CN106629894A - A low-cost sewage treating agent specially used for printing and dyeing waste water and a preparing method thereof - Google Patents
A low-cost sewage treating agent specially used for printing and dyeing waste water and a preparing method thereof Download PDFInfo
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- CN106629894A CN106629894A CN201611049080.5A CN201611049080A CN106629894A CN 106629894 A CN106629894 A CN 106629894A CN 201611049080 A CN201611049080 A CN 201611049080A CN 106629894 A CN106629894 A CN 106629894A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/30—Nature of the water, waste water, sewage or sludge to be treated from the textile industry
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- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
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- Organic Chemistry (AREA)
- Water Treatment By Sorption (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
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Abstract
A low-cost sewage treating agent specially used for printing and dyeing waste water is disclosed. The treating agent comprises following raw materials by weight: 35-40 parts of fly ash, 20-25 parts of water-soluble chitosan, 16-19 parts of polyacrylamide, 8-12 parts of sodium silicate, 10-15 parts of sodium hexametaphosphate, 5-9 parts of alum, 23-28 parts of bentonite, 2-5 parts of magnesium sulfate, 2-5 parts of glacial acetic acid, 4-8 parts of sodium dodecylbenzenesulfonate, 1-3 parts of glycerol monostearate and 15-20 parts of vermiculite. A preparing method of the treating agent is also disclosed. The treating agent has efficient cleaning capability, and can effectively remove color of the printing and dyeing waste water. The fly ash and other raw materials are adopted so that utilization of waste materials is achieved and no environment pollution is generated.
Description
Technical field
The present invention relates to technical field of sewage, the special inexpensive sewage-treating agent of specifically a kind of dyeing waste water and
Its preparation method.
Background technology
At present, China's water resource receives pollution in various degree, and situation is also constantly being aggravated.Especially in recent years, spin
Knit industry development rapid, its yield and quality have and greatly improve, it has also become China's water consumption is maximum, waste discharge amount is most
One of industrial department, and direction of the use of dyestuff also just towards anti-light solution, the degraded of anti-oxidant and antibiont is developed.With spinning
Weaver's industry is developed rapidly, and the kind and quantity of dyestuff increasingly increase, and DYE PRODUCTION and dyeing waste water have become the weight of water environment
One of point pollution source, is also a great problem of the current urgent need solution of field of water pollution control both at home and abroad.According to statistics, in DYE PRODUCTION
During, often produce 1 ton of dyestuff, with waste water loss 2% dye product, and in waste water remaining dye component, even if
Concentration is very low, enters the reduction that water body will also result in water body light transmittance, and the destruction of water ecosystem is most caused at last.
Conventional administering method has recycling and harmless treatment.Recycle:(1) waste water can be distinguished by water quality characteristicses
Recycle, such as the shunting of bleaching boiled-off waste water and dyeing and printing waste water, the former can be washed with convection current.Multi-purpose water, the row of reduction
High-volume;(2) recycle of alkali liquor is utilized, and is generally reclaimed using evaporation, and such as alkali lye amount is big, can be reclaimed with triple effect evaporation, and alkali lye amount is little,
Can be reclaimed with thin film evaporation;(3) dyestuff is reclaimed, and such as intellectual circle's dyestuff is acidificable becomes hidden bar acid, in colloidal particles, is suspended in raffinate
In, recycle Jing after precipitation is filtered.
Mainly there are bioanalysis, electrolysis, chemical method and photocatalytic method in the existing processing method for processing dyeing and printing sewage.It is biological
Method floor space is big, and narrow application range, effect is also undesirable;Although electrolysis effect is better than bioanalysis, energy resource consumption is big,
Difficulty.Photocatalytic method is got most of the attention due to making organic matter permineralization without secondary pollution, but photocatalytic method
For precipitating, suspension is still effective, and unsatisfactory for the effect for reducing COD, BOD and colourity, particularly deodorizing effect
It is worse, can additionally bring secondary pollution, it is impossible to fundamentally solve pollution problem.Chemical treatment method is with the chemistry thrown in
Agent treatment pollutant, including the reaction such as neutralization, flocculation, redox, it is more thorough that this mode processes sewage, energy after process
Enough reach discharge standard.Sewage-treating agent is then the primary raw material of method of chemical treatment.At present, it is domestic to be used at dyeing industrial sewage
Reason agent has a lot, but relatively costly, and process and the technological process of purification sewage are loaded down with trivial details, and treatment effect has much room for improvement.
