CN105968633A - Formaldehyde-removal indoor decorative film - Google Patents

Formaldehyde-removal indoor decorative film Download PDF

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Publication number
CN105968633A
CN105968633A CN201610356406.2A CN201610356406A CN105968633A CN 105968633 A CN105968633 A CN 105968633A CN 201610356406 A CN201610356406 A CN 201610356406A CN 105968633 A CN105968633 A CN 105968633A
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China
Prior art keywords
parts
formaldehyde
interior decoration
decorative film
film
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Pending
Application number
CN201610356406.2A
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Chinese (zh)
Inventor
朱静江
郝恩全
李宏杰
张仁彪
杨阳
傅朝辉
陈小平
金国利
张婷
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ZHEJIANG MSD NEW MATERIAL CO Ltd
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ZHEJIANG MSD NEW MATERIAL CO Ltd
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Priority to CN201610356406.2A priority Critical patent/CN105968633A/en
Publication of CN105968633A publication Critical patent/CN105968633A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3415—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K2003/023—Silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films

Abstract

The invention relates to a formaldehyde-removal indoor decorative film which is prepared from the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin powder, 40-60 parts of plasticizer, 1-5 parts of calcium-zinc stabilizer, 2-8 parts of formaldehyde absorbent, 1-4 parts of pigment, 5-11 parts of titanium white and 2-8 parts of anti-freezing agent. By selecting the environment-friendly raw materials and improving the production technique, the formaldehyde-removal indoor decorative film has the formaldehyde absorption function which is not possessed by the conventional decorative film, and has the effect of removing indoor formaldehyde pollution. Besides, the tensile strength, tear strength and various indexes of the formaldehyde-removal indoor decorative film satisfy the Chinese standard. The formaldehyde-removal indoor decorative film overcomes the defect of low high-temperature stability in the formaldehyde absorbent; and calendering temperature control, calcium zinc stabilizer addition and other means are adopted to lower the processing difficulty of the product. The formaldehyde-removal indoor decorative film has the advantages of favorable environment friendliness, high stability, favorable formaldehyde absorptivity and the like.

