CN105884502A - Fertilizer-pesticide double-effect double-chelated multi-element multi-functional medical stone liquid fertilizer and preparation method thereof - Google Patents

Abstract

The invention discloses a fertilizer-pesticide double-effect double-chelated multi-element multi-functional medical stone liquid fertilizer and a preparation method thereof. The liquid fertilizer is prepared by compounding and mixing raw powder of medical stones, soluble silicon, limestone, compound amino acid, ammonium phosphate, urea, potassium oxide, magnesium sulfate, ferrous sulfate, manganese sulfate, copper sulfate, boracic acid, zinc sulfate, ammonium molybdate, selenium powder, poly(potassium aspartate) and the like, a botanical pesticide composition agent prepared from ricin, veratrine, herba asari volatile oil, rotenone, clausena dunniana essential oil, coptis chinensis alkaloid and glycyrrhizic acid, an amino-oligosaccharin bacteriostatic agent, gibberellin, alum, DA-6, EDTA, hydrochloric acid, ethyl alcohol and the like. The preparation method of the liquid fertilizer comprises the steps that the raw materials are mixed and compounded to generate a hot-melting reaction with aqueous diluted hydrochloric acid, the materials and urea are added with water, mixed dissolving is conducted by increasing the temperature to 100 DEG C, then the reactants and the botanical pesticide composition agent are diluted, mixed, compounded and foamed to be mixed with synergistic liquid, the materials are heated until the temperature is 80 DEG C to 120 DEG C and dissolved and mixed, solid-liquid separation is conducted to remove residues, the obtained liquid is delivered into the reaction kettle to be subjected to secondary chelation with EDTA and DA-6, and then the high-concentration suspension type liquid fertilizer is prepared in a mixed mode.

Description

Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer and preparation method thereof

Technical field

The present invention relates to a kind of agricultural fertilizer, particularly to a kind of Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer And preparation method thereof.

Background technology

At present, in China's agricultural production plantation, generally there is fertilizer variety and nutrient simple in construction, element proportioning is not Comprehensively, fertilizer is uneven, and applying fertilizer technology is the most extensive, fertilizer efficiency utilization rate is low, chemical fertilizer takes off on field is used mutually with pesticide Joint, agricultural material product almost without fertile medicine one, field management cost is high, and effect is low, fertile medicine residual is big, soil compaction, Environmental pollution is serious, feeder capability declines, planting cost rises year by year, and agricultural output and quality decline the most year by year, single Solid fertilizer product and simple foliage fertilizer cannot meet the needs of increasing both production and income on China's agricultural planting.Just for more than These are badly in need of solving to need by a fertile difficult problem and agricultural development, make up the defect that China's present fertilizer and pesticide product disconnects on using mutually And deficiency.On the basis of practice, and special creativity and innovation this to save chemical fertilizer pesticide dosage, function complete, nutrient is complete Face, fertilizer equalize, integrate Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer product of fertilizer efficiency drug effect.

Summary of the invention

Present invention aim to solve chronic administration common N P and K solid fertilizer injustice on China's agricultural planting produces at present The various drawbacks that fertilising of weighing is brought and the problem increasing income difficulty, and a kind of nutrient specializing in invention is comprehensive, fertilizer equalizes, Fertile medicine one, reaches the residual fertilizer in activating soil, improves chemical fertilizer utilization ratio, and solidification utilizes nitrogen in air, bionomic control disease pest Evil, improves crops anti-adversity ability, saves planting cost, improves Crop yield and quality, and that increases farmers' income is multi-functional green Colour circle protects dynamical double-effect manure product, promotes improving rapidly and upgrading of China's agricultural production plantation level.Maifanitum Fertile medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer is exactly the fluidization of solid fertilizer, and its technical characterstic is exactly product function Completely, performance efficiency safety, produce low-carbon environment-friendly, use low cost, product harmless and fertile drug effect fruit and volume increase are substantially.It produces The ultra concentration of product nutrient, Releasing nutrient are strong, instant effect, fertilizer efficiency utilization rate medicine high, fertile economic benefits and social benefits dynamic complex one, both Having prevented and treated the physiological disturbance caused due to nutrient deficiency disease, broad spectrum activity ground has effectively prevented and treated hundreds of evils in infringement crops again Worm and pathogenic bacteria, organically merged the plant growing defencive function of fertile medicine economic benefits and social benefits, significantly reduced pesticide residues, dissolved change The harm of fertile heavy metal ion, crops good absorbing effect, root, stem and leaf growing way are prominent, can be greatly enhanced crops to various nutrients Cycling and reutilization level, agricultural output is high, and quality better is entirely capable of reaching green food standard, and it not only complies fully with me The exploitation of state's fertilizer industry policy requires and the developing direction of high-tech fertilizer product, is also the development trend of world fertilizer industry.