The content of the invention
It is an object of the invention to provide special inexpensive sewage-treating agent of a kind of dyeing waste water and preparation method thereof, with
Solve the problems, such as to be proposed in above-mentioned background technology.
For achieving the above object, the present invention provides following technical scheme:
A kind of special inexpensive sewage-treating agent of dyeing waste water, is made up of the following raw material according to weight portion:Flyash 35-40
Part, water soluble chitosan 20-25 parts, polyacrylamide 16-19 parts, sodium metasilicate 8-12 parts, calgon 10-15 parts, alum
5-9 parts, bentonite 23-28 parts, magnesium sulfate 2-5 parts, glacial acetic acid 2-5 parts, neopelex 4-8 parts, monostearate are sweet
Grease 1-3 parts, vermiculite 15-20 parts.
As further scheme of the invention:It is made up of the following raw material according to weight portion:It is flyash 36-39 parts, water-soluble
It is property shitosan 21-24 parts, polyacrylamide 17-18 parts, sodium metasilicate 9-11 parts, calgon 11-14 parts, alum 6-8 parts, swollen
Profit soil 24-27 parts, magnesium sulfate 3-4 parts, glacial acetic acid 3-4 parts, neopelex 5-7 parts, glycerin monostearate 1.2-
2.7 parts, vermiculite 16-19 parts.
As further scheme of the invention:It is made up of the following raw material according to weight portion:37 parts of flyash, water solubility
23 parts of shitosan, 17.5 parts of polyacrylamide, 10 parts of sodium metasilicate, 12 parts of calgon, 7 parts of alum, 25 parts of bentonite, sulfuric acid
3.7 parts of magnesium, 3.4 parts of glacial acetic acid, 6 parts of neopelex, 1.8 parts of glycerin monostearate, 17 parts of vermiculite.
The preparation method of the special inexpensive sewage-treating agent of the dyeing waste water, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 80-100 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 100-200 mesh sieves is crossed, and mixes 1-2h with the stirring of the first mixed-powder, obtained second and mix
Close powder;
3)Calcination processing 3-4h at second mixed-powder is placed in into 700-800 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 55-60 DEG C, stirring mixing 20-30min is obtained
Obtain the first mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, is added into the first mixed liquor, be warming up to 62-68
DEG C, stirring mixing 40-50min obtains the second mixed liquor;
6)Second mixed liquor is cooled into 40-50 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor
Interior, stirring mixing 40-50min obtains the 3rd mixed liquor;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 3-4h is added, you can.
Compared with prior art, the invention has the beneficial effects as follows:
1st, sewage-treating agent prepared by the present invention has efficient detergent power, and the COD clearances in dyeing waste water can be made high
Up to more than 95%, and the color of dyeing waste water can be effectively removed, percent of decolourization can be to 96%, high treating effect and easy to use,
Greatly reduce the intractability of dyeing waste water.
2nd, sewage-treating agent prepared by the present invention adopts the raw material such as flyash and shitosan, realizes twice laid, will not
To environment, and the dyeing waste water after processing can be used for recycling, and reach the purpose of saving water resource.
Specific embodiment
Technical scheme is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of special inexpensive sewage-treating agent of dyeing waste water, is made up of the following raw material according to weight portion:35 parts of flyash,
20 parts of water soluble chitosan, 16 parts of polyacrylamide, 8 parts of sodium metasilicate, 10 parts of calgon, 5 parts of alum, 23 parts of bentonite,
2 parts of magnesium sulfate, 2 parts of glacial acetic acid, 4 parts of neopelex, 1 part of glycerin monostearate, 15 parts of vermiculite.
