CN105969237B - The preparation method of anisotropic conductive film - Google Patents

The preparation method of anisotropic conductive film Download PDF

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Publication number
CN105969237B
CN105969237B CN201610493208.0A CN201610493208A CN105969237B CN 105969237 B CN105969237 B CN 105969237B CN 201610493208 A CN201610493208 A CN 201610493208A CN 105969237 B CN105969237 B CN 105969237B
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anisotropic conductive
film
conductive film
preparation
membrane material
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CN105969237A (en
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李兰艳
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TCL China Star Optoelectronics Technology Co Ltd
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Shenzhen China Star Optoelectronics Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/06Elements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J9/00Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
    • C09J9/02Electrically-conducting adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/18Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet characterized by perforations in the adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/314Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Non-Insulated Conductors (AREA)

Abstract

The present invention provides a kind of preparation method of anisotropic conductive film, hole that is several being arranged regularly and running through the resin glue film is first produced on resin glue film, then in the several holes for the conduction liquid comprising conducting particles being instilled the resin glue film by the way of spraying, obtain anisotropic conductive adhesive layer, wherein, the arrangement mode of hole can carry out special designing according to the concrete application scene of anisotropic conductive film on resin glue film, so as to accurately control distribution situation of the conducting particles in anisotropic conductive film, anisotropic conductive film material especially suitable for high-precision requirement.

