CN105967261A - Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent - Google Patents
Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent Download PDFInfo
- Publication number
- CN105967261A CN105967261A CN201610378662.1A CN201610378662A CN105967261A CN 105967261 A CN105967261 A CN 105967261A CN 201610378662 A CN201610378662 A CN 201610378662A CN 105967261 A CN105967261 A CN 105967261A
- Authority
- CN
- China
- Prior art keywords
- parts
- sulfate
- microbial inoculum
- mixture
- waste water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Microbiology (AREA)
- Biodiversity & Conservation Biology (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Treatment Of Sludge (AREA)
Abstract
The invention discloses a sewage treatment agent special for printing and dyeing wastewater. The sewage treatment agent is prepared from, by weight, coal ash, wooden activated carbon, poly aluminium chloride, polyferric sulfate, polyacrylamide, ammonium persulfate, sodium carbonate, poly-ferric aluminum sulfate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, zeolite, sepiolite, modified lignin sulfonate, alkylphenol ethoxylates, amino trimethylene phosphonic acid, menthone, thiourea, cationoid starch derivatives, sodium dodecyl benzene sulfonate, dimethyl diallyl ammonium chloride, octaphenyl polyoxyethyiene, glycerin monostearate, peroxiredoxin and microbial bacterial liquid. The microbial bacterial liquid is prepared from saccharomycetes, fusarium oxysporum, proteusbacillus vulgaris, neurospora and mycoplana. The invention further provides a preparation method of the sewage treatment agent. The prepared sewage treatment agent is good in treatment effect on the printing and dyeing wastewater, the preparation method is simple, and no secondary pollution exists.
Description
Technical field
The present invention relates to technical field of sewage, specifically a kind of special sewage-treating agent of dyeing waste water and preparation method thereof.
Background technology
Dyeing waste water is to process the waste water that cotton, fiber crops, chemical fibre and blending product thereof are main printing and dyeing mill's discharge.Dyeing waste water
The water yield is relatively big, and 1 ton of textile water consumption of every dyeing and printing process 100～200 tons, wherein 80～90% become waste water.Textile printing and dyeing is given up
Water has the features such as the water yield is big, organic pollution content high, alkalescence is big, change of water quality is big, belong to intractable industrial wastewater it
One.Dyeing waste water is industrial wastewater discharge rich and influential family, and statistical data shows, textile waste discharge capacity 2,300,000,000 tons in 2008,
Occupy each industrial trade the 3rd, account for the 10.60% of whole nation discharged volume of industrial waste water.COD in textile industry waste discharge
(CODCr) discharge capacity 31.4 ten thousand tons, occupy each industrial trade the 4th, account for the 7.76% of whole nation industrial wastewater CODCr.This number
According to being the statistical data of enterprise above to scale, real data may be much larger.Actually dyeing is with medium-sized and small enterprises
Being main competitive industry, medium-sized and small enterprises proportion accounts for 99.6%, and non-public enterprises account for 95%, and a large amount of small enterprises data are not
Including Tong Ji.If need to carry out in terms of dyeing and printing process by the 70% of fiber process amount, then year waste discharge is about at about 3,000,000,000 tons.Existing
With the presence for the treatment of of dyeing wastewater medicament complicated process of preparation, poor processing effect, there is the defects such as secondary pollution.
Summary of the invention
It is an object of the invention to provide a kind of special sewage-treating agent of dyeing waste water and preparation method thereof, to solve above-mentioned background
The problem proposed in technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of special sewage-treating agent of dyeing waste water, is made up of according to the raw material of weight portion following: flyash 43-46 part, wood
Activated carbon 25-28 part, aluminium polychlorid 26-30 part, bodied ferric sulfate 16-20 part, polyacrylamide 18-21 part,
Ammonium persulfate. 10-13 part, sodium carbonate 15-17 part, PAFS 12-16 part, aluminum sulfate 9-13 part, yttrium oxalate
3-5 part, manganese sulfate 6-8 part, sodium bentonite 21-24 part, zeolite 18-20 part, meerschaum 16-19 part, modified sulphur
Change lignin 13-15 part, alkylphenol polyoxyethylene 6-9 part, ATMP 2-6 part, menthone 9-11 part,
Thiourea 10-13 part, cationic starch derivant 17-20 part, dodecylbenzene sodium sulfonate 14-16 part, dimethyl diene
Propyl ammonium chloride 9-12 part, OPEO 14-17 part, glyceryl monostearate 10-13 part, peroxidating are also
Protoenzyme 20-23 part, microbial inoculum 43-46 part；Described microbial inoculum by yeast, Fusarium oxysporum, Bacillus proteus,
Neurospora and branch lever bacterium composition, and yeast in microbial inoculum, Fusarium oxysporum, Bacillus proteus, Neurospora and
The ratio of branch lever bacterium is 5:3:7:4:2.