In the present embodiment, the preparation method of the special inexpensive sewage-treating agent of the dyeing waste water, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 80 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 100 mesh sieves is crossed, and mixes 1h with the stirring of the first mixed-powder, obtain the second mixed powder
End;
3)Calcination processing 3h at second mixed-powder is placed in into 700 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 55 DEG C, stirring mixing 20min obtains first
Mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, are added into the first mixed liquor, be warming up to 62 DEG C,
Stirring mixing 40min, obtains the second mixed liquor;
6)Second mixed liquor is cooled into 40 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor, stirred
Mixing 40min is mixed, the 3rd mixed liquor is obtained;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 3h is added, you can.
Embodiment 2
A kind of special inexpensive sewage-treating agent of dyeing waste water, is made up of the following raw material according to weight portion:36 parts of flyash,
22 parts of water soluble chitosan, 18 parts of polyacrylamide, 12 parts of sodium metasilicate, 10 parts of calgon, 7 parts of alum, 25 parts of bentonite,
2.5 parts of magnesium sulfate, 3 parts of glacial acetic acid, 5 parts of neopelex, 1.5 parts of glycerin monostearate, 15 parts of vermiculite.
In the present embodiment, the preparation method of the special inexpensive sewage-treating agent of the dyeing waste water, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 100 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 100 mesh sieves is crossed, and mixes 1.5h with the stirring of the first mixed-powder, obtain the second mixed powder
End;
3)Calcination processing 3h at second mixed-powder is placed in into 730 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 58 DEG C, stirring mixing 20min obtains first
Mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, are added into the first mixed liquor, be warming up to 65 DEG C,
Stirring mixing 45min, obtains the second mixed liquor;
6)Second mixed liquor is cooled into 50 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor, stirred
Mixing 40min is mixed, the 3rd mixed liquor is obtained;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 3.5h is added, you can.
Embodiment 3
A kind of special inexpensive sewage-treating agent of dyeing waste water, is made up of the following raw material according to weight portion:37 parts of flyash,
23 parts of water soluble chitosan, 17.5 parts of polyacrylamide, 10 parts of sodium metasilicate, 12 parts of calgon, 7 parts of alum, bentonite 25
Part, 3.7 parts of magnesium sulfate, 3.4 parts of glacial acetic acid, 6 parts of neopelex, 1.8 parts of glycerin monostearate, 17 parts of vermiculite.
In the present embodiment, the preparation method of the special inexpensive sewage-treating agent of the dyeing waste water, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 100 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 200 mesh sieves is crossed, and mixes 1.5h with the stirring of the first mixed-powder, obtain the second mixed powder
End;
3)Calcination processing 3.5h at second mixed-powder is placed in into 750 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 58 DEG C, stirring mixing 25min obtains first
Mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, are added into the first mixed liquor, be warming up to 66 DEG C,
Stirring mixing 45min, obtains the second mixed liquor;
6)Second mixed liquor is cooled into 45 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor, stirred
Mixing 45min is mixed, the 3rd mixed liquor is obtained;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 3.5h is added, you can.
Embodiment 4
A kind of special inexpensive sewage-treating agent of dyeing waste water, is made up of the following raw material according to weight portion:38 parts of flyash,
25 parts of water soluble chitosan, 17 parts of polyacrylamide, 8 parts of sodium metasilicate, 12 parts of calgon, 6 parts of alum, 27 parts of bentonite,
5 parts of magnesium sulfate, 3.7 parts of glacial acetic acid, 6 parts of neopelex, 2.5 parts of glycerin monostearate, 17 parts of vermiculite.
In the present embodiment, the preparation method of the special inexpensive sewage-treating agent of the dyeing waste water, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 100 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 100 mesh sieves is crossed, and mixes 1h with the stirring of the first mixed-powder, obtain the second mixed powder
End;
3)Calcination processing 3h at second mixed-powder is placed in into 780 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 60 DEG C, stirring mixing 20min obtains first
Mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, are added into the first mixed liquor, be warming up to 63 DEG C,
Stirring mixing 48min, obtains the second mixed liquor;
6)Second mixed liquor is cooled into 44 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor, stirred
Mixing 48min is mixed, the 3rd mixed liquor is obtained;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 3.5h is added, you can.