Description

Except formaldehyde interior decoration film
Technical field
The present invention relates to a kind of decorating film, especially relate to a kind of except formaldehyde interior decoration film.
Background technology
Decorating film is a kind of novel glass decorative material, and the gloss containing metal, in plane pattern Prominent third dimension, possesses outstanding texture and security performance.Decorating film can be used for ice painting, glass Glass sliding door, glass case door, partition, tracery etc., product style is multiple, has broken conventional master Using strengthening description material as the traditional handicraft of glass decoration, thus instead of description material master The markets such as glass decorative material such as glass sliding door, glass case, glass background wall are led.
Formaldehyde is commonly called as formalin, be colourless, there is the irritative gas of overpowering odor, its 35～40% aqueous solution common name formalin.Formaldehyde is oleo stock poisonous substance, energy and protein bound, After sucking high-concentration formaldehyde, it may appear that the serious of respiratory tract stimulates and edema, eye twinge, headache, Bronchial asthma also can occur.Direct skin contact formaldehyde, can cause dermatitis, mottle, necrosis. Often suck a small amount of formaldehyde, chronic poisoning can be caused, occur mucous hyperemia, skin irritation disease, Allergic dermatitis, fingernail keratinization and fragility, nail matrix finger tip pain, anemia of pregnant woman sucks for a long time and may lead Cause ewborn infant deformity, even dead, man sucks for a long time and may result in man's sperm deformity, dead Die, sexual disorder, serious may result in reproductive performance disappearance, General Symptoms has headache, weary Power, stomach poor appetite, cardiopalmus, have a sleepless night, lose weight and autonomic nervous dysfunction etc..So removing Formaldehyde contained by indoor is extremely important.
Existing indoor mainly have except the method for formaldehyde: ventilation method removes formaldehyde, activated carbon adsorption Method, plant taste removal method, chemical method remove formaldehyde, but also do not have a kind of decorating film playing dress Effect of purifying formaldehyde is also had concurrently while decorations effect.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of except formaldehyde indoor Decorating film.
A kind of except formaldehyde interior decoration film, described decorating film is by the raw material preparation of following weight parts : polyvinyl chloride resin powder 100 parts, plasticizer 40～60 parts, calcium zinc stabilizer 1～5 parts, Formaldehyde absorbent 2～8 parts, colorant 1～4 parts, titanium dioxide 5～11 parts, cold-resistant agent 2～8 Part.
The present invention will add a kind of formaldehyde absorbent, obtained indoor dress in PVC film formula Decorations film has effect of purifying formaldehyde, is a kind of brand-new house decorative material.
As preferably, formaldehyde absorbent is nano silica fume, 2-amino-2-methyl-1-propanol, different One in butylene succimide, N-hydroxy-succinamide.
As preferably, described decorating film is prepared by the raw material of following weight parts: polrvinyl chloride Resin-oatmeal 100 parts, plasticizer 50 parts, calcium zinc stabilizer 3 parts, nano silica fume 5 parts, color Expect 2.5 parts, titanium dioxide 8 parts, cold-resistant agent 5 parts.
As preferably, described cold-resistant agent is DOA cold resistant plasticizer.Its plasticizing efficiency is high, is subject to Hot plasticizing efficiency is high, and heated discoloration is little, it is adaptable to polrvinyl chloride, vinyl chloride copolymer, poly- The various kinds of resin such as styrene and synthetic rubber；The good low-temperature pliability of goods and fast light can be given Property, the handling property of goods is preferable.
As preferably, described plasticizer is DOTP plasticizer.
As preferably, described decorating film is prepared by following step: warp after sieve material, dispensing High-speed stirred, storage tank, shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, Draw take, Wen Lian, more cooled sizing, through cutting edge tentering, finally batch and obtain.
As preferably, described high-speed stirred rotating speed is 600～700r/min, mixing time 200～ 250s。
As preferably, during four-roll calendaring, controlling 1# roll temperature is 140～160 DEG C, turns Speed is 10～13m/min, and 2# roll temperature is 140～160 DEG C, and rotating speed is 13～15m/min, 3# roll temperature is 140～160 DEG C, and rotating speed is 13～16m/min, and 4# roll temperature is 140～160 DEG C, rotating speed is 15～18m/min.
The present invention is by preferred environmental protection raw material and improves production technology so that it is possess conventional decorative film Not available formaldehyde absorption function, has the effect except Formaldehyde Pollution of Indoor Air；It addition, it draws Stretching intensity, tearing strength, indices all meets national standard；Instant invention overcomes formaldehyde to inhale Receive the shortcoming that agent high temperature is unstable, by controlling rolling temperature, adding the means such as calcium zinc stabilizer, Reduce Product processing difficulty.The present invention has that the feature of environmental protection is good, stability is high, formaldehyde absorption is good Etc. advantage.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described, but claimed by the present invention Scope be not limited to this.