As the further scheme of the present invention: be made up of according to the raw material of weight portion following: flyash 44-45 part, wooden work
Property charcoal 26-27 part, aluminium polychlorid 27-29 part, bodied ferric sulfate 17-19 part, polyacrylamide 19-20 part, over cure
Acid ammonium 11-12 part, sodium carbonate 15.3-16.7 part, PAFS 13-15 part, aluminum sulfate 10-12 part, yttrium oxalate
3.4-4.7 part, manganese sulfate 6.2-7.5 part, sodium bentonite 22-23 part, zeolite 18.5-19.5 part, meerschaum 17-18
Part, modification sulphonation lignin 13.6-14.3 part, alkylphenol polyoxyethylene 7-8 part, ATMP 3-5 part,
Menthone 9.2-10.5 part, thiourea 11-12 part, cationic starch derivant 18-19 part, dodecylbenzene sodium sulfonate
14.5-15.5 part, dimethyl diallyl ammonium chloride 10-11 part, OPEO 15-16 part, monostearate
Glyceride 11-12 part, oxidization-reduction enzyme 21-22 part, microbial inoculum 44-45 part.
As the present invention further scheme: be made up of according to the raw material of weight portion following: 44.5 parts of flyash, wooden
Activated carbon 26 parts, aluminium polychlorid 28 parts, bodied ferric sulfate 18 parts, polyacrylamide 19 parts, Ammonium persulfate. 11.4
Part, sodium carbonate 16 parts, PAFS 14 parts, 11 parts of aluminum sulfate, yttrium oxalate 3.8 parts, manganese sulfate 6.6 parts,
Sodium bentonite 22.5 parts, 19 parts of zeolite, meerschaum 17.4 parts, modification sulphonation lignin 13.9 parts, alkyl phenol polyoxy
Vinyl Ether 7.3 parts, ATMP 4 parts, menthone 9.7 parts, thiourea 11.6 parts, cationic starch are derivative
Thing 18.4 parts, dodecylbenzene sodium sulfonate 14.8 parts, dimethyl diallyl ammonium chloride 10.5 parts, octyl phenol polyoxy second
15 parts of alkene ether, glyceryl monostearate 12 parts, oxidization-reduction enzyme 21.3 parts, microbial inoculum 45 parts.
The preparation method of the special sewage-treating agent of described dyeing waste water, step is as follows:
1) flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, boiling are weighed
Stone, meerschaum, cross 150-200 mesh sieve, ball milling mixing 3-5h, it is thus achieved that the first mixture after pulverizing；
2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium,
Obtain microbial inoculum, standby；
3) weigh aluminium polychlorid, bodied ferric sulfate and polyacrylamide, after mix homogeneously, be warming up to 43-48 DEG C, add
PAFS, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing
30-40min, then it is warming up to 55-58 DEG C, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl two
Allyl ammonium chloride, stirring mixing 20-30min, after natural cooling, add OPEO, glycerol monostearate
Ester and Ammonium persulfate., stirring mixing 1-2h, it is thus achieved that the second mixture；
4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing
1-2h, it is thus achieved that the 3rd mixture；
5) the 3rd mixture is merged mixing with microbial inoculum,.
Above-mentioned sewage-treating agent can be used in processing dyeing waste water.
Compared with prior art, the invention has the beneficial effects as follows:
The special sewage-treating agent of dyeing waste water prepared by the present invention can be substantially reduced the COD in dyeing waste waterCr, ammonia nitrogen and SS,
High treating effect, instant effect, preparation method is simple, and there is not secondary pollution.The special dirt of dyeing waste water prepared by the present invention
Water treatment agent is coordinated by the symbiosis between each strain, and collaborative chemical treatments, greatly strengthen this sewage-treating agent to printing and dyeing
The treatment effect of waste water.
Detailed description of the invention
Below in conjunction with detailed description of the invention, technical scheme is described in more detail.
Embodiment 1
A kind of special sewage-treating agent of dyeing waste water, is made up of according to the raw material of weight portion following: 43 parts of flyash, wooden
Activated carbon 25 parts, aluminium polychlorid 26 parts, bodied ferric sulfate 16 parts, polyacrylamide 18 parts, Ammonium persulfate. 10 parts,
Sodium carbonate 15 parts, PAFS 12 parts, 9 parts of aluminum sulfate, yttrium oxalate 3 parts, manganese sulfate 6 parts, sodium bentonite
21 parts, 18 parts of zeolite, meerschaum 16 parts, modification sulphonation lignin 13 parts, alkylphenol polyoxyethylene 6 parts, amino
Three methylenephosphonic acids 2 parts, menthone 9 parts, thiourea 10 parts, cationic starch derivant 17 parts, DBSA
14 parts of sodium, dimethyl diallyl ammonium chloride 9 parts, OPEO 14 parts, glyceryl monostearate 10 parts,
Oxidization-reduction enzyme 20 parts, microbial inoculum 43 parts；Described microbial inoculum is by yeast, Fusarium oxysporum, deformed rod
Bacterium, Neurospora and branch lever bacterium composition, and yeast, Fusarium oxysporum, Bacillus proteus, Neurospora in microbial inoculum
The ratio of bacterium and branch lever bacterium is 5:3:7:4:2.
