CN105885740A - Cationic binder for denim paint dyeing - Google Patents
Cationic binder for denim paint dyeing Download PDFInfo
- Publication number
- CN105885740A CN105885740A CN201610200245.8A CN201610200245A CN105885740A CN 105885740 A CN105885740 A CN 105885740A CN 201610200245 A CN201610200245 A CN 201610200245A CN 105885740 A CN105885740 A CN 105885740A
- Authority
- CN
- China
- Prior art keywords
- cationic
- monomer
- cationic binder
- binder
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 125000002091 cationic group Chemical group 0.000 title claims abstract description 33
- 238000004043 dyeing Methods 0.000 title claims abstract description 33
- 239000011230 binding agent Substances 0.000 title claims abstract description 31
- 239000003973 paint Substances 0.000 title abstract description 6
- 239000000178 monomer Substances 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004744 fabric Substances 0.000 claims abstract description 16
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 10
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000012153 distilled water Substances 0.000 claims abstract description 8
- 239000003999 initiator Substances 0.000 claims abstract description 6
- 238000004132 cross linking Methods 0.000 claims abstract description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- 239000011248 coating agent Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 22
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 18
- 239000000049 pigment Substances 0.000 claims description 16
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 239000003093 cationic surfactant Substances 0.000 claims description 8
- 238000009835 boiling Methods 0.000 claims description 7
- 238000010992 reflux Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 6
- 229920003081 Povidone K 30 Polymers 0.000 claims description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 5
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims description 4
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- 235000000177 Indigofera tinctoria Nutrition 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 238000005189 flocculation Methods 0.000 claims description 4
- 230000016615 flocculation Effects 0.000 claims description 4
- 229940097275 indigo Drugs 0.000 claims description 4
- COHYTHOBJLSHDF-UHFFFAOYSA-N indigo powder Natural products N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000012875 nonionic emulsifier Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- -1 1,6-hexanediyl ester Chemical class 0.000 claims description 3
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 3
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 claims description 3
- 229940117958 vinyl acetate Drugs 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 239000003002 pH adjusting agent Substances 0.000 claims description 2
- 238000004383 yellowing Methods 0.000 claims description 2
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 210000000481 breast Anatomy 0.000 claims 1
- 150000002576 ketones Chemical class 0.000 claims 1
- 229920006316 polyvinylpyrrolidine Polymers 0.000 claims 1
- ILWRPSCZWQJDMK-UHFFFAOYSA-N triethylazanium;chloride Chemical compound Cl.CCN(CC)CC ILWRPSCZWQJDMK-UHFFFAOYSA-N 0.000 claims 1
- 239000000839 emulsion Substances 0.000 abstract description 11
- 238000001816 cooling Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 20
- 238000010792 warming Methods 0.000 description 10
- 238000001035 drying Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 241001062009 Indigofera Species 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 230000000149 penetrating effect Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920006052 Chinlon® Polymers 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229920002593 Polyethylene Glycol 800 Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000004759 spandex Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/003—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/6025—Natural or regenerated cellulose using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
- D06P3/8228—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1806—C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Coloring (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a cationic binder emulsion for denim paint dyeing. The binder emulsion is generated after a reaction of soft monomers, hard monomers, cationic monomers, crosslinking monomers, a compound emulsifier and an initiator. During preparation, a mixture of all the monomers and an initiator water solution are added into the emulsifier and distilled water for a reaction, cooling and filtering are conducted, and the cationic binder is prepared. The cationic binder is used for the denim yarn/fabric paint dyeing process or the paint overdyeing process, and during use, it is not needed to pretreat yarn/fabric or paint.
Description
Technical field
The invention belongs to technical field of textile printing, relate to pigment dyeing macromolecule emulsion, specially denim yarn/knit
Thing pigment dyeing binding agent.
Background technology
Traditional denim or the classical denim of title, refer to make warp thread with Quality Pure Cotton Yarn Production indigo dyeing, and beyber yarn makees weft yarn, adopts
With thick the twill that on three, once twill left to right tissue is interwoven, its yarn count is generally the low count yarn of about 16, cloth cover ratio
More thick and heavy.And now jean is not only cotton fiber, the natural fiber such as fiber crops, hair, silk, viscose glue, tencel, Modal etc. are again
Raw fiber, the synthetic fibers such as terylene, chinlon, acrylon, spandex are widely used.Therefore, in current cowboy's textile dyeing, it is coated with
Material dyeing, adaptability is wider, and is the process for cleanly preparing that can really realize energy-saving and emission-reduction.
