CN105949643A - 一种抗菌塑料 - Google Patents

一种抗菌塑料 Download PDF

Info

Publication number
CN105949643A
CN105949643A CN201610318251.3A CN201610318251A CN105949643A CN 105949643 A CN105949643 A CN 105949643A CN 201610318251 A CN201610318251 A CN 201610318251A CN 105949643 A CN105949643 A CN 105949643A
Authority
CN
China
Prior art keywords
parts
plastic
antibiotic plastic
antibiotic
plasticizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610318251.3A
Other languages
English (en)
Inventor
高忠青
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zibo Kuake Pharmaceutical Technology Co Ltd
Original Assignee
Zibo Kuake Pharmaceutical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zibo Kuake Pharmaceutical Technology Co Ltd filed Critical Zibo Kuake Pharmaceutical Technology Co Ltd
Priority to CN201610318251.3A priority Critical patent/CN105949643A/zh
Publication of CN105949643A publication Critical patent/CN105949643A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/13—Phenols; Phenolates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
    • C08K5/3462—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/37—Thiols
    • C08K5/372—Sulfides, e.g. R-(S)x-R'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/45—Heterocyclic compounds having sulfur in the ring
    • C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring
    • C08K5/47—Thiazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0806—Silver
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0893—Zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明公开了一种抗菌塑料，包括以下重量份的组分：塑料原料300～500份，苯酚5～10份，四甲基哌啶氮氧化物5～10份，硫代二乙酸二甲酯6～12份，乙酸芳樟酯5～10份，纳米材料10～30份，载体10～30份，增塑剂5～12份。本发明提供的塑料，杀菌、抑菌效果好，持续时间长，耐用性强，使用寿命长，应用范围广。

Description

一种抗菌塑料
技术领域
本发明涉及塑料技术领域，尤其涉及一种抗菌塑料。
背景技术
塑料制品的种类繁多，应用范围广，日常生活中塑料制品的例子比比皆是，如鞋底、矿泉水瓶，水杯，鼠标，餐盒，保鲜膜等。随着塑料制品的使用范围越来越广，人们对塑料制品的要求也越来越高。然而，现如今的塑料制品长期使用仍会存在一些问题，如塑料制品长时间使用会在塑料制品表面和内部滋生细菌，这既会直接影响着人们的身体健康，也会导致塑料制品的自身性质发生改变，缩短使用寿命。
发明内容
基于背景技术存在的技术问题，本发明提出了一种抗菌塑料。
本发明提出的一种抗菌塑料，包括以下重量份的组分：塑料原料300～500份，苯酚5～10份，四甲基哌啶氮氧化物5～10份，硫代二乙酸二甲酯6～12份，乙酸芳樟酯5～10份，纳米材料10～30份，载体10～30份，正辛基异噻唑啉酮5～10份，增塑剂5～12份。
优选的，一种抗菌塑料，包括以下重量份的组分：塑料原料450份，苯酚8份，四甲基哌啶氮氧化物7份，硫代二乙酸二甲酯9份，乙酸芳樟酯7份，纳米材料20份，载体20份，正辛基异噻唑啉酮7份，增塑剂8份。
优选的，所述塑料原料为聚氯乙烯树脂和酚醛树脂中的一种。
优选的，所述纳米材料采用纳米银和纳米锌中的一种或两种。
优选的，所述载体采用沸石、二氧化钛、磷酸锆、硅胶中的一种或几种。
优选的，所述增塑剂为磷酸酯、氯化石蜡、邻苯二甲酸酯、聚酯中的一种。
本发明提供的塑料，纳米材料的加入既可以提高塑料的耐老化，耐腐蚀性，又可以与载体相互作用，能有效杀菌，使塑料具有抗菌性；加入的乙酸芳樟酯进一步增强了塑料的抗菌性能，同时又使塑料的气味有所改善，增大塑料制品的使用范围；正辛基异噻唑啉酮能有效的抑制霉菌等微生物生长，防止塑料降解；而且苯酚、四甲基哌啶氮氧化物与硫代二乙酸二甲酯协同作为抗氧化剂可以提高塑料的抗氧化性能，延长使用寿命。
具体实施方式
下面结合具体实施例对本发明作进一步解说。
实施例一
本发明提出的一种抗菌塑料，包括以下重量份的组分：聚氯乙烯树脂450份，苯酚8份，四甲基哌啶氮氧化物7份，硫代二乙酸二甲酯9份，乙酸芳樟酯7份，纳米银20份，二氧化钛20份，正辛基异噻唑啉酮7份，邻苯二甲酸酯8份。
实施例二
本发明提出的一种抗菌塑料，包括以下重量份的组分：酚醛树脂500份，苯酚5份，四甲基哌啶氮氧化物8份，硫代二乙酸二甲酯12份，乙酸芳樟酯10份，纳米银5份，纳米锌10份，磷酸锆20份，正辛基异噻唑啉酮10份，氯化石蜡7份。
实施例三
本发明提出的一种抗菌塑料，包括以下重量份的组分：聚氯乙烯树脂450份，苯酚10份，四甲基哌啶氮氧化物10份，硫代二乙酸二甲酯12份，乙酸芳樟酯8份，纳米银30份，沸石30份，正辛基异噻唑啉酮5份，聚酯12份。
实施例四
本发明提出的一种抗菌塑料，包括以下重量份的组分：酚醛树脂350份，苯酚10份，四甲基哌啶氮氧化物7份，硫代二乙酸二甲酯8份，乙酸芳樟酯10份，纳米银15份，纳米锌10份，磷酸锆15份，硅胶10份，正辛基异噻唑啉酮8份，邻苯二甲酸酯7份。
实施例一～四制备的抗菌塑料按照中国人民共和国轻工行业标准QB/T2591-2003《抗菌塑料-抗菌性能试验方法和抗菌效果》，使用金黄色葡萄球菌ATCC 6538进行测试，测试结果如下；
本发明提供的塑料，纳米材料的加入既可以提高塑料的耐老化，耐腐蚀性，又可以与载体相互作用，能有效杀菌，使塑料具有抗菌性；加入的乙酸芳樟酯进一步增强了塑料的抗菌性能，同时又使塑料的气味有所改善，增大塑料制品的使用范围；正辛基异噻唑啉酮能有效的抑制霉菌等微生物生长，防止塑料降解；而且苯酚、四甲基哌啶氮氧化物与硫代二乙酸二甲酯协同作为抗氧化剂可以提高塑料的抗氧化性能，延长使用寿命。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (6)