Description

The preparation method of anisotropic conductive film
Technical field
The present invention relates to field of display technology more particularly to a kind of preparation methods of anisotropic conductive film.
Background technique
With the development of electronic technology, electronic product, liquid crystal are increasingly be unable to do without in daily life and work Important component of the display screen as electronic product, also closely affects the usage experience of people.
Anisotropic conductive film (Anisotropic Conductive Film, ACF) be have simultaneously then, it is conductive, absolutely The conduction that the translucent polymer continuous material of three kinds of characteristics of edge mainly includes resin glue material and is mixed in resin glue material Particle has the characteristic in vertical direction conducting, horizontal direction insulation.The application of ACF has had more than 60 years to go through so far History, as lighter, thinner, shorter, the smaller market demands of binding structure (bonding) and development trend, ACF are widely used in In the design of domestic electronic appliances, especially prominent is the application in liquid crystal display (LCD), can be used to form display panel Binding structure between circuit layer, for example, liquid crystal display connects flexible circuit board in the manufacturing process of liquid crystal display panel When (Flexible Printed Circuit, FPC), the connecting lead wire on the connecting lead wire and FPC on liquid crystal display is led to It crosses label to be accurately positioned, then hot pressing ACF is bonded;Using ACF bound to be mainly characterized by pressing against the time short, The reliability of connection is high, is easy for minute protrusions (bump), and be easy for the electricity of fine mode (fine pitch patterns) Interpolar conducting.
The preparation process of traditional anisotropic conductive film specifically includes that the mixing by resin glue material and conducting particles The step of, by the mixture coating film forming of resin glue material and conducting particles the step of, segmentation step, winding step and encapsulation walk This rapid 5 steps.But the anisotropic conductive film produced in this way, in conducting particles distribution situation can not It is controlled, it is difficult between electrode in the binding structure formed using anisotropic conductive film made from the conventional preparation techniques To maintain identical conducting resistance, there are partial electrodes not in contact with the risk for arriving conducting particles, sends out so as to cause the situation of open circuit Raw, therefore, the electric conductivity of material is restricted.
Summary of the invention
The purpose of the present invention is to provide a kind of preparation methods of anisotropic conductive film, can accurately control conducting particles Distribution situation, the anisotropic conductive film material especially suitable for high-precision requirement.
To achieve the above object, the present invention provides a kind of preparation methods of anisotropic conductive film, comprising the following steps:
Step 1 provides a hard plate and substrate membrane material, and the substrate membrane material is fixed on the hard plate;
Step 2 is coated with one layer of resin material in the substrate membrane material, forms resin glue film;
Step 3 produces several holes through the resin glue film on the resin glue film;
Step 4 provides conducting particles and solvent, disperses the conducting particles in the solvent, obtains conduction liquid, so In several holes that conduction liquid is instilled the resin glue film by the way of spraying afterwards, then by the solvent in several holes Removal, obtains anisotropic conductive adhesive layer, and the anisotropic conductive adhesive layer includes resin glue film and positioned at the hole of the resin glue film Conducting particles in hole;
Step 5 separates substrate membrane material with hard plate, then carries out to substrate membrane material and anisotropic conductive adhesive layer Cutting;Or first substrate membrane material and anisotropic conductive adhesive layer are cut, then substrate membrane material is separated with hard plate;
Step 6 carries out winding and encapsulation to substrate membrane material and anisotropic conductive adhesive layer, completes the system of anisotropic conductive film It is standby, obtain include substrate membrane material and anisotropic conductive adhesive layer anisotropic conductive film.
In the step 2, the coating layer thickness for the resin material being coated in the substrate membrane material is 15-45 μm.
In the step 2, the resin material being coated in the substrate membrane material is epoxy system resin or acrylic compounds tree Rouge.
The conducting particles provided in the step 4 is carbon fiber, carbon nanotube ball, metallic or conductive gold spacer;
Wherein, the conductive gold spacer include polymer core and successively coat from inside to outside the polymer core nickel layer and Layer gold.
In the step 3, the several holes formed on the resin glue film being answered according to the specific of anisotropic conductive film It is accordingly arranged with scene.
The hard plate provided in the step 1 is glass plate, and the substrate membrane material provided is polyimide film.
In the step 2, resin material is coated in the substrate membrane material using spin coating or slot coated mode.
The solvent provided in the step 4 is ethyl alcohol;It will be in several holes by way of baking in the step 4 Solvent removal.
In the step 5, the cutting width cut to substrate membrane material and anisotropic conductive adhesive layer is 1.5-3.5mm.
In the step 3, number is produced on the resin glue film using yellow light process or using nanometer embossing A hole.
Beneficial effects of the present invention: the present invention provides a kind of preparation methods of anisotropic conductive film, first in resin glue Hole that is several being arranged regularly and running through the resin glue film is produced on film, it then will be comprising leading by the way of spraying The conduction liquid of charged particle instills in several holes of the resin glue film, obtains anisotropic conductive adhesive layer, wherein on resin glue film The arrangement mode of hole can carry out special designing according to the concrete application scene of anisotropic conductive film, so as to accurately control Distribution situation of the conducting particles processed in anisotropic conductive film, the anisotropic conductive film material especially suitable for high-precision requirement Material.
