CN101289601A - Cationic binder emulsion for coating coloring, preparation method and uses - Google Patents
Cationic binder emulsion for coating coloring, preparation method and uses Download PDFInfo
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- CN101289601A CN101289601A CNA2008101239584A CN200810123958A CN101289601A CN 101289601 A CN101289601 A CN 101289601A CN A2008101239584 A CNA2008101239584 A CN A2008101239584A CN 200810123958 A CN200810123958 A CN 200810123958A CN 101289601 A CN101289601 A CN 101289601A
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Abstract
The invention relates to cation adhesive emulsion, a method for making the same and a use of the same. The adhesive emulsion is generated through the reaction of the following compositions: soft monomer, hard monomer, crosslinking monomer, compound emulsifier of cation and nonionic emulsifier and initiator. When made, a mixed body of the soft monomer, the hard monomer and the crosslinking monomer and an initiator aqueous solution are added in the emulsifier and distilled water to carry out reaction; and the cation adhesive emulsion is made after cooling down and filtration. The aqueous latex not only has a simple making method, but also can be used in textile fabric coating dyeing, textile fabric function finish or the gluing fixative during nano material afterfinish; moreover, the aqueous latex can be used as the film former of an aqueous coating material.
Description
Technical field
The present invention relates to coating and pigment dyeing, be specifically related to a kind of preparation method and purposes of cationic binder.
Background technology
Pigment dyeing is one of anhydrous few water dyeing and finishing technique of advocating for many years, but present employed normal dyeing technology is merely the method for medium with the anion adhesive realizes that coating is to coloration of textile materials, exist that depth is poor, colour fastness is low, open defect such as Boardy Feeling and roll banding tube, restricted applying of pigment dyeing.
On pigment dyeing mechanism, coating does not have avidity to fiber, and coating is by the tackiness agent effect coating to be attached on the fiber to the dyeing of fiber.Conventional tackiness agent is cloudy lotus property.Because most of fibers are electronegative in dye bath, coating is also electronegative, because of electrostatic repulsion, causes coating not firm with combining of fiber, makes the colour fastness of DYED FABRICS not high.If will be distributed in coating comparatively securely equably on the fiber, brushing-on color dispersions need carry out cation-modified through the pre-treatment of special auxiliary agent and fiber, and this has increased the operation of pigment dyeing processing and has increased chemicals usage, has increased tooling cost.
If adopt cation type emulsion to use as the tackiness agent in the pigment dyeing, not only help the absorption of electronegative fiber surface and bonding, improve the colour fastness of pigment dyeing, can also reduce cotton fibre is carried out cation-modified operation, cationic tackiness agent is a kind of very promising function latex, it has good balance quality to positive and negative charge, and effects such as softness, sterilization are arranged.Adopt cationic monomer to prepare the water-soluble cationic polymer powder product among the patent CN1583811, be used for clay stablizer, paper making intensifier etc., but being used for pigment dyeing does not almost have, and the pigment dyeing binding agent (as patent CN101020805) of present lot of documents and patent report is anionic, and the research of introducing cation group is then fewer.Therefore study for the cationic type coating tackiness agent and have realistic meaning and economic outlook.
Summary of the invention
The invention provides a kind of pigment dyeing with cationic adhesive agent emulsion and method for making and purposes, it is characterized in that adhesive agent emulsion adopts the emulsion polymerisation process reaction to generate, not only the preparation method is simple, and does not have APEO, formaldehydeless pollution when the textile printing and dyeing processed and applied.
Tackiness agent provided by the invention is generated by following composition reaction:
(1) cross-linking monomer: 1,3 butylene glycol dimethacrylate, acrylamide etc.; Can be used alone or as a mixture.
(2) soft monomer: butyl acrylate, Isooctyl acrylate monomer, vinylformic acid heptyl ester, vinylformic acid pentyl ester or Ethyl acrylate etc.; Can use or mix use separately.
(3) hard monomer: vinylbenzene, methyl methacrylate or ethyl propenoate etc. can be used alone or as a mixture.
(4) emulsifying agent: the compound of cats product and nonionic emulsifier, cats product are wherein one or more mixture such as dodecyl amine hydrochlorate, cetyl trimethylammonium bromide, distearyl dimethyl ammonium chloride; Described nonionic emulsifier is wherein one or more a mixture such as XL-50 (isomery C10 polyoxyethylenated alcohol), T-07 (isomery C13 polyoxyethylenated alcohol), paregal O, the usage ratio 1～5: 1～5 of cation surface activating and nonionogenic tenside.
(6) initiator: ammonium persulphate or Potassium Persulphate.