The preparation method of the special sewage-treating agent of dyeing waste water described in the present embodiment, step is as follows:
1) flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, boiling are weighed
Stone, meerschaum, cross 150 mesh sieves, ball milling mixing 3h, it is thus achieved that the first mixture after pulverizing；
2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium,
Obtain microbial inoculum, standby；
3) weigh aluminium polychlorid, bodied ferric sulfate and polyacrylamide, after mix homogeneously, be warming up to 43 DEG C, add poly-
Close aluminium iron sulfate, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing
30min, then it is warming up to 55 DEG C, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl diallyl
Ammonium chloride, stirring mixing 20min, after natural cooling, add OPEO, glyceryl monostearate and over cure
Acid ammonium, stirring mixing 1h, it is thus achieved that the second mixture；
4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing
1h, it is thus achieved that the 3rd mixture；
5) the 3rd mixture is merged mixing with microbial inoculum,.
Embodiment 2
A kind of special sewage-treating agent of dyeing waste water, is made up of according to the raw material of weight portion following: 44 parts of flyash, wooden
Activated carbon 28 parts, aluminium polychlorid 28 parts, bodied ferric sulfate 20 parts, polyacrylamide 18 parts, Ammonium persulfate. 12 parts,
Sodium carbonate 17 parts, PAFS 12.5 parts, 9.6 parts of aluminum sulfate, yttrium oxalate 4.2 parts, manganese sulfate 8 parts, sodio
Bentonite 22 parts, 18.4 parts of zeolite, meerschaum 16 parts, modification sulphonation lignin 15 parts, alkylphenol polyoxyethylene 6.7
Part, ATMP 6 parts, menthone 9 parts, thiourea 11 parts, cationic starch derivant 20 parts, dodecane
Base benzene sulfonic acid sodium salt 15 parts, dimethyl diallyl ammonium chloride 10.5 parts, OPEO 17 parts, monostearate
Glyceride 13 parts, oxidization-reduction enzyme 20 parts, microbial inoculum 45 parts；Described microbial inoculum is by yeast, point spore
Fusarium spp., Bacillus proteus, Neurospora and branch lever bacterium composition, and yeast, Fusarium oxysporum, change in microbial inoculum
The ratio of shape bacillus, Neurospora and branch lever bacterium is 5:3:7:4:2.
The preparation method of the special sewage-treating agent of dyeing waste water described in the present embodiment, step is as follows:
1) flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, boiling are weighed
Stone, meerschaum, cross 160 mesh sieves, ball milling mixing 3.5h, it is thus achieved that the first mixture after pulverizing；
2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium,
Obtain microbial inoculum, standby；
3) weigh aluminium polychlorid, bodied ferric sulfate and polyacrylamide, after mix homogeneously, be warming up to 47 DEG C, add poly-
Close aluminium iron sulfate, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing
32min, then it is warming up to 55 DEG C, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl diallyl
Ammonium chloride, stirring mixing 25min, after natural cooling, add OPEO, glyceryl monostearate and over cure
Acid ammonium, stirring mixing 1.5h, it is thus achieved that the second mixture；
4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing
1h, it is thus achieved that the 3rd mixture；
5) the 3rd mixture is merged mixing with microbial inoculum,.
Embodiment 3
A kind of special sewage-treating agent of dyeing waste water, is made up of according to the raw material of weight portion following: 44.5 parts of flyash, wood
Activated carbon 26 parts, aluminium polychlorid 28 parts, bodied ferric sulfate 18 parts, polyacrylamide 19 parts, Ammonium persulfate. 11.4
Part, sodium carbonate 16 parts, PAFS 14 parts, 11 parts of aluminum sulfate, yttrium oxalate 3.8 parts, manganese sulfate 6.6 parts,
Sodium bentonite 22.5 parts, 19 parts of zeolite, meerschaum 17.4 parts, modification sulphonation lignin 13.9 parts, alkyl phenol polyoxy
Vinyl Ether 7.3 parts, ATMP 4 parts, menthone 9.7 parts, thiourea 11.6 parts, cationic starch are derivative
Thing 18.4 parts, dodecylbenzene sodium sulfonate 14.8 parts, dimethyl diallyl ammonium chloride 10.5 parts, octyl phenol polyoxy second
15 parts of alkene ether, glyceryl monostearate 12 parts, oxidization-reduction enzyme 21.3 parts, microbial inoculum 45 parts；Described micro-life
Thing bacterium solution is made up of yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium, and ferment in microbial inoculum
The ratio of female bacterium, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium is 5:3:7:4:2.
