备方法,其特征在于,该抗菌性织物通过以下步骤制得:
S1:称量:通过使用分析天平称取一定量的纳米ZnO粉体,去离子水、分散剂和偶联剂均按照所需要的比例取出,备用;
S2:在定量的纳米ZnO粉体中滴加备用的分散剂以及偶联剂,得到初制液体;
S3:将初制液体放在水浴锅中,设置温度40℃,并高速搅拌10min,得到中制液体;
S4:把中制液体放置到超声波中,超声10-15min,得到纳米ZnO分散液;
S5:将织物试样放入到纳米ZnO分散液,控制温度为40℃,浴比为1:60,保持纳米ZnO分散液没过织物试样,并同时使用振荡器对其进行振荡10-15min;
S6:采用二浸二轧的上浆工序对植物进行上浆,控制轧余率为70%,得到初制织物;
S7:在烘干设备中对初制织物进行预烘,设置烘干时间为5min,得到中制织物;
S8:将中制织物放置到烘焙设备中,焙烘3min,再将其放置到超声波中洗涤5次,晾干,至此,抗菌性织物制备完成。
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