CN1058936A - The method for filling of packing container and device - Google Patents

The method for filling of packing container and device Download PDF

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Publication number
CN1058936A
CN1058936A CN91105543A CN91105543A CN1058936A CN 1058936 A CN1058936 A CN 1058936A CN 91105543 A CN91105543 A CN 91105543A CN 91105543 A CN91105543 A CN 91105543A CN 1058936 A CN1058936 A CN 1058936A
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CN
China
Prior art keywords
liquid
nozzle
aperture plate
mentioned
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN91105543A
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Chinese (zh)
Other versions
CN1025308C (en
Inventor
让·马利·丹尼斯
帕特里克·狄沃
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
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Colgate Palmolive Co
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Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of CN1058936A publication Critical patent/CN1058936A/en
Application granted granted Critical
Publication of CN1025308C publication Critical patent/CN1025308C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B67OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
    • B67CCLEANING, FILLING WITH LIQUIDS OR SEMILIQUIDS, OR EMPTYING, OF BOTTLES, JARS, CANS, CASKS, BARRELS, OR SIMILAR CONTAINERS, NOT OTHERWISE PROVIDED FOR; FUNNELS
    • B67C3/00Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus; Filling casks or barrels with liquids or semiliquids
    • B67C3/02Bottling liquids or semiliquids; Filling jars or cans with liquids or semiliquids using bottling or like apparatus
    • B67C3/22Details
    • B67C3/26Filling-heads; Means for engaging filling-heads with bottle necks
    • B67C3/2608Filling-heads; Means for engaging filling-heads with bottle necks comprising anti-dripping means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B3/00Packaging plastic material, semiliquids, liquids or mixed solids and liquids, in individual containers or receptacles, e.g. bags, sacks, boxes, cartons, cans, or jars
    • B65B3/04Methods of, or means for, filling the material into the containers or receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B39/00Nozzles, funnels or guides for introducing articles or materials into containers or wrappers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B39/00Nozzles, funnels or guides for introducing articles or materials into containers or wrappers
    • B65B39/001Nozzles, funnels or guides for introducing articles or materials into containers or wrappers with flow cut-off means, e.g. valves
    • B65B39/004Nozzles, funnels or guides for introducing articles or materials into containers or wrappers with flow cut-off means, e.g. valves moving linearly
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B39/00Nozzles, funnels or guides for introducing articles or materials into containers or wrappers
    • B65B39/12Nozzles, funnels or guides for introducing articles or materials into containers or wrappers movable towards or away from container or wrapper during filling or depositing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B39/00Nozzles, funnels or guides for introducing articles or materials into containers or wrappers
    • B65B2039/008Strainer means

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Basic Packing Technique (AREA)
  • Supply Of Fluid Materials To The Packaging Location (AREA)
  • Filling Of Jars Or Cans And Processes For Cleaning And Sealing Jars (AREA)
  • Containers And Plastic Fillers For Packaging (AREA)

Abstract

A kind of nozzle that is used for container filling, during container filling, the nozzle upward movement, thus during can with container in solution on keep a fixed range.In addition, when the flow of liquid delivery nozzle, it is by a splashproof aperture plate.Also have characteristics, one or more aspirators link to each other with aperture plate, and these aspirators are worked when stopping from nozzle liquid flowing so that water clock is discharged and prevented to liquid from aperture plate.The nozzle of upward movement during container filling, aperture plate, being combined in during the can and preventing sputter afterwards of the aspirator function that links to each other with aperture plate.

