CN105906885A - Rubber compound of spinning rubber roll - Google Patents

Rubber compound of spinning rubber roll Download PDF

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Publication number
CN105906885A
CN105906885A CN201610284867.3A CN201610284867A CN105906885A CN 105906885 A CN105906885 A CN 105906885A CN 201610284867 A CN201610284867 A CN 201610284867A CN 105906885 A CN105906885 A CN 105906885A
Authority
CN
China
Prior art keywords
parts
rubber
spinning
antistatic
plasticizer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610284867.3A
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Chinese (zh)
Inventor
卓理财
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUXI LANXIANG PLASTIC INDUSTRY Co Ltd
Original Assignee
WUXI LANXIANG PLASTIC INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUXI LANXIANG PLASTIC INDUSTRY Co Ltd filed Critical WUXI LANXIANG PLASTIC INDUSTRY Co Ltd
Priority to CN201610284867.3A priority Critical patent/CN105906885A/en
Publication of CN105906885A publication Critical patent/CN105906885A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/06—Sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a rubber compound of a spinning rubber roll. The rubber compound is prepared from, by weight, 100 parts of carboxyl nitrile rubber, 8-12 parts of titanium dioxide, 2-4 parts of aging proof agent, 10-20 parts of antistatic plasticizer, 3-7 parts of sulphur, 4-6 parts of zinc oxide, 1-3 parts of accelerant, 10-20 parts of white carbon black and 1-3 parts of stearic acid. The antistatic plasticizer is plasticizer TP-90B. By adopting the plasticizer TP-90B, the rubber compound has plasticization effect and antistatic effect, so that smooth production of products and safe storage of semi-finished products are guaranteed, volume resistance of rubber can reach 10>8, good antistatic effect is achieved, and further spinning quality is assured effectively.

Description

The rubber compounding of spinning rubber-roller
Technical field
The present invention relates to rubber compounding technical field, particularly relate to the rubber compounding of a kind of spinning rubber-roller.
Background technology
Rubber roll is as one of the vitals in spinning, drawing region, and the quality of its quality concerns the resultant yarn matter of spinning Amount, production efficiency and recruitment cost.Spinning rubber-roller must possess good springiness, characteristic wear-resisting, anlistatig. The antistatic behaviour of rubber roll is usually interpolation antistatic additive in formula and realizes.
At present, the interpolation of major part antistatic additive all can make sizing material be easier to scrap, and gives and produces and semi-products Storage bring adverse effect.Thus, the interpolation number general control of antistatic additive within 1%, its goods Volume resistance at 10^9～10^10, during spinning, anlistatig effect is the most inconspicuous, thus, be badly in need of solve Certainly.
Summary of the invention
Present invention aims to the problems referred to above, it is provided that the rubber compounding of a kind of spinning rubber-roller, to solve The unconspicuous problem of antistatic effect of existing spinning rubber-roller.
It is an object of the invention to be achieved through the following technical solutions:
A kind of rubber compounding of spinning rubber-roller, it is made up of the raw material of following parts by weight:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 8～12 parts, antiaging agent 2～4 parts, antistatic plasticising Agent 10～20 parts, sulfur 3～7 parts, zinc oxide 4～6 parts, accelerator 1～3 parts, White Carbon black 10～20 Part, stearic acid 1～3 parts；Wherein, described antistatic elasticizer is plasticizer TP-90B.
As a preferred embodiment of the present invention, it is made up of the raw material of following parts by weight:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 10 parts, antiaging agent 3 parts, antistatic elasticizer 15 Part, 5 parts of sulfur, zinc oxide 5 parts, accelerator 2 parts, White Carbon black 15 parts, stearic acid 2 parts.
As a preferred embodiment of the present invention, described accelerator is accelerant CZ；Its chemical name is N- Cyclohexyl-2-[4-morpholinodithio sulfenamide.
As a preferred embodiment of the present invention, described antiaging agent is 2-mercaptobenzimidazole.
Beneficial effects of the present invention is, the rubber compounding of described spinning rubber-roller by use plasticizer TP-90B, It had both had plasticization, has again antistatic effect, thus is ensureing that product produces smoothly, semi-products are pacified While full storage so that the volume resistance of rubber can reach 10^8, has preferable antistatic effect, enters And spinning quality has been effectively ensured.
Detailed description of the invention
Technical scheme is further illustrated below by detailed description of the invention.It is understood that Embodiment described herein is used only for explaining the present invention, rather than limitation of the invention.
Embodiment 1
In the present embodiment, the rubber compounding of a kind of spinning rubber-roller, it is made up of the raw material of following parts by weight:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 8 parts, antiaging agent 2 parts, antistatic elasticizer 10 parts, 3 parts of sulfur, zinc oxide 4 parts, accelerator 1 part, White Carbon black 10 parts, stearic acid 1 part；Wherein, described Antistatic elasticizer is plasticizer TP-90B, and described accelerator is accelerant CZ；Its chemical name is N-ring Base-2-[4-morpholinodithio sulfenamide, described antiaging agent is 2-mercaptobenzimidazole.
Embodiment 2
In the present embodiment, the rubber compounding of a kind of spinning rubber-roller, it is made up of the raw material of following parts by weight:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 12 parts, antiaging agent 4 parts, antistatic elasticizer 20 Part, 7 parts of sulfur, zinc oxide 6 parts, accelerator 3 parts, White Carbon black 20 parts, stearic acid 3 parts；Wherein, Described antistatic elasticizer is plasticizer TP-90B, and described accelerator is accelerant CZ；Its chemical name is N-cyclohexyl-2-[4-morpholinodithio sulfenamide, described antiaging agent is 2-mercaptobenzimidazole.
Embodiment 3
In the present embodiment, the rubber compounding of a kind of spinning rubber-roller, it is made up of the raw material of following parts by weight:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 10 parts, antiaging agent 3 parts, antistatic elasticizer 15 Part, 5 parts of sulfur, zinc oxide 5 parts, accelerator 2 parts, White Carbon black 15 parts, stearic acid 2 parts, wherein, Described antistatic elasticizer is plasticizer TP-90B, and described accelerator is accelerant CZ；Its chemical name is N-cyclohexyl-2-[4-morpholinodithio sulfenamide, described antiaging agent is 2-mercaptobenzimidazole.
The present embodiment is highly preferred embodiment of the present invention, by using above-described embodiment, can produce anti-smoothly The spinning rubber-roller that electrostatic efficiency is good, the volume resistance of the rubber on spinning rubber-roller produced can reach 10^8.
Above example simply elaborates ultimate principle and the characteristic of the present invention, and the present invention is not by above-described embodiment Limiting, without departing from the spirit and scope of the present invention, the present invention also has various change and change, this A little changes and change both fall within scope of the claimed invention.Claimed scope is by appended Claims and equivalent thereof define.