For further understanding of the features and technical contents of the present invention, it please refers to below in connection with of the invention detailed Illustrate and attached drawing, however, the drawings only provide reference and explanation, is not intended to limit the present invention.
Detailed description of the invention
With reference to the accompanying drawing, by the way that detailed description of specific embodiments of the present invention, technical solution of the present invention will be made And other beneficial effects are apparent.
In attached drawing,
Fig. 1 is the flow chart of the preparation method of anisotropic conductive film of the invention;
Fig. 2-3 is the schematic diagram of the preparation method step 1 of anisotropic conductive film of the invention;
Fig. 4-5 is the schematic diagram of the preparation method step 2 of anisotropic conductive film of the invention;
Fig. 6-7 is the schematic diagram of the preparation method step 3 of anisotropic conductive film of the invention;
Fig. 8-9 is the schematic diagram of the preparation method step 4 of anisotropic conductive film of the invention;
Figure 10 is the schematic diagram of the preparation method step 5 of anisotropic conductive film of the invention.
Specific embodiment
Further to illustrate technological means and its effect adopted by the present invention, below in conjunction with preferred implementation of the invention Example and its attached drawing are described in detail.
Referring to Fig. 1, the present invention provides a kind of preparation method of anisotropic conductive film, comprising the following steps:
Step 1, as Figure 2-3, provide a hard plate 100, with substrate membrane material 210, the substrate membrane material 210 is consolidated It is scheduled on the hard plate 100.
Wherein, fixation of the substrate membrane material 210 on the hard plate 100 can be used in the art at present existing soft Property film fixed form carry out because being the prior art, details are not described herein.
Specifically, the hard plate 100 provided in the step 1 is glass plate.
Specifically, the substrate membrane material 210 provided in the step 1 is polyimide film.
Step 2, as illustrated in figures 4-5, using spin coating (spin coater) or slot coated (slit) mode in the substrate It is coated with the resin material that a layer thickness is 15-45 μm in membrane material 210, forms resin glue film 221.
Specifically, in the step 2, the resin material being coated in the substrate membrane material 210 can be thermoplastic resin Such as acrylic resin, or thermosetting resin such as epoxy system resin etc..
Step 3, as shown in fig. 6-7, using yellow light process, using mask plate (mask) by way of exposure development, Several holes 222 through the resin glue film 221 being arranged regularly are produced on the resin glue film 221;Alternatively, using Nanometer embossing produces several holes through the resin glue film 221 being arranged regularly on the resin glue film 221 Hole 222.
Specifically, the size and spacing of hole 222 can be conductive according to prepared anisotropy on the resin glue film 221 The concrete application scene of glue film and carry out special designing.
Step 4, as Figure 8-9, conducting particles 223 and solvent are provided, dispersed the conducting particles 223 in described molten In agent, conduction liquid is obtained, in several holes 222 that conduction liquid is then instilled the resin glue film 221 by the way of spraying, Then the solvent in several holes 222 is removed, obtains anisotropic conductive adhesive layer 220, the anisotropic conductive adhesive layer 220 wraps Include resin glue film 221 and the conducting particles 223 in the hole 222 of the resin glue film 221.
Specifically, the conducting particles 223 provided in the step 4 can for carbon fiber, carbon nanotube ball (CNT ball), The particle of all conductive energy such as metallic, traditional conductive gold spacer, wherein the conductive gold spacer includes polymer Core and nickel (Ni) layer and golden (Au) layer for successively coating the polymer core from inside to outside.
Specifically, the solvent provided in the step 4 is ethyl alcohol, can be by way of baking by the number in the step 4 Solvent removal in a hole 222.
Specifically, since in the present invention, conducting particles 223 is targetedly distributed in several holes of the resin glue film 221 In hole 222, so that special designing is carried out by concrete application scene by the arrangement mode to the hole 222 on resin glue film 221, Distribution situation of the conducting particles 223 in anisotropic conductive film can be accurately controlled, therefore uses preparation method of the invention Obtained anisotropic conductive film and in the binding structure that is formed, be easy to maintain identical conducting resistance between electrode, and Can be avoided partial electrode causes the situation of open circuit to occur not in contact with to conducting particles.
Step 5, as shown in Figure 10, substrate membrane material 210 is separated with hard plate 100, then to substrate membrane material 210 It is cut with anisotropic conductive adhesive layer 220;Alternatively, first being cut to substrate membrane material 210 and anisotropic conductive adhesive layer 220, then will Substrate membrane material 210 is separated with hard plate 100.
Specifically, in the step 5, cutting that the substrate membrane material 210 is cut with anisotropic conductive adhesive layer 220 Width is 1.5-3.5mm.
Step 6 carries out winding and encapsulation to substrate membrane material 210 and anisotropic conductive adhesive layer 220, completes anisotropic conductive adhesive paste The preparation of film, obtain include substrate membrane material 210 Yu anisotropic conductive adhesive layer 220 anisotropic conductive film.
In conclusion first being made on resin glue film the present invention provides a kind of preparation method of anisotropic conductive film Hole that is several being arranged regularly out and running through the resin glue film, then will include conducting particles by the way of spraying Conduction liquid instills in several holes of the resin glue film, obtains anisotropic conductive adhesive layer, wherein the row of hole on resin glue film Column mode can carry out special designing according to the concrete application scene of anisotropic conductive film, so as to accurately control conductive particle Distribution situation of the son in anisotropic conductive film, the anisotropic conductive film material especially suitable for high-precision requirement.
The above for those of ordinary skill in the art can according to the technique and scheme of the present invention and technology Other various corresponding changes and modifications are made in design, and all these change and modification all should belong to the claims in the present invention Protection scope.