Description

The method for filling of packing container and device
The present invention relates to a kind of liquid pouring package utensil of using, for example pour into the method and the device of soft bag, and prevent the Splash that flies of the material that pours into.More particularly, the present invention relates to a spray nozzle device, it comprises and prevents that too much liquid from flowing to the device in soft bag or the bottle, remain on the device on the liquid plane in soft bag or the bottle with outlet, use the method for soft bag of this valve (nozzle) perfusion and bottle in addition at flush phase chien shih nozzle.
In the work of the soft bag of perfusion, be faced with many problems.One of them problem is that the liquid that pours into during container filling can produce Fei Splash.Another problem is that container is poured with the rear nozzle place and has water clock.This Fei Splash and water clock will cause the pollution to the seal of vessel zone.In addition, excessive De Fei Splash also will cause liquid in the container to be less than the amount of regulation.When container was a kind of soft bag, the pollution of sealing area was just even more serious.This situation occurring is because the manufacturing and the perfusion of soft bag are in same conveyor line under many situations.That is soft bag is to be made by a kind of film, and, when soft bag is worked into the degree with leak free bottom and a plurality of sealing lips, just by can.Then, sealing top.
A problem is, it is coated that the zone that comprises top seal can be poured the material of soft bag.This be since soft when perfusion bag material eddy current Fei Splash and spray when finishing water clock cause.Yet, well-known, do not consider the definite reason that these inside faces apply owing to product, be disadvantageous for later formation excellent sealing.Thereby present task is to make this Fei Splash reduce to minimum degree, and the water clock of perfusion end cycle rear nozzle is minimized.
The present invention be directed to a method and apparatus of pouring package container, and specifically, be used to pour into the soft bag of flexible film.This device is made of a nozzle, and it comprises the tube-like piece of an elongation, and this pipe fitting has the aperture by the mobile a kind of liquid of its discountinuity.In the upper end, be equipped with the device of a conducting liquid and, have at least an aperture plate device when flow of liquid stops, forming water clock in order to cause a kind of laminar flow and to reduce in the bottom.Bottom in one or more aperture plates zone can be equipped with an aspirator so that remove excess liquid from the aperture plate zone.In addition, this comprises the whole elongate tubular part of nozzle, then can upward movement when a container is poured so that keep the exit end of nozzle to be higher than the distance of a regulation of liquid in containers horizontal surface, like this, it is minimum that the Impact energy that produces in the time of can making fluid enter packing container reduces to.
In the method, nozzle is inserted in the soft bag, and then, nozzle is opened liquid is flowed in this container.In liquid inlet container, the nozzle upward movement so that the outlet of nozzle remain on during this perfusion operation the liquid in container horizontal surface above.Nozzle is just closed when soft bag filling is intact, and then aspirator just starts to remove the next drip-proof formation of unnecessary liquid in aperture plate or the aperture plate group zone.Then, this nozzle is just prepared another perfusion operation.
When a soft bag will be poured, this nozzle was the part of a manufacturing/can operation usually.When this soft bag was worked into the degree with leak free bottom and side, this soft bag just was in state to be filled.Carve at this moment, nozzle is near the bottom of soft bag, and nozzle is opened so that certain amount of liquid flows to soft bag.Simultaneously, nozzle is done upward movement to keep nozzle to be higher than flowing into the liquid level in the soft bag.When the liquid in flowing to soft bag reaches the amount of regulation, mobile then stop, and by aspirator the unnecessary liquid in one or more aperture plates zone of nozzle is got rid of.The formation of water clock in the time of so just can reducing the flow of liquid termination.
Fig. 1 is the positive view of a perfusion spray nozzle device when off position;
Fig. 2 is the positive view of perfusion spray nozzle device when the open position;
Fig. 3 is that perfusion spray nozzle device among Fig. 1 is along the cross-sectional figure in 3-3 cross section;
Fig. 4 is the positive view of this perfusion spray nozzle device when beginning to pour into for a container;
The positive view that Fig. 5 is this perfusion spray nozzle device when having poured into that container is over half;
Fig. 6 is the positive view of this perfusion spray nozzle device when filling with container.
In Fig. 1, these perfusion nozzle 10 expressions are in the closed position.In this position, there is not liquid to discharge by the perforate 23 of nozzle 10.This nozzle comprises housing 14, and it holds the liquid by passage 12 inflows of conduit 11.And liquid flows to by perforate 35 with from conduit 36.And this conduit 11 is supporting nozzle and is providing the device that makes nozzle rise and descend cycle period in the container perfusion.Conduit 11 is made screw thread fit with nozzle body 14 by screw thread 13.Conduit 15 in nozzle body allows liquid to flow to valve-rod cavity 16 and to the zone of nozzle valve seat 17.This liquid is to flow to valve seat 17 zones around the guide rod 26 by valve rod 18.The lower part of this valve rod contacts with valve seat when valve is in the closed position.The mobile of liquid stopped.When as shown in Figure 2 open position, conduit 15 will be communicated with so that liquid flows to cavity 21 from conduit 15 with passage 21.In the lower part of cavity 21, be equipped with one or more aperture plates so that make the liquid that flows through form laminar flow.After the aperture plate of flowing through, liquid will be discharged this nozzle by aperture 23.What be connected with cavity 21 is one or more conduits 20, is used for after 21 mobile the stopping, removing the too much liquid of cavity 21 from conduit 15 to cavity at liquid.These liquid are to remove with the aspirator that is connected on the conduit 20.