The preparation method of the special sewage-treating agent of dyeing waste water described in the present embodiment, step is as follows:
1) flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, boiling are weighed
Stone, meerschaum, cross 180 mesh sieves, ball milling mixing 4h, it is thus achieved that the first mixture after pulverizing；
2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium,
Obtain microbial inoculum, standby；
3) weigh aluminium polychlorid, bodied ferric sulfate and polyacrylamide, after mix homogeneously, be warming up to 45 DEG C, add poly-
Close aluminium iron sulfate, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing
35min, then it is warming up to 56 DEG C, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl diallyl
Ammonium chloride, stirring mixing 25min, after natural cooling, add OPEO, glyceryl monostearate and over cure
Acid ammonium, stirring mixing 1.5h, it is thus achieved that the second mixture；
4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing
1.5h, it is thus achieved that the 3rd mixture；
5) the 3rd mixture is merged mixing with microbial inoculum,.
Embodiment 4
A kind of special sewage-treating agent of dyeing waste water, is made up of according to the raw material of weight portion following: 45 parts of flyash, wooden
Activated carbon 28 parts, aluminium polychlorid 29 parts, bodied ferric sulfate 16.9 parts, polyacrylamide 18 parts, Ammonium persulfate. 13
Part, sodium carbonate 15.7 parts, PAFS 12.6 parts, 13 parts of aluminum sulfate, yttrium oxalate 3 parts, manganese sulfate 6 parts,
Sodium bentonite 21 parts, 19 parts of zeolite, meerschaum 19 parts, modification sulphonation lignin 13.2 parts, alkylphenol-polyethenoxy
9 parts of ether, ATMP 2 parts, menthone 10 parts, thiourea 10.3 parts, cationic starch derivant 19 parts,
Dodecylbenzene sodium sulfonate 14.8 parts, dimethyl diallyl ammonium chloride 9.2 parts, OPEO 17 parts, list
Tristerin 10 parts, oxidization-reduction enzyme 22 parts, microbial inoculum 46 parts；Described microbial inoculum by yeast,
Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium composition, and yeast in microbial inoculum, Fusarium oxysporum,
The ratio of Bacillus proteus, Neurospora and branch lever bacterium is 5:3:7:4:2.
The preparation method of the special sewage-treating agent of dyeing waste water described in the present embodiment, step is as follows:
1) flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, boiling are weighed
Stone, meerschaum, cross 200 mesh sieves, ball milling mixing 4h, it is thus achieved that the first mixture after pulverizing；
2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium,
Obtain microbial inoculum, standby；
3) weigh aluminium polychlorid, bodied ferric sulfate and polyacrylamide, after mix homogeneously, be warming up to 47 DEG C, add poly-
Close aluminium iron sulfate, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing
35min, then it is warming up to 58 DEG C, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl diallyl
Ammonium chloride, stirring mixing 28min, after natural cooling, add OPEO, glyceryl monostearate and over cure
Acid ammonium, stirring mixing 1.5h, it is thus achieved that the second mixture；
4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing
2h, it is thus achieved that the 3rd mixture；
5) the 3rd mixture is merged mixing with microbial inoculum,.
Embodiment 5
A kind of special sewage-treating agent of dyeing waste water, is made up of according to the raw material of weight portion following: 46 parts of flyash, wooden
Activated carbon 28 parts, aluminium polychlorid 30 parts, bodied ferric sulfate 20 parts, polyacrylamide 21 parts, Ammonium persulfate. 13 parts,
Sodium carbonate 17 parts, PAFS 16 parts, 13 parts of aluminum sulfate, yttrium oxalate 5 parts, manganese sulfate 8 parts, Na-bentonite
24 parts of soil, 20 parts of zeolite, meerschaum 19 parts, modification sulphonation lignin 15 parts, alkylphenol polyoxyethylene 9 parts, ammonia
Base three methylenephosphonic acid 6 parts, menthone 11 parts, thiourea 13 parts, cationic starch derivant 20 parts, detergent alkylate
Sodium sulfonate 16 parts, dimethyl diallyl ammonium chloride 12 parts, OPEO 17 parts, glyceryl monostearate
13 parts, oxidization-reduction enzyme 23 parts, microbial inoculum 46 parts；Described microbial inoculum by yeast, Fusarium oxysporum,
Bacillus proteus, Neurospora and branch lever bacterium composition, and yeast in microbial inoculum, Fusarium oxysporum, Bacillus proteus,
The ratio of Neurospora and branch lever bacterium is 5:3:7:4:2.