Claims (4)

1. the rubber compounding of a spinning rubber-roller, it is characterised in that: it is made up of the raw material of following parts by weight:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 8～12 parts, antiaging agent 2～4 parts, antistatic plasticising Agent 10～20 parts, sulfur 3～7 parts, zinc oxide 4～6 parts, accelerator 1～3 parts, White Carbon black 10～20 Part, stearic acid 1～3 parts；Wherein, described antistatic elasticizer is plasticizer TP-90B.
The rubber compounding of spinning rubber-roller the most according to claim 1, it is characterised in that: it is by following heavy The raw material of amount number is made:
Carboxy terminated nitrile rubber 100 parts, titanium dioxide 10 parts, antiaging agent 3 parts, antistatic elasticizer 15 Part, 5 parts of sulfur, zinc oxide 5 parts, accelerator 2 parts, White Carbon black 15 parts, stearic acid 2 parts.
The rubber compounding of spinning rubber-roller the most according to claim 1 and 2, it is characterised in that: described rush Entering agent is accelerant CZ.
The rubber compounding of spinning rubber-roller the most according to claim 1, it is characterised in that: described anti-aging Agent is 2-mercaptobenzimidazole.
CN201610284867.3A 2016-04-29 2016-04-29 Rubber compound of spinning rubber roll Pending CN105906885A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610284867.3A CN105906885A (en) 2016-04-29 2016-04-29 Rubber compound of spinning rubber roll

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610284867.3A CN105906885A (en) 2016-04-29 2016-04-29 Rubber compound of spinning rubber roll

Publications (1)

Publication Number Publication Date
CN105906885A true CN105906885A (en) 2016-08-31

Family

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Family Applications (1)

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CN201610284867.3A Pending CN105906885A (en) 2016-04-29 2016-04-29 Rubber compound of spinning rubber roll

Country Status (1)