The preparation method of cationic tackiness agent water-based emulsion provided by the invention specifically comprises the following steps:
The four-hole boiling flask that reflux condensing tube, agitator, dropping funnel are housed is placed constant temperature water bath, at 70-90 ℃, emulsifying agent is added in the distilled water, stir, drip the mixing liquid of initiator solution and cross-linking monomer, soft monomer, hard monomer by filling a prescription, drip and in 10～150 minutes, finish, reacted 1～5 hour, with the vinegar acid for adjusting pH value is 3～7, is cooled to 60～80 ℃, filters.The median size that makes cationic binder emulsion is about the 60-260 micron.
The weight ratio of the gross weight of wherein said soft monomer and hard monomer, emulsifying agent and water is 26: 1～3: 71～73; The weight ratio of the gross weight of soft monomer and hard monomer, cross-linking monomer, initiator is 1: 0.004～0.08: 0.004～0.009, and the weight ratio of soft monomer and hard monomer is 65～80: 20～35.
Described cationic tackiness agent can carry out pigment dyeing, or is used for finishing functions of textile fabrics, or as in the water-borne coatings prescription, as the membrane-forming agent use of its water-borne coatings.
Advantage of the present invention is: it adopts non-formaldehyde to carry monomer, formaldehydeless pollution.
Utilize this cationic tackiness agent to carry out pigment dyeing, can realize energy-saving and water-saving and dyeing back fabrics feel soft, dried, fastness to wet rubbing all reaches the quality product requirement; This cationic binder water-based emulsion can be used for finishing functions of textile fabrics, can effectively set nano material in nano material arrangement, and the washing fastness of increase nano material.This cationic tackiness agent also can be used as in the water-borne coatings prescription simultaneously, and as the membrane-forming agent use of its water-borne coatings, sticking power is good, and can save the coating consumption.
Embodiment
To help to understand the present invention by following examples, but not limit content of the present invention.Especially the data among the embodiment do not limit the consumption of each composition in the invention.
The preparation of example 1 cationic binder emulsion
Reflux condensing tube will be housed, agitator, the four-hole boiling flask of dropping funnel places constant temperature water bath, add emulsifying agent cetyl trimethylammonium bromide 2.5g, 3g nonionic emulsifying agent XL-50,3g nonionic emulsifying agent paregal O and distilled water 620g, stir, be warming up to 85 ℃, add the 1.8g ammonium persulphate, drip the 132g butyl acrylate, the 70g ethyl propenoate, 0.88g1, mixtures such as 3-butylene glycol dimethacrylate are regulated ph value of emulsion to 3～5, the control rate of addition, the dropping time is 3 hours, drip and add the 0.18g ammonium persulphate, be incubated 1 hour, be warming up to 90 ℃, be incubated 1 hour, be cooled to 60 ℃ and filter discharging.
The preparation of example 2 cationic binder emulsions
Reflux condensing tube will be housed, agitator, the four-hole boiling flask of dropping funnel places constant temperature water bath, add the mixed emulsifying agent 8g of emulsifying agent cetyl trimethylammonium bromide and distearyl dimethyl ammonium chloride, 4g nonionic emulsifying agent T-70,6g nonionic emulsifying agent XL-50 and distilled water 430g, stir, be warming up to 81 ℃, add the 0.6g ammonium persulphate, drip the 124g butyl acrylate then, 31.2g Isooctyl acrylate monomer, vinylbenzene, 12.5g mixtures such as acrylamide, regulate ph value of emulsion to 5～6, the control rate of addition, the dropping time is 4 hours, drip and add the 0.024g ammonium persulphate, be incubated 0.5 hour, be warming up to 90 ℃, be incubated 0.5 hour, be cooled to 65 ℃ and filter discharging.
The preparation of example 3 cationic binder emulsions
Reflux condensing tube will be housed, agitator, the four-hole boiling flask of dropping funnel places constant temperature water bath, add the mixed emulsifying agent 6g of emulsifying agent dodecyl amine hydrochlorate and distearyl dimethyl ammonium chloride, 4g nonionic emulsifying agent T-70,6g nonionic emulsifying agent paregal O and distilled water 420g, stir, be warming up to 85 ℃, add the 1.5g ammonium persulphate, drip the 140g butyl acrylate then, the 81g ethyl propenoate, 10g1, mixtures such as 3-butylene glycol dimethacrylate, regulate ph value of emulsion to 3～5, the control rate of addition, the dropping time is 3 hours, drip and add the 0.07g Potassium Persulphate, be incubated 1 hour, be warming up to 88 ℃, be incubated 1 hour, be cooled to 70 ℃ and filter discharging.