Embodiment 1
A kind of except formaldehyde interior decoration film, described decorating film is by the raw material preparation of following weight parts : polyvinyl chloride resin powder 100 parts, DOTP plasticizer 50 parts, calcium zinc stabilizer 3 parts, Nano silica fume 5 parts, 2.5 parts of colorant, titanium dioxide 8 parts, DOA cold-resistant agent 5 parts.
Described decorating film is prepared by following step: sieve material, after dispensing through high-speed stirred, Storage tank, shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, draw take, Wen Lian, The most cooled sizing, through cutting edge tentering, finally batches and obtains.Wherein, described high-speed stirred turns Speed is 650r/min, mixing time 220s；During four-roll calendaring, controlling 1# roll temperature is 150 DEG C, rotating speed be 11m/min, 2# roll temperature be 150 DEG C, rotating speed is 14m/min, 3# Roll temperature is 155 DEG C, rotating speed be 14.5m/min, 4# roll temperature be 150 DEG C, rotating speed is 16.5m/min。
Embodiment 2
A kind of except formaldehyde interior decoration film, described decorating film is by the raw material preparation of following weight parts : polyvinyl chloride resin powder 100 parts, DOTP plasticizer 40 parts, calcium zinc stabilizer 1 part, Nano silica fume 2 parts, 1 part of colorant, titanium dioxide 5 parts, DOA cold-resistant agent 2 parts.
Described decorating film is prepared by following step: sieve material, after dispensing through high-speed stirred, Storage tank, shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, draw take, Wen Lian, The most cooled sizing, through cutting edge tentering, finally batches and obtains.Wherein, described high-speed stirred turns Speed is 600r/min, mixing time 200s；During four-roll calendaring, controlling 1# roll temperature is 140 DEG C, rotating speed be 10m/min, 2# roll temperature be 140 DEG C, rotating speed is 13m/min, 3# Roll temperature is 140 DEG C, rotating speed be 13m/min, 4# roll temperature be 140 DEG C, rotating speed is 15m/min。
Embodiment 3
A kind of except formaldehyde interior decoration film, described decorating film is by the raw material preparation of following weight parts : polyvinyl chloride resin powder 100 parts, DOTP plasticizer 60 parts, calcium zinc stabilizer 5 parts, Nano silica fume 8 parts, 4 parts of colorant, titanium dioxide 11 parts, DOA cold-resistant agent 8 parts.
Described decorating film is prepared by following step: sieve material, after dispensing through high-speed stirred, Storage tank, shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, draw take, Wen Lian, The most cooled sizing, through cutting edge tentering, finally batches and obtains.Wherein, described high-speed stirred turns Speed is 700r/min, mixing time 250s；During four-roll calendaring, controlling 1# roll temperature is 160 DEG C, rotating speed be 13m/min, 2# roll temperature be 160 DEG C, rotating speed is 15m/min, 3# Roll temperature is 160 DEG C, rotating speed be 16m/min, 4# roll temperature be 160 DEG C, rotating speed is 18m/min。
Embodiment 4
A kind of except formaldehyde interior decoration film, described decorating film is by the raw material preparation of following weight parts : polyvinyl chloride resin powder 100 parts, DOTP plasticizer 55 parts, calcium zinc stabilizer 2 parts, 2-amino-2-methyl-1-propanol 6.5 parts, 3.5 parts of colorant, titanium dioxide 9 parts, DOA cold-resistant agent 6 parts.
Described decorating film is prepared by following step: sieve material, after dispensing through high-speed stirred, Storage tank, shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, draw take, Wen Lian, The most cooled sizing, through cutting edge tentering, finally batches and obtains.Wherein, described high-speed stirred turns Speed is 650r/min, mixing time 220s；During four-roll calendaring, controlling 1# roll temperature is 150 DEG C, rotating speed be 11m/min, 2# roll temperature be 150 DEG C, rotating speed is 14m/min, 3# Roll temperature is 155 DEG C, rotating speed be 14.5m/min, 4# roll temperature be 150 DEG C, rotating speed is 16.5m/min。
Embodiment 5
A kind of except formaldehyde interior decoration film, described decorating film is by the raw material preparation of following weight parts : polyvinyl chloride resin powder 100 parts, DOTP plasticizer 50 parts, calcium zinc stabilizer 3 parts, Isobutene. succimide 5 parts, 2.5 parts of colorant, titanium dioxide 8 parts, DOA cold-resistant agent 5 Part.
Described decorating film is prepared by following step: sieve material, after dispensing through high-speed stirred, Storage tank, shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, draw take, Wen Lian, The most cooled sizing, through cutting edge tentering, finally batches and obtains.Wherein, described high-speed stirred turns Speed is 680r/min, mixing time 230s；During four-roll calendaring, controlling 1# roll temperature is 160 DEG C, rotating speed be 12.5m/min, 2# roll temperature be 160 DEG C, rotating speed is 15m/min, 3# Roll temperature is 145 DEG C, rotating speed be 14m/min, 4# roll temperature be 140 DEG C, rotating speed is 17.5m/min。
Embodiment 1～5 obtain except formaldehyde interior decoration film, its formaldehyde collecting rate such as table 1 institute Show:
Table 1
Formaldehyde collecting rate, %
Embodiment 1 98.9
Embodiment 2 92.3
Embodiment 3 93.5
Embodiment 4 94.6
Embodiment 5 96.8