This nozzle 10 is an electric apparatus valve preferably, but also can be a mechanical valve.As an electric apparatus nozzle, in coil 25, produce an electromagnetic field so that magnet 27 upward movements.This magnet is a component part of valve-stem guide 26.Brake component 28 and valve seat 18 are with the motion of limiting lever 17.
Fig. 2 represents that nozzle is in an open position.This valve rod is in a downward position, so allow liquid to flow to cavity 21 by conduit 15.This liquid will flow through aperture plate 22 and discharge through small holes 23.When nozzle is closed again, on conduit 20, be added with a swabbing action so that remove unnecessary liquid from cavity 21.
The cross-sectional figure in nozzle 3-3 along the line cross section, is shown with nozzle body 14 herein in Fig. 3 presentation graphs 1, cavity 21, valve rod 18 and suction catheter 20.
Fig. 4 represents container of said nozzle perfusion to Fig. 6, represents that in Fig. 4 nozzle 10 is arranged in container 30 fully, so that liquid 31 is injected this container.Liquid flows out from nozzle 10 in the mode of base layer stream.This is owing to the result by aperture plate.In Fig. 5, container 30 expressions are in the state of approximately partly filling with.In this view, nozzle 10 upward movement just in time is higher than liquid in containers 31 horizontal surfaces with the aperture 23 that keeps nozzle.In Fig. 6, expression container 36 has been filled with.And nozzle is placed in the top of liquid level, and, also stopped from the flow of liquid of nozzle.At this constantly, have a swabbing action on conduit 20 so that unnecessary liquid remove from the bottom of nozzle that is remove from aperture plate or aperture plate group zone.
The main function of this aperture plate or aperture plate group 22 is fluid separation applications stratified flows of making discharge nozzle to help nozzle to prevent the water clock of nozzle when the off position.This aperture plate can be single aperture plate or also can be several stacked aperture plate groups.Preferably use an independent aperture plate, and thickness is about 0.1 millimeter (mm) to 10 millimeters, is preferably 0.2 millimeter to 5 millimeters.This aperture plate also has a kind of mesh and is about 0.1 to 5 millimeter, and preferably about 0.5 to 2.5 millimeter.To be enough to like this produce and a kind ofly make flow of liquid form a kind of passage of base layer stream by it.
And preferably the diameter of nozzle is the cross-sectional plane that is full of container when perfusion substantially, and for the situation of soft bag, this diameter will be about 60 to 90% of container diameter.When container is a jar, the diameter of nozzle will approximately be 60 to 90% of jar neck perforate so.A large diameter nozzle is with the less Splash that flies, because liquid flows with lower speed.In addition, it is minimum that the danger of high whirling current just reduces to, and container inner wall De Fei Splash and pollution have just reduced by this way.
Nozzle 10 both can mechanical type, fluid pressure type or the motion up and down of pneumatic type ground.In the situation of fluid pressure type or pneumatic actuating mechanism, will there be a piston to append to directly or indirectly on the conduit 11.A kind of liquid or the gas that act on this piston will make nozzle 10 rise and descend.In a kind of mechanical operation, it for example is a kind of rack gear arrangement and as the part of its outer surface that this conduit 11 can have a gear mechanism.Like this, a kind of meshed transmission gear with this tooth bar will make nozzle rise and decline.And can use other mechanical device.In Fig. 1, illustrate a hydraulic pressure or compressed-air controlled mechanism be used for the rising and the decline of nozzle 10.Be shown with a bar 37 herein, it is connected on the piston rod 38 of piston 39, and this piston 39 moves in clutch release slave cylinder 40.Clutch release slave cylinder 40 is installed on the supporting member 41.A kind of fluid or gas be pumped to aperture 42 ' or aperture 42 " in to promote piston and and then valve 10.A kind of mechanical device of expression in Fig. 2, herein, tooth bar 43 is arranged on the conduit 11 rigidly.Swing pinion 44 just can make nozzle 10 do motion up and down.
Under the soft bag of a kind of film of can situation, nozzle is moved downwardly into the bottom near soft bag, and liquid begins to flow to soft bag.When liquid flows to soft when bag, nozzle with regard to upward movement in case the bottom that keeps nozzle in soft bag on the liquid level.When the liquid that flows to soft bag reached specified amount, then the mobile of liquid stopped, and near the bottom of valve (nozzle) swabbing action arranged, to prevent to form water clock.Unnecessary liquid is drawn into the recycle tank from one or more aperture plates zone of nozzle.Yet in a single day this swabbing action stops, and this nozzle is just prepared to start and another circulation beginning.
Primary goal of this perfusion nozzle is to prevent to be filled to liquid in soft bag and other containers around outside Fei Splash and prevent that in the end the film that a step must form in the leak free zone during operation is got wet around the nozzle.If get wet with product (filling liquid), so, just there is the possibility that forms poor sealing in formation leak free zone.
Just the preferred embodiments of the present invention noted earlier.According to specific purposes various modifications and variations can also be arranged, yet these improve and modification all will be a practical structures scheme of the present invention.