Pigment dyeing is by non-water-soluble pigment, is attached on fabric or yarn by the auxiliary agent such as binding agent, cross-linking agent
A kind of colouring method.Owing to coating itself and fabric or yarn are without affinity, when using coating that cowboy is dyeed, first it is right
Yarn or fabric carry out cation modifying process, carry out padding coating the most again, and follow-up carrying out again dries sizing technique.Ratio
Coating ready-made clothes chromatography flow process as traditional: openpore ready-made clothes → cation-modified process (3～5%, 60 DEG C, 20min) → l road cold water
Road, → pigment dyeing → 1 cold water → fastness to wet rubbing agent processes road, (90 DEG C, 20min) → 1 cold water → drying.
In cationization processes, someone have employed traditional cation modifier, and cation modifier is first to fabric
Process, it is easy to bring local concentration too high, cause the defect that mottle occurs during dye on the coating in later stage.Also there is people as specially
Profit CN104372690 is attempted with a kind of cationic acrylic polymer emulsion and first processes fabric, then impregnates
Coating dispersing liquid.Patent CN 101289601 then uses the mode of cationic surfactant to be prepared for cationic bonding
Agent, when reality is applied, (another patent 102605649) remains and first uses cationic binder to carry out pre-to pigment printing paste
Process, make coating surface again it be dyeed with uniform positive charge.They have employed a point multistep, in order to prevent sun from
Breakdown of emulsion or the problem of flocculation is there is between subtype polymer and anionic auxiliary.
Summary of the invention
The present invention overcomes the ionic problem of pigment dyeing in prior art, it is provided that one can be used for cowboy's pigment dyeing with viscous
Mixture and preparation method thereof.This cationic adhesives can be with coating solution intimate blending, without flocculation or deposited phenomenon.Permissible
In the pigment dyeing or coating set dyeing technique of denim yarn/fabric, and without yarn/fabrics, coating are done when using
Pretreatment.
For solving above-mentioned technical problem, the technical solution adopted in the present invention is:
The binding agent that the present invention provides is generated by following composition reaction:
(1) hard monomer: styrene, methyl methacrylate, ethyl methacrylate or vinylacetate etc., can be independent
Or be used in mixed way
(2) soft monomer: butyl acrylate, Isooctyl acrylate monomer or hexyl acrylate etc., can be used alone or as a mixture
(3) cationic monomer: DAC (acrylamide oxy-ethyl-trimethyl salmiac), DMC (methylacryoyloxyethyl front three
Ammonium chloride) etc., can be used alone or as a mixture
(4) cross-linking monomer: acrylamide, Hydroxypropyl acrylate or 1,6-hexanediyl ester etc., can individually or mixed
Close and use
(5) emulsifying agent: cationic surfactant and the compound of nonionic emulsifier, cationic surfactant is
The one of which such as benzyltriethylammoinium chloride, Dodecyl trimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride or two kinds
Above mixture, described nonionic emulsifier is T-07 (isomery C13 polyoxyethylenated alcohol), PVP-K30 (polyethylene pyrrole
Pyrrolidone), one of which or the two or more mixture such as PEG (Polyethylene Glycol)；Cationic surfactant and nonionic table
The usage ratio 1～5:1～5 of face activating agent
(6) initiator: 2,2 '-azo diisopropylamidinateand hydrochlorate.
The cowboy that the present invention provides dyes by the preparation method of cationic adhesives, specifically includes the following step:
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, at 40-80 DEG C,
Being added by emulsifying agent in distilled water, stir, regulation pH value is 4～6, single by formula dropping initiator solution and crosslinking
Body, soft monomer, the mixing liquid of hard monomer, dropping completed in 10～150 minutes, reacts 2.5～5 hours, is cooled to 20-30
DEG C, filter.The mean diameter preparing cationic binder emulsion is about 320-460 micron.
In wherein said formula, shared by each composition, mass percent is:
As preferably, described soft monomer and the weight ratio of hard monomer are 1.4～4:1, and cationic monomer accounts for total monomer matter
Amount ratio is 8%～30%.
As preferably, the usage ratio 0.5～2:1 of described cationic surfactant and nonionic surfactant.
As preferably, the pH adjusting agent used in described cationic binder preparation process can be acetic acid, citric acid
In one of which.
Cationic binder provided by the present invention can be with coating solution intimate blending, without flocculation or deposited phenomenon.Can
Pigment dyeing or coating for denim yarn/fabric are overlapped in dyeing technique, and without to yarn/fabrics, coating when using
Do pretreatment.Using commercial coating mill base, its pigment dyeing technique can be:
Dyeing: pad (liquid carrying rate 70%)-preliminary drying-drying (80～100 DEG C)-tentering (120 DEG C × 20～120s)
Impregnation liquid formula:
Coating 2～30g/L
Penetrating agent 1～5g/L
The present invention provides cationic binder 10～30g/L
After dyeing, denim yarn/fabric can keep white core, the i.e. characteristic of ring dye, and feel is excellent, and dry and wet crock fastness reaches 3 grades
More than and, fastness index is preferable.