Claims (8)

1. one kind is removed formaldehyde interior decoration film, it is characterised in that: described decorating film is by following weight parts Raw material be prepared: polyvinyl chloride resin powder 100 parts, plasticizer 40～60 parts, calcium Zinc stabilizer 1～5 parts, formaldehyde absorbent 2～8 parts, colorant 1～4 parts, titanium dioxide 5～ 11 parts, cold-resistant agent 2～8 parts.
It is the most according to claim 1 except formaldehyde interior decoration film, it is characterised in that: described first Aldehyde absorbent be nano silica fume, 2-amino-2-methyl-1-propanol, isobutene. succimide, One in N-hydroxy-succinamide.
It is the most according to claim 1 except formaldehyde interior decoration film, it is characterised in that: described dress Decorations film is prepared by the raw material of following weight parts: polyvinyl chloride resin powder 100 parts, increasing Mould agent 50 parts, calcium zinc stabilizer 3 parts, nano silica fume 5 parts, 2.5 parts of colorant, titanium white 8 parts of powder, cold-resistant agent 5 parts.
It is the most according to claim 1 and 2 except formaldehyde interior decoration film, it is characterised in that: institute Stating cold-resistant agent is DOA cold resistant plasticizer.
It is the most according to claim 1 and 2 except formaldehyde interior decoration film, it is characterised in that: institute Stating plasticizer is DOTP plasticizer.
It is the most according to claim 1 except formaldehyde interior decoration film, it is characterised in that: described dress Decorations film is prepared by following step: sieve expects, after dispensing through high-speed stirred, storage tank, Shape star extrusion after, through two rollers plastify, extrusion filtration, four-roll calendaring, draw take, Wen Lian, The most cooled sizing, through cutting edge tentering, finally batches and obtains.
It is the most according to claim 6 except formaldehyde interior decoration film, it is characterised in that: described height Speed speed of agitator is 600～700r/min, mixing time 200～250s.
It is the most according to claim 6 except formaldehyde interior decoration film, it is characterised in that: four roll-ins During prolonging, controlling 1# roll temperature is 140～160 DEG C, and rotating speed is 10～13m/min, 2# roll temperature is 140～160 DEG C, and rotating speed is 13～15m/min, 3# roll temperature be 140～ 160 DEG C, rotating speed is 13～16m/min, and 4# roll temperature is 140～160 DEG C, rotating speed be 15～ 18m/min。
CN201610356406.2A 2016-05-26 2016-05-26 Formaldehyde-removal indoor decorative film Pending CN105968633A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832674A (en) * 2017-02-27 2017-06-13 安徽埃克利环境工程有限公司 A kind of environment-friendly type interior decoration film of removable formaldehyde and preparation method thereof
CN107880453A (en) * 2018-01-08 2018-04-06 金华观瑞科技有限公司 A kind of preparation technology of PVC decorative Film
CN109851944A (en) * 2018-12-27 2019-06-07 江苏盈泰新材料科技有限公司 A kind of antiultraviolet wall film and its processing technology
CN110655731A (en) * 2018-06-29 2020-01-07 3M创新有限公司 Polyvinyl chloride composition for removing formaldehyde and product for removing formaldehyde
CN113292803A (en) * 2021-06-30 2021-08-24 浙江铭隆装饰设计工程有限公司 Decorative material and preparation method thereof
CN110204844B (en) * 2019-06-10 2021-09-21 浙江明士达新材料有限公司 Impact-resistant efficient flame-retardant decorative film and preparation method thereof

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CN104194217A (en) * 2014-09-01 2014-12-10 东莞市悠悠美居家居制造有限公司 PVC (polyvinyl chloride) diamante shower curtain and preparation method thereof
CN105298085A (en) * 2015-10-28 2016-02-03 嘉善贝马五金配件有限公司 Wood-plastic floor and manufacturing method thereof
CN105419158A (en) * 2015-11-30 2016-03-23 蚌埠市华科机电有限责任公司 Modified composite plastic
CN105419156A (en) * 2015-11-30 2016-03-23 蚌埠市华科机电有限责任公司 Wear-resistant modified plastic

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CN103739908A (en) * 2013-11-27 2014-04-23 苏州市丰盛塑业有限公司 Modified fire retardation plastic product preparation method
CN104194217A (en) * 2014-09-01 2014-12-10 东莞市悠悠美居家居制造有限公司 PVC (polyvinyl chloride) diamante shower curtain and preparation method thereof
CN105298085A (en) * 2015-10-28 2016-02-03 嘉善贝马五金配件有限公司 Wood-plastic floor and manufacturing method thereof
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832674A (en) * 2017-02-27 2017-06-13 安徽埃克利环境工程有限公司 A kind of environment-friendly type interior decoration film of removable formaldehyde and preparation method thereof
CN107880453A (en) * 2018-01-08 2018-04-06 金华观瑞科技有限公司 A kind of preparation technology of PVC decorative Film
CN111253697A (en) * 2018-01-08 2020-06-09 金华观瑞科技有限公司 Preparation process of PVC decorative film
CN107880453B (en) * 2018-01-08 2020-11-27 金华观瑞科技有限公司 Preparation process of PVC decorative film
CN111253697B (en) * 2018-01-08 2021-08-06 浙江建新塑胶股份有限公司 Preparation process of PVC decorative film
CN110655731A (en) * 2018-06-29 2020-01-07 3M创新有限公司 Polyvinyl chloride composition for removing formaldehyde and product for removing formaldehyde
CN110655731B (en) * 2018-06-29 2022-03-04 3M创新有限公司 Polyvinyl chloride composition for removing formaldehyde and product for removing formaldehyde
CN109851944A (en) * 2018-12-27 2019-06-07 江苏盈泰新材料科技有限公司 A kind of antiultraviolet wall film and its processing technology
CN110204844B (en) * 2019-06-10 2021-09-21 浙江明士达新材料有限公司 Impact-resistant efficient flame-retardant decorative film and preparation method thereof
CN113292803A (en) * 2021-06-30 2021-08-24 浙江铭隆装饰设计工程有限公司 Decorative material and preparation method thereof

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Application publication date: 20160928