1.一种抗菌塑料，其特征在于，包括以下重量份的组分：塑料原料300～500份，苯酚5～10份，四甲基哌啶氮氧化物5～10份，硫代二乙酸二甲酯6～12份，乙酸芳樟酯5～10份，纳米材料10～30份，载体10～30份，正辛基异噻唑啉酮5～10份，增塑剂5～12份。
2.一种抗菌塑料，其特征在于，包括以下重量份的组分：塑料原料450份，苯酚8份，四甲基哌啶氮氧化物7份，硫代二乙酸二甲酯9份，乙酸芳樟酯7份，纳米材料20份，载体20份，正辛基异噻唑啉酮7份，增塑剂8份。
3.根据权利要求1所述的一种抗菌塑料，其特征在于，所述塑料原料为聚氯乙烯树脂和酚醛树脂中的一种。
4.根据权利要求1所述的一种抗菌塑料，其特征在于，所述纳米材料采用纳米银和纳米锌中的一种或两种。
5.根据权利要求3所述的一种抗菌塑料，其特征在于，所述载体采用沸石、二氧化钛、磷酸锆、硅胶中的一种或几种。
6.根据权利要求1所述的一种抗菌塑料，其特征在于，所述增塑剂为磷酸酯、氯化石蜡、邻苯二甲酸酯、聚酯中的一种。
CN201610318251.3A 2016-05-15 2016-05-15 一种抗菌塑料 Pending CN105949643A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610318251.3A CN105949643A (zh) 2016-05-15 2016-05-15 一种抗菌塑料

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610318251.3A CN105949643A (zh) 2016-05-15 2016-05-15 一种抗菌塑料

Publications (1)

Publication Number Publication Date
CN105949643A true CN105949643A (zh) 2016-09-21

Family

ID=56911687

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610318251.3A Pending CN105949643A (zh) 2016-05-15 2016-05-15 一种抗菌塑料

Country Status (1)

Country Link
CN (1) CN105949643A (zh)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589671A (zh) * 2016-11-10 2017-04-26 南宁市钜丰塑业有限公司 一种抗菌塑料瓶及其制备方法
CN106751128A (zh) * 2016-11-10 2017-05-31 南宁市钜丰塑业有限公司 一种抗菌塑料瓶及其制备方法
WO2018137360A1 (zh) * 2017-01-26 2018-08-02 淄博齐鼎立专利信息咨询有限公司 一种抗菌塑料
CN110317419A (zh) * 2019-06-10 2019-10-11 金达科技股份有限公司 一种抗菌塑料片材