The invention has the beneficial effects as follows, pigment dyeing technique can directly configure coating padding liquid, it is not necessary to solution is entered
Row additional pre-treatment, shortens traditional cowboy's pigment dyeing technique flow process, it is not necessary to carry out cation-modified to cowboy.And warp
After the paint adhesive dyeing of the present invention, denim yarn/fabric tinctorial yield improves, and keeps the characteristic of white core, dry and wet friction jail
Degree reach 3 grades and more than, fastness index is preferable.The technique that the present invention provides is applied in the indigo resisdye of cowboy, cowboy can be improved
Yellowing-resistant performance.
Detailed description of the invention
Embodiment 1
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, add emulsifying agent
Benzyltriethylammoinium chloride 2.5g, PVP-K30 3g and distilled water 200g, stirs, and is warming up to 40 DEG C, adds 0.15g 2,
2 '-azo diisopropylamidinateand hydrochlorate (V-50), drips 30g butyl acrylate, 9g ethyl methacrylate, 15g DAC, 3g1,
The mixture such as 6-hexanediyl ester, use acetic acid regulation ph value of emulsion to 4～5, control rate of addition, and time for adding is
3 hours, drip and add 0.18g V-50, be incubated 1 hour, be warming up to 65 DEG C, be incubated 1 hour, be cooled to 30 DEG C and filter discharging.
Embodiment 2
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, add emulsifying agent
Dodecyl trimethyl ammonium chloride 3g, PVP-K30 6g and distilled water 200g, stir, and is warming up to 45 DEG C, adds 3.6g 2,
2 '-azo diisopropylamidinateand hydrochlorate (V-50), drips 60g Isooctyl acrylate monomer, 20g styrene, 15g DMC, 4.5g propylene
The mixture such as amide, use citric acid regulation ph value of emulsion to 5～6, control rate of addition, and time for adding is 2.5 hours, dropping
The complete 0.3g V-50 that adds, is incubated 1 hour, is warming up to 70 DEG C, is incubated 1 hour, is cooled to 30 DEG C and filters discharging.
Embodiment 3
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, add emulsifying agent
Dioctadecyl dimethyl ammonium chloride 2g, PEG-800 0.6g, T-07 0.4g and distilled water 200g, stir, be warming up to 50
DEG C, add 4.4g 2,2 '-azo diisopropylamidinateand hydrochlorate (V-50), drip 75g hexyl acrylate, 30g methyl methacrylate
The mixture such as ester, 45g DAC, 30g Hydroxypropyl acrylate, use acetic acid regulation ph value of emulsion to 4～5, control rate of addition, drip
Adding the time is 4 hours, drips and adds 1.6g V-50, be incubated 1 hour, be warming up to 75 DEG C, is incubated 1 hour, is cooled to 20 DEG C of mistakes
Leach material.
Embodiment 4
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, add emulsifying agent
Dodecyl trimethyl ammonium chloride 3g, PVP-K30 3g and distilled water 200g, stir, and is warming up to 40 DEG C, adds 1.8g 2,
2 '-azo diisopropylamidinateand hydrochlorate (V-50), drips 75g butyl acrylate, 45g styrene, 8g vinylacetate, 15g
The mixture such as DAC, 30g Hydroxypropyl acrylate, use acetic acid regulation ph value of emulsion to 5, control rate of addition, and time for adding is 5
Hour, drip and add 0.18g V-50, be incubated 1 hour, be warming up to 80 DEG C, be incubated 1 hour, be cooled to 30 DEG C and filter discharging.
Embodiment 5
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, add emulsifying agent
Dodecyl trimethyl ammonium chloride 1g, PVP-K30 5g and distilled water 200g, stir, and is warming up to 40 DEG C, adds 2.6g 2,
2 '-azo diisopropylamidinateand hydrochlorate (V-50), drips 36g butyl acrylate, 9g styrene, 20g DMC, 3g acrylic acid hydroxypropyl
The mixture such as ester, use acetic acid regulation ph value of emulsion to 5, control rate of addition, and time for adding is 5 hours, drips and adds
0.26g V-50, is incubated 1 hour, is warming up to 80 DEG C, is incubated 1 hour, is cooled to 30 DEG C and filters discharging.
Embodiment 6
The textile warp yarns (16s) of bleaching
The gorgeous blue 25g/L of coating
Penetrating agent 2g/L
Cationic binder (embodiment 3 provides) 20g/L
Dyeing: pad (liquid carrying rate 70%)-preliminary drying-drying (80～100 DEG C)-tentering (120 DEG C × 20s)
After dyeing, denim yarn can keep the characteristic of white core, dry and wet crock fastness reach 3 grades and more than, fastness index is preferable.