Claims (11)

1, antidrip nozzle with liquid filling container comprises: an elongate tubular part, and it has an aperture that is used for circulating liquid; Be equipped with the device of guiding liquids in above-mentioned tube-like piece upper end, at least one aperture plate device of the other end of above-mentioned tube-like piece to guide the formation of flowing and reducing water clock; Be equipped with an aspirator at least at above-mentioned aperture plate near zone removing online excess liquid, and be used at the liquid level of the device that during the container filling tube-like piece is raise in order to container after the aperture plate on the other end of above-mentioned tubular body is remained on can.
2, an antidrip nozzle wherein has a plurality of aperture plates.
3, antidrip nozzle according to claim 2, wherein above-mentioned aperture plate has about 0.1~10cm thickness.
4, an antidrip nozzle according to claim 1 wherein has a plurality of aspirators.
5, antidrip nozzle according to claim 1, wherein above-mentioned elongated member is filled up the cross-sectional plane of container filling basically.
6, method with liquid filling container comprises:
A) provide a channelled elongate tubular nozzle, be used for transmitting liquid to one container, this nozzle comprises a plurality of aperture plates and a plurality of aspirators adjacent with aperture plate;
B) said nozzle is moved to the bottom of said vesse;
C) make exit end that liquid passes through said nozzle and mobile said nozzle with the exit end that keeps said nozzle on liquid in containers;
D) ending liquid flows out from said nozzle; And
E) start above-mentioned aspirator so that liquid is discharged from above-mentioned aperture plate district.
7, a kind of method according to claim 6, wherein the liquid of being discharged by above-mentioned aspirator flows to a recycle tank.
8, a kind of method according to claim 6, wherein liquid is selected from such one group of liquid: bleaching liquid, washer solvent, fabric softener and various cleaning liquid.
9, a kind of method according to Claim 8, wherein aforesaid liquid is a bleaching liquid.
10, a kind of method according to Claim 8, wherein aforesaid liquid is a fabric softener.
11, a kind of method according to Claim 8, wherein above-mentioned packing is the film packed in flexible pouchy.
CN91105543A 1990-08-13 1991-08-12 Package filling method and apparatus Expired - Fee Related CN1025308C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US56690390A 1990-08-13 1990-08-13
US566,903 1990-08-13

