CN105951444A - Environment-friendly fabric stiffening agent - Google Patents
Environment-friendly fabric stiffening agent Download PDFInfo
- Publication number
- CN105951444A CN105951444A CN201610429724.7A CN201610429724A CN105951444A CN 105951444 A CN105951444 A CN 105951444A CN 201610429724 A CN201610429724 A CN 201610429724A CN 105951444 A CN105951444 A CN 105951444A
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- Prior art keywords
- acrylic acid
- fragility
- spirulina
- stiffening agent
- straw
- Prior art date
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an environment-friendly fabric stiffening agent. The environment-friendly fabric stiffening agent is prepared in the steps that an acrylic acid complex solution is obtained for use; a spirulina extraction solution is prepared; a brittle straw extraction solution is prepared; the obtained acrylic acid complex solution, the spirulina extraction solution and the brittle straw extraction solution are mixed according to the ratio of 80:2:1. The sizing agent is good in stability, little in smell, hygienic and environmentally friendly, stiffness is high after sizing, hand feeling is hard, warm and soft, and the fabric stiffening agent is particularly suitable for natural fiber and particularly used for sizing of precious fiber like silk.
Description
Technical field
The present invention relates to textile starching slurry used in weaving process, be specifically related to a kind of environmental protection and knit
Thing stiffening agent.
Background technology
Hard finishing is the one of fabric post-treatment, and it is by padding stiffening agent, make between the fiber in fabric yarn
Under certain condition produce cementation, stiffening agent between fibrous inside, fiber or fiber surface formed thin film or produce crosslinking,
So that fabric produces stiffening, abundant, plentiful feel.During it is widely used in the Final finishing of drapery, especially window
The hard finishing of cord, suitcase cloth, WARP-KNITTING and lining cloth.
Due to the non-renewable of petroleum-based products and close the reasons such as fine fabric wearing comfort is poor, natural fiber (as
Cotton, hair, silkworm silk) advantage display again, the demand of natural fabric and consumption also present and rise year by year
Trend.Making a general survey of the existing sizing agent being applied to natural fiber, starch is one of of paramount importance kind, accounts for spinning sizing agent
About the 70% of total amount consumed.Starch is good to the sizing performance of natural fiber especially cellulose fibre, environmentally friendly, so
And, global " crisis in food " is the most increasingly serious, and domestic provision price increases substantially the most especially, the price of starch
When the river rises the boat goes up, and the demand of " starching is without grain " seems again urgently；Polyvinyl alcohol (PVA) is also the main slurry for natural fiber
One of material, its consumption is only second to starch size, accounts for the 20% of spinning sizing agent total amount consumed.Biodegradable due to PVA
Performance extreme difference, is unfavorable for that environmental conservation, more American-European countries are just classified as " unclean slurry " as far back as the beginning of this century and are prohibited
With, spinning sizing agent circle of China also begins to vigorously advocate use no or little PVA in recent years；And as consumption in three big slurries
Little polyacrylic size, although the elongation at break of its serous coat is higher, but film phonograph strength is the lowest, is referred to as by professional person
For " soft and the hardest ".Additionally, the moisture absorption of polyacrylic size to glue phenomenon more extremely serious, these defects make this slurry usual
Other main slurry can only be assisted to be used in mixed way with small scale.
It is contemplated that overcome the shortcoming of prior art, by great many of experiments, finally give a kind of novel environmental protection
Composite acrylic acid fabric stiffening agent, and determine its optimum proportioning.The sizing agent that the present invention provides has good stability, abnormal smells from the patient
Less, hygienic environment-protecting, the stiffness after starching is high, but hard middle feel is gentle soft, is especially suitable for natural fiber, especially precious
The starching of your fiber such as real silk processes.
Summary of the invention
It is desirable to provide the composite acrylic acid fabric stiffening agent of a kind of novel environmental protection, and it is optimal to determine it
Proportioning.The sizing agent that the present invention provides has good stability, and abnormal smells from the patient is less, hygienic environment-protecting, and the stiffness after starching is high, but firmly
Middle feel is gentle soft, is especially suitable for natural fiber, and the starching of especially precious fiber such as real silk processes.
The successful breeding of crisp stalk Oryza sativa L., on the one hand adds the lodging resistance of Oryza sativa L., on the other hand, crisp stalk fiber cellulose content
The features such as reduction, nutritional labeling change and fragility increase so that it is be expected to develop into a kind of novel feed resource.But also do not have
Have tried to as raw material prepared by fragility straw printing and dyeing assistant.