Embodiment 7
Polyester-cotton blend cowboy's openpore (65/35)
The red 2g/L of coating
Penetrating agent 3g/L
Cationic binder (embodiment 4 provides) 30g/L
Dyeing: pad (liquid carrying rate 70%)-preliminary drying-drying (80～100 DEG C)-tentering (120 DEG C × 70s)
Jean excellent touch after dyeing, dry and wet crock fastness reach 3 grades and more than, fastness index is preferable.
Embodiment 8
Through indigo dyeing cotton textiles cowboy
Coating indigo plant 10g/L
Penetrating agent 10g/L
Cationic binder (embodiment 1 provides) 20g/L
Dyeing: pad (liquid carrying rate 70%)-preliminary drying-drying (80～100 DEG C)-tentering (120 DEG C × 120s)
Jean excellent touch after dyeing, dry and wet crock fastness reach 3 grades and more than, ozone-resistant xanthochromia is up to 3-4 level.
With the above-mentioned desirable embodiment according to the present invention for enlightenment, by above-mentioned description, relevant staff is complete
Entirely can carry out various change and amendment in the range of without departing from this invention technological thought.The technology of this invention
The content that property scope is not limited in description, it is necessary to determine its technical scope according to right.
Claims (9)
1. cowboy's pigment dyeing cationic binder, it is characterised in that described cationic binder may be used for cowboy
In the pigment dyeing of yarn/fabrics or coating set dyeing technique, and without yarn/fabrics, coating are done pretreatment when using.
Cationic binder the most according to claim 1, it is characterised in that described binding agent is raw by following composition reaction
Become:
(1) hard monomer: styrene, methyl methacrylate, ethyl methacrylate or vinylacetate etc., can individually or mixed
Close and use
(2) soft monomer: butyl acrylate, Isooctyl acrylate monomer or hexyl acrylate etc., can be used alone or as a mixture
(3) cationic monomer: DAC (acrylamide oxy-ethyl-trimethyl salmiac), DMC (methylacryoyloxyethyl trimethyl
Ammonium chloride) etc., can be used alone or as a mixture
(4) cross-linking monomer: acrylamide, Hydroxypropyl acrylate or 1,6-hexanediyl ester etc., can individually or mixing
Use
(5) emulsifying agent: cationic surfactant and the compound of nonionic emulsifier, cationic surfactant is benzyl
The one of which or two or more such as triethyl ammonium chloride, Dodecyl trimethyl ammonium chloride, dioctadecyl dimethyl ammonium chloride
Mixture, described nonionic emulsifier is T-07 (isomery C13 polyoxyethylenated alcohol), PVP-K30 (polyvinylpyrrolidine
Ketone), one of which or the two or more mixture such as PEG (Polyethylene Glycol)；Cationic surfactant and non-ionic surface are lived
The usage ratio 1～5:1～5 of property agent
(6) initiator: 2,2 '-azo diisopropylamidinateand hydrochlorate.
3. according to the preparation method of the cationic binder described in claim 1,2, it is characterised in that specifically include the following step:
Will be equipped with reflux condensing tube, agitator, the four-hole boiling flask of Dropping funnel are placed in constant temperature water bath, at 40-80 DEG C, by breast
Agent adds in distilled water, stirs, and regulation pH value is 4～6, by formula dropping initiator solution and cross-linking monomer, soft
Monomer, the mixing liquid of hard monomer, dropping completed in 10～150 minutes, reacts 2.5～5 hours, is cooled to 20-30 DEG C, mistake
Filter.
4. according to the cationic binder described in claim 1,2, it is characterised in that: in wherein said formula shared by each composition
Mass percent is:
5. according to the cationic binder preparation method described in claim 2,3, it is characterised in that: described soft monomer and hard list
The weight ratio of body is 1.4～4:1, and it is 8%～30% that cationic monomer accounts for total monomer quality ratio.
6. according to the cationic binder preparation method described in claim 2,3, it is characterised in that: described cationic surface is lived
Property agent and the usage ratio 0.5～2:1 of nonionic surfactant.
7. according to the cationic binder preparation method described in claim 2,3, it is characterised in that: described cationic binder
The pH adjusting agent used in preparation process can be the one of which in acetic acid, citric acid.
Cationic binder the most according to claim 1, it is characterised in that described binding agent can be total to by homogenizing with coating solution
Mixed, without flocculation or deposited phenomenon.
Cationic binder the most according to claim 1, it is characterised in that described binding agent drawings is in the indigo resisdye of cowboy
In technique, the yellowing-resistant performance of cowboy can be improved.
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| CN108822248A (en) * | 2018-06-20 | 2018-11-16 | 邢台职业技术学院 | A kind of pigment dyeing cationic binder emulsion and its preparation method and application |
| CN109403089A (en) * | 2018-10-15 | 2019-03-01 | 安阳师范学院 | A kind of coating dye printing Environment-friendlyadhesive adhesive and its preparation method and application |
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