The preparation method of the special sewage-treating agent of dyeing waste water described in the present embodiment, step is as follows:
1) flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, boiling are weighed
Stone, meerschaum, cross 200 mesh sieves, ball milling mixing 5h, it is thus achieved that the first mixture after pulverizing；
2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium,
Obtain microbial inoculum, standby；
3) weigh aluminium polychlorid, bodied ferric sulfate and polyacrylamide, after mix homogeneously, be warming up to 48 DEG C, add poly-
Close aluminium iron sulfate, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing
40min, then it is warming up to 58 DEG C, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl diallyl
Ammonium chloride, stirring mixing 30min, after natural cooling, add OPEO, glyceryl monostearate and over cure
Acid ammonium, stirring mixing 2h, it is thus achieved that the second mixture；
4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing
2h, it is thus achieved that the 3rd mixture；
5) the 3rd mixture is merged mixing with microbial inoculum,.
Use the special sewage-treating agent of dyeing waste water prepared by above-described embodiment 1-5, at certain printing and dyeing mill's waste discharge
Reason experiment, the COD wherein intakeCrFor 3400mg/L, ammonia nitrogen be 95mg/L, SS be 550mg/L；Arrange after treatment
The waste water quality index put is as shown in table 1.
Table 1 result of the test table
| Project | CODCr(mg/L) | Ammonia nitrogen (mg/L) | SS(mg/L) | Whether reach discharge standard |
| Dyeing waste water | 3400 | 95 | 550 | No |
| Embodiment 1 | 48 | 7 | 32 | It is |
| Embodiment 2 | 50 | 9 | 34 | It is |
| Embodiment 3 | 45 | 6 | 28 | It is |
| Embodiment 4 | 46 | 6 | 29 | It is |
| Embodiment 5 | 45 | 8 | 31 | It is |
As can be seen from the above table, the dyeing waste water after using embodiment of the present invention 1-5 to process, its every water quality index all reaches
The discharge standard of national regulation.
The special sewage-treating agent of dyeing waste water prepared by the present invention can be substantially reduced the COD in dyeing waste waterCr, ammonia nitrogen and SS,
High treating effect, instant effect, preparation method is simple, and there is not secondary pollution.The special dirt of dyeing waste water prepared by the present invention
Water treatment agent is coordinated by the symbiosis between each strain, and collaborative chemical treatments, greatly strengthen this sewage-treating agent to printing and dyeing
The treatment effect of waste water.
Above the better embodiment of the present invention is explained in detail, but the present invention is not limited to above-mentioned embodiment,
In the ken that those of ordinary skill in the art is possessed, it is also possible to make each on the premise of without departing from present inventive concept
Plant change.
Claims (5)
- null1. the special sewage-treating agent of dyeing waste water，It is characterized in that，It is made up of according to the raw material of weight portion following: flyash 43-46 part、Wood activated charcoal 25-28 part、Aluminium polychlorid 26-30 part、Bodied ferric sulfate 16-20 part、Polyacrylamide 18-21 part、Ammonium persulfate. 10-13 part、Sodium carbonate 15-17 part、PAFS 12-16 part、Aluminum sulfate 9-13 part、Yttrium oxalate 3-5 part、Manganese sulfate 6-8 part、Sodium bentonite 21-24 part、Zeolite 18-20 part、Meerschaum 16-19 part、Modification sulphonation lignin 13-15 part、Alkylphenol polyoxyethylene 6-9 part、ATMP 2-6 part、Menthone 9-11 part、Thiourea 10-13 part、Cationic starch derivant 17-20 part、Dodecylbenzene sodium sulfonate 14-16 part、Dimethyl diallyl ammonium chloride 9-12 part、OPEO 14-17 part、Glyceryl monostearate 10-13 part、Oxidization-reduction enzyme 20-23 part、Microbial inoculum 43-46 part；Described microbial inoculum is made up of yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium, and in microbial inoculum, the ratio of yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium is 5:3:7:4:2.
- nullThe special sewage-treating agent of dyeing waste water the most according to claim 1，It is characterized in that，It is made up of according to the raw material of weight portion following: flyash 44-45 part、Wood activated charcoal 26-27 part、Aluminium polychlorid 27-29 part、Bodied ferric sulfate 17-19 part、Polyacrylamide 19-20 part、Ammonium persulfate. 11-12 part、Sodium carbonate 15.3-16.7 part、PAFS 13-15 part、Aluminum sulfate 10-12 part、Yttrium oxalate 3.4-4.7 part、Manganese sulfate 6.2-7.5 part、Sodium bentonite 22-23 part、Zeolite 18.5-19.5 part、Meerschaum 17-18 part、Modification sulphonation lignin 13.6-14.3 part、Alkylphenol polyoxyethylene 7-8 part、ATMP 3-5 part、Menthone 9.2-10.5 part、Thiourea 11-12 part、Cationic starch derivant 18-19 part、Dodecylbenzene sodium sulfonate 14.5-15.5 part、Dimethyl diallyl ammonium chloride 10-11 part、OPEO 15-16 part、Glyceryl monostearate 11-12 part、Oxidization-reduction enzyme 21-22 part、Microbial inoculum 44-45 part.