Claims (10)

1. a kind of preparation method of anisotropic conductive film, which comprises the following steps:
Step 1 provides a hard plate (100) and substrate membrane material (210), the substrate membrane material (210) is fixed on described hard On matter plate (100);
Step 2 is coated with one layer of resin material on the substrate membrane material (210), is formed resin glue film (221);
Step 3 produces several holes (222) through the resin glue film (221) on the resin glue film (221);
Step 4 provides conducting particles (223) and solvent, disperses the conducting particles (223) in the solvent, is led It is electro-hydraulic, in several holes (222) that conduction liquid is then instilled the resin glue film (221) by the way of spraying, then will Solvent removal in several holes (222), obtains anisotropic conductive adhesive layer (220), anisotropic conductive adhesive layer (220) packet The conducting particles (223) for including resin glue film (221) and being located in the hole (222) of the resin glue film (221);
Step 5 separates substrate membrane material (210) with hard plate (100), then to substrate membrane material (210) and anisotropy Conductive adhesive layer (220) is cut;Alternatively, first cut to substrate membrane material (210) and anisotropic conductive adhesive layer (220), then by base Counterdie material (210) is separated with hard plate (100);
Step 6 carries out winding and encapsulation to substrate membrane material (210) and anisotropic conductive adhesive layer (220), completes anisotropic conductive adhesive paste The preparation of film, obtain include substrate membrane material (210) Yu anisotropic conductive adhesive layer (220) anisotropic conductive film.
2. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that in the step 2, described The coating layer thickness for the resin material being coated in substrate membrane material (210) is 15-45 μm.
3. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that in the step 2, described The resin material being coated in substrate membrane material (210) is epoxy system resin or acrylic resin.
4. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that provided in the step 4 Conducting particles (223) is carbon fiber, carbon nanotube ball, metallic or conductive gold spacer;
Wherein, the conductive gold spacer includes polymer core and successively coats the nickel layer and layer gold of the polymer core from inside to outside.
5. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that in the step 3, described The several holes (222) formed on resin glue film (221) are accordingly carried out according to the concrete application scene of anisotropic conductive film Arrangement.
6. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that provided in the step 1 Hard plate (100) is glass plate, and the substrate membrane material (210) provided is polyimide film.
7. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that in the step 2, using rotation It applies or slot coated mode is coated with resin material on the substrate membrane material (210).
8. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that provided in the step 4 Solvent is ethyl alcohol;The solvent in several holes (222) is removed by way of baking in the step 4.
9. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that in the step 5, to substrate The cutting width that membrane material (210) and anisotropic conductive adhesive layer (220) are cut is 1.5-3.5mm.
10. the preparation method of anisotropic conductive film as described in claim 1, which is characterized in that in the step 3, use Yellow light process or use nanometer embossing produce several holes (222) on the resin glue film (221).
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CN108611002B (en) * 2016-12-05 2019-09-13 航天特种材料及工艺技术研究所 A kind of polyimide support glue film and preparation method thereof
CN107452438B (en) 2017-07-27 2019-10-11 京东方科技集团股份有限公司 A kind of anisotropy conductiving glue band and tape roll, binding structure and display device
KR102254467B1 (en) * 2018-07-12 2021-05-21 에이치엔에스하이텍(주) Manufacturing method for anisotropic conductive adhesive film
CN109628002B (en) * 2018-11-21 2020-06-02 武汉华星光电半导体显示技术有限公司 Anisotropic conductive adhesive tape and manufacturing method thereof
CN109637699B (en) * 2018-12-12 2020-05-12 武汉华星光电半导体显示技术有限公司 Method and apparatus for manufacturing anisotropic conductive film
CN112521873A (en) * 2020-12-01 2021-03-19 湖南省凯纳方科技有限公司 Method for manufacturing anisotropic conductive film
CN115368849B (en) * 2021-05-20 2023-10-03 中国科学院福建物质结构研究所 Anisotropic conductive adhesive film and preparation method and application thereof
US20230310336A1 (en) * 2022-03-31 2023-10-05 Novocure Gmbh Electrode Assembly Having Perforated Anisotropic Layer, And Systems And Methods Of Applying Tumor-Treating Fields Using Same
WO2023219357A1 (en) * 2022-05-09 2023-11-16 주식회사 마이다스에이치앤티 Stretchable anisotropic conductive film containing liquid metal particles and manufacturing method therefor
CN115386318B (en) * 2022-09-02 2023-10-13 中国科学院合肥物质科学研究院 Anisotropic conductive adhesive, preparation and application thereof in ultra-fine pitch electrode packaging

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CN102318141A (en) * 2009-02-17 2012-01-11 富士胶片株式会社 Anisotropically conductive member and method for producing the same
CN101510575A (en) * 2009-03-27 2009-08-19 南开大学 Method for producing medlin plastic substrate flexible silicon-based film solar battery integrated component
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CN103050170A (en) * 2011-10-17 2013-04-17 财团法人工业技术研究院 Anisotropic conductive film and manufacturing method thereof
CN103151113A (en) * 2013-01-31 2013-06-12 中国科学院化学研究所 Preparation method of pressure-sensitive conductive membrane

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