The preparation of example 4 cationic binder emulsions
Reflux condensing tube will be housed, agitator, the four-hole boiling flask of dropping funnel places constant temperature water bath, add emulsifying agent dodecyl amine hydrochlorate, cetyl trimethylammonium bromide mixes emulsifying agent 4g, 2g nonionic emulsifying agent XL-50,3g nonionic emulsifying agent paregal O and distilled water 300g, stir, be warming up to 85 ℃, add the 1.45g ammonium persulphate, drip the 102g butyl acrylate then, the 54g ethyl propenoate, 60g vinylformic acid pentyl ester, 13g 1, mixtures such as 3-butylene glycol dimethacrylate, regulate ph value of emulsion to 6～7, the control rate of addition, the dropping time is 3 hours, drip and add the 0.07g Potassium Persulphate, be incubated 0.5 hour, be warming up to 90 ℃, be incubated 1 hour, be cooled to 60 ℃ and filter discharging.
The purposes of example 5 cation emulsions of the present invention in textile coating dyeing
Fabric: textile ramuscule fabric
Pigment dyeing technique:
Pre-treatment: singe-move back and boil-bleach-mercerising
Dyeing: two soak two roll (liquid carrying rate 70%)-infrared preliminary drying-hot-air seasoning-tentering (130 ℃ * 40s)
Dyeing recipe:
8204 yellow 4.1g/l
8501 yuan of 18.5g/l
8801 brown 3.4g/l
Cationic binder emulsion (preparation in the example 1) 20g/l
Dyeing back colour fastness to washing reaches more than 4 grades, and dried fastness to wet rubbing reaches more than 3 grades, and the fastness index is preferable, and by test, the free content of formaldehyde is zero on the fabric.
The purposes of example 6 cation emulsions of the present invention in the textiles spice finish
Fabric: color cotton fabrics
Technology: adopt and pad mode: pad (two soak two rolls liquid carry over 70%) → dry (90-100 ℃)
The padding liquid prescription:
Lavandula angustifolia fragrant microcapsule 50g/L
Cationic binder emulsion (preparation in the example 4) 30g/L
Color cotton fabric color before and after the arrangement is basic identical, and several no changes of feel, fabric give out pleasant lavandula angustifolia fragrance.
Example 7 application of cation emulsion of the present invention in water-borne coatings
Water-based pigmented coating prescription:
Cationic binder emulsion (preparation in the example 3) 30g
Tinting pigment 9g
Filler pigment (silicon-dioxide) 6g
Silicon 2g
Virahol 4g
Water 49g
Stiffening agent (polyisocyanate aqueous solution of ester) 20g
Total amount 120g
The purposes of example 8 cation emulsions of the present invention in the local dyeing of textile coating (stamp)
Fabric: textile ramuscule fabric
Pigment dyeing technique:
Pre-treatment: singe-move back and boil-bleach-mercerising
Stamp: stamp-oven dry (100-105 ℃ * 2min)-tentering (130-140 ℃ * 3min)
The printing paste prescription:
8111 bright red 5%
Huang 1% in 8220
Thickening agent PTF 1.8%
Cationic binder emulsion (preparation in the example 2) 25%
Urea 0.5%
Colour fastness to washing reaches more than 3 grades behind the stamp, and dried fastness to wet rubbing reaches more than 3 grades, and the fastness index is preferable, and by test, the free content of formaldehyde is zero on the fabric, no APEO.
Claims (5)
1, a kind of cationic binder emulsion is characterized in that, described emulsion is generated by following composition reaction:
(1) cross-linking monomer: 1,3 butylene glycol dimethacrylate, acrylamide; Be used alone or as a mixture;
(2) soft monomer: butyl acrylate, Isooctyl acrylate monomer, vinylformic acid heptyl ester, vinylformic acid pentyl ester or hexyl acrylate; Use separately or the mixing use;
(3) hard monomer: vinylbenzene, methyl methacrylate or ethyl propenoate are used alone or as a mixture;
(4) emulsifying agent: the compound of cats product and nonionic emulsifier, cats product are wherein one or more mixture such as dodecyl amine hydrochlorate, cetyl trimethylammonium bromide, distearyl dimethyl ammonium chloride; Described nonionic emulsifier is that XL-50 is that isomery C10 polyoxyethylenated alcohol, T-07 are wherein one or more mixture such as isomery C13 polyoxyethylenated alcohol, paregal O, the usage ratio 1～5: 1～5 of cation surface activating and nonionogenic tenside;
(6) initiator: ammonium persulphate or Potassium Persulphate.