- nullThe special sewage-treating agent of dyeing waste water the most according to claim 2，It is characterized in that，It is made up of according to the raw material of weight portion following: 44.5 parts of flyash、Wood activated charcoal 26 parts、Aluminium polychlorid 28 parts、Bodied ferric sulfate 18 parts、Polyacrylamide 19 parts、Ammonium persulfate. 11.4 parts、Sodium carbonate 16 parts、PAFS 14 parts、11 parts of aluminum sulfate、Yttrium oxalate 3.8 parts、Manganese sulfate 6.6 parts、Sodium bentonite 22.5 parts、19 parts of zeolite、Meerschaum 17.4 parts、Modification sulphonation lignin 13.9 parts、Alkylphenol polyoxyethylene 7.3 parts、ATMP 4 parts、Menthone 9.7 parts、Thiourea 11.6 parts、Cationic starch derivant 18.4 parts、Dodecylbenzene sodium sulfonate 14.8 parts、Dimethyl diallyl ammonium chloride 10.5 parts、OPEO 15 parts、Glyceryl monostearate 12 parts、Oxidization-reduction enzyme 21.3 parts、Microbial inoculum 45 parts.
- 4. the preparation method of the special sewage-treating agent of the dyeing waste water as described in claim 1-3 is arbitrary, it is characterised in that step is as follows:1) weigh flyash, wood activated charcoal, sodium carbonate, aluminum sulfate, yttrium oxalate, manganese sulfate, sodium bentonite, zeolite, meerschaum, after pulverizing, cross 150-200 mesh sieve, ball milling mixing 3-5h, it is thus achieved that the first mixture；2) water is used to be activated by the flora containing yeast, Fusarium oxysporum, Bacillus proteus, Neurospora and branch lever bacterium, it is thus achieved that microbial inoculum, standby；3) aluminium polychlorid, bodied ferric sulfate and polyacrylamide are weighed, after mix homogeneously, it is warming up to 43-48 DEG C, add PAFS, modification sulphonation lignin, alkylphenol polyoxyethylene, ATMP and thiourea, stirring mixing 30-40min, it is warming up to 55-58 DEG C again, add cationic starch derivant, dodecylbenzene sodium sulfonate and dimethyl diallyl ammonium chloride, stirring mixing 20-30min, after natural cooling, add OPEO, glyceryl monostearate and Ammonium persulfate., stirring mixing 1-2h, it is thus achieved that the second mixture；4) by the first mixture and the second mixture mix homogeneously, and menthone and oxidization-reduction enzyme are added, stirring mixing 1-2h, it is thus achieved that the 3rd mixture；5) the 3rd mixture is merged mixing with microbial inoculum,.
- 5. the purposes in processing dyeing waste water of the sewage-treating agent as described in claim 1-3 is arbitrary.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610378662.1A CN105967261A (en) | 2016-05-26 | 2016-05-26 | Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610378662.1A CN105967261A (en) | 2016-05-26 | 2016-05-26 | Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105967261A true CN105967261A (en) | 2016-09-28 |
Family
ID=57009969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610378662.1A Pending CN105967261A (en) | 2016-05-26 | 2016-05-26 | Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105967261A (en) |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106430361A (en) * | 2016-11-25 | 2017-02-22 | 南宁市黑晶信息技术有限公司 | Special efficient low-cost sewage treatment agent for domestic sewage and preparation method of sewage treatment agent |
| CN106629894A (en) * | 2016-11-25 | 2017-05-10 | 南宁市黑晶信息技术有限公司 | A low-cost sewage treating agent specially used for printing and dyeing waste water and a preparing method thereof |
| CN106630184A (en) * | 2016-11-25 | 2017-05-10 | 南宁市黑晶信息技术有限公司 | Compound sewage treating agent for treating oilfield sewage and preparation method thereof |
| CN106865646A (en) * | 2017-03-05 | 2017-06-20 | 张红卫 | A kind of inexpensive treatment of dyeing/printing wastewaters and preparation method thereof |
| CN106865784A (en) * | 2017-03-16 | 2017-06-20 | 王冰 | A kind of wastewater treatment material of smelting iron and steel and preparation method thereof |
| CN107963690A (en) * | 2017-11-28 | 2018-04-27 | 芜湖上水源环保科技有限公司 | A kind of efficiently dyeing waste water flocculant preparation method |
| CN108083376A (en) * | 2017-12-25 | 2018-05-29 | 芜湖皖江知识产权运营中心有限公司 | A kind of sewage-treating agent and preparation method thereof |
