CN107337878A - A kind of plastic package material - Google Patents

A kind of plastic package material Download PDF

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Publication number
CN107337878A
CN107337878A CN201710698754.2A CN201710698754A CN107337878A CN 107337878 A CN107337878 A CN 107337878A CN 201710698754 A CN201710698754 A CN 201710698754A CN 107337878 A CN107337878 A CN 107337878A
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CN
China
Prior art keywords
parts
plastic package
package material
antioxidant
nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710698754.2A
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Chinese (zh)
Inventor
程海生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Cat Soft Packing Co Ltd
Original Assignee
Anhui Cat Soft Packing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Cat Soft Packing Co Ltd filed Critical Anhui Cat Soft Packing Co Ltd
Priority to CN201710698754.2A priority Critical patent/CN107337878A/en
Publication of CN107337878A publication Critical patent/CN107337878A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • B65D65/466Bio- or photodegradable packaging materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention provides a kind of plastic package material, is made up of the raw material of following parts by weight:30 60 parts of polyvinyl chloride resin powder, 20 50 parts of LLDPE, 5 15 parts of makrolon, 5 10 parts of diisononyl phthalate, 58 parts of trioctyl trimellitate (TOTM), 38 parts of nanometer grade calcium carbonate, 36 parts of Nano titanium dioxide, 10 18 parts of nano-graphene, 13 parts of lubricant, 4 10 parts of polyoxyethylene dodecyl amine, 3 12 parts of octadecyldiethanol amine, 59 parts of polytetrafluoroethylene (PTFE), 14 parts of antioxidant, 25 parts of organic tin heat stabilizer.The formula can improve the heat endurance and oxidation resistance of packaging material, plasticizer and antistatic additive both increase the performance of packaging material, the plastic package material prepared simultaneously has fabulous rigidity and impact property, and has good stability and certain degradation property and also certain environmental-protecting performance.