2, according to the preparation method of the described cationic binder emulsion of claim 1, its feature comprises the following steps:
At 70-90 ℃, emulsifying agent is added in the distilled water, stir, drip the mixing liquid of initiator solution and cross-linking monomer, soft monomer, hard monomer by filling a prescription, drip and in 10～150 minutes, finish, reacted 1～5 hour, with the vinegar acid for adjusting pH value is 3～7, is cooled to 60～80 ℃, filters; The weight ratio of the gross weight of described soft monomer and hard monomer, emulsifying agent and water is 26: 1～3: 71～73; The weight ratio of the gross weight of soft monomer and hard monomer, cross-linking monomer, initiator is 1: 0.004～0.08: 0.004～0.009, and the weight ratio of soft monomer and hard monomer is 65～80: 20～35.
3,, it is characterized in that being used for textile coating dyeing according to the application of the described cationic binder emulsion of claim 1.
4, according to the application of the described cationic binder emulsion of claim 1, it is characterized in that being used for finishing functions of textile fabrics, also can be used for the bonding fixing agent of putting in order after the nano material.
5,, it is characterized in that membrane-forming agent as water-borne coatings according to the application of the described cationic binder emulsion of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2008101239584A CN101289601B (en) | 2008-05-30 | 2008-05-30 | Cationic binder emulsion for coating coloring, preparation method and uses |
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| CN2008101239584A CN101289601B (en) | 2008-05-30 | 2008-05-30 | Cationic binder emulsion for coating coloring, preparation method and uses |
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| CN101289601A true CN101289601A (en) | 2008-10-22 |
| CN101289601B CN101289601B (en) | 2010-09-08 |
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Cited By (17)
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| CN101928367A (en) * | 2010-08-24 | 2010-12-29 | 华南理工大学 | Environmentally-friendly acrylic ester coating printing adhesive emulsion and preparation method |
| CN102212164A (en) * | 2011-05-04 | 2011-10-12 | 合众（佛山）化工有限公司 | Method for preparing long-lasting antibacterial polyacrylate emulsion |
| CN102532399A (en) * | 2011-12-10 | 2012-07-04 | 江阴市尼美达助剂有限公司 | Acrylic acid textile size and preparation method thereof |
| CN102558427A (en) * | 2011-12-20 | 2012-07-11 | 四川大学 | Polymer emulsion for water-based printing ink and preparation method thereof |
| CN102605649A (en) * | 2012-03-15 | 2012-07-25 | 常州大学 | Pigment dyeing method of denim yarn |
| CN103790041A (en) * | 2013-11-11 | 2014-05-14 | 山东岱银纺织集团股份有限公司 | Method for dyeing short-process environment-friendly coating padding jean fabric |
| CN105885740A (en) * | 2016-03-31 | 2016-08-24 | 常州大学 | Cationic binder for denim paint dyeing |
| CN106223073A (en) * | 2016-08-12 | 2016-12-14 | 青岛大学 | A kind of one-bath one-step dyeing colouring method of polyester/cotton blended fabric |
| CN107059437A (en) * | 2016-12-28 | 2017-08-18 | 无为竟成服饰有限公司 | A kind of coating dyeing method with temperature adjustment function fabric |
| CN108301235A (en) * | 2018-02-05 | 2018-07-20 | 广东德美精细化工集团股份有限公司 | A kind of resistance to washing and dry burning crock fastness elevator and preparation method thereof |
| CN108396572A (en) * | 2018-02-06 | 2018-08-14 | 南通大学 | A kind of print weaving process of pure cotton fabric low temperature coating |
| CN108486909A (en) * | 2018-02-06 | 2018-09-04 | 南通大学 | One kind is yarn beam printed to exempt from starching method for weaving |
| CN108486908A (en) * | 2018-02-06 | 2018-09-04 | 南通大学 | A kind of sodolin low temperature coating print-slurry prints weaving process in combination |
| CN108822248A (en) * | 2018-06-20 | 2018-11-16 | 邢台职业技术学院 | A kind of pigment dyeing cationic binder emulsion and its preparation method and application |
| CN109403089A (en) * | 2018-10-15 | 2019-03-01 | 安阳师范学院 | A kind of coating dye printing Environment-friendlyadhesive adhesive and its preparation method and application |