| CN108298699A (en) * | 2018-03-02 | 2018-07-20 | 云南龙帜环境工程有限公司 | A kind of pharmaceutical wastewater integrated processing technique |
| CN108609744A (en) * | 2018-05-31 | 2018-10-02 | 四川奥恒环保科技有限公司 | A kind of sewage-treating agent and preparation method thereof |
| CN108715508A (en) * | 2018-06-29 | 2018-10-30 | 河南妙天控股有限公司 | A kind of pig farm excrement object inorganic agent and preparation method thereof |
| CN109576170A (en) * | 2018-08-30 | 2019-04-05 | 常州大学 | One plant height imitates application of the sulfur oxidizing bacterium in Containing Sulfur Black wastewater treatment |
| CN110143627A (en) * | 2019-07-04 | 2019-08-20 | 李洪 | A kind of city domestic sewage inorganic agent and sewage treatment process |
| CN111268776A (en) * | 2018-12-04 | 2020-06-12 | 上海泽戌化学科技有限公司 | Flocculant for petrochemical wastewater treatment and preparation method thereof |
| CN113582285A (en) * | 2021-07-27 | 2021-11-02 | 武汉理工大学 | Black and odorous water composite phosphorus locking agent and preparation method and application thereof |
| CN114874916A (en) * | 2022-03-28 | 2022-08-09 | 中国地质大学（武汉） | Scopulariopsis fungus (Sarocladium kiliense) ZJ-1 and application thereof |
| CN115739023A (en) * | 2022-11-29 | 2023-03-07 | 中国科学技术大学 | Iron-nitrogen co-doped biological carbon material based on microbial enrichment, and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101243794A (en) * | 2007-12-20 | 2008-08-20 | 山东亿嘉农化有限公司 | Water-based fungicide and preparation thereof |
| CN103665394A (en) * | 2012-09-24 | 2014-03-26 | 中国石油化工股份有限公司 | Method for preparing emulsified residual oil by using cyclohexanone wastewater |
| CN103771560A (en) * | 2014-01-16 | 2014-05-07 | 江苏集贤绿色化学科技研究院有限公司 | Oilfield sewage treatment agent and preparation method thereof |
| CN104193011A (en) * | 2014-08-27 | 2014-12-10 | 镇江华域环保设备制造有限公司 | Dyeing wastewater purifying agent |
| CN105565403A (en) * | 2015-12-21 | 2016-05-11 | 天津欧盼科技开发有限公司 | Preparation method of environment-friendly sewage treatment agent |
-
2016
- 2016-05-26 CN CN201610378662.1A patent/CN105967261A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101243794A (en) * | 2007-12-20 | 2008-08-20 | 山东亿嘉农化有限公司 | Water-based fungicide and preparation thereof |
| CN103665394A (en) * | 2012-09-24 | 2014-03-26 | 中国石油化工股份有限公司 | Method for preparing emulsified residual oil by using cyclohexanone wastewater |
| CN103771560A (en) * | 2014-01-16 | 2014-05-07 | 江苏集贤绿色化学科技研究院有限公司 | Oilfield sewage treatment agent and preparation method thereof |
| CN104193011A (en) * | 2014-08-27 | 2014-12-10 | 镇江华域环保设备制造有限公司 | Dyeing wastewater purifying agent |
| CN105565403A (en) * | 2015-12-21 | 2016-05-11 | 天津欧盼科技开发有限公司 | Preparation method of environment-friendly sewage treatment agent |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106629894A (en) * | 2016-11-25 | 2017-05-10 | 南宁市黑晶信息技术有限公司 | A low-cost sewage treating agent specially used for printing and dyeing waste water and a preparing method thereof |
| CN106630184A (en) * | 2016-11-25 | 2017-05-10 | 南宁市黑晶信息技术有限公司 | Compound sewage treating agent for treating oilfield sewage and preparation method thereof |
| CN106430361A (en) * | 2016-11-25 | 2017-02-22 | 南宁市黑晶信息技术有限公司 | Special efficient low-cost sewage treatment agent for domestic sewage and preparation method of sewage treatment agent |
| CN106865646A (en) * | 2017-03-05 | 2017-06-20 | 张红卫 | A kind of inexpensive treatment of dyeing/printing wastewaters and preparation method thereof |
| CN106865784A (en) * | 2017-03-16 | 2017-06-20 | 王冰 | A kind of wastewater treatment material of smelting iron and steel and preparation method thereof |
| CN107963690A (en) * | 2017-11-28 | 2018-04-27 | 芜湖上水源环保科技有限公司 | A kind of efficiently dyeing waste water flocculant preparation method |
| CN108083376A (en) * | 2017-12-25 | 2018-05-29 | 芜湖皖江知识产权运营中心有限公司 | A kind of sewage-treating agent and preparation method thereof |
| CN108083376B (en) * | 2017-12-25 | 2020-10-20 | 芜湖皖江知识产权运营中心有限公司 | Sewage treatment agent and preparation method thereof |
| CN108298699B (en) * | 2018-03-02 | 2020-10-16 | 云南龙帜环境工程有限公司 | Integrated treatment process for medical wastewater |
| CN108298699A (en) * | 2018-03-02 | 2018-07-20 | 云南龙帜环境工程有限公司 | A kind of pharmaceutical wastewater integrated processing technique |