Embodiment 5
A kind of special inexpensive sewage-treating agent of dyeing waste water, is made up of the following raw material according to weight portion:40 parts of flyash,
25 parts of water soluble chitosan, 19 parts of polyacrylamide, 12 parts of sodium metasilicate, 15 parts of calgon, 9 parts of alum, 28 parts of bentonite,
5 parts of magnesium sulfate, 5 parts of glacial acetic acid, 8 parts of neopelex, 3 parts of glycerin monostearate, 20 parts of vermiculite.
In the present embodiment, the preparation method of the special inexpensive sewage-treating agent of the dyeing waste water, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 100 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 200 mesh sieves is crossed, and mixes 2h with the stirring of the first mixed-powder, obtain the second mixed powder
End;
3)Calcination processing 4h at second mixed-powder is placed in into 800 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 60 DEG C, stirring mixing 30min obtains first
Mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, are added into the first mixed liquor, be warming up to 68 DEG C,
Stirring mixing 50min, obtains the second mixed liquor;
6)Second mixed liquor is cooled into 50 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor, stirred
Mixing 50min is mixed, the 3rd mixed liquor is obtained;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 4h is added, you can.
Sewage-treating agent prepared by the present invention has efficient detergent power, can make the COD clearances in dyeing waste water
Up to more than 95%, and the color of dyeing waste water can be effectively removed, percent of decolourization can be to 96%.Sewage disposal prepared by the present invention
Agent adopts the raw material such as flyash and shitosan, realizes twice laid, will not be to environment, and the printing and dyeing after processing are given up
Water can be used for recycling, and reach the purpose of saving water resource.
The better embodiment of the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can be with the premise of without departing from present inventive concept
Various changes can be made.
Claims (4)
1. the special inexpensive sewage-treating agent of a kind of dyeing waste water, it is characterised in that by the following raw material group according to weight portion
Into:Flyash 35-40 parts, water soluble chitosan 20-25 parts, polyacrylamide 16-19 parts, sodium metasilicate 8-12 parts, hexa metaphosphoric acid
Sodium 10-15 parts, alum 5-9 parts, bentonite 23-28 parts, magnesium sulfate 2-5 parts, glacial acetic acid 2-5 parts, neopelex 4-8
Part, glycerin monostearate 1-3 parts, vermiculite 15-20 parts.
2. the special inexpensive sewage-treating agent of dyeing waste water according to claim 1, it is characterised in that by it is following according to
The raw material composition of weight portion:Flyash 36-39 parts, water soluble chitosan 21-24 parts, polyacrylamide 17-18 parts, sodium metasilicate 9-
11 parts, calgon 11-14 parts, alum 6-8 parts, bentonite 24-27 parts, magnesium sulfate 3-4 parts, glacial acetic acid 3-4 parts, dodecane
Base benzene sulfonic acid sodium salt 5-7 parts, glycerin monostearate 1.2-2.7 parts, vermiculite 16-19 parts.
3. the special inexpensive sewage-treating agent of dyeing waste water according to claim 2, it is characterised in that by it is following according to
The raw material composition of weight portion:It is 37 parts of flyash, 23 parts of water soluble chitosan, 17.5 parts of polyacrylamide, 10 parts of sodium metasilicate, six inclined
12 parts of sodium phosphate, 7 parts of alum, 25 parts of bentonite, 3.7 parts of magnesium sulfate, 3.4 parts of glacial acetic acid, 6 parts of neopelex, list
1.8 parts of tristerin, 17 parts of vermiculite.