| CN111909631A (en) * | 2020-08-24 | 2020-11-10 | 临沂天勤塑业有限公司 | Bactericidal emulsion pressure-sensitive adhesive, dust-sticking pad and preparation method thereof |
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2008
- 2008-05-30 CN CN2008101239584A patent/CN101289601B/en active Active
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| CN101928367A (en) * | 2010-08-24 | 2010-12-29 | 华南理工大学 | Environmentally-friendly acrylic ester coating printing adhesive emulsion and preparation method |
| CN101928367B (en) * | 2010-08-24 | 2012-06-20 | 华南理工大学 | Environmentally-friendly acrylic ester coating printing adhesive emulsion and preparation method |
| CN102212164A (en) * | 2011-05-04 | 2011-10-12 | 合众（佛山）化工有限公司 | Method for preparing long-lasting antibacterial polyacrylate emulsion |
| CN102532399A (en) * | 2011-12-10 | 2012-07-04 | 江阴市尼美达助剂有限公司 | Acrylic acid textile size and preparation method thereof |
| CN102558427B (en) * | 2011-12-20 | 2013-09-25 | 四川大学 | Polymer emulsion for water-based printing ink and preparation method thereof |
| CN102558427A (en) * | 2011-12-20 | 2012-07-11 | 四川大学 | Polymer emulsion for water-based printing ink and preparation method thereof |
| CN102605649A (en) * | 2012-03-15 | 2012-07-25 | 常州大学 | Pigment dyeing method of denim yarn |
| CN103790041A (en) * | 2013-11-11 | 2014-05-14 | 山东岱银纺织集团股份有限公司 | Method for dyeing short-process environment-friendly coating padding jean fabric |
| CN105885740B (en) * | 2016-03-31 | 2018-12-07 | 常州大学 | A kind of cowboy's pigment dyeing cationic binder |
| CN105885740A (en) * | 2016-03-31 | 2016-08-24 | 常州大学 | Cationic binder for denim paint dyeing |
| CN106223073A (en) * | 2016-08-12 | 2016-12-14 | 青岛大学 | A kind of one-bath one-step dyeing colouring method of polyester/cotton blended fabric |
| CN107059437A (en) * | 2016-12-28 | 2017-08-18 | 无为竟成服饰有限公司 | A kind of coating dyeing method with temperature adjustment function fabric |
| CN107059437B (en) * | 2016-12-28 | 2020-07-10 | 宣城加特林机械有限公司 | Pigment dyeing method of fabric with temperature adjusting function |
| CN108301235A (en) * | 2018-02-05 | 2018-07-20 | 广东德美精细化工集团股份有限公司 | A kind of resistance to washing and dry burning crock fastness elevator and preparation method thereof |
| CN108396572A (en) * | 2018-02-06 | 2018-08-14 | 南通大学 | A kind of print weaving process of pure cotton fabric low temperature coating |
| CN108486908A (en) * | 2018-02-06 | 2018-09-04 | 南通大学 | A kind of sodolin low temperature coating print-slurry prints weaving process in combination |
| CN108486908B (en) * | 2018-02-06 | 2020-04-17 | 南通大学 | Printing and weaving process of flax fabric low-temperature coating printing-pulp combination |
| CN108486909A (en) * | 2018-02-06 | 2018-09-04 | 南通大学 | One kind is yarn beam printed to exempt from starching method for weaving |
| CN108486909B (en) * | 2018-02-06 | 2020-08-04 | 南通大学 | Warp beam printing sizing-free weaving method |
| CN108822248A (en) * | 2018-06-20 | 2018-11-16 | 邢台职业技术学院 | A kind of pigment dyeing cationic binder emulsion and its preparation method and application |
| CN109403089A (en) * | 2018-10-15 | 2019-03-01 | 安阳师范学院 | A kind of coating dye printing Environment-friendlyadhesive adhesive and its preparation method and application |
| CN111909631A (en) * | 2020-08-24 | 2020-11-10 | 临沂天勤塑业有限公司 | Bactericidal emulsion pressure-sensitive adhesive, dust-sticking pad and preparation method thereof |
| CN111909631B (en) * | 2020-08-24 | 2022-05-13 | 临沂天勤塑业有限公司 | Bactericidal emulsion pressure-sensitive adhesive, dust-sticking pad and preparation method thereof |
| CN115414519A (en) * | 2022-08-22 | 2022-12-02 | 东莞市金保利卫生用品有限公司 | Sanitary towel for relieving cold in uterus and preparation method thereof |
| CN115414519B (en) * | 2022-08-22 | 2024-03-26 | 东莞市金保利卫生用品有限公司 | Sanitary towel for relieving cold in uterus and preparation method thereof |
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Change date: 20150106 Contract record no.: 2012320000414 Assignor after: Liyang Chang Technology Transfer Center Co., Ltd. Assignor before: Jiangsu Polytechnic University |
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| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model |