CN105936696A - 一种用茶麸制造的功能塑料母料 - Google Patents

一种用茶麸制造的功能塑料母料 Download PDF

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CN105936696A
CN105936696A CN201610568528.8A CN201610568528A CN105936696A CN 105936696 A CN105936696 A CN 105936696A CN 201610568528 A CN201610568528 A CN 201610568528A CN 105936696 A CN105936696 A CN 105936696A
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丁飞鹏
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Abstract

本发明公开了一种用茶麸制造的功能塑料母料，其制备方法，包括步骤为：按质量比1份油脂和9份茶麸，将油脂和茶麸低于100℃下混合搅拌5～30min后，得到初级塑化茶麸；按质量比1份塑料和9份塑化茶麸搅拌均匀后螺杆挤出造粒；该方法生产工艺简单，具有降解性高，抗菌效果好，环保健康，缓释性能好，生产成本低，具有很好的市场前景。

Description

一种用茶麸制造的功能塑料母料
技术领域
本发明涉及制备全茶麸生物灭菌全降解功能母料塑料的方法，属生物化工范围。
背景技术
淀粉降解塑料自问世以来得到了迅速发展，但都只具备安全性、降解性、茶麸功能母料相对于一般淀粉塑料具有独特的灭菌灭虫功能，茶麸塑料母料即可单独用于制造热塑型热固型塑料制品，还可作为生物灭菌灭虫塑料制品中的添加剂使用，因此具有独特的应用价值。
发明内容
本发明的目的正是为了利用每年产生的大量天然茶麸全利用，克服茶麸行业现行基本只提取茶皂素，浪费茶麸剩余的80%物质缺点，利用茶麸内含有茶皂素、淀粉、纤维素、蛋白等制备独特的全降解茶麸塑料功能母料，同单一淀粉基塑料母料颗粒相比其优势在于：由于茶皂素具有高双亲性，灭菌性，因而具有塑化性能优良，独特的灭菌灭虫功能、完全降解，成本低。
本发明的主要技术方案是 ：一种用茶麸制造功能塑料母料的方法，其特征是，包括以下步骤 ：
(1) 将茶麸粉碎至 100-2000 目加入高速搅拌罐中，喷入油脂，茶麸与油脂比例为85~99:15~1在低于100℃下混合搅拌 5～ 30min 后， 得到塑化茶麸；
(2)将塑化茶麸与树脂搅拌均匀后螺感杆挤出成型即可，塑化茶麸与树脂比例为50~90: 50~10。
本发明所述的茶麸是指山茶科果仁压榨油后的剩余物。
本发明所述的茶麸包含未改性茶麸、离子改性茶麸、糊化茶麸、氧化茶麸。
本发明所述的塑料树脂是指低分子聚烯烃蜡、石蜡、EVA蜡、松香树脂、涤纶树脂、聚乙烯、聚乙烯醇、EVA树脂、PU、SBS、POE、聚丙烯、聚氯乙烯、ABS树脂、尼龙。
具体实施方式
结合实例对本发明更进一步说明 ：
实施例 1 ：
(1)将 100 公斤500目的烘干离子改性茶麸，投入搅拌罐中，然后喷入5公斤甘油，常温混合均匀后， 得初级塑化淀粉 105公斤。
(2) 将初级塑化淀粉 105公斤与20公斤LDPE树脂搅拌混合后，经螺杆挤出造粒机捏合挤出切粒后的125公斤聚乙烯用天然降解灭菌功能母料。
(3) 将100公斤LDPE加入10公斤降解灭菌母料，经吹塑得到农用灭菌自然降解薄膜。
实施例 2 ：
(1)将 100 公斤1000目的烘干预糊化改性茶麸，投入搅拌罐中，然后喷入10公斤甲基硅油，常温混合均匀后， 得初级塑化淀粉 110公斤。
(2) 将初级塑化淀粉 110公斤与100公斤聚丙烯树脂末，5公斤松香树脂末混合，经螺杆挤出成型即可。
实施例 3：
(1)将 100 公斤800目的烘干氧化茶麸，投入搅拌罐中，然后喷入10公斤环氧大豆油，常温混合均匀后， 得初级塑化淀粉 110公斤。
(2) 将初级塑化淀粉 110公斤与80公斤EVA树脂混合，经螺杆挤出成型即可。
实施例 4：
(1) 将 100 公斤200目的烘干离子改性茶麸，投入搅拌罐中，然后喷入10公斤环氧大豆油，常温混合均匀后， 得初级塑化淀粉 110公斤。
(2) 将初级塑化淀粉 110公斤与20公斤涤纶树脂混合，经螺杆挤出成型即可。
实施例 5：
(1) 将 100 公斤600目的烘干离子改性茶麸，投入搅拌罐中，然后喷入10公斤环氧大豆油，常温混合均匀后， 得初级塑化淀粉 110公斤。
(2) 将初级塑化淀粉 110公斤与50公斤POE树脂混合，经螺杆挤出成型即可。
实施例 6：
(1) 将 100 公斤200目的烘干未改性茶麸，投入搅拌罐中，然后喷入10公斤环氧甲酯，常温混合均匀后， 得初级塑化淀粉 110公斤。
(2) 将初级塑化淀粉 110公斤与30公斤PU树脂混合，经反应挤出成型即可。
实施例 7：
(1)将 100 公斤100目的烘干未改性茶麸，投入搅拌罐中，然后喷入10公斤环氧大豆油，常温混合均匀后， 得初级塑化淀粉 110公斤。
(2)将初级塑化淀粉 110公斤与100公斤聚氯乙烯树脂末，2公斤聚氯乙烯稳定剂混合，经螺杆挤出成型即可。

Claims (4)

1.一种用茶麸制造功能塑料母料的方法，其特征是，包括以下步骤 ：
(1) 将茶麸粉碎至 100-2000 目加入高速搅拌罐中，喷入油脂，茶麸与油脂比例为85~99:15~1在低于100℃下混合搅拌 1 ～ 30min 后， 得到初级塑化茶麸；
(2)将塑化茶麸与树脂搅拌均匀后螺感杆挤出成型即可，塑化茶麸与树脂比例为50~90: 50~10。
2.如权利要求 1 所述的一种用茶麸制造功能塑料母料的方法，其特征是：所述的茶麸是指山茶科果仁压榨油后的剩余物。
3.如权利要求2 所述的一种用茶麸制造功能塑料母料的方法，其特征是：所述的茶麸包含未改性茶麸、离子改性茶麸、糊化茶麸、氧化茶麸。
4.如权利要求 1 所述的一种用茶麸制造功能塑料母料的方法，其特征是：所述的塑料树脂是指低分子聚烯烃蜡、石蜡、EVA蜡、PU、SBS、POE、松香树脂、涤纶树脂、聚乙烯、聚乙烯醇、EVA树脂、聚丙烯、聚氯乙烯、ABS树脂、尼龙。
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CN107987544A (zh) * 2017-11-06 2018-05-04 湖南望隆企业管理咨询有限公司 一种低成本可降解塑料及其制备方法

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CN103289298A (zh) * 2013-06-24 2013-09-11 苏州新区佳合塑胶有限公司 一种抗静电抗菌abs色母粒
CN103666793A (zh) * 2013-09-27 2014-03-26 红河五里冲生态茶业有限公司 茶皂粉及其用途
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