Publications (2)

Publication Number Publication Date
CN1058936A true CN1058936A (en) 1992-02-26
CN1025308C CN1025308C (en) 1994-07-06

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CN91105543A Expired - Fee Related CN1025308C (en) 1990-08-13 1991-08-12 Package filling method and apparatus

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JP (1) JPH04253602A (en)
KR (1) KR920004043A (en)
CN (1) CN1025308C (en)
AU (1) AU648328B2 (en)
CA (1) CA2048950A1 (en)
DE (1) DE4126556A1 (en)
EG (1) EG19214A (en)
ES (1) ES2051159B1 (en)
FR (1) FR2665682B1 (en)
GB (1) GB2247672B (en)
GR (1) GR910100349A (en)
HK (1) HK1000141A1 (en)
HU (1) HUT60687A (en)
IT (1) IT1249438B (en)
MY (1) MY107956A (en)
NZ (1) NZ239049A (en)
PT (1) PT98650A (en)
RO (1) RO107913B1 (en)
RU (1) RU2043268C1 (en)
TR (1) TR27996A (en)
ZA (1) ZA915594B (en)

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CN102202978A (en) * 2008-09-30 2011-09-28 Sig技术股份公司 Filling method and device
CN102372242A (en) * 2010-07-21 2012-03-14 克朗斯公司 Apparatus and method of filling containers with cleaning device
CN102556914A (en) * 2012-03-02 2012-07-11 南通苏诺特包装机械有限公司 Fully-automatic filling system for high-consistence mucilage
CN104105588A (en) * 2012-02-10 2014-10-15 潘特克股份公司 Method and device for making tubular bags of thin plastic films by means of an ultrasound welding process
CN108688878A (en) * 2018-05-22 2018-10-23 张汀仁 A kind of medicinal fluid bag filling liquid special medical equipment
CN108910103A (en) * 2018-05-22 2018-11-30 张汀仁 It is a kind of can stability and high efficiency filling medical fluid Medical Devices
CN110167869A (en) * 2017-01-05 2019-08-23 莱宾格有限公司 Method for filling cylindrical containers, in particular cans, and filling device and filling system for containers
CN111232905A (en) * 2020-03-11 2020-06-05 江西阳光乳业股份有限公司 Yoghourt filling device

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JP5440011B2 (en) * 2009-07-31 2014-03-12 カシオ計算機株式会社 Discharge nozzle, discharge device and coating device
EP2797833B1 (en) * 2011-12-30 2016-08-03 Grinon Industries Fluid transfer assembly and methods of fluid transfer
DE102014011075B4 (en) * 2014-07-30 2017-07-20 Benhil Gmbh Process for packaging liquid or pasty products and packaging machine suitable for this purpose
CN104691832B (en) * 2014-12-24 2017-01-25 杭州中亚机械股份有限公司 Filling valve
RU2706958C2 (en) * 2015-04-22 2019-11-21 Тетра Лаваль Холдингз Энд Файнэнс С.А. Device and method for filling container with product
US10023333B2 (en) * 2016-03-07 2018-07-17 The Procter & Gamble Company Vacuum assisted nozzle and apparatus
GB2569364B (en) * 2017-12-15 2022-11-30 Elopak Gmbh Improved filling device
CN109019490A (en) * 2018-08-20 2018-12-18 成都味科自动化设备有限公司 A kind of automatic filling system
CN110272008B (en) * 2019-07-24 2020-12-25 阜阳智企生产力促进中心有限公司 Oil filling head for edible oil production line based on self oil pressure difference principle
CN111924785A (en) * 2020-08-17 2020-11-13 陈芳 Filling equipment for beverage production
IT202200003755A1 (en) * 2022-03-01 2023-09-01 Sasib Spa Apparatus and method for dosing molasses into containers