For realizing the purpose of the present invention, the fertile medicine economic benefits and social benefits Mobyneb high-tech liquid fertilizer producing green high-efficient energy-conserving and environment-protective produces Product, this invention product concrete raw material composition and percentage by weight as follows: medical stone powder 7%-13%, solubility silica flour 5%-10%, Agstone 7%-13%, aminoacids complex former powder 7%-15%, ammonium phosphate 4%-8%, carbamide powder 7%-12, potassium oxide 4%-8%, Magnesium sulfate 3%-7%, ferrous oxide 1%-2%, manganese sulfate 1%-2%, copper sulfate 1%-2%, boric acid 1%-2%, zinc sulfate 1%-2%, Ammonium molybdate 0.15%-0.3%, selenium powder 1%-2%, poly-aspartic-acid potassium 0.5%-1.5%；Botanical pesticide combination agent 4%-8%, Amino-oligosaccharide antibacterial 3%-8%, gibberellins 3%-5%, Alumen 0.5%-1%；DA-61%-1.5%, EDTA1%-1.5%； Hydrochloric acid 2%-3%, ethanol 2%-3%.Wherein said botanical pesticide component raw material formula composition and percentage by weight are as follows: Semen Ricini Toxin 0.5%-1%, jervine 0.5%-1%, Herba Asari volatile oil 0.5%-1%, rotenone 0.5%-1%, Clausena dunniana quintessence oil 0.5%-1%, Rhizoma Coptidis alkaloid 0.5%-1%, glycyrrhizic acid 1%-2%.

The high-tech liquid fertilizer product of the environmental type modern agriculture of fertile medicine that the present invention produces one, be by medical stone powder, The former powder of solubility silica flour, agstone, aminoacids complex, ammonium phosphate, carbamide powder, potassium oxide powder, sulphuric acid magnesium powder, sulphuric acid are sub- Ferrum, manganese sulfate, copper sulfate, boric acid, zinc sulfate, ammonium molybdate, selenium powder, poly-aspartic-acid potassium；Botanical pesticide combination agent (Ricin, jervine, Herba Asari volatile oil, rotenone, Clausena dunniana quintessence oil, Rhizoma Coptidis alkaloid, glycyrrhizic acid), amino are few Sugar element antibacterial, gibberellins, Alumen；DA-6、EDTA；Hydrochloric acid, the material such as ethanol, through multiple tracks composite synthesis production technology Assemble a kind of Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer being blended.Its manufacture method is first by wheat After the mixing of meal stone powder, solubility silica flour, agstone, aminoacids complex former powder, incoming steam fuses in tank, and presses the dilute salt of water The ratio of sour and above material 3: 1 adds water dilute hydrochloric acid, is warmed to 180--320 degree and carries out hot melt reaction, passes after reacting 3 hours Going out in holding vessel stand-by, chelating generates calcium metasilicate ispol, is compounded with effective silicon of chelating amino acids state, calcium unit Element；Again by incoming for carbamide powder Heat of Hydrolysis bath, in the ratio water filling of water and carbamide powder 10: 1, it is warmed to 100 degree, dissolves 2 After hour, make nitridation liquid；When nitrogenize temperature of liquid be down to 2-30 spend time, pass and be placed in hydrolysis tank, and simultaneously by phosphorus Acid ammonium, potassium oxide, magnesium sulfate, ferrous sulfate, manganese sulfate, copper sulfate, boric acid, zinc sulfate, ammonium molybdate, selenium powder and poly-sky After the materials such as aspartic acid configure mixing in proportion, pass and be placed in hydrolysis tank, be then warmed to 80-150 degree, dissolve 3 After hour fluidization, make nutrient potentiation liquid, when nutrient synergy liquid temperature be down to 50-70 spend time, incoming mixing In dissolving tank；By botanical pesticide combination agent (Ricin, jervine, Herba Asari volatile oil, rotenone, Clausena dunniana quintessence oil, Rhizoma Coptidis alkaloid, glycyrrhizic acid) and the ratio of the material such as amino-oligosaccharide antibacterial, gibberellins, Alumen and alcohol-water solution 1: 3 exist Mixed liquid tank dilution mixture, is warmed to 75 DEG C of steep raising 3 hours；Incoming next mixing after when admixing medical solutions thing steep raising 3 is little In dissolving tank, mixing with nutrient synergy liquid, heating-up temperature soaks dissolving and nutrient drug effect between 80-120 DEG C, and to merge 2 little Time, mixture generates fertile medicine mixture；After 2 hours, will be to spread manure medicine mixture liquid and calcium metasilicate ispol liquid simultaneously Solid-liquid separation is carried out in incoming solid-liquid separation sieve, through filter and remove residue, by incoming for both lysates reactor, the most incoming EDTA With DA-6 mixed liquor, the most in a kettle. secondary chelating, it is blended into the double chelating of high-concentration suspension type Medical stone fertilizer-medicine economic benefits and social benefits polynary Element full-service fluid fertilizer.Through after the assay was approved, metering filling storage on incoming electronics baling press.