Spirulina breeding has formed large-scale cultivation in China from Hainan Island for many years and has produced to ancient capital, Inner Mongol, jail, basis
Gu, technology maturation, China is the country that yield of spirulina is the highest in the world at present.The most in recent years in Etuoke Banner, the Inner Mongol
Establishing " spirulina industry industrial park ", spirulina breeding base takes up an area nearly 10,000 mu more than, produces food stage Spirulina powder per year
More than 5000 tons, having become as spirulina breeding production base maximum in the world, products export sells multiple countries, for Hubei Province
The returning husbandry to grassland of Er Duosi prairie, herdsman gets rich and creates Liao Yitiaoxin road.Spirulina is a kind of aquatile, protein content
Up to 60 one 70%, possibly together with nitrogen, phosphorus, potassium, selenium, zinc, ferrum multiple element and various active organic components, it is alkaline matter.
Spirulina breeding enterprise all can be using leftover bits and pieces when as waste disposal in recent years, such as: culturing pool clear bottom point deposition material, produce
The material the most up to standard of each link is finally all disposed as waste, causes serious pollution to environment.The present invention uses useless
The spirulina goods abandoned, are greatly saved cost.
The invention provides and a kind of endure with all one's will dosage form for starching of printing and dyeing, the starching that makes cloth increase hardness and filling density, its system
Preparation Method is:
1) first add water 100kg in a kettle., is heated up to 75 DEG C afterwards；
2) add initiator (Ammonium persulfate .), stop heating simultaneously；
3) compound material worked good is dripped while stirring, the most about 60 minutes；
4) insulation 2 hours after；
5) adding 40kg ammonia, the rear 70kg ethanol that adds obtains acrylic acid complex liquid, standby；
6) spirulina extract is prepared:
Weigh 300g Spirulina powder, be placed in 0.5% citric acid solution of 10L process 5-8min, then anti-with distilled water
Post-drying is washed in after backwashing, then is placed in the boil-off liquid of calcium chloride that 1L mass concentration is 60% process 20min, and part helix algae powder is molten
Solve, above-mentioned mixed solution filtered through gauze is slightly carried, it is thus achieved that spirulina extract；
7) fragility straw extracting solution is prepared:
Weigh 1000g fragility powder of straw, be placed in the 0.5% boil-off liquid of citric acid of 10L process 45min, then regulate pH
It is 7, then pours process 20min in the boil-off liquid of calcium chloride that 3L mass concentration is 60% into, by above-mentioned mixed solution filtered through gauze
Slightly carry, it is thus achieved that fragility straw extracting solution；
8) by the acrylic acid complex liquid obtained and spirulina extract, fragility straw extracting solution mixes；
9) finally finished product released, pack.
Preferably, step 3) described compound material is: vinylacetate 10kg；Styrene 5kg；Acrylic acid methyl ester. 90kg；
Butyl acrylate 20kg；Methyl methacrylate 15kg；Acrylic acid 25kg.
Preferably, it is thus achieved that acrylic acid complex liquid and spirulina extract, fragility straw extracting solution is with weight ratio 80:2:1
Ratio mix.
The invention have benefit that:
1, the present invention use Spirulina powder and fragility straw from waste material, with low cost, it contains abundant each hatching egg
White and aminoacid, has good affinity to natural fiber, and effect of impregnation is good；
2, the stiffness after the sizing agent starching that the present invention provides is high, but hard middle feel is gentle soft, is especially suitable for sky
So fiber, the starching of especially precious fiber such as real silk processes；
3, determining optimum proportioning, the sizing agent emulsifying obtained is uniform, it is easy to storage and transport.
Detailed description of the invention
Embodiment 1
Prepare acrylic acid complex liquid:
1) first add water 100kg in a kettle., is heated up to 75 DEG C afterwards；
2) add initiator (Ammonium persulfate .), stop heating simultaneously；
3) compound material worked good is dripped while stirring, the most about 60 minutes；
4) insulation 2 hours after；
5) adding 40kg ammonia, the rear 70kg ethanol that adds obtains acrylic acid complex liquid, standby；
Described compound material is: vinylacetate 10kg；Styrene 5kg；Acrylic acid methyl ester. 90kg；Butyl acrylate
20kg；Methyl methacrylate 15kg；Acrylic acid 25kg.