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Cited By (13)

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Publication number Priority date Publication date Assignee Title
CN102202978A (en) * 2008-09-30 2011-09-28 Sig技术股份公司 Filling method and device
CN102202978B (en) * 2008-09-30 2013-09-25 Sig技术股份公司 Filling method and device
CN102372242B (en) * 2010-07-21 2015-09-09 克朗斯公司 Be provided with the Apparatus and method for for container perfusion of cleaning device
CN102372242A (en) * 2010-07-21 2012-03-14 克朗斯公司 Apparatus and method of filling containers with cleaning device
CN104105588B (en) * 2012-02-10 2016-06-01 潘特克股份公司 Method and the device of the tubular bag that thin plastic is formed is manufactured by ultrasonic welding method
CN104105588A (en) * 2012-02-10 2014-10-15 潘特克股份公司 Method and device for making tubular bags of thin plastic films by means of an ultrasound welding process
CN102556914A (en) * 2012-03-02 2012-07-11 南通苏诺特包装机械有限公司 Fully-automatic filling system for high-consistence mucilage
CN110167869A (en) * 2017-01-05 2019-08-23 莱宾格有限公司 Method for filling cylindrical containers, in particular cans, and filling device and filling system for containers
US10894704B2 (en) 2017-01-05 2021-01-19 Leibinger Gmbh Method for filling cylindrical containers, in particular cans, and filling arrangement of a filling device and a container
CN108688878A (en) * 2018-05-22 2018-10-23 张汀仁 A kind of medicinal fluid bag filling liquid special medical equipment
CN108910103A (en) * 2018-05-22 2018-11-30 张汀仁 It is a kind of can stability and high efficiency filling medical fluid Medical Devices
CN108910103B (en) * 2018-05-22 2020-04-10 吉林大学第一医院 Medical equipment capable of stably and efficiently filling liquid medicine
CN111232905A (en) * 2020-03-11 2020-06-05 江西阳光乳业股份有限公司 Yoghourt filling device

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CN1025308C (en) 1994-07-06
TR27996A (en) 1995-11-13
HU912680D0 (en) 1992-01-28
AU8171591A (en) 1992-02-20
ES2051159A1 (en) 1994-06-01
GB2247672B (en) 1995-01-11
KR920004043A (en) 1992-03-27
FR2665682A1 (en) 1992-02-14
CA2048950A1 (en) 1992-02-14
HUT60687A (en) 1992-10-28
GR910100349A (en) 1992-08-31
PT98650A (en) 1993-09-30
DE4126556A1 (en) 1992-02-20
RU2043268C1 (en) 1995-09-10
AU648328B2 (en) 1994-04-21
HK1000141A1 (en) 1997-12-24
ES2051159B1 (en) 1994-10-16
ZA915594B (en) 1993-03-31
IT1249438B (en) 1995-02-23
JPH04253602A (en) 1992-09-09
FR2665682B1 (en) 1995-09-22
MY107956A (en) 1996-07-15
GB9117498D0 (en) 1991-09-25
NZ239049A (en) 1994-05-26
RO107913B1 (en) 1994-01-31
ITRM910608A1 (en) 1993-02-09
GB2247672A (en) 1992-03-11
EG19214A (en) 1994-11-30
ITRM910608A0 (en) 1991-08-09

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