Description

A kind of plastic package material
Technical field
The invention belongs to plastic material technical field, and in particular to a kind of plastic package material.
Background technology
With the fast development of China's economy, the purchasing power of domestic resident is horizontal and consumption wish also progressively strengthens, and consumes Idea will tend to further improve the quality of living, the also more and more higher of the requirement to packaging material.
Corvic has good heat resistance, toughness and ductility, and is widely used, polytetrafluoroethylene (PTFE) life The microporous membrane of production, there is the advantages that Waterproof Breathable, corrosion-resistant, environment-protecting and non-poisonous again, makrolon (PC), be a kind of water white transparency (or pale yellow transparent) firm and tough and tensile material, satisfactory mechanical property, tensile strength, rigidity, wearability and electrical insulating property Also it is fine.The resistance to diluted acids of PC, oxidant, reducing agent, grease type, aliphatic hydrocarbon, not ultraviolet resistance, not alkaline-resisting.And by makrolon with Corvic and polytetrafluoroethylene (PTFE) make packaging material together also seldom to be occurred.
The content of the invention
To solve the above problems, it is an object of the invention to provide a kind of plastic package material, specific technical scheme is:
A kind of plastic package material, it is made up of the raw material of following parts by weight:It is polyvinyl chloride resin powder 30-60 parts, linear low Density polyethylene 20-50 parts, makrolon 5-15 parts, diisononyl phthalate 5-10 parts, trioctyl trimellitate (TOTM) 5-8 Part, nanometer grade calcium carbonate 3-8 parts, Nano titanium dioxide 3-6 parts, nano-graphene 10-18 parts, lubricant 1-3 parts, polyoxy second It is alkene lauryl amine 4-10 parts, octadecyldiethanol amine 3-12 parts, polytetrafluoroethylene (PTFE) 5-9 parts, antioxidant 1-4 parts, organic Tin type thermal stabilizing agent 2-5 parts.Further, a kind of plastic package material of the present invention, by the raw material system of following parts by weight Into:50 parts of polyvinyl chloride resin powder, 35 parts of LLDPE, 10 parts of makrolon, diisononyl phthalate 8 Part, 6 parts of trioctyl trimellitate (TOTM), 5 parts of nanometer grade calcium carbonate, 4 parts of Nano titanium dioxide, 15 parts of nano-graphene, lubricant 2 Part, 6 parts of polyoxyethylene dodecyl amine, 7 parts of octadecyldiethanol amine, 6 parts of polytetrafluoroethylene (PTFE), 3 parts of antioxidant, organotin 3 parts of type thermal stabilizing agent.
Further, the organic tin heat stabilizer is dibutyl tin laurate, Bis(lauroyloxy)dioctyltin, horse Come sour dibutyl tin, double (butyl maleate) dibutyl tins, one kind of maleic acid dioctyltin.
Further, the mesh number of the polyvinyl chloride resin powder is 100-200 mesh.
Further, the antioxidant was four [methyl-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons penta One kind of four alcohol esters or phosphorous acid three (24- di-tert-butyl-phenyls) ester.
Beneficial effect:Heat stabilizer and anti-oxidant is added the invention provides a kind of plastic package material, in the present invention Agent can improve the heat endurance and oxidation resistance of packaging material, and plasticizer and antistatic additive both increase packaging material Performance, while the plastic package material prepared has fabulous rigidity and impact property, and there is good stability and one Fixed degradation property and also certain environmental-protecting performance.
Embodiment
The invention will now be further described with reference to specific embodiments, and following examples are only the optimal implementation of the present invention Example, any restrictions are not formed to the scope of the present invention.It will be understood by those skilled in the art that without departing from the present invention's The details and form of technical solution of the present invention can be modified or replaced under spirit and scope, but these modifications and replacement are equal Fall within the scope of protection of the present invention.
Embodiment 1
A kind of plastic package material, it is made up of the raw material of following parts by weight:50 parts of polyvinyl chloride resin powder, linea low density 35 parts of polyethylene, 10 parts of makrolon, 8 parts of diisononyl phthalate, 6 parts of trioctyl trimellitate (TOTM), nanometer grade calcium carbonate 5 Part, 4 parts of Nano titanium dioxide, 15 parts of nano-graphene, 2 parts of lubricant, 6 parts of polyoxyethylene dodecyl amine, octadecyl 7 parts of diethanol amine, 6 parts of polytetrafluoroethylene (PTFE), 3 parts of antioxidant, 3 parts of organic tin heat stabilizer.
Further, the organic tin heat stabilizer is dibutyl tin laurate.
Further, the mesh number of the polyvinyl chloride resin powder is 150 mesh.
Further, the antioxidant was four [methyl-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons penta Four alcohol esters.
Embodiment 2
A kind of plastic package material, it is made up of the raw material of following parts by weight:30 parts of polyvinyl chloride resin powder, linea low density 20 parts of polyethylene, 5 parts of makrolon, 5 parts of diisononyl phthalate, 5 parts of trioctyl trimellitate (TOTM), nanometer grade calcium carbonate 3 Part, 3 parts of Nano titanium dioxide, 10 parts of nano-graphene, 1 part of lubricant, 4 parts of polyoxyethylene dodecyl amine, octadecyl 3 parts of diethanol amine, 5 parts of polytetrafluoroethylene (PTFE), 1 part of antioxidant, 2 parts of organic tin heat stabilizer.
Further, the organic tin heat stabilizer is Bis(lauroyloxy)dioctyltin.
Further, the mesh number of the polyvinyl chloride resin powder is 100 mesh.
Further, the antioxidant is or phosphorous acid three (24- di-tert-butyl-phenyls) ester.
Embodiment 3
A kind of plastic package material, it is made up of the raw material of following parts by weight:60 parts of polyvinyl chloride resin powder, linea low density 50 parts of polyethylene, 15 parts of makrolon, 10 parts of diisononyl phthalate, 8 parts of trioctyl trimellitate (TOTM), nanometer grade calcium carbonate 8 parts, Nano titanium dioxide 3-6 parts, 18 parts of nano-graphene, 3 parts of lubricant, 10 parts of polyoxyethylene dodecyl amine, 18 12 parts of alkyldiethanolamine, 9 parts of polytetrafluoroethylene (PTFE), 4 parts of antioxidant, 5 parts of organic tin heat stabilizer.
Further, the organic tin heat stabilizer is dibutyl tin laurate, Bis(lauroyloxy)dioctyltin, horse Come sour dibutyl tin, double (butyl maleate) dibutyl tins, one kind of maleic acid dioctyltin.
Further, the mesh number of the polyvinyl chloride resin powder is 200 mesh.
Further, the antioxidant was four [methyl-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid] seasons penta Four alcohol esters.
Embodiment 4
A kind of plastic package material, it is made up of the raw material of following parts by weight:50 parts of polyvinyl chloride resin powder, linea low density 40 parts of polyethylene, 12 parts of makrolon, 6 parts of diisononyl phthalate, 7 parts of trioctyl trimellitate (TOTM), nanometer grade calcium carbonate 7 Part, 4 parts of Nano titanium dioxide, 13 parts of nano-graphene, 2 parts of lubricant, 8 parts of polyoxyethylene dodecyl amine, octadecyl 11 parts of diethanol amine, 6 parts of polytetrafluoroethylene (PTFE), 3 parts of antioxidant, 4 parts of organic tin heat stabilizer.
Further, the organic tin heat stabilizer is double (butyl maleate) dibutyl tins.
Further, the mesh number of the polyvinyl chloride resin powder is 130 mesh.
Further, the antioxidant is phosphorous acid three (24- di-tert-butyl-phenyls) ester.