Embodiment 2
Prepare spirulina extract:
Weigh 300g Spirulina powder, be placed in 0.5% citric acid solution of 10L process 5-8min, then anti-with distilled water
Post-drying is washed in after backwashing, then is placed in the boil-off liquid of calcium chloride that 1L mass concentration is 60% process 20min, and part helix algae powder is molten
Solve, above-mentioned mixed solution filtered through gauze is slightly carried, it is thus achieved that spirulina extract.
Preparation fragility straw extracting solution:
Weigh 1000g fragility powder of straw, be placed in the 0.5% boil-off liquid of citric acid of 10L process 45min, then regulate pH
It is 7, then pours process 20min in the boil-off liquid of calcium chloride that 3L mass concentration is 60% into, by above-mentioned mixed solution filtered through gauze
Slightly carry, it is thus achieved that fragility straw extracting solution；
The acrylic acid complex liquid obtained and spirulina extract, fragility straw extracting solution mixes with the ratio of weight ratio 80:2:1
Get togather.
Embodiment 3: serum viscosity and stability test
It is used for testing by the sizing agent that embodiment 2 obtains.
Viscosity is tested: starts after room temperature, tests the situation of change of viscosity at set intervals on viscosity apparatus.
Stability test: main by objective observational method, starts after room temperature to observe whether serosity is layered at set intervals
And stratified proportional (upper strata is than lower floor).
Table 1 serum viscosity and stability test
As can be seen from Table 1, the sizing agent viscosity obtained by the present invention is the lowest, it is easy to use, and stability is splendid, protects
Hold 180d all without substantially layering.
Embodiment 4: the compatible stability result synopsis of slurry of the present invention and textile auxiliary or slurry
Being measured the slurry of the present invention and the compatible stability of textile auxiliary or slurry, result is as shown in table 2.
The compatible stability result synopsis of table 2 slurry of the present invention and textile auxiliary or slurry
| Auxiliary agent kind | The slurry compatibility of the present invention | Stablize the not stratified time/h |
| PVA/205 | Fully compatible | >72 |
| PVA/1799 | Fully compatible | >72 |
| Sizing greases | Fully compatible | >72 |
| Sizing wax disk(-sc) | Fully compatible | >72 |
| Destaticizer | Fully compatible | >72 |
As can be seen from Table 2, slurry of the present invention and conventional sizing fabric auxiliary agent are fully compatible, also can be complete with PVA
Compatible and the most sufficiently stable after mixing.
Embodiment 5: cloth is carried out hard finishing and tests
The test of sample stiffness is according to the standard GB/T 18318.1-2009 " mensuration of textile bending property the 1st
Point: inclined plane method ", use LFY-207 automatic stiffness tester to be measured.
Select the vinyl acetate esters stiffening agent DM-3563 of certain company as a control group, carry out together with bathing Experimental Comparison.
Stiffening agent sample embodiment 3 obtained and DM-3563, be made into the stiffening agent working solution of 50g/L respectively, then divide
Do not add the waterproofing agent DM-3668 of 10g/L, observe the stable case of working solution, and measure its stiffening application effect.Again with horizontal
Delaying unloading (pressure 2Kgf/cm2, speed 11rpm), → setting (cotton 160 DEG C × 50sec) is dried in immersing and rolling → 100 DEG C, surveys bending resistance
Length.
Slurry of the present invention is at common textile, Pilus Caprae seu Ovis and the warp sizing experimental test of real silk, and result shows relative to commonly
Acrylic size, its wellability significantly improves.
In addition hardness and the inclusion power of yarn is significantly improved, and firmness is high, is difficult to destarch, and moisture absorption is glued phenomenon again and obtained
Improve.
Testing the stiffness after hard finishing, its result is as shown in table 3.
Table 3 is in textile, Pilus Caprae seu Ovis and the stiffening process result of the test of real silk
| Textile | Pilus Caprae seu Ovis | Real silk | |
| Matched group stiffness | 49.06 | 23.5 | 20.2 |
| Stiffness of the present invention | 59.8 | 29.2 | 28.8 |
As can be seen from Table 3, the present invention all has good enduring with all one's will for cotton textiles, Pilus Caprae seu Ovis and 3 kinds of natural fabric materials of real silk
Finishing effect, and it is substantially better than control sample DM-3563.