Appended drawings is the technological process of production schematic diagram of the manufacture method of the embodiment of the present invention.

Detailed description of the invention

The production operation of product of the present invention is organized and implemented according to the technological process of production that front accompanying drawing illustrates just can produce quality Zhuo More, technological precedence, Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer product of perfect in shape and function.Product of the present invention For liquid fertilizer, different with planting patterns according to on-farm facilities, fertilizing method can be divided into, be watered after dilution directly foliage-spray, Drip irrigation is executed and seed soaking is used.These fertilizing methods are in liquid fertilizer is applied, and agriculture technical staff and application peasant household are well known and grasp. Specifically using, may also be combined with product attribute of the present invention, instructing peasant household according to regulation of fertilizer requirement, feature and the use of different crops Amount requirement, uses description with reference to product usage and dosage of the present invention and uses.

Claims (2)

1. Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer, its product feature is the concrete of this invention product Raw material composition and percentage by weight are as follows: medical stone powder 7%-13%, silica flour 5%-10%, agstone 7%-13%, compound ammonia Base acid former powder 7%-15%, ammonium phosphate 4%-8%, nitrogen powder 7%-12, potassium oxide 4%-8%, magnesium sulfate 3%-7%, titanium dioxide Ferrum 1%-2%, manganese sulfate 1%-2%, copper sulfate 1%-2%, boric acid 1%-2%, zinc sulfate 1%-2%, ammonium molybdate 0.15%-0. 3%, selenium powder 1%-2%, poly-aspartic-acid potassium 0.5%-1.5%；Botanical pesticide combination agent 4%-8%, amino-oligosaccharide is antibacterial Agent 3%-8%, gibberellins 3%-5%, Alumen 0.5%-1%；DA-61%-1.5%, EDTA1%-1.5%；Hydrochloric acid 2%-3%, Ethanol 2%-3%.Wherein said botanical pesticide component raw material formula composition and percentage by weight are as follows: Ricin 0.5%-1%, Jervine 0.5%-1%, Herba Asari volatile oil 0.5%-1%, rotenone 0.5%-1%, Clausena dunniana quintessence oil 0.5%-1%, Rhizoma Coptidis are raw Alkaloids 0.5%-1%, glycyrrhizic acid 1%-2%.

2. for producing the production work of the Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer described in claim 1 Skill, is characterized in that, including:

First incoming steam after medical stone powder, solubility silica flour, agstone, the mixing of aminoacids complex former powder is fused in tank, And add water dilute hydrochloric acid in the ratio of water dilute hydrochloric acid and above material 3: 1, and it is warmed to 180--320 degree and carries out hot melt reaction, reaction In spreading out of holding vessel after 3 hours stand-by, chelating generate calcium metasilicate ispol, be compounded with having of chelating amino acids state Effect silicon, calcium constituent；

Again by incoming for carbamide powder Heat of Hydrolysis bath, in the ratio water filling of water and carbamide powder 10: 1, it is warmed to 100 degree, dissolves 2 After hour, make nitridation liquid；

When nitrogenize temperature of liquid be down to 2-30 spend time, pass and be placed in hydrolysis tank, and simultaneously by ammonium phosphate, potassium oxide, sulphuric acid The materials such as magnesium, ferrous sulfate, manganese sulfate, copper sulfate, boric acid, zinc sulfate, ammonium molybdate, selenium powder and poly-aspartic-acid potassium are pressed After proportional arrangement mixing, pass and be placed in hydrolysis tank, be then warmed to 80-150 degree, after dissolving 3 hours fluidizations, make Nutrient potentiation liquid, when nutrient synergy liquid temperature be down to 50-70 spend time, in incoming mixed dissolution tank；

By botanical pesticide combination agent (Ricin, jervine, Herba Asari volatile oil, rotenone, Clausena dunniana quintessence oil, Rhizoma Coptidis Alkaloid, glycyrrhizic acid) and the ratio of the material such as amino-oligosaccharide antibacterial, gibberellins, Alumen and alcohol-water solution 1: 3 at mixed liquid Tank dilution mixture, is warmed to 75 DEG C of steep raising 3 hours；

After when admixing medical solutions thing steep raising 3 is little in incoming next mixed dissolution tank, mix with nutrient synergy liquid, heating temperature Degree soaks to dissolve between 80-120 DEG C and merges 2 hours with nutrient drug effect, and mixture generates fertile medicine mixture；

After 2 hours, will be to carry out in spread manure medicine mixture liquid and the most incoming solid-liquid separation sieve of calcium metasilicate ispol liquid Solid-liquid separation, through filter and remove residue, by incoming for both lysates reactor, the most incoming EDTA and DA-6 mixed liquor, so After secondary chelating in a kettle., be blended into high-concentration suspension type Medical stone fertilizer-medicine economic benefits and social benefits double chelating multielement full-service fluid fertilizer. Through after the assay was approved, metering filling storage on incoming electronics baling press.