Claims (5)

1. a kind of plastic package material, it is characterised in that be made up of the raw material of following parts by weight:Polyvinyl chloride resin powder 30-60 Part, LLDPE 20-50 parts, makrolon 5-15 parts, diisononyl phthalate 5-10 parts, tri trimellitate Monooctyl ester 5-8 parts, nanometer grade calcium carbonate 3-8 parts, Nano titanium dioxide 3-6 parts, nano-graphene 10-18 parts, lubricant 1-3 Part, polyoxyethylene dodecyl amine 4-10 parts, octadecyldiethanol amine 3-12 parts, polytetrafluoroethylene (PTFE) 5-9 parts, antioxidant 1- 4 parts, organic tin heat stabilizer 2-5 parts.
2. a kind of plastic package material according to claim 1, it is characterised in that be made up of the raw material of following parts by weight: 50 parts of polyvinyl chloride resin powder, 35 parts of LLDPE, 10 parts of makrolon, 8 parts of diisononyl phthalate, partially It is 6 parts of three monooctyl ester of benzenetricarboxylic acid, 5 parts of nanometer grade calcium carbonate, 4 parts of Nano titanium dioxide, 15 parts of nano-graphene, 2 parts of lubricant, poly- 6 parts of oxygen ethene lauryl amine, 7 parts of octadecyldiethanol amine, 6 parts of polytetrafluoroethylene (PTFE), 3 parts of antioxidant, organic tin heat 3 parts of stabilizer.
A kind of 3. plastic package material according to claim 1 or 2, it is characterised in that the organic tin heat stabilizer For dibutyl tin laurate, Bis(lauroyloxy)dioctyltin, dibutyitin maleate, double (butyl maleate) dibutyl One kind of tin, maleic acid dioctyltin.
A kind of 4. plastic package material according to claim 1, it is characterised in that the mesh number of the polyvinyl chloride resin powder For 100-200 mesh.
A kind of 5. plastic package material according to claim 1, it is characterised in that the antioxidant be four [methyl- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester or phosphorous acid three (24- di-tert-butyl-phenyls) ester It is a kind of.
CN201710698754.2A 2017-08-15 2017-08-15 A kind of plastic package material Pending CN107337878A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710698754.2A CN107337878A (en) 2017-08-15 2017-08-15 A kind of plastic package material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710698754.2A CN107337878A (en) 2017-08-15 2017-08-15 A kind of plastic package material

Publications (1)

Publication Number Publication Date
CN107337878A true CN107337878A (en) 2017-11-10

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CN201710698754.2A Pending CN107337878A (en) 2017-08-15 2017-08-15 A kind of plastic package material

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108676285A (en) * 2018-05-28 2018-10-19 安徽顺彤包装材料有限公司 A kind of degradable plastic packaging material and preparation method thereof
CN108912406A (en) * 2018-08-06 2018-11-30 徐州奥博包装制品有限公司 A kind of plastic package material
CN111925604A (en) * 2020-06-30 2020-11-13 广州南洋电缆有限公司 Cable material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105015904A (en) * 2015-05-29 2015-11-04 铜陵方正塑业科技有限公司 High-temperature-resistant paper-plastic composite bag and preparation method thereof
CN105086241A (en) * 2015-08-25 2015-11-25 桐城市福润包装材料有限公司 Plastic packaging material
CN105153597A (en) * 2015-10-10 2015-12-16 绍兴翔宇绿色包装有限公司 Anti-static multifunctional thin film and preparation method thereof
CN105331024A (en) * 2015-11-23 2016-02-17 安徽国泰印务有限公司 Flame-retardant calendered film and production process thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105015904A (en) * 2015-05-29 2015-11-04 铜陵方正塑业科技有限公司 High-temperature-resistant paper-plastic composite bag and preparation method thereof
CN105086241A (en) * 2015-08-25 2015-11-25 桐城市福润包装材料有限公司 Plastic packaging material
CN105153597A (en) * 2015-10-10 2015-12-16 绍兴翔宇绿色包装有限公司 Anti-static multifunctional thin film and preparation method thereof
CN105331024A (en) * 2015-11-23 2016-02-17 安徽国泰印务有限公司 Flame-retardant calendered film and production process thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108676285A (en) * 2018-05-28 2018-10-19 安徽顺彤包装材料有限公司 A kind of degradable plastic packaging material and preparation method thereof
CN108912406A (en) * 2018-08-06 2018-11-30 徐州奥博包装制品有限公司 A kind of plastic package material
CN111925604A (en) * 2020-06-30 2020-11-13 广州南洋电缆有限公司 Cable material and preparation method thereof
CN111925604B (en) * 2020-06-30 2022-06-14 广州南洋电缆集团有限公司 Cable material and preparation method thereof

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Application publication date: 20171110

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