Additionally, its wellability significantly improves, relative to matched group, soft during fabric is hard, feel is plump, and abnormal smells from the patient is little in addition,
It it is the novel stiffening agent of a kind of excellence.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (4)
1. the production method of a green environment-friendly fabric stiffening agent, it is characterised in that its production stage is as follows:
1) first add water 100kg in a kettle., is heated up to 75 DEG C afterwards；
2) add initiator (Ammonium persulfate .), stop heating simultaneously；
3) compound material worked good is dripped while stirring, the most about 60 minutes；
4) insulation 2 hours after；
5) adding 40kg ammonia, the rear 70kg ethanol that adds obtains acrylic acid complex liquid, standby；
6) spirulina extract is prepared:
Weigh 300g Spirulina powder, be placed in 0.5% citric acid solution of 10L process 5-8min, then use distilled water cyclic washing
Post-drying, then be placed in the boil-off liquid of calcium chloride that 1L mass concentration is 60% and process 20 min, part helix algae powder dissolves, by upper
State mixed solution filtered through gauze slightly to carry, it is thus achieved that spirulina extract；
7) fragility straw extracting solution is prepared:
Weighing 1000g fragility powder of straw, be placed in the 0.5% boil-off liquid of citric acid of 10L process 45min, then regulation pH is 7, then
Pour in the boil-off liquid of calcium chloride that 3L mass concentration is 60% and process 20 min, above-mentioned mixed solution filtered through gauze is carried out slightly
Carry, it is thus achieved that fragility straw extracting solution；
8) by the acrylic acid complex liquid obtained and spirulina extract, fragility straw extracting solution mixes；
9) finally finished product released, pack.
Preferably, preferably.
2. the method described in claim 1, it is characterised in that:
Compound material described in step 3) is: vinylacetate 10kg；Styrene 5kg；Acrylic acid methyl ester. 90kg；Butyl acrylate
20kg；Methyl methacrylate 15kg；Acrylic acid 25kg.
3. the method described in claim 1, it is characterised in that:
The acrylic acid complex liquid obtained and spirulina extract, fragility straw extracting solution mixes with the ratio of weight ratio 80:2:1
Good.
4. the fabric stiffening agent prepared by the method described in claim 1-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610429724.7A CN105951444A (en) | 2016-06-16 | 2016-06-16 | Environment-friendly fabric stiffening agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610429724.7A CN105951444A (en) | 2016-06-16 | 2016-06-16 | Environment-friendly fabric stiffening agent |
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| CN105951444A true CN105951444A (en) | 2016-09-21 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610429724.7A Pending CN105951444A (en) | 2016-06-16 | 2016-06-16 | Environment-friendly fabric stiffening agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108130736A (en) * | 2017-12-11 | 2018-06-08 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of environment-friendlytype type fabric deflection reinforcing agent |
| CN108978218A (en) * | 2018-07-24 | 2018-12-11 | 裴泽民 | A kind of preparation method of cotton fabric stiffening agent |
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|---|---|---|---|---|
| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
| CN103408657A (en) * | 2013-08-27 | 2013-11-27 | 福清市新大泽螺旋藻有限公司 | Phycocyanin production process and product thereof |
| CN104233804A (en) * | 2014-08-29 | 2014-12-24 | 湖州天鑫皮革涂饰剂厂 | Fabric stiffening agent |
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| CN103087332A (en) * | 2013-01-21 | 2013-05-08 | 东华大学 | Preparation method of proteins and protein-based sizes for warp sizing |
| CN103408657A (en) * | 2013-08-27 | 2013-11-27 | 福清市新大泽螺旋藻有限公司 | Phycocyanin production process and product thereof |
| CN104233804A (en) * | 2014-08-29 | 2014-12-24 | 湖州天鑫皮革涂饰剂厂 | Fabric stiffening agent |
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| 吴冬梅: "螺旋藻的藻胆蛋白的提取与应用", 《亚太多肽学会多肽抗肿瘤国际论坛论文集》 * |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108130736A (en) * | 2017-12-11 | 2018-06-08 | 江苏新瑞贝科技股份有限公司 | A kind of preparation method of environment-friendlytype type fabric deflection reinforcing agent |
| CN108978218A (en) * | 2018-07-24 | 2018-12-11 | 裴泽民 | A kind of preparation method of cotton fabric stiffening agent |
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Application publication date: 20160921 |