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1412240A (zh) * 2001-10-16 2003-04-23 上海欧亚合成材料有限公司 抗菌型酚醛模塑料
CN101519516A (zh) * 2009-03-24 2009-09-02 山东威高集团医用高分子制品股份有限公司 纳米改性聚氯乙烯复合材料
CN101550259A (zh) * 2009-05-14 2009-10-07 威海洁瑞医用制品有限公司 医用多功能聚氯乙烯复合材料
CN105462105A (zh) * 2015-11-25 2016-04-06 全椒祥瑞塑胶有限公司 一种具有抑菌作用的聚氯乙烯
CN105542341A (zh) * 2016-01-20 2016-05-04 苏州市景荣科技有限公司 一种防臭抗菌pvc鞋底材料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1412240A (zh) * 2001-10-16 2003-04-23 上海欧亚合成材料有限公司 抗菌型酚醛模塑料
CN101519516A (zh) * 2009-03-24 2009-09-02 山东威高集团医用高分子制品股份有限公司 纳米改性聚氯乙烯复合材料
CN101550259A (zh) * 2009-05-14 2009-10-07 威海洁瑞医用制品有限公司 医用多功能聚氯乙烯复合材料
CN105462105A (zh) * 2015-11-25 2016-04-06 全椒祥瑞塑胶有限公司 一种具有抑菌作用的聚氯乙烯
CN105542341A (zh) * 2016-01-20 2016-05-04 苏州市景荣科技有限公司 一种防臭抗菌pvc鞋底材料及其制备方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106589671A (zh) * 2016-11-10 2017-04-26 南宁市钜丰塑业有限公司 一种抗菌塑料瓶及其制备方法
CN106751128A (zh) * 2016-11-10 2017-05-31 南宁市钜丰塑业有限公司 一种抗菌塑料瓶及其制备方法
WO2018137360A1 (zh) * 2017-01-26 2018-08-02 淄博齐鼎立专利信息咨询有限公司 一种抗菌塑料
CN110317419A (zh) * 2019-06-10 2019-10-11 金达科技股份有限公司 一种抗菌塑料片材

Similar Documents

Publication Publication Date Title
CN105949643A (zh) 一种抗菌塑料
KR102631330B1 (ko) 시너지 효과를 나타내는 항균제
Kannappan et al. Inhibitory efficacy of geraniol on biofilm formation and development of adaptive resistance in Staphylococcus epidermidis RP62A
Azevedo et al. Polyethyleneimine and polyethyleneimine-based nanoparticles: novel bacterial and yeast biofilm inhibitors
CA2647642C (en) Antimicrobial composition
KR20040012800A (ko) 항균 폴리우레탄 필름
KR102198915B1 (ko) 구리-철 합금의 나노분말을 포함하는 항바이러스 및 항균용 조성물
KR20190078186A (ko) 항균 필름
CN103113693A (zh) 一种纳米银pvc片膜及其制备方法
Zander et al. Microbial susceptibility of various polymers and evaluation of thermoplastic elastomers with antimicrobial additives
Lovato et al. Performance-Enhancing Materials in Medical Gloves
CN109553882A (zh) 一种聚氯乙烯抗菌材料及其制备方法和应用
BRPI0704197A (pt) métodos para fabricar uma composição de produto de laticìnio, uma composição de laticìnio e um produto de queijo fresco
KR102413388B1 (ko) 폴리카보네이트 항균필름 및 그 제조방법
CN108794916A (zh) 一种抗菌塑料
CN108359189A (zh) 一种抗菌塑料
JPH10109906A (ja) 工業用抗菌防黴剤
JP2009084542A (ja) 抗菌性水性組成物
WO2002085542A8 (en) Antimicrobial polymeric surfaces
KR102522104B1 (ko) 항균 및 항바이러스 코팅용 조성물 및 항균 및 항바이러스 코팅용 조성물이 코팅된 항균 제품
US20230404072A1 (en) Biocide
KR20160118425A (ko) 정유를 유효성분으로 포함하는 항균 조성물
JPH08239507A (ja) 抗菌性樹脂組成物
JP2010202733A (ja) 看板用コート剤
CN103333475A (zh) 一种杀菌聚碳酸酯荧光薄膜

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160921

WD01 Invention patent application deemed withdrawn after publication