| CN108609744A (en) * | 2018-05-31 | 2018-10-02 | 四川奥恒环保科技有限公司 | A kind of sewage-treating agent and preparation method thereof |
| CN108715508A (en) * | 2018-06-29 | 2018-10-30 | 河南妙天控股有限公司 | A kind of pig farm excrement object inorganic agent and preparation method thereof |
| CN109576170A (en) * | 2018-08-30 | 2019-04-05 | 常州大学 | One plant height imitates application of the sulfur oxidizing bacterium in Containing Sulfur Black wastewater treatment |
| CN111268776A (en) * | 2018-12-04 | 2020-06-12 | 上海泽戌化学科技有限公司 | Flocculant for petrochemical wastewater treatment and preparation method thereof |
| CN110143627A (en) * | 2019-07-04 | 2019-08-20 | 李洪 | A kind of city domestic sewage inorganic agent and sewage treatment process |
| CN113582285A (en) * | 2021-07-27 | 2021-11-02 | 武汉理工大学 | Black and odorous water composite phosphorus locking agent and preparation method and application thereof |
| CN114874916A (en) * | 2022-03-28 | 2022-08-09 | 中国地质大学（武汉） | Scopulariopsis fungus (Sarocladium kiliense) ZJ-1 and application thereof |
| CN115739023A (en) * | 2022-11-29 | 2023-03-07 | 中国科学技术大学 | Iron-nitrogen co-doped biological carbon material based on microbial enrichment, and preparation method and application thereof |
| CN115739023B (en) * | 2022-11-29 | 2024-02-09 | 中国科学技术大学 | Iron-nitrogen co-doped biological carbon material based on microbial enrichment, and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105967261A (en) | Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent | |
| CN106145381A (en) | A kind of high efficiency sewage treating agent and preparation method thereof | |
| CN101413225B (en) | Method for producing corrugated paper and textile spool paper by manioc slag and wine stillage slag | |
| Rahman et al. | The use of biotechnologies in textile processing and environmental sustainability: An emerging market context | |
| CN106865646A (en) | A kind of inexpensive treatment of dyeing/printing wastewaters and preparation method thereof | |
| CN105753174B (en) | A kind of sewage-treating agent and preparation method thereof for dyeing waste water | |
| CN102162198B (en) | Multienzyme complex preparation and preparation method and application thereof | |
| CN101649548A (en) | Batching medium | |
| CN108358494A (en) | A kind of liquid alkali-free quick-coagulant and preparation method thereof | |
| CN105019221A (en) | Chemical fiber additive for improving whiteness of chemical fibers | |
| CN106833778B (en) | A kind of method that recycling sludge processing prepares water-coal-slurry | |
| CN107163614A (en) | A kind of permanent bordeaux pigment and preparation method thereof | |
| CN107216188A (en) | A kind of sludge aerobic compost Biostimulation agent and application method | |
| CN112778796A (en) | Energy-saving emission-reducing high-stability liquid disperse dye and preparation method and application thereof | |
| CN102817227A (en) | Feather decolorization treatment process | |
| CN110305914A (en) | A kind of method that reinforcement sludge produces sour mixed fermentation | |
| CN103741462B (en) | A kind of bamboo fiber process for cleanly preparing | |
| CN106862260A (en) | A kind of biochemical process for administering Cadmium Pollution in Soils | |
| CN102888358B (en) | A kind of Pseudomonas fluorescens and biological bacteria liquid pulping method | |
| CN102876575B (en) | Compound bacterium used for pulping biological bacterium fluid and application of compound bacterium | |
| CN106283788A (en) | A kind of for the chemical-biological pulping process with non-wood material | |
| CN1272288C (en) | Organic manure special for green nuisanceless farm products and preparation method thereof | |
| CN1212978C (en) | Process for high-quality treatment of waste dyeing water with waste solution of ferrous sulfate or ferrous chloride | |
| do Carmo et al. | Dyeability of polyester and polyamide fabrics employing citric acid | |
| CN104389225B (en) | A kind of method of bioremediation black liquor of pulp making |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160928 |
|
| RJ01 | Rejection of invention patent application after publication |