Country Link
CN (1) CN105906885A (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337824A (en) * 2017-06-05 2017-11-10 薛念念 A kind of anti-static and abrasion-resistant damages rubber roll elastomeric material
CN109438795A (en) * 2018-12-27 2019-03-08 无锡市兰翔胶业有限公司 A kind of device for turbo-spinning cushion rubber
CN109485951A (en) * 2018-12-27 2019-03-19 无锡市兰翔胶业有限公司 A kind of high-performance rubber roller
CN109679178A (en) * 2018-12-27 2019-04-26 无锡市兰翔胶业有限公司 A kind of high-wearing feature rubber roller
CN109851930A (en) * 2018-12-27 2019-06-07 无锡市兰翔胶业有限公司 A kind of paint brushing rubber roller
CN110041584A (en) * 2019-04-23 2019-07-23 无锡二橡胶股份有限公司 A kind of high oil resistant, resistance to compression become the factory formula of spinning rubber-roller
CN110105643A (en) * 2019-05-06 2019-08-09 无锡二橡胶股份有限公司 A kind of factory formula of chemical fibre twin-core covering yarn spinning rubber-roller
CN111087663A (en) * 2019-12-30 2020-05-01 长沙中京机械有限公司 Wear-resistant nitrile rubber composition and application thereof
CN113583317A (en) * 2021-08-03 2021-11-02 无锡二橡胶股份有限公司 Production formula of rubber roller for lyocell fiber spinning
CN113896961A (en) * 2021-10-25 2022-01-07 无锡二橡胶股份有限公司 Production formula of rubber roller for compact siro spinning
CN115403837A (en) * 2022-10-11 2022-11-29 无锡二橡胶股份有限公司 Production formula of drafting rubber roll suitable for spinning high-speed and high-count differential fiber

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101260580A (en) * 2007-03-09 2008-09-10 天津市靖隆纺织橡胶有限公司 Treatment-free rubber-roller and manufacturing method thereof
CN101580634A (en) * 2009-06-10 2009-11-18 广州华工百川科技股份有限公司 Millable polyurethane rubber for spinning cot and preparation method thereof
CN103756059A (en) * 2014-02-21 2014-04-30 河北春风银星胶辊有限公司 Environment-friendly coating rubber material of printing rubber roll
CN103819770A (en) * 2014-03-06 2014-05-28 无锡二橡胶股份有限公司 Vortex spinning rubber roll
CN104693526A (en) * 2013-12-09 2015-06-10 王东奎 Reinforced roller sizing material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101260580A (en) * 2007-03-09 2008-09-10 天津市靖隆纺织橡胶有限公司 Treatment-free rubber-roller and manufacturing method thereof
CN101580634A (en) * 2009-06-10 2009-11-18 广州华工百川科技股份有限公司 Millable polyurethane rubber for spinning cot and preparation method thereof
CN104693526A (en) * 2013-12-09 2015-06-10 王东奎 Reinforced roller sizing material
CN103756059A (en) * 2014-02-21 2014-04-30 河北春风银星胶辊有限公司 Environment-friendly coating rubber material of printing rubber roll
CN103819770A (en) * 2014-03-06 2014-05-28 无锡二橡胶股份有限公司 Vortex spinning rubber roll

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337824A (en) * 2017-06-05 2017-11-10 薛念念 A kind of anti-static and abrasion-resistant damages rubber roll elastomeric material
CN109438795A (en) * 2018-12-27 2019-03-08 无锡市兰翔胶业有限公司 A kind of device for turbo-spinning cushion rubber
CN109485951A (en) * 2018-12-27 2019-03-19 无锡市兰翔胶业有限公司 A kind of high-performance rubber roller
CN109679178A (en) * 2018-12-27 2019-04-26 无锡市兰翔胶业有限公司 A kind of high-wearing feature rubber roller
CN109851930A (en) * 2018-12-27 2019-06-07 无锡市兰翔胶业有限公司 A kind of paint brushing rubber roller
CN110041584A (en) * 2019-04-23 2019-07-23 无锡二橡胶股份有限公司 A kind of high oil resistant, resistance to compression become the factory formula of spinning rubber-roller
CN110105643A (en) * 2019-05-06 2019-08-09 无锡二橡胶股份有限公司 A kind of factory formula of chemical fibre twin-core covering yarn spinning rubber-roller
CN111087663A (en) * 2019-12-30 2020-05-01 长沙中京机械有限公司 Wear-resistant nitrile rubber composition and application thereof
CN113583317A (en) * 2021-08-03 2021-11-02 无锡二橡胶股份有限公司 Production formula of rubber roller for lyocell fiber spinning
CN113896961A (en) * 2021-10-25 2022-01-07 无锡二橡胶股份有限公司 Production formula of rubber roller for compact siro spinning
CN115403837A (en) * 2022-10-11 2022-11-29 无锡二橡胶股份有限公司 Production formula of drafting rubber roll suitable for spinning high-speed and high-count differential fiber
CN115403837B (en) * 2022-10-11 2024-04-05 无锡二橡胶股份有限公司 Production formula of high-speed spinning high-count differential fiber drafting rubber roller

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PB01 Publication
C10 Entry into substantive examination
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RJ01 Rejection of invention patent application after publication

Application publication date: 20160831

RJ01 Rejection of invention patent application after publication