4. the preparation method of the special inexpensive sewage-treating agent of a kind of dyeing waste water as described in claim 1-3 is arbitrary, its
It is characterised by, step is as follows:
1)Bentonite and vermiculite are weighed, after crushing, 80-100 mesh sieves is crossed, the first mixed-powder is obtained;
2)Flyash is weighed, after crushing, 100-200 mesh sieves is crossed, and mixes 1-2h with the stirring of the first mixed-powder, obtained second and mix
Close powder;
3)Calcination processing 3-4h at second mixed-powder is placed in into 700-800 DEG C, is cooled to room temperature, obtains calcined powder;
4)Glacial acetic acid and polyacrylamide are weighed, is added to reactor, be warming up to 55-60 DEG C, stirring mixing 20-30min is obtained
Obtain the first mixed liquor;
5)Sodium metasilicate, calgon and neopelex are weighed, is added into the first mixed liquor, be warming up to 62-68
DEG C, stirring mixing 40-50min obtains the second mixed liquor;
6)Second mixed liquor is cooled into 40-50 DEG C, magnesium sulfate and glycerin monostearate is weighed, is added to the second mixed liquor
Interior, stirring mixing 40-50min obtains the 3rd mixed liquor;
7)After 3rd mixed liquor is dried, crush, obtain the 3rd mixed-powder;
8)Calcined powder is merged with the 3rd mixed-powder, water soluble chitosan and alum, stirring mixing 3-4h is added, you can.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107082456A (en) * | 2017-05-12 | 2017-08-22 | 湖州梦源环保科技有限公司 | A kind of sanitary sewage special treating agent and preparation method thereof |
CN108163909A (en) * | 2017-12-25 | 2018-06-15 | 苏州纳贝通环境科技有限公司 | A kind of composite water disposal agent and preparation method thereof |
CN108190979A (en) * | 2018-01-12 | 2018-06-22 | 苏州仁尔必思电子科技有限公司 | A kind of eutrophication water treatment agent and preparation method thereof |
CN108503001A (en) * | 2018-04-09 | 2018-09-07 | 长沙秋点兵信息科技有限公司 | Novel water pollution remediation agent and preparation method thereof |
CN108726621A (en) * | 2018-05-25 | 2018-11-02 | 许崇兰 | A kind of cleanser and the preparation method and application thereof of processing dyeing waste water |
CN110436554A (en) * | 2019-08-23 | 2019-11-12 | 河南亿群环保科技有限公司 | A kind of environment protection sewage inorganic agent and preparation method thereof |
CN115140799A (en) * | 2022-08-02 | 2022-10-04 | 内蒙古美赢环保科技有限公司 | Printing and dyeing wastewater treatment agent and preparation method thereof |
Citations (1)
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CN105967261A (en) * | 2016-05-26 | 2016-09-28 | 许婷 | Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent |
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2016
- 2016-11-25 CN CN201611049080.5A patent/CN106629894A/en not_active Withdrawn
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105967261A (en) * | 2016-05-26 | 2016-09-28 | 许婷 | Sewage treatment agent special for printing and dyeing wastewater and preparation method of sewage treatment agent |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107082456A (en) * | 2017-05-12 | 2017-08-22 | 湖州梦源环保科技有限公司 | A kind of sanitary sewage special treating agent and preparation method thereof |
CN108163909A (en) * | 2017-12-25 | 2018-06-15 | 苏州纳贝通环境科技有限公司 | A kind of composite water disposal agent and preparation method thereof |
CN108190979A (en) * | 2018-01-12 | 2018-06-22 | 苏州仁尔必思电子科技有限公司 | A kind of eutrophication water treatment agent and preparation method thereof |
CN108503001A (en) * | 2018-04-09 | 2018-09-07 | 长沙秋点兵信息科技有限公司 | Novel water pollution remediation agent and preparation method thereof |
CN108503001B (en) * | 2018-04-09 | 2020-10-27 | 安徽金兄弟环保科技股份有限公司 | Novel water pollution remediation agent and preparation method thereof |
CN108726621A (en) * | 2018-05-25 | 2018-11-02 | 许崇兰 | A kind of cleanser and the preparation method and application thereof of processing dyeing waste water |
CN110436554A (en) * | 2019-08-23 | 2019-11-12 | 河南亿群环保科技有限公司 | A kind of environment protection sewage inorganic agent and preparation method thereof |
CN115140799A (en) * | 2022-08-02 | 2022-10-04 | 内蒙古美赢环保科技有限公司 | Printing and dyeing wastewater treatment agent and preparation method thereof |
CN115140799B (en) * | 2022-08-02 | 2023-10-20 | 内蒙古美赢环保科技有限公司 | Printing and dyeing wastewater treatment agent